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By Satya Harpalani, Xue Zhao

This paper discusses the results of an experimental investigation to study the release of methane in coalbeds. Absolute porosity of coal samples was first determined experimentally. Following the porosity measurement, adsorption/ desorption tests were carried out to determine the gas content of coal and the rate at which it is released. Finally, micrographs were obtained using electron microscopy and the use of a physical model, developed to explain the gas flow behavior of coal, was justified. The results of this study indicated that the measured absolute porosity of the coal sample was between 5 an 6%. This was significantly lower than the porosity estimated by comparing the micrograph area occupied by the pores and the area of observation for several micrographs, suggesting that coal has a large number of pores with a very small volume. The micrographs also clearly indicated that coal has a large interconnected network of cleats and microfractures. The adsorption/desorption experiments showed a hysteresis between the adsorption and desorption isotherms. Also, the rate of desorption was found to be strongly dependent on the particle size of the specimen.

Jan 1, 1989

By C. Maltesh, P. Somasundaran, G. A. Gruber

Anionic conditioning of phosphate ores prior to fatty acid flotation is a critical step that determines the selectivity, recovers and, hence, the economics of the process. However, the chemical mechanisms operating during this conditioning step are not very well established. In this work, a comprehensive surrey of plant practice was conducted. Then, adsorption on flotation feed and francolite were studied under simulated plant conditions. Different adsorption mechanisms were found to be dominant under laboratory and plant conditions. In plant water, there was sonic physisorption of oleic acid on phosphate flotation feed and francolite, in addition to chemisorption. However, in distilled water under laboratory conditions, only chemisorption was detected. Fuel oil reduces the residual oleic acid in solution after adsorption, which explains the beneficial role of extender in phosphate flotation. The dissolved species in solution arising from the flotation feed or plant processing water are shown to clearly play a major role in determining the adsorption of oleic- acid on the substrates. The study also specifically demonstrates that, for the results to be used commercially, it is important to conduct the tests under plant mixing conditions and with the same plant water chemistry.

Jan 1, 1997

By Stephen R. Pogorski, Nicholas Busigin, Colin R. Phillips

The movement of radon away from its source in porous media is determined by two key parameters: the fraction of the total radon formed which enters the intergranular pore spaces, termed the emanation coefficient, and the transport processes which exist in these pores such as diffusion and convection. The first parameter, the emanation coefficient, is of primary importance since it is a measure of the actual amount of radon which is free to migrate within the media. The effects of particle size and radium concentration on the emanation coefficient were examined using a quartz-pebble conglomerate ore from the Elliot Lake mining district of Ontario. It was found that the smallest particle size examined (<74 µm) had the highest radium concentration and contributed the most to the radon emanation. A one-to-one correspondence between radium concentrations for the various particle size fractions and radon emanation was not observed. Samples were examined using scanning electron microscopy and very small particulates were observed to be present on the particle surfaces. When these very small particulates were removed from the host particle surfaces by rinsing, the radon emanation decreased by a factor of 17. This result indicates that most of the emanation comes from the very small particles. The effect of moisture on the emanation coefficient was examined qualitatively and a trend of increased radon release with moisture content was noted.

Jan 1, 1981

By Terry L. Logan, Arfon H. Jones, James C. Seccombe

Deeply buried coal seams [greater than 3000 ft (914 m)] are difficult and sometimes hazardous to test and complete due to coal sloughing, formation pressure anomalies and coal fine generation. Data collected while stimulating two deep coalbed methane wells located at the Gas Research Institute/Resource Enter¬prises, Inc. "Deep Coal Sean Project" test site in the Piceance Basin, Colorado, is presented in this paper. A single thick coal seam was completed openhole in each well. Core data, reservoir data, in-situ stress measurements, and pre-stimulation calibration test data were collected at the site to use in the design of the fracture stimulation treatments for both wells. A nitrogen foam fracture fluid treatment was selected for the first well and a linear gelled water for the second well. Treatment pressures were monitored with a downhole quartz pressure transducer. Atypically high treating pressures were observed, possibly indicating coal fines plugging at the fracture tip or increase in fluid viscosity caused by interaction of the generated coal fines with the fracturefl uid. In addition, a comprehensive fracture diagnostic effort was employed during the fracturing of the second well; namely, triaxial borehole seismic, seismic televiewer, hydraulic impedance monitoring, gamma ray log (in conjunction with radioactive additives in the sand), and temperature log. The results indicate a vertical fracture was created parallel to the face cleat as expected.

