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By Donald L. Gaughenbaugh

Under the terms of the 1970 amendments to the Clean Air Act, the EPA established national ambient air quality standards for a number of pollutants. Sulfur dioxide (SO2) was one of these pollutants. These ambient air quality standards have had perhaps their biggest impact on the power utilities. In an effort to meet the air quality standards set forth by the EPA, utilities using high sulfur fuels have been forced to install flue gas desulfurization (FGD) systems. The majority of FGD systems in operation today are nonregenerable systems, that is the by-product of the system is disposed of, usually into settling ponds. Limestone slurry is the most common reagent used to remove SO from the flue gases. The calcium carbonate (limestone) slurry interacts with the flue gas, absorbing the SO2 and forming a by-product of calcium sulfate/sulfite which is disposed of.

Jan 1, 1986

By Richard I. Grass

The White Pine Mine is located 4- 1 /2 miles south of Lake Superior in the western part of Michigan's Upper Peninsula. The orebody occurs in tabular, gently dipping Keweenawan sediments. GEOLOGY The orebody outcrops beneath 30-50 feet of Pleistocene clays and dips to the east and northeast to a depth of 3, 000 feet in five miles. It lies midway between the Porcupine Mountains and the Bergland Hills, both of which are steeply dipping felsite and coarse porphyry intrusives, extrusives and sediments (Figures 1 and 2). The orebody sediments were deposited in the Keweenawan basin during mid- and upper Keweenawan times. Mineralization occurs in the basal 20 to 25 feet of the Nonesuch formation, which is made up primarily of laminated siltstone s. Native copper, chalcocite, and silver are the ore minerals. The ore is mined by trackless room-and-pillar methods.

Jan 1, 1967

By A. D. Paul, Yoon R. H., C. I. Basilio

Considerable amounts of Fe3+ ions are released into solution when coal is exposed to 1-3 M acid solutions. These ions superficially oxidize the coal surface, and are reduced to Fe2+ ions. When provisions are made to generate the Fe3+ ions in solution, e.g., by inserting an anode whose potential is above the reversible potential for the Fe3+/Fe2+ couple, considerable amounts of mineral matter are liberated from the coal matrix. With many eastern U.S. bituminous coals, this mineral liberation is achieved selectively without significant breakage of the coal. It is believed that this process is induced by the osmotic pressure set-up in the crevices between the mineral matter and coal that are exposed to the solution. A theoretical model predicting the osmotic pressure is presented in this work, along with some results obtained with different coal samples.

Jan 1, 1992

Zirconium chloride is of great commercial importance as starting materials for production of ZrO2, Zirconium metal and other Zirconium compounds from its main resources (Zircon Sands). The present study concerns with preparation of pure ZrO2 from Zircon by direct chlorination technique. Different parameters affecting the chlorination process are studied viz. carbon, chlorine flow rate temperature and time. The chlorination extent is determined from the loss in weight and chemical analysis of reaction products. The maximum chlorination extent -92% are achieved at 1100°C for 30 min. Zirconium oxide is produced from the collected zirconium tetrachloride either by calcination at 900°C or by hydrolysis in water in presence of RCI with a purity = 99%. Evaluations of the products of the process are investigated microscopically and by X-ray diffraction. The apparent activation energy of the chlorination of Zircon is determined to equal 36 kJ/mole.

Jan 1, 1997

By H. L. O. Huyck

A microcomputer equipped with spreadsheet, data management, and FOR- TRAN programming software is used to update and quantify a model for ranking seventeen economically important metal commodities in terms of market potential (Huyck, 1982). Weighted factors are used for the ranking: (1) demand growth trends, (2) end-use substitution vulnerability, (3) recycling trends, (4) price trends, and (5) cumulative demand versus world reserves factor. Price trends are defined using (1) price-vs.-year slopes (with prices in 1967 constant dollars) and (2) standard deviations of slopes (to indicate price volatility). Substitution vulnerability is defined as the percent of end-use which is replace- able by other commodities, and a factor indicating the likelihood of such substitution. Factors are normalized and linearly combined to produce a ranking of the seventeen metals. Microcomputer software is essential for organizing data and calculating statistical parameters and linear combinations of factors.

