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By Charles L. Kimbell

The series summarizing the prices of the major nonferrous metals on the stock exchanges of the United States and the United Kingdom has been continued this year in tables 23 and 24. As a result of the lack of availability of comprehensive data on the prices of metals in Canada, the table that had presented that information in past years in this chapter has been discontinued and the price series for nickel that had been in that table now appears in the table presenting metal prices in the United States.

Jan 1, 1993

By E. D. Eastman

The recent determination by Eckman and Rossini of the heat of formation of sulphur dioxide appears to be of much greater accuracy than any previous measurement . The value obtained by them , 70,940 cal . , is in good agreement with that of Thomsen ( 71,080 ) , but differs by about 1,700 calories from Berthelot's result ( 69,260 ) , and by 1,940 calories from the provisional figure ( 69,000 ) adopted by Lewis and Randall in their studies of the free energies of the sulphur compounds . This large discrepancy suggested the desirability of a recalculation of the free energy of sulphur dioxide . In addition it is now possiblt to fix the specific heat of S₂ gas with greater certainty than at the time of the original calculations . These two changes are incorporated in the recalculations described below , and directly affect the values of AH , and the Ar terms in the free energy equation . In the determination of the integration constant of the latter equation , the free energies and specific heats of water vapor and the oxides of carbon are required as auxiliary data . In this work these are based , with certain exceptions , upon the equations previously deduced , which differ appreciably from the corresponding equations of Lewis and Randall . 56 · The principal equilibria employed below , and the plan of calculation , remain the same as in the calculations of Lewis and Randall . Before beginning this revision a search of the literature was made , extending to August , 1930 , for studies of additional equilibria . Only one reaction was found that gives promise of increased accuracy . This is the equilibrium of sulphur dioxide with copper , cuprous oxide , and cuprous sulphide . In this case , however , certain of the subsidiary data are lacking , and until they become available , the existing studies of the equilibrium in this system can not be successfully utilized . The changes in the numerical data mentioned above , especially in the thermochemical constants , are therefore solely responsible for the rather significant differences of the revised from the original values of the free energy .

Apr 1, 1931

By Richard O. Kneisley

Microseismic activity observed in both the laboratory and underground indicates that a quiet period, associated with the closure of existing fractures and strongly influenced by coal seam microstructure, occurs prior to coal bumps. Field studies conclude that coal mine bumps occur against a background of this so-called microseismic calm. This Bureau of Mines report summarizes microseismic activity associated with face bumps and floor bursts in a deep, western U.S. coal mine. Results conclude that while bumps are often accompanied by panel-wide increases in microseismic activity, bumps are not only preceded by a localized decrease in activity, but occur within these quiet zones. The results of this study concluded that microseismic activity may be applicable to the global detection of potential bump-prone zones, but that future studies are necessary to confirm these findings and to improve the techniques for evaluating stress control effectiveness.

Jan 1, 1989

To minimize support costs and to improve ground control by improving wood-crib design and utilization through the development of engineering methods that will match the placement and performance of the wood cribs to the load conditions imposed by the mine environment. Background While wood cribs are used extensively to stabilize mine openings, their utilization is often based on historical practice or trial-and-error rather than on engineering design. This has led to conservative crib utilization where more capacity than is necessary is employed or inadequate capacity is provided when mine conditions worsen. Critical design parameters, such as the stiffness of the support structure, are often ignored. Optimum crib design and employment is becoming increasingly important as the utilization of wood cribs increase due to the growth of longwall mining, and as the cost of wood continues to rise. A single longwall operation will spend as much as a million dollars per year on the support of the gate roads.

