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By Gurses Oner

In situ leaching is a relatively old mineral extraction method; however, historically only a small portion of copper has been produced from small scale operations. Recently, in situ leaching technology because of its intrinsic advantages over conventional mining and milling is being considered as a viable option for recovering copper from both low grade oxide and sulfide deposits. This paper presents the application of computers to investigate in situ technology using large whole core leaching experiments. Computers were applied to three different areas: (1) experimental control and data acquisition, (2) non-destructive evaluation of samples using x-ray computed tomography and image processing and (3) mathematical modelling and data analysis.

Jan 1, 1992

By W. A. Rickelton

The first commercial use of phosphine derivatives as solvent extraction reagents began in the mid 1970's with the construction of several plants to recover uranium from wet process phosphoric acid. The process eventually adopted by all of these plants used the well known trioctylphosphine oxide (TOPO) in synergic combination with D2EHPA to extract U(6+). This prompted the development of other phosphine - based reagents and led to the discovery of a variety of interesting commercial and potential applications which are summarized in this paper. The applications include cobalt-nickel and niobium-tantalum separation and the selective recovery of silver and zinc.

Jan 1, 1994

By A. W. Laughlin

Laser-Induced Breakdown Spectroscopy or LIBS can be used to provide exploration companies with precise and accurate chemical analyses in the field, in real-time, resulting in major time and cost savings. Using a Field-Portable Analyzer (FPA), anomalies can be followed up immediately while crews are still in the field. Lower limits of detection (LLDs) are element dependent, but many are sufficiently low to be useful in exploration. LLDs in ppm for selected elements of interest are: Be-2, Cu-3, Zn-20, As-200, Sb-500, Pb-30, Ag4, Mo-100, B-33, Ti-500, V-350, and Cr-1. LIBS analyses require little or no sample preparation.

Jan 1, 1999

By J. J. Gusek, T. C. Richmond, R. W. Reisinger

A high-altitude (9,500-ft [2,900-m]) historic underground copper mine in Wyoming discharges neutral but copper-laden water into a pristine creek. Under a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) deferral agreement, the Wyoming Abandoned Mine Land Program performed site characterization and treatment studies in preparation for reclamation of the site. An integral part of the project included addressing the needs of a variety of interested and affected parties, including property owners, local populations, government agencies, and the media. This paper discusses an overall approach and specific methods employed to enlist public support for the project as well as some of the successes and failures experienced.

Jan 1, 2004

By Gordon T. Clark

The preliminary design of four mined stations and 7.2 km (4.5 miles) of tunnels for Seattle’s light rail transit system is described. Constraints that influenced the design and options that were studied are discussed. The hilly post-glacial soft-ground geology of the Puget Sound Region pushed the alignment deep. Mined underground stations at depths up to 75 m (250 ft) and shafts with excavated diameters of 20-m (65-ft) are required. A 460 m (1,500 ft) sub-aqueous crossing of Portage Bay and undercrossing of an active 12-lane multi-level freeway were two of the more significant design constraints.

Jan 1, 2001

By James J. Guesk, Robert W. Reisinger, Timothy C. Richmond

A high-altitude (2,900 m [9,500 ft]) historic underground copper mine in Wyoming is discharging copper-laden water with a neutral pH into an otherwise pristine creek. The Wyoming Abandoned Mine Land program is reclaiming the site under a CERCLA deferral agreement. The clean-up goal is to reduce copper in the mine discharge so that the creek can eventually support a trout fishery. A pilot-scale passive treatment test utilizing sulfate-reducing bacteria has been conducted at the site beginning in summer 1997. Test results show significant reduction in copper concentrations in near-freezing mine water at flow rates ranging to 19 liters per minute (5 gpm)

Jan 1, 2000

By D. W. Tedder

Several bauxite feeds and residue sands and muds, produced by Bayer plants in the US and over-seas, were fractionated using dry and wet magnetic separators. The magnetic sand fractions typically contained about 50 to 60 wt % Fe2O3 and the bulk of the radioactivity in the sands. The muds are more difficult to process, but some fractionation is possible using a combination of classification and magnetic separation techniques. Among the mud samples, higher radiation levels are often associated with the less magnetic fractions. Bauxite is more easily fractionated using dry magnetic separation. Much of the radioactivity in bauxite appears to concentrate in the sand and mud residuals.