Jan 1, 1986

By Richard D. Doepker, Cathy A. Summers

Part 1: Physical Characteristics The physical and mineralogical characteristics of samples from five sources in the Western United States were determined using size analyses, microscopic studies, and point counts. These results were combined with leachability assays and the chemistry of leachates obtained during slurry tests to predict sample dissolution characteristics during column leaching tests. Part 2: Dissolution Characteristics Two columns of each sample were leached over a period of 3 years with synthetic rain. Residence times were between 2 and 11 weeks. The samples were subjected to daily and seasonal temperature fluctuations and wet-dry and freeze-thaw cycles. During the latter part of this study, a biocide leachant (sodium benzoate) was substituted for synthetic rain to assess the degree of dissolution caused by biological oxidation. It was found that the presence or absence of barite or carbonate minerals can be used to predict the leaching behavior of the column material.

Jan 1, 1995

By Robert M. St. Louis, Janet M. Edgecombe

The Mercur Mine's autoclave is an alkaline pressure oxidation system, operating at 220°(428°F) and 3061 kPa (444 psig) (total). Up to 725 metric tons (800 st) of ore, grading 2.02 g per mt (0.059 oz/st) Au and containing 1 to 2% sulfide sulfur, are treated daily in this circuit. A mineralogical and chemical investigation was initiated to locate the cause of lower than anticipated gold recoveries. Greater than 70 wt. % of reduced sulfur is oxidized; therefore, the autoclave is operating at specification. The low recoveries were attributed to increased concentrations of organic carbon in refractory ore. Activated carbon concentration in the attached CIL circuit was increased from 15 to 40 g per 1, leach temperature held below 21°C (70°F), and carbon flow changed to counterflow. These measures resulted in gold recovery improving from 75 to 82%.

Jan 1, 1990

By Gill G. Geesey, Michael R. Hankins, Paul L. Wichlacz, Anita Gianotto, John G. Jolley, Randy B. Wright

Thin films of copper [2.0 nm on germanium internal reflection elements (IREs) and 3.4 nm on germanium discs] were exposed to 10% gum arabic (aqueous solution) , 2% alginic acid (aqueous solution), 1% bacterial culture supernatant (BCS, simulated seawater solution) and 0.5% Pseudomonas atlantica exopolymer (simulated seawater solution). The IRES were monitored in situ, in real time using fourier transform infrared/cylindrical internal reflection/attenuated total reflection spectroscopy as a function of time at ambient conditions. The discs were characterized (pre- and post-exposure) by X-ray photoelectron and Auger electron spectroscopies. Ancillary graphite furnace atomic absorption spectroscopy was used to monitor the removal process of the copper thin film from the germanium substrates. Results indicate that Cu was oxidized by gum arabic, alginic acid and BCS. Furthermore, Cu was removed from the Cu/Ge interface by all four polymers. The Cu was found associated with the polymer solutions.

Jan 1, 1989

By N. A. Frazier

The technology for using limestone or lime to scrub SO2 from power-plant flue gas has significant implications to the limestone industry. A brief status report on these processes will be made, possible process requirements on the limestone properties will be reviewed, and projections on the buildup of demand with respect to time will be reviewed. Disposal problems inherent with the use of these throwaway processes will also be summarized. Given a viable technology, relations among (1) distance of power plants from low- and high-sulfur coal and limestone deposits, (2) modes of handling and transporting immense tonnages of bulk material-coal and/or limestone, and (3) regional air-quality standards are some of the factors which will ultimately determine the demand for limestone. A discussion of these factors will be presented, with the intent of identifying geographic regions where significant increases in production can reasonably be expected.

Jan 1, 1974

By John Chapman, Daryl Hockley, Michael Paul, Silvia Jahn

As part of the waste characterisation program to address site reclamation, WISMUT GmbH initiated 56 columns operated as large-scale humidity cell tests. The columns were initiated to assess the acid generation characteristics of waste rock from 14 waste rock piles distributed around the site. Of the 56 tests, 11 are ongoing and have been operational in excess of 160 weeks. The results to date from these long-term tests are surnrnarised. In particular, the methods for, and importance of, establishing the availability of the carbonate neutralisation potential and acid generation potential respectively, are discussed. Geochemical controls on uranium, and the conformity between the geochemical models MINTEQA2 and EQ3/6 in assessing these controls are discussed. Testing indicates that waste rock with an MS-NP:AP ratio in excess of about 2.7 should result in net neutral pH conditions.

Jan 1, 2000

By A. D. Davis, G. A. Zabolotney

A ground-water flow model was developed to simulate the postmining recharge rate from precipitation at the Belle Ayr surface coal mine, which is located in the Powder River Basin near Gillette, WY Wyoming state regulations require that reclaimed lands should provide a rate of recharge that approximates the premining rate. Steady-state calibration and transient simulations showed that the postmining recharge rate through spoil is at least 50 mm (2 in.) per year, exceeding the original infiltration rate of 4 mm (0.16 in.) per year to shallow overburden aquifers. Major reasons for the increase include the flat topography of the reclaimed areas and the decreased spoil density. It is expected that the backfill will disaggregate and settle over time, eventually resulting in a nearly constant recharge rate that is less than 50 mm (2 in.) per year but still somewhat greater than the premining rate.