Jan 1, 1994

Develop personal computer (PC) based software for analyzing and/or filtering time- and frequency-domain attributes of seismic and electromagnetic signals from geophysical surveys for the enhanced interpretation of rock masses and subsurface geologic structure. The Problem Both mining and petroleum geophysicists utilize seismic signals to characterize rock masses for delineating subsurface stratigraphy and structural conditions. However, a vast amount of information available in seismic project evaluation data often is unavailable for interpretation unless these data are enhanced. New processing technology increases the quality of these signals for analysis and interpretation. Comprehensive signal processing software is mostly written for petroleum exploration companies. Commercially available signal processing programs are often limited to a single application or are restricted for use with specific hardware, e.g., a digital oscilloscope or a mainframe computer. The programs may use computer codes that are proprietary, restrict user modification to expand capabilities, or may be hard to interface. They may have insufficient documentation for easy use and be support dependent.

Jan 1, 1990

By R. J. Shanley

This report presents a computer code that has been developed by the Bureau of Mines for isolating naturally occurring clusters of data plotted on the unit hemisphere and testing these clusters against a probability distribution which admits elliptical symmetry about its mean. A listing of the computer code is provided along with an example output illustrating the delineation and analysis of clusters in fracture orientations measured in a porphyry copper deposit.

Jan 1, 1975

Enable prospective in situ leach mine operators to evaluate the economic potential of an ore body by using a user-friendly, computerized in situ copper oxide leach mining cost model. Background As part of its research on in situ leach mining technology, the Bureau of Mines produced a 5-volume contract report that mining companies can use to design an in situ mining operation for copper oxide deposits. Written for the Bureau by the Science Applications International Corporation (SAIC) in 1988, the generic design manual also contains a computerized cost model for evaluating the economic feasibility of in situ leach mining for any specific copper oxide deposit. The cost model is to be used with Volume II of the contract report. But because of certain complexities associated with running it, the Bureau found that the model could be improved by making it more user friendly. Approach The approach taken by Bureau researchers to make the original model more user friendly was to incorporate a HELP function to define input parameters, and to enable the display of output on the monitor. An accompanying handbook, U.S. Bureau of Mines Information Circular (IC) 9284, contains further details on running, the 1990 model.

Jan 1, 1991

By M. J. Ferrante

Relative enthalpies of cuprous iodide (CuI) were measured at the Bureau of Mines to provide thermodynamic data for the advancement of min-eral technology. Enthalpy measurements between 298.15 and 1,396.3 K were made with a copper-block drop calorimeter. The temperatures of transition were measured by differential scanning calorimetry (DSC). Reversible transitions were determined at 643 K with a standard enthalpy of transition [(6Htr)] = 0.74 kca1/mol, at 679 K with a [6Htr = 0.65 kca1/mo1, and at 868 K] with a standard enthalpy of fusion [(6H~) = 1.895 kca1/mol.] Tabulated values are listed at selected temperature increments from 298.15 to 1,600 K for the standard relative enthalpy (HO -H298), heat capacity (CpO), entropy (SO), and Gibbs energy function [-(Go -H298)!T]. The enthalpy data are also given in the form of equations and combined with thermodynamic data from other investigations to derive values of standard entha1pies of formation [(~HfO)], Gibbs energies of formation [(6GfO)], and logarithms of the equilibrium constants of formation (log Kf).

Jan 1, 1987

By E. J. Matson

The Little Castle Creek chromite deposit was examined in February and May 1941, respectively, by W. O. Vandenburg and O. H. Metzger, engineers of the Bureau of Mines. The Federal Geological Survey started a magnetometer survey of the area in November 1940 and completed its work during April and May 1941. Field work by the Bureau of Mines was conducted during May and June 1941. The purpose of the Bureau of Mines investigation was to search for a continuation of the chromite mineralization. The property at one time was the largest chromite producer in California.

