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By D. Koren, D. Carson

Disposal of smelter slag may be subjected to regulatory leach tests to deter- mine whether they produce a leachate containing contaminants in excess of stated limits. Contaminants that are most often of concern for smelter slags are As, Cd, Cr, Cu, Ni, Pb, and Zn. The present regulatory tests are based on the assumption of storage in a municipal landfill dump, where wastes are in contact with organic acids. Since slags are not normally stored in such an environment, these tests do not adequately assess the true leachability potential of the slags. Ten slags from six major Canadian nonferrous sulfide smelters were studied. Leaching was done following regulatory and modified tests, including leaching in columns with synthetic acid rain for a 25-week period. The slags were characterized by mineralogical analysis before and after leaching with synthetic rain. The synthetic mineral equivalents (hereafter referred simply as phases) in the slow cooled slags consist of fayalite grains and dendrites, amorphous glass, some spinel and small quantities of complex sulfidic prills and metallics. The phases in the quenched slags consist of amorphous glass, some spinel and small quantities of complex sulfidic prills and metallics. Some metal dissolution took place during leaching. However, for all leaching tests, the concentrations were always below the regulated limits. In general, the content of the potentially leachable elements remains unchanged in the fayalite, in the amorphous glass and in the spinel, whereas the quantity of sulfidic prill and metallics decreases after leaching. Therefore, most of the deleterious element dissolution comes from the sulfidic prills and metallic phases. Metal dissolution increases by crushing the slag, probably due to an increased exposure of the sulfidic prills to the leaching solutions.

Jan 1, 1998

By W. E. Horst

Historically, research organizations have made significant contributions to the development and commercialization of new chemical products for the mining industry and examples of commercial results are cited With the recent demise of research organizations within the mining industry and dynamic changes in the industry, the supporting role of R&D groups has become limited or non-existent. Cat- reduction requirements and new raw-material sources offer future opportunities for R&D organizations to continue their effective participation in the commerical development of new chemical products. Potential areas of interest for future process applications are reviewed.

Jan 1, 1986

By Vanessa M. Torres

Diagnostic leaching tests provide a good indication of gold deportation in its various occurrence phases. With the results of these tests, possible flowsheets for difficult ore treatment can be established for further evaluation and plant operation can be optimized. The use of this technique can be extended, including heap leach evaluation and complex copper-gold ores. The results on the use of diagnostic leaching tests in gold ores from Companhia Vale do Rio Doce (CVRD) are presented and discussed, as well as the methodology to select steps and interpret results used at CVRD Technology Center (Sutec).

Jan 1, 1998

By D. Edward, C. Clarkson, B. A. Firth

The presence of misplaced ultrafine particles decreases the separation efficiency of unit operations used in coal preparation. Although the classification of fine coal was considered to be adequate for the needs of the coal industry during the 1970s and 1980s, it is apparent that further improvements in the yield/ash/moisture relationship achieved by coal preparation plants will require increased efficiency in this size-separation step. This paper describes the capability of current and developing techniques to address the problems that need to be overcome.

Jan 1, 1998

By Gerald H. Luttrell, Rick Q. Honaker

A coal preparation plant incorporates a variety of solid-solid separation processes that operate in relatively independent parallel circuits. Studies have shown that total plant performance can be optimized by selecting circuit cutpoints that maximize total clean coal yield irrespective of the performance of individual circuits. Although the optimum cutpoints can be determined using simulation programs, these mathematical routines require detailed washability data and empirical partition information that is not often available to plant operators. In addition, routine fluctuations in the washability characteristics of the plant feed make this approach impractical to implement in industrial facilities. As an alternative, practical optimization criteria can be developed for plant operators through a fundamental understanding of scientific principles involved in coal cleaning operations. This article provides an overview of the most important optimization criteria and presents several industrial case studies that illustrate the financial benefits of this practical approach m plant optimization.

Jan 1, 2005

By P. Bevilacqua, G. Ferrara, U. Preti

In the last decade, Meloy developed the IAC - Interfacial Area Conservation - model of liberation. His work included three conservation laws and a mathematical tool called textural transform. This paper reviews the developments and applications of the IAC model. From simple spherical two-phase locked particles with planar interfaces, the model has been developed for curved interfaces and solids with complex textures. Moreover, complex shaped particles and ores having more than two phases have been considered. The model equations give the degree of liberation of the component phases for different ore textures – platy blocky and acicular - as well as for different sue distributions. Lockedness profiles are offered for defining the middlings composition, so that from the model it is possible to predict washability curves.

Jan 1, 1992

Iron ores may be upgraded by flotation of iron oxides or siliceous gangue using either cationic or anionic collectors. The electrostatic mechanism of adsorption can account for the complex chemistry involved. In industrial practice, only cationic silica flotation is used at present in North America. Some of the seemingly paradoxical phenomena of cationic silica flotation behaviors in meeting the demand for low silica concentrates are reviewed.