Jan 1, 1987

By J. B. Hiskey, V. P. Atluri

Resin-in-leach (RIL) cyanidation experiments were performed on a refractory carbonaceous gold ore. The objective of this investigation was to determine if strong-base ion exchange resins could adsorb the soluble aurocyanide complex in preference to natural "preg robbing" organic constituents. Direct cyanidation of the carbonaceous gold ore used in this study resulted in less than 2% gold extraction in 24 hr. RIL cyanidation resulted in about 70% gold recovery onto the resin. Kinetic experiments indicated that 50% of the gold is extracted after 1 hr of leaching. Resin breakage was investigated for as-received and preattrited resins. Similar results were obtained with three different strong base resins.

Jan 1, 1990

By Stanley R. Riggs

Extensive phosphate resources occur within the Miocene Hawthorn and Pungo River Formations which have not been considered in the past since they were poorly known and were not available to conventional mining. These resources include 1) deep phosphates that occur below 75 meters of overburden within major sediment basins throughout the southeastern coastal plain, and 2) offshore phosphates that occur on the continental shelf and within the U.S. Exclusive Economic Zone (EEZ). The future potential of these two vast resources will be realized with development of new mining technologies such as hydraulic slurry mining and integrated with advanced technolgy already being utilized in the offshore petroleum industry.

Jan 1, 1986

By J. B. Hiskey, X. H. Jiang

The extraction of gold from chloride solutions by ion exchange is examined. It is shown that at initial gold concentrations between 1 - 5 ppm, 20 g/l C1- and pH 5, the kinetics of loading on weak base resins are slightly slower than those observed with activated charcoal. Equilibrium loading of auric chloride varies considerably as a function of pH from one resin to another. For all of the resins studied, nearly complete gold extraction was achieved between pH 2 and pH 6.5. Sodium hypochlorite was found to exhibit a slight effect on the equilibrium loading of gold chloride.

Jan 1, 1990

By S. Michael Feroz, Paul Gribbon, Jan Rosholt

Approximately six billion gallons of combined sewage are discharged annually into Willamette River and Columbia Slough through Portland’s combined sewer system. The Columbia Slough Consolidation Conduit (CSCC) is an important element of mandated Combined Sewer Overflow (CSO) abatement. It includes2,548m (8,361 ft.) of 3.7 m. (12 ft.) internal diameter tunnel. The CSCC alignment traverses the UP railroad, Columbia Boulevard and parallels an old sewer. Geologic conditions include river alluvium and fine to coarse-grained flood deposits containing cobbles and boulders. This paper describes design and construction of a tunnel in soft-ground, with shallow cover and close to an old concrete sewer.

Jan 1, 1999

By I. Iwasaki, H. Dho

The role of sodium silicate in the anionic flotation of a Florida phosphate ore was investigated using laboratory continuous flotation tests, frothabiliry tests and SEM observations. In the absence of sodium silicate, Ca I+ promoted the unwanted activation of quartz by forming calcium bearing precipitates. The addition of sodium silicate enhanced the flotation efficiency through: 1) the removal of impurity minerals and calcium-bearing precipitates from quartz surfaces by dispersion, 2) drier and more persistent froths stabilized by oily droplets containing calcium silicate precipitates, and 3) higher specific flotation rates of phosphate relative to quartz, leading to faster flotation rates and increased selectivity of separation.

Jan 1, 1991

Mill #4 processes mildly refractory ore from Carlin Trend deposits. Diagnostic analysis of plant operating data was used to generate a mathematical model containing the key parameters influencing the gold recovery. The model was used to direct modifications to plant operating practice. The cyanide dosing strategy was changed to reduce preg-rob gold masses and cut reagent consumption A finer grind was achieved without capital investment. The density in CIL was lowered, and tighter control was exercised over plant throughput. These changes resulted in a recovery increase of at least 2%, worth $111,000/month at $300/oz, and concomitant reagent cost savings of $55,000/month.

Jan 1, 1999

By I. S. Parrish, D. W. Kappes, G. G. Austin

Micron-sized gold disseminated in lower Cambrian siltstone has been found at the Sterling mine near Beatty, NV. A shoestring-shaped body has been developed by central and fringe drifts and is being mined via a modified retreat room and pillar system. The siliceous ore crushed to 5.08 cm (2 in ) is stacked to 4.6 m (15 ft) over a layered sand, gravel, and impervious PVC base. Gold is leached using a 0.1% cyanide solution and deposited on activated coconut shell carbon. Stripping of the carbon by hot solutions of 1% NaOH and 20% Ethanol yields overall recovery of about 75% of the fire assay head.