Jan 1, 1997

By Donald P. Richards, David W. Campo, Michel Coudry

This paper presents a review of the grouting works of Line 2 of the Greater Cairo MetroSystem. The Nile River alluvial deposits underlying this ancient city provided for a challenging and sometimes difficult grouting project. Permeation grouting using state-of-the-art computerized grouting techniques, as well as extensive ground treatment by jet grout, was per-formed for soil consolidation and/or groundwater control. During the project, over 425,000m3 of ground was treated, requiring 1.4 million linear meters of drilling and PVC injection pipe, 54,000 m3 of bentonite cement and 230,000 m3 of chemical and mineral grout. In addition, over 70,000 m3 of ground was treated using the jet grout method. Relative to major international transportation projects, the grouting works for Line 2 of the Cairo Metro represent one of the largest worldwide grouting endeavors to date.

Jan 1, 1997

By D. P. Patil, T. C. Rao, J. P. Barnwal

Factorial design of column flotation experiments was used to understand the main and interactional effects of the column parameters. In the experiments, the air flog rate, the wash-water, flow rate and the froth depth were varied at two levels. Analysis of the results showed that an increase in airflow rate had a deleterious effect on the grade of the concentrate, whereas, an increase in froth height increased the grade. The interactions between airflow and wash water and between airflow and froth height were significant with respect to grade of the concentrate. These results demonstrated that, from an ore containing 12.76% P2O5, it is possible in a single-stage flotation column to obtain a concentrate containing 31 % P2O5 (10.6% Si02) with a recovery of 94%, thus reducing the number of cleaning stages that would be required if conventional flotation cells were used.

Jan 1, 1997

By Gary N. Greenfield

This morning, gentlemen, I should like to discuss resin anchors of a type introduced to North America approximately 2-1/2 years ago. We shall also briefly review the basics of mechanically anchored rockbolts so that a general comparison may be made. Previous efforts with synthetic resins were aimed at aiding a mechanical Or "point" anchor, obtain a better purchase in the rock mass. Resin cartridges of the type to be described in this paper are capable of achieving point anchorage or full encapsulation of mine roof or rockbolts. Of significance, therefore, is that unlike a mechanical bolt, placed and tensioned, celtite rockbolts may be fully grouted and tensioned or left untensioned in the installation sequence. Our principle effort has been to offer this system to mining and civil engineers who have encountered difficult rock conditions and wish to reinforce strata to achieve a greater degree of permanence and safety.

Jan 1, 1972

By D. D. Harbuck, G. K. Green

The Bokan Mountain area on Prince of Wales Island, AK, contains vast quantities of heavy rare earth minerals. To lessen the US dependence on foreign sources, the US Bureau of Mines (USBM) investigated yttrium recovery from this ore. By sulfating the ore at 250 ° C for 1 hr at an H2S04:ore ratio of 1:1 and then water leaching the sulfated material for 1 hr at 20% solids and 25ºC, over 74% of the yttrium, cerium, and lanthanum were solubilized. Solvent extraction (SX), using a synergistic combination of OPAP and DEHPA, selectively loaded 100% of the yttrium. Yttrium was stripped directly as a solid using a 2M, 35 ° C NaOH liquor. When the OPAP/DEHPA mixture was tested in a continuous SX circuit, yttrium loading and stripping were 100% and 96%, respectively. The organic showed excellent recyclability properties with minimal solvent loss.