Jan 1, 1986

By Thomas H. Hibner, Daniel Tempelis, John E. Shamma

Environmental protection of nearby resources is an issue that can not be ignored in tunnel construction. The Inland Feeder Arrowhead Tunnels Project is no exception. With keen interest from various stakeholders, Metropolitan developed a Groundwater Monitoring and Mitigation Plan. This plan provides for monitoring and management of selected water resource features within the San Bernardino National Forest along the proposed tunnel alignment. The plan specifically provides for monitoring of streams, springs, seeps, and piezometers for water temperature, pH, specific conductance, and chemical analyses, as well as flow or groundwater elevation. Metropolitan uses the data to evaluate for and manage potential impacts from groundwater ingress during construction of the Arrowhead Tunnels.

Jan 1, 2003

By J. B. Zachwieja

Cationic reagents have been utilized in mineral processing since the mid 1930&apos;s and are based upon fatty nitrogen derivatives. The initial commercial development was centered around a flotation collector capable of separating potassium chloride from sodium chloride - potash flotation. The first commercial sale for Akzo, known then as Amour and Company, was realized in the summer of 1940 to a potash producer in Carlsbad, New Mexico for the flotation of potash. The success of the potash flotation collector led to the development of other cationic mineral processing reagents. Flotation collectors for iron ore, phosphate, calcium carbonate, silica sand, feldspar, and other silicates materialized into a large commercial business. Another area that realized commercial success was the development and use of anticaking/antidusting reagents for hygroscopic salts, fertilizer mixes, and granular fertilizers. A more recent development has found use in the trona industry as a defoamer and crystal growth modifier during the crystallization of sodium carbonate liquors. A review of cationic reagent chemistry and applications will be given and the potential for new application areas will be explored.

Jan 1, 1994

By G. Adel, J. M. Richardson

Mine-to-mill optimization is a holistic approach to the optimization of mining and processing operations. Developed at the Julius Kruttschnitt Mineral Research Centre, it attempts to minimize energy consumption through the optimization of the particle size reduction process. The approach involves sampling and modeling of blasting and processing, computer simulation to optimize the operation and develop alternatives, implementation of the most promising alternatives, and sampling to quantify energy savings. The primary objective of the present effort is to adapt mine-to-mill technology to the aggregates industry. This paper presents an update of work being conducted at quarries operated by the Luck Stone Corporation of Richmond, Virginia.

Jan 1, 2006

By J. T. Sitarski, R. C. Emmett, L. W. Luinstra, R. P. Klepper

A mining operation in Zimbabwe produces a pyritic gold concentrate that requires oxidative pretreatment prior to cyanidation in order to liberate 80 percent of the gold values. Bio- oxidation offered the potential of increased gold recovery and was considered to be an economically advantageous alternative to the existing practice of roasting the concentrate. Based on bench- scale test work, a small bio-oxidation plant, capable of processing approximately 50 percent of the concentrator production, was installed at the mine to evaluate this approach. The plant included two 57 m3 bioreactors in series and the ancillary equipment needed to prepare the feed concentrate, to wash the leached residue prior to cyanidation, and to neutralize the waste liquor. The plant was operated for a year-and-a-half, and the conditions needed to achieve a 90 percent liberation of gold values were determined. A number of critical technical problems were encountered, and many were resolved on-site. Others have been addressed since the pilot plant was moth-balled in June 1988. Valuable insight was gained from the operation of the pilot plant, which has provided useful guidance for continued process and equipment improvement.