Jan 1, 1949

By Gregory J. Chekan

In This Chapter [Drilling, blasting, and crushers Diesel particulate Enclosed cabs Ventilation with jet fans Stopping construction methods Propeller fans as main fans] This chapter explains how to control dust in large-entry stone mines, including both silica dust and diesel particulate. Most stone mines are limestone mines, but a substantial minority are marble, sandstone, and granite mines. These mines differ from most others in that entry widths are 30 ft or more and entry heights are 25 ft or more. Such mines, developed with room-and-pillar methods, have large open areas that can make ventilation and dust control more difficult. Because of the difficulty of ventilating stone mines, improved ventilation is a major focal point of this chapter. However, the chapter also covers the control of dust from drills, blasting, and crushers. Another part of the chapter covers enclosed cabs, an effective dust control technique for some workers. BACKGROUND The major dust compliance problem in stone mines is caused by silica (quartz) in the rock. Mines in high-silica rock, 8% or more, are far more likely to have a dust problem than those where there is less silica. Geographically, the limestone in the Northeastern and South Central United States has higher silica than the rest of the country. Chekan and Colinet [2002] have analyzed Mine Safety and Health Administration (MSHA) dust sampling results [MSHA 2001] from the stone industry. They have concluded that, on average across the United States, the workers exposed to the highest dust concentrations are rotary drill operators, front-end loader operators, truck drivers, and crusher operators. However, there are many regional differences. Also, occupations that work outside of cabs, such as blasters, roof bolters, and laborers, can be exposed to high dust levels.

Jan 6, 2003

By N. S. Dalal, V. Castranova, K. Van Dyke, V. Vallyathan

"IntroductionInhalation of crystalline silica is often associated with the development of pulmonary disease (Ziskind et al., 1976). Recently, it has been proposed that freshly sheared silica .may have surface properties that make it more reactive with lung tissue than aged silica, and that this unique reactivity ·of freshly crushed silica enhances its pathogenicity. A recent study in our laboratory strongly supports this theory (Vallyathan, et al., 1988a; 1988b). We found that grinding of silica cleaves bonds in a silica tetrahedral lattice generating reactive free radicals sites on the surface of the silica particles. The presence of surface radicals on freshly ground silica was monitored by electron spin resonance (ESR) spectroscopy. The ESR signal generated from fresh silica in air is characteristic of Si-0 and Si radicals. Evidence, i.e., the ESR signal after the addition of a spin trap (DMPO) and its sensitivity to ethanol, indicates that these silicon-based surface radicals can react with water to form hydroxyl radicals (OH). Results also indicate that these surface radicals make fresh silica more cytotoxic than aged silica; i.e., fresh silica causes more membrane damage as evidenced by hemolysis and lipid peroxidation. Therefore, the presence of reactive sites on the surface of freshly cleaved silica may play a significant role in its pathogenicity.If surface· free radicals are related to cytotoxicity, then screening dusts for the existence of such radicals may predict their relative pathogenicity. Since an ESR spectrometer is not available to many laboratories, the objective of this study was to develop a quick and simple technique to monitor the existence of reactive surface sites on dust. The technique chosen was the measurement of chemiluminescence using a liquid scintillation counter; i.e., an instrument which·would be accessible to most investigators."

Jan 1, 1989

By Wils L. Cooley, Herman W. Hill

'The electrical behavior of ground beds is often quite different from what would be expected based on experience with electric circuits. An explanation for this unique behavior is given, through means of an analogy, which should promote intuitive understanding of ground beds. The nonmathematical development of the text is complemented by an extensive appendix which describes the details of ground bed calculations. This work was supported by U.S. Bureau of Mines contract G0144138.

Jan 1, 1979

To increase awareness of float coal dust explosion hazards in the mining industry.

Jan 4, 2006

By Albert W. Deurbrouck

Dense-medium cyclone tests in 4-and 8-inch-diameter units have shown the ability of cyclones to make sharp separations down to 100 mesh when washing coals of a finer top size than normally fed to dense-medium cyclones. The reduced top size of the feed apparently allows the finer size particles to report to the proper product by reducing the effect of very coarse particles in the congested separation zone of the dense-medium cyclone.