Jan 1, 1989

By G. D. Schena

A decision support system for the management of the mineral resources of a developing country has been derived. The system allows the evaluation of the impact of a mineral project in a developing country in the broad context of its economy. The analysis permits the assessment of the overall socio-economic consequences of mineral prospects and allows incorporation in the evaluation of issues that are broader in scope than the pure financial objectives. The system is built around the Leontief framework of economic analysis. The original input-output model, enhanced to incorporate country-specific behaviour is integrated with cost-benefit analysis and shadow pricing. The analysis leads to synthetic measures of profitability at market and shadow prices. These measures are useful to direct the mineral policy of a developing country through the exploitation of those mineral resources which are most likely to bring about economic growth and social advancement.

Jan 1, 1992

By R. N. Chakravorty

It is well established that coal can react with oxygen in air at ambient temperature and as a result heat is produced. If the heat is not fully dissipated the temperature of the coal mass will increase, thereby enhancing the rate of oxidation with a greater production of heat. If this phenomena continues, the coal mass can ignite under favourable heat accumulation conditions. A number of mine fires are caused each year due to this phenomena, commonly known as spontaneous combustion. The early detection of spontaneous combustion is of prime importance to mining engineers since any fire which could be detected at an early stage may save the mine from considerable damage and subsequent loss of production. Obviously, there is no single general criteria by which one can assess whether the under- ground mining of a coal seam will result in liability to spontaneous combustion. This has made it imperative to develop systems for the early detection of heating and to follow its development. In recent years considerable advances have been made in the design and development of methods for the early detection of spontaneous combustion. The Mining Research Laboratories (CANMET) is presently investigating the problem of spontaneous combustion in coal mines with Kaiser Resources Ltd. at their hydraulic mine at Sparwood, B.C. on a co-operative basis, and some of the work was described earlier in the Canadian Institute of Mining & Metallurgy Bulletin (1,Z). This paper summarizes and updates the work done by CANMET on the detection of spontaneous combustion in coal mines.

Jan 1, 1980

By G. Baudet, M. Save

Ethoxylated phosphoric ester surfactants were evaluated as collectors for flotation of carbonates from sedimentary phosphate ores, at slightly acidic pulp pH, using sulfuric acid or sodium fluorosilicate as a phosphate depressant. With 12 to 15 carbon atoms in the hydrophobic chain, maximum collecting power was observed for 9 to 10 ethylene oxide units. Only fine carbonates, ranging in size from about 20 to 160 µm or 40 to 200 µm, were effectively removed with phosphoric ester collectors. Utilization of seawater, or water of extremely high hardness, did not detrimentally affect selectivity. Silica, silicates, and residual fine carbonates can be separated in a second flotation stage, with primary amine as a collector. Coarse carbonates are separated by direct flotation of phosphate with fluoride ion as a phosphate activator and primary amine as a collector. In a seawater pulp, fluoride ion was not required. Typical examples of laboratory and pilot- scale test results are given to illustrate capabilities of the various flotation flowsheets.

Jan 1, 1999

A general form of pore pressure in a saturated porous medium, which is subject to external forces it has the pressurization of a borehole in hydraulic fracturing, is derived. The pore pressure consists of two parts: the preexisting initial pore pressure and the pressure induced by fluid flow due to the pressure difference caused by pressurizing the borehole The initial pore pressure associates with the effective stresses in the stress, fields of crustal stresses and a thick hollow cylinder subjected to internal and external pressures. The pure pressure weaned by fluid flow is implied in Biot's (1941) constitutive equation for three-dimensional consolidation and proved to be the exact effective pore pressure (Nur and Byerlee, 1971). Using this general form of pore pressure, a general poroelastic model for hydraulic-fracturing breakdown (fracture-initiation) pressure was derived. This model was validated by laboratory experimental results on Indiana limestone. Three sets of tests were conducted under the conditions of preexisting pore pressures of 6, 21 and 28 MPa, respectively. The equal horizontal (confining) pressures applied in the tests ranged from 6 to 60 MPa. Hainison and Fairhurst's (1967) model appear to be applicable to rocks having microcracks or flows. Experimental results of fracture reopening pressures on Indiana limestone supported this assertion. The test results also demonstrated that, when the pressure difference between the confining and the initial pore pressure grows larger than 14 to 21 MPa, the breakdown pressures agree well with the general poroelastic model developed in this paper. This indicates that the developed model will be superior when hydrofacturing stress measurements are conducted at great depth.

Jan 1, 1997

By V. K. Karra

Research by various workers has shown compressive comminution to be significantly more efficient than impact comminution. Based on the work being done at Nordberg, wet compressive crushing in cone crushers producing finer and finer products, shows the feasibility for partial substitution of conventional tumbling mills. For further substitution, major challenges are processing of fine feed slurries in cone crushers to realize a significant size reduction of the particles, and understanding the limitation of the gyratory type units in terms of finest product achievable. The paper addresses the challenges involved, efforts at Nordberg, and the implications to conventional comminution flowsheets.