Jan 1, 1990

By P. E. Richardson, N. P. Finkelstein, Z. Chen

The large band gap and insulating properties of sphalerite have limited the application of standard electrochemical techniques for studying its reactions with flotation reagents. This problem has been overcome by developing electrodes that rely on the surface conductance produced when sphalerite is activated with copper or other heavy metals. A brief exposure of the mineral in copper sulfate solutions results in electrodes that exhibit significant electrochemical activity characteristic of copper sulfides. Voltammetry studies conducted on sphalerite activated in 10-4 M CuS04, solutions at pH 4.6 provide information on both the amount and the nature of the activation product(s). It is shown that copper activation is strongly dependent on the electrochemical potential applied during activation. Activation at potentials increasingly negative of the rest potential causes a progressive increase in the amount of copper on the surface; activation at potentials positive of the rest potential decreases the amount of copper on the surface. The results indicate that both the kinetics of copper uptake and, possibly, the chemical composition (stoichiometry) of the activation product are controlled by the electrochemical potential.

Jan 1, 1995

By M. G. Karfakis

This paper examines the chimney occurrences in the Hanna Coal Field, Wyoming. Chimney caving is defined, previously proposed mechanisms involved in the development of a chimney are critically reviewed, and factors controlling chimney cave are identified. The main portion of this paper deals with the identification and characterization of chimney subsidence due to underground coal mining in the Hanna Mining District. In an attempt to characterize the subsidence, sink-hole occurrences are correlated with the depth of coal, thickness of mined-out beds, mining methods, nature of overburden, structural geology, and hydrology. Most sinkholes in the Hanna Basin appear to be conical in profile, with the apex upward. The average diameter is 15 meters (50 feet), with an average depth of 11 feet. Most have developed above an overburden of less than 61 meters (200 feet). The average mining height to width ratio is 5. Much of the chimney development is governed by the thickness and character of the overburden, the width and height of the mine opening, and the in situ state of stress.

Jan 1, 1986

By Jean-Michel Rendu

The semivariogram is one of the most important tools available to the geostatistician for the analysis of mineral deposits. To be complete, a semivariogram study must include a minimum of three parts which are highly interdependent. These are: calculation of the semivariogram, mathematical modeling, and geologic interpretation. The known factors and conditions which controlled or influenced the distribution of mineralization within the body being studied should be considered in the analysis .of the semivariogram. The presence and characteristics of successive phases of mineralization, the chemical and physical properties of the host rocks and the mineralization should all be considered. This requires close and continued communication between the geologist and the geostatistician prior to and during the semi-variogram study. Geologic stationarity is needed if meaningful semivariogram results are to be obtained. The first step is, therefore, to determine whether the mineralization can be analyzed as a whole or if different geologically homogeneous sections must be defined and evaluated separately. Different methods can be used to calculate an experimental semivariogram from known sample values. The method chosen will depend not only on the anticipated and actual statistical properties of the deposit, but also on its geologic characteristics.

Jan 1, 1982

By Kadri Dagdelen

Production scheduling of an open pit mine is one of the most important steps in open pit mine planning. The production schedule of a mine defines the distribution of cash flows and as a result directly influences the net present value and overall economic feasibility of a project. It is becoming more and more critical to obtain an exploitation schedule of a deposit such that highest possible returns are achieved from a project. As the mining industry mines lower and lower grade ores, production scheduling is becoming a key item which can make or break a project. Although the need to plan and operate a mine with an optimum production schedule has been obvious for some time, the methods used to obtain such a schedule have not been. There is not a single, mathematically proven, optimum mine production scheduling algorithm which is widely accepted and used today. In an attempt to determine a production schedule which is optimum, a new algorithm was developed. This algorithm, in theory, is based on the lagrangian concepts of mathematics and in practice is based on the parameterization concept of mining. This paper describes the fundamentals of this newly developed algorithm.