Jan 1, 1974

By L. C. Headley

Surface areas of two synthetic and three natural consolidated porous samples were obtained by the Orr low-pressure permeametry technique. The results suggest that the Orr technique is a useful substitute for the low-temperature gas adsorption (BET) method for determining the surface area of rock samples. It was more rapid than the BET method, and the surface-area values obtained were larger but agreed better with BET values than values calculated from the Kozeny-Carman equation. Efforts were unsuccessful to demonstrate the influence of channel-size distribution on pressure-flow rate curves by means of experimental data and a parallel channel model.

Jan 1, 1971

By Ronald D. Hill, Elmore C. Grim

The goal of blasting is to get maximum fragmentation of the consolidated material in the overburden with optimum drilling and blasting cost. The amount of fragmentation required is determined by the stripping unit to be used In overburden removal. Many coal seams must also be broken by blasting; this is conducted before coal removal. There are environmental factors as well as due regard for public safety, health, and welfare that must be considered in choosing the blasting plan. The blasting plan should be made during preplanning and is based on data from the overburden cores. Analysis of the data will help In determining the kind of drilling equipment and bit types that will be needed for overburden preparation.

Jan 1, 1974

By Pablo Velasco

The Ecuadorean mineral sector and overall economy have retained their traditional dependence upon the production and export of hydrocarbon products. Exports of crude oil and its products accounted for 62% of the country's export earnings in 1985. Ecuador's major mineral commodities produced and exported were cement, gold, limestone, liquefied natural gas, liquefied petroleum gas, natural gas, natural gasoline, crude petroleum and condensate, raw steel, semimanufactured steel products, and sulfur.

Jan 1, 1987

The twelve latexes listed in Table XI penetrated A horizon soil as shown by elution through a laboratory soil column and gave good sealing efficiency. See details in Table XII. High elution through laboratory soil columns of 4 to 6 inches depth is desirable because it predicts penetration of latex to a greater depth in the field. No definite correlation was evident between penetrating ability and particle size, surface tension, or pH. Most of the materials, however, were characterized by low surface tensions in the 36 to 53 dynes/cm range while particle sizes were usually in the intermediate range of about 1500 to 2500 Å. Naugatex J-3471 (a highly crosslinked styrene-butadiene copolymer) was the most promising of this group for stability, penetrating ability; and sealant efficiency. It also showed utility with [B] profile soil. Many of the other latexes tested in this investigation showed good sealing efficiency but were judged unsatisfactory because they gave low penetration or formed surface films with & horizon top soil. In general, latexes containing cationic surfactants were not satisfactory because they formed a heavy surface film. This is due to neutralization of the positive latex charge by the negatively charged soil particles.

Jan 1, 1972

By Peter F. Steidl

Seven degasification wells have been completed in the Pittsburgh coalbed at the new Emerald mine near Waynesburg, Pa. Funding was provided by the Bureau of Mines to perform stimulation treatments on five of the wells, to show that this is a feasible and economical means of degasifying part of a coalbed. The seven wells ranged in depth from 590 to 910 feet. Stimulation treatments used 25,260 to 42,660 gallons of foam and 7,400 to 12,800 pounds of 20/40-mesh prop sand. Pumping rates were 10.8 to 11.6 bbl/min and treating pressures were from 1,050 to 1,600 psig. On the day following stimulation, gas production ranged from a few hundred cubic feet per day to more than 100,000 cu ft/day.

Jan 1, 1978

By H. R. Shell

Variations between laboratories on the silica and alumina content of calcined kyanite led to this Bureau of Mines study of the extent and nature of the differences. In particular, Bureau scientists hoped the study would lead to correction of the causes of the dissimilarities. A sample of calcined Kenya kyanite was analyzed by seven different laboratories familiar with silicate analysis. The compiled data indicated differences originating from lack of recovery of silica after two acidic dehydrations, from high alumina caused by several factors, from loss or gain of iron during sample fusion, and from indifference regarding the accurate determination of minor constituents.

Jan 1, 1959