Jan 1, 1989

By Thomas D. Barkand

Investigation of several serious hoisting accidents identified machine brake failure as the most common cause. The recent revelation of this potential hazard has prompted regulatory authorities to require an additional, independent, emergency braking system. As a result of this initiative, a new generation of braking systems have been developed and applied to mine elevators. This paper will discuss the design and testing of an electrical dynamic brake, pneumatic rope brake, and traction sheave brake. The effect of compound braking on hoisting systems equipped with multiple brakes will also be addressed.

Jan 1, 1992

By D. T. Maiers, P. L. Wichlacz, P. A. Pryfogle, J. H. Wolfram

The effects of metal solution concentration, biomass density, length of exposure time, and pH were determined for biosorption of molybdenum (Mo) and chromium (Cr) by three organisms. Results indicate that it is possible to sorb Mo and Cr from dilute solutions. Differences were observed in the abilities of an organism to sorb Mo and Cr as well as among respective abilities of the three microorganisms. This suggests an inherent selectivity of the organism which may afford the means to control a sorption-based process. Results also indicate that the metal sorption abilities of these microorganisms depend on duration of exposure, biomass density, solution pH, and the metal concentration of the solution. Each of these parameters suggests an additional means of controlling the sorption process.

Jan 1, 1989

By Subash Chander, B. Arnold

Many developments have occurred in coal flotation with regard to increasing recovery from the flotation circuit and its impact on overall coal preparation plant recovery. This includes innovative design of flotation circuits, equipment modification and development, methods of enhancing the use of reagents, effect of slimes, and recognizing the effect of water chemistry. This paper will review recent advances and present some guidelines to improve process efficiency.

Jan 1, 2005

By D. E. Ranta, Leigh A. Readdy

Defining classes of ore using geostatistical methods that match historical classifications has presented problems in the past. A simplistic and practical approach to this problem is presented. An example of the approach is presented using a porphyry-type system as a case study. The technique described uses area of drill-hole influence and known conditions from similar deposits, or the production history of the deposit being studied. It provides a practical bridging mechanism for defining the class of ore on a block-by-block basis using the error of estimation value developed during kriging. The approach provides a filtering method that refocuses attention on the adequacy of drill-hole spacing.

Jan 1, 1992

By D. Denton, C. Peppin, D. Tesarik, D. Bayer, J. B. Seymour

Hecla Mining Company and NIOSH cooperated in a study to document the safety of rock support supplied by reinforced cemented paste backfill at the Lucky Friday Mine. Data are presented on backfill modulus values from laboratory tests and compared with modulus values from in-mine wall closure on the backfill. It is theorized that a compressive zone is created in the backfill between the upper and lower bearing plates on the reinforcing bolts, and that the backfill remains stable as long as the compressive zones from adjacent bolts overlap.

Jan 1, 2001

By R. P. King

A new device, called the dual impact load cell, has been developed and built at the Comminution Center to measure fracture energy and damage accumulation in brittle particles that are subject to impact. The results show that damage accumulation during impact is not a significant factor in determining the fracture energy or the particle strength. However, predamage induced by thermal pretreatment of the particles has a significant effect on both fracture energy and particle strength.

Jan 1, 1995

By Ian Sheppard, John J. Chen

This paper describes the development of the underground mining methods employed for narrow silver-lead-zinc orebodies at the Isa Lead Mine. Cut-and-fill methods were the chief underground mining methods for the narrow orebodies at the mine over 35 years ago. Benching methods were introduced approximately two decades later, and quickly replacing the cut-and-fill methods. The cut-and-fill methods and the benching methods are briefly reviewed in the paper. The benching methods and technologies have been continually evolving and one of the recent achievements is a multi-lift benching method. The multi-lift benching method is described in detail.

Jan 1, 2001

By J. A. Procarione, M. K. McCarter, Bradley C. Paul

A numerical technique is described which can be used to model the quantity and distribution of air flow through broken rock. The method can also describe gas concentration and temperature distribution. A computer code implementing the numerical approach was developed to assist in determining the feasibility of a proposed modified in-situ leaching method for extracting copper from sulfide porphyry deposits. This mining method requires air to be forced through cells of rubblized ore. The flow serves to supply oxygen for the leaching reactions and to dissipate heat that would other-wise build due to the exothermic reactions. The method substitutes the Carman equation into the Laplace equation. The solution of the resulting non-linear formulation is done on a finite difference grid using SOR with iteration improvement of coefficients. This procedure yields the required air flow pattern and pressure drop. An equation for advection with absorption is then solved over the same grid using explicit schemes to yield oxygen concentration. Finally, a similar technique is applied to the convective heat transfer formula to yield the temperature profile. The model is potentially applicable to such mining problems as the prediction of leakage through caved ground, the prediction of methane concentration in gobbed ground, and the prediction of heat build-up in caved workings.

Jan 1, 1989