Jan 1, 1996

By T. N. Moore, E. M. De Souza

J. Dasher Regarding the March 1991 ME technical paper by De Souza and Moore: For more than a decade since my February 1981 article on how to use modern metric, which SME-AIME had decided to do, I have monthly pointed out metric errors to the editors. In part, I do this because there has been no action to allow editors to fix figures and tables or to allow them to require authors to do so. The latest resulting atrocity provokes this discussion of vibrating drill handle units being stated in decibels. Reply by T. Moore We have read the discussion of our paper by Mr. Dasher. Our reaction is one of surprise and incredulity. It would seem that Mr. Dasher takes exception to the use of the decibel scale to present vibration acceleration data, and the use of hertz as the unit for frequency. The basis for his objection to the decibel appears to be that it has no dimensions (which somehow invalidates its use), that it is "non-metric" and, finally, that it is parochial (of limited or narrow scope). His objection to the use of the term hertz is not stated, but we will assume that it stands condemned as "non-metric" and parochial. Obviously we disagree with Mr. Dasher's views and will now outline our reasons. Although the decibel scale originates from transmission line theory and telephone engineering, it is also at present widely used, not only in the fields of electronic engineering and acoustics, but also in the area of vibration. The original definition of the decibel (dB) was based on power ratios: dB = 10 log 10(W/W0) where Wo is a reference power. However, as the power measured across a given impedance is related to the square of the force acting upon this impedance, Z, a more commonly used definition is: [2 dB = 10 logF /Z) = 20 log F/F 10\ F0 2 /Z(0)] where F and F0 are the r.m.s. values of the forces. Now, if the measurements are related to one and the same impedance, the decibel notation in the form of 20log10(X/Xo) may be used as a convenient relative magnitude scale for a variety of quantities. Thus, X may, for instance, be an r.m.s. displacement, velocity or acceleration. It is only required that XD always be a reference quantity of the same type as X. That is, when X represents an acceleration, then X0 represents a reference acceleration. This is the formulation used in our paper. This was not an arbitrary choice on our behalf but reflects standard practice as specified in the International Standard ISO 5349-1986(E) Mechanical Vibration - Guidelines for the Measurement and the Assessment of Human Despite the metric prefix, the decibel is a parochial expression of (l) the logarithmic ratio of the loudness of a sound to what is normally audible or (2) the logarithmic ratio of two power signals in radio or electronics. A decibel is not a unit, much less an SI, unit and has nothing whatsoever to do with the acceleration of drill handles. Stating that m/s2 (acceleration) is decibels is without reason. Whoever reviewed this material should not have allowed publication of figures of dB and H.[ ] Exposure to Hand-Transmitted Vibration. This was clearly stated in the "measurement protocol" section of our paper. This quantity is then referred to as the acceleration level and is expressed in dB. We may have inadvertently caused some confusion when we simply used the term acceleration to refer to acceleration level on our diagrams. At the time, we felt the use of dB or m/s2 would make the context clear to the reader. For any confusion this decision may have engendered, we apologize. Since the decibel expresses the ratio of two like quantities, it certainly has no dimensions. It is, however, common practice to treat "decibel" as a unit as, for example, in the sentence, "The acceleration level measured at the operator's hand was 160 dB." The expression of measured quantities in dimensionless form is not inherently unacceptable. In fact, in many areas of engineering it is standard practice (consider the use of Reynolds Number, Nusselt Number, etc.). The fact that the decibel is a dimensionless quantity makes the question of whether it is a SI unit nonsensical. However, it is valid to insist that the dimensional quantities used to obtain the decibel values be expressed in SI units. A careful reading of our paper will make it clear that the measured acceleration was, in fact, expressed in units of m/s2 as was the reference acceleration (l x 10-6 m/S2). These are the accepted derived SI units for acceleration. See, for example, the standard ASTM E380-89a Standard Practice for Use of the International System of Units (SI) (The Modernized Metric System). Concerning Mr. Dasher's implication that hertz (Hz) is an unacceptable unit of measure for frequency, we would again refer him to the standard ASTM E380-89a. Here, he will find (section 2.4.2) that hertz is an accepted "special name" for the derived SI units-1. This is in keeping with numerous other international standards including ISO 5349-1986(E) to which we referred in our paper. In conclusion, we agree with Mr. Dasher on the desirability of expressing measurements in modern SI units. But we would remind him that the standards that define the use of these units, and the accepted means of presenting measured data, are in a continual state of refinement. It is, therefore, incumbent upon him to keep abreast of these changes if he wishes to constructively critique the work of others.[ ]

Jan 1, 1992

By M. J. Zdunczyk

Sand is one of the most common materials on the earth’s surface. It is a naturally occurring material resulting from the physical and chemical breakdown of rocks. The definition of sand varies, as do the number of products made from the material. Sand is generally classified by grain size, however the measurement or scales differ depending on the context in which it is being used. Geologist define sand as particles of rock between .05 and 2 millimeters in diameter. The variability of the mineral composition generally dictates which sand can be used for different industrial purposes. For example, sand used for Portland cement concrete and asphaltic concrete mixtures can be very different in physical and chemical composition than sand used in the making of fiberglass. In this paper, construction uses of silica sand, which consists almost entirely of the mineral quartz (SiO2), will be discussed and analyzed.