Jan 1, 1986

By Louise H. Michaud

An interactive mine planning system that employs recent advances in 3D computer graphics capabilities and 3D geologic modelling to aid with the tasks involved in producing dragline mine plans was developed. As well as offering large potential saving in the time required to carry out the planning tasks, the system offers immediate visual feedback to the planning engineer. This can greatly aid in the conceptual understanding of complex geology and mine plans. The package incorporates the generation of a three dimensional Gridded Seam Model (GSM) as the basis for the development of the geologic database. This modelling method is capable of accurately representing rugged topography and multiple coal seams, including folding and faulting. The GSM is then integrated with an interactive graphics mine planning system in order to develop one model and one database for the generation of the mine design, the depletion of the coal resources and the movement of spoil material. The gridded structure of the model also provides the foundation on which all mine and spoil pile volumes are calculated.

Jan 1, 1992

By R. J. Wesely, Corby G. Anderson, L. Ernest Krys, John B. Ackerman, A. D. Zunkel, Suzzann M. Nordwick

Processing of the refractory precious metal ore from the Sunshine Mine is done in a fully integrated hydrometallurgical facility. This operating philosophy began with the construction of an antimony plant during World War 11, and it continued with the construction of a silver-copper refinery in 1984. The antimony plant relies on an alkaline sulfide ambient pressure leach combined with antimony electrowinning and antimony compound production. This plant is the largest producer of antimony metal in the United States. The one-of-a-kind silver- copper refinery uses a nitrogen species catalyzed sulfuric acid pressure leach system. The plant contains innovative downstream silver recovery processes as well as copper solvent extraction and electrowinning. This paper presents the pertinent process chemistries and flow sheets for the two unique hydrometallurgical processing plants.

Jan 1, 1993

By Robert A. Haney

During the last ten years, longwall mining systems have undergone many changes. Panel widths and lengths have increased. Longwall faces have become more automated. Average production from individual longwall panels has increased from 1,000 to 3,600 tons per shift. To control the dust generation resulting from the higher production, longwall dust control systems have integrated various dust control techniques. Systems designed to control dust generated at the crusher/stageloader, shearer, and supports are common to most longwall faces. A survey was made of the dust controls that are currently in place on all the longwalls in the U.S. This survey addressed the types of controls used to reduce dust generated at the crusher/stageloader, shearer and roof support movement. Additionally, information on face ventilation rates, cutting cycle and level of automation was obtained. The purpose of this paper is to review the dust control practices that have been implemented throughout the United States and to identify those controls that are being used on high production longwall faces. Additionally, a model is used to demonstrate how ventilation and automation affect occupational exposure. Automation of roof support movement can offer some of the greatest reductions in occupational dust exposures. While technically feasible, its full benefit has not been fully realized by the industry. Until technology to fully automate longwall mining systems becomes more reliable, future dust control systems must rely on increased ventilation, application of headgate dust collectors, improved shearer dust controls and improved shield dust suppression systems.

Jan 1, 1995

By Jon Holder, Brann Johnson

Pore-fluid/rock chemical interactions on both short and long time scales can produce significant pore structure and mineralic changes that can markedly alter transport properties, such as fluid permeability. The introduction of the chemical factor requires modification of experimental systems and methodologies developed for measurements in which chemical effects are minimal. Particular attention must be given to temperature effects, fluid chemistry, fluid/rock reactions and kinetics, fluid flow rate, and fluid/experimental-system reactions. The ability to obtain very low, steady flow rates at constant fluid pressure is important for study of some fluid/rock systems. Minimization of metal corrosion is of paramount importance and requires choice of proper metals, such as titanium, and certain Ti-alloys and Ni-alloys. In this paper, we briefly discuss the relevant chemical factors affecting system and experimental design. The primary focus, however, is on the characteristics of highly corrosion resistant metals, thermal and chemical resistant jacketing materials, and the attributes and limitations of various flow-rate and back-pressure control systems and flow-rate measurement systems.