Jan 1, 1983

By W. Douglas Gould, Mei-Lin K. Stichbury, Jeffrey G. Bain, Blowes David W.

The mechanisms of release of arsenic in gold mine tailings were investigated. The highest concentration of dissolved As (75 mg/L) was observed near the base of the tailings impoundment, in close association with a peat layer. Elevated concentrations of reduced iron and hydrogen sulfide were also measured at the base of the impoundment. High numbers of iron-reducing and sulfate-reducing bacteria were detected at depths within the impoundment which correlated with dissolved As, Fe and H2S. The data presented in this paper suggest that arsenic is released from the tailings by bacterially-mediated reductive dissolution of As-bearing iron minerals.

Jan 1, 2000

By Jerry Wang, Greg Bold, Mahmood Khwaja, Rebecca Caldon, William Simcoe

Phase III and Phase IV of the Beaver Creek Clean River Project, Albany, NY, includes microtunnel construction of 2,320 feet of 48-inch/36-inch internal diameter (ID) conveyance pipe and a 525 foot long 9.5-ft horseshoe shape roadheader excavated tunnel. Notable challenges were encountered during the construction including mixed face tunnel conditions, undocumented existing fill ground conditions that resulted in settlement during shaft construction, and unstable tunnel face conditions. This paper discusses several of the key challenges encountered during construction and selected solutions to construction sequencing and methodology to successfully complete Phase III and Phase IV of the Beaver Creek Clean River Project.

Dec 1, 2022

By Allen Pratt, Guy Deschênes, Mike Fulton, Hai Guo

Calaverite is a gold telluride species, with the composition, AuTe2. Calaverite is usually characterized by an exceedingly slow dissolution rate in a cyanide solution. Cyanidation of a slurry containing synthetic calaverite (P90 of 10 microns) was studied to determine the leaching kinetics and surface reactions. Alkalinity, dissolved oxygen, lead nitrate and sulphide minerals (pyrite and chalcopyrite) were among the parameters evaluated. The reaction products at the surface of calaverite were documented using X-ray photoelectron spectroscopy. High lime concentration with lead nitrate and injection of oxygen produced the fastest leaching rates. New gold leaching mechanisms were identified which appeared to be related to the parameters selected.

Jan 1, 2005

By Gu Guohua, Hu Yuehua, Zhang Qin

The flotation behavior of pyrrhotite was investigated by using ethyl xanthate as a collector. Results showed that pyrrhotite had good floatability from pH 2 to pH 11, and poor floatability when pH was >12. The flotation of pyrrhotite was dependent on pulp potential on various pH values. The potential-pH range for pyrrhotite flotation was established. Cyclic voltammeny and FTIR spectroscopic analysis showed that the major adsorption product of ethyl xanthate on pyrrhotite was dixanthogen. The intensity of FTIR signals of dixanthogen adsorption on pyrrhotite and the anode current of a pyrrhotite electrode and flotation response of pyrrhotite are correlated with pulp potentials.

Jan 1, 2005

By J. Engel

The talc deposit in Gemerská Poloma lies 350 to 400 m under the surface; the whole deposit is located at the highest-level drinking-water-source protection zone, therefore, opening in this mining area (a well, a ramp) requires higher investment, operational and water protection costs. The adit, outside the mining area, with a length of 4200 m, rising with a gradient of 3? and a diameter of 10.3 m2, allows free passage/runoff of mining-water through the adit, and guarantees low costs for transporting produced material and equipment. This solution is in total less demanding from both investment and operational point of view.

Jan 1, 2007

By Shulin Xu, Moreno Pescara, Nicola Avagnina, Piergiorgio Grasso

The Roreto Tunnel is a shallow, twin-bore, road tunnel on the connection between the A6 and the A21 motorway in NW Italy. The challenges faced the design and construction of this tunnel derive from 1) the presence of groundwater, both phreatic and artesian; 2) excavation in loose and/or little cohesive materials; 3) excavation in cohesive materials containing water-saturated, sand lenses; and 4) surface constraints due to the urban environment. In this paper, these problems are examined and the rationale led to the optimum design choices and construction solutions explained. The experience should be useful to others when tunneling in similar situations.

Jan 1, 2003