Jan 1, 2001

By R. Stanevich

Studies by the National Institute for Occupational Safety and Health (NIOSH) and the Bureau of Mines (BOM) have demonstrated that: (1) 90% of diesel particulate is less than one (1) micrometer in aerodynamic diameter; (2) more than 90% of the respirable mass in electric coal mines was greater than one (1) micrometer in aerodynamic diameter; and (3) in coal mines using diesel equipment, average diesel concentrations can represent up to 53% of the MRE respirable coal dust standard. For mines approaching the 2 mg/m3 standard, compliance may be easier to attain by controls directed at diesel exhaust particulate as opposed to coal dust control. First, however, a Simple instrument is needed to measure diesel exhaust particulate concentrations. This paper describes such a sampler, its construction, and use. While results from this sampler are primarily utilized to identify control areas, NIOSH is also using the sampler for estimating worker exposures in epidemiologic studies.

Jan 1, 1988

By Walter R. Lawrence

Newmont Gold Company, formerly Carlin Gold Mining Company, is a publicly owned corporation, 95% owned by Newmont Mining Corporation. Newmont Gold Company has operated gold recovery operations North of Carlin, Nevada, since 1965. Development of the Gold Quarry ore body, 19 kilometers south of the original mine, resulted in the decision to construct gold recovery and ancillary facilities in what is referred to as the Southern Area. Plant No. 2, located 11 kilometers North of Carlin, Nevada, was designed to treat 6350 tonnes per day of oxidized gold bearing ore assaying 2.5 grams per tonne of Au at an average recovery of 87%. Flowsheet development conducted by Newmont personnel resulted in the decision to construct a carbon-in-pulp recovery circuit preceded by two-stage grinding, Detailed engineering was done at Toronto by Bechtel of Canada beginning on January 1, 1984. Actual construction began on March 1, 1984, and was completed in June, 1985. First feed was run on June 22, 1985.

Jan 1, 1987

By G. Kemp Williams, Peter H. Dohms, Barry A. Hillman, Laurie A. Williams

Introduction In 1969, the US devalued the dollar. This action, over the ensuing four years, resulted in the deregulation of the price of gold. It also resulted in the rebirth of the US gold mining industry. The extreme inflation of the 1970s led to a dramatic increase in the price of precious metals. Consequently an increased interest in the exploration for and mining of gold has occurred. The enthusiasm began among the few existing producers who had survived on marginal profits during a prolonged period of fixed prices and constantly rising costs. Then came the newcomers. They saw the opportunity to enter an industry that historically had been characterized by small operations with low capital costs. It was not until the late 1970s that large mining companies recognized that investment in gold projects could generate cash flows that previously were associated only with world class deposits. Today, gold mining has tremendous appeal for the entire mining community, despite the dramatic price drop from 1980-81 levels. There are even major firms with no mining experience attempting to gain a foothold. But how easy is it to enter the US gold mining industry? What are the basic factors that influence the economics, and what are they likely to be for the remainder of the decade? How has the industry changed, and what is the composition of the active companies? An examination of the industry will help to answer these questions. US Gold Mining History The current gold rush is actually the fifth in the 208-year history of the US. The first recorded commercial mining of gold occurred in the Southeast in 1799. It produced from small, yet relatively rich placer deposits. The famous California gold rush of 1848 placed the US as a major producer with 62.2 t (2 million oz) of output by 1850. More than 93.3 t (3 million oz) was mined by 1853, equivalent to 63% of world production. But the richest placers were soon depleted. By the end of the Civil War, annual production had declined to well below 62.2 t (2 million oz). The government then relaxed prices and the industry again began to recover. The 1870-80s saw the great mines of the California Mother Lode and Grass Valley brought into production. This was followed by development of Nevada's Comstock, which later became one of the world's largest producers. Discovery of gold at Cripple Creek in 1892, coupled with technological advances in the use of large dredges in the California placers, resulted in significant production increases. And, with the expansion of the Homestake mine at Lead, SD, in 1898, US output again surpassed the 93.3-t (3 million-oz) level. By 1905, produc¬tion climbed to 124.4 t (4 million oz) with the addition of the Alaskan deposits, new output at Goldfields, NV, and the introduction of the cyanidation process. During World War I, the government forced the shutdown of gold mines. By 1920, total production had dropped to little more than 62.2 t (2 million oz). Many mines remained closed until the Great Depression. This, combined with the devaluation of the US dollar in 1934, resulted in a gold price increase to about $1.13/g ($35 per oz). Then began the fourth gold rush. By 1937, output had again surpassed 124.4 t (4 million oz). This was due to an increase in primary production and new byproduct production from base metal operations. Unlike the previous period of growth, however, this period was short-lived. The imposition of Executive Order L-208 in 1942 once again forced the shutdown of most mines. At the end of World War II, cumulative US gold production had

Jan 12, 1984