Jan 1, 1986

By J. A. Ryder

Compressed air is a relatively inefficient yet very convenient vehicle for transmitting mechanical energy. It is inefficient when compared to, say, hydraulic or electric energy systems since compressor and pneumatic machine efficiencies are quite low (in the range 20-65%) and reticulation losses can be quite high unless adequate pipe diameters are used to minimize friction drops. It is convenient in that capital and maintenance costs of pipes and machines are exceptionally low, the equipment is flexible and lightweight, the technological level is simple, the form of the energy supply is intrinsic- ally safe, and as an additional minor but psychologically important benefit, it provides a ready source of cooling and air supply for emergency use in deep hot mines. It is for these reasons that compressed air is a premier source of energy for many forms of underground equipment, in particular hand or rig-mounted rockdrills, some forms of rock- handling equipment, and a host of minor applications including agitators, small-lift pumps and temporary f am installations. In a typical S. African deep-level gold or platinum mine, compressed air generation accounts for 15% of the total mine electrical energy bill - more than is used for hoisting. In these mines it is not uncommon for over 100 km of underground compressed air piping to be installed, primarily to supply handheld rockdrills.

Jan 1, 1979

By Christoph Wels, Michael Royle, Shannon Shaw

Intrinsic remediation is the effect of natural attenuation mechanisms - dilution, dispersion, sorption/precipitation and biodegradation - reducing contaminant concentrations in ground water to specified levels at predetermined compliance points in the aquifer. Current monitoring and modeling for post closure was used to assess the current and long-term potential of intrinsic remediation of contaminated seepage originating from a large reactive (sulfidic) tailings impoundment near Questa, New Mexico. It is concluded that the natural attenuation mechanisms of precipitation within the tailings (as a result of buffering) and dilution/dispersion within the aquifer are currently active and likely sufficient to reduce contaminant concentrations to below state standards in the long-term. Other natural attenuation mechanisms such as sorption and biodegradation within the receiving aquife4s) were not assessed here, but are likely further reducing contaminant concentrations. Active interception and recovery of the seepage water is being maintained until monitoring demonstrates that intrinsic remediation has successfully achieved the level of water quality control required.

Jan 1, 2000

By Thierry Coléou

In this paper, we consider open pit optimization. At present, most methods specify the economic parameters and then find the corresponding optimal pit. But as the economic environment varies (which it does regularly these days), the "optimal" pit changes and quite often changes markedly. The questions are: by how much does it change and which parameters are most influential? The functional approach of Technical Parameterization of Reserves, devised by Matheron in 1975, gives the set of all the different optimal pits, under any economic condition. It separates technical design and economic assumptions and thus permits the use of several optimality criteria when choosing the final pit, and not just the maximization of an additive profit formula. Very efficient specific algorithms are presented to obtain all the potentially optimal pits. Fluctuations in the parameters induce changes in the optimum design. Inclusion relations that exist generate very tight bounds and hence very quickly detect optima, even when using a classical adaptation of maximization techniques (graph theory, moving cone, dynamic programming ...). The advantage of Technical Parameterization of Reserves over other methods is that it provides a nested sequence of optimal pits which can then be used for mine scheduling. Many possible mining schedules can be obtained by using the family of technically optimal projects to split up the orebody. The "optimal" schedule, which is in fact a compromise between the different requirements of the economists, the mine planner and the metallurgist, can be chosen from within the wide scope of possibilities. A practical example of mine scheduling for a chromite mine is presented in detail.

Jan 1, 1989

By G. Gaidajis

For the environmentally safe management of the sulphidic waste rock produced from the Stratoni mining facilities, TVX Hellas has examined, within the frame of the funded European research program ROLCOSMOS, the effectiveness of an alternative rehabilitation scheme involving the segregation of the sulphide rich components of waste rock and the engineered application of alkaline additives. The examined waste rock management scheme was evaluated with laboratory test work followed by pilot-scale field applications. In this paper, the results from the two-year monitoring period of the pilot scale application are presented.

Jan 1, 2002