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By M. A. Reyes

This experiment investigated the effects of different machine mounted area lighting technologies on visual performance. The primary objective was to conduct a comparative evaluation of the lighting technologies based on the visual performance of thirty-six human subjects in a simulated underground mine environment. Incandescent (Incand), fluorescent (Fluor), and light-emitting diode (LED) technologies were used to create four lighting combinations. Visual performance was quantified for the detection of movement in the peripheral field of view and the identification of ground hazards. Measurements were made of the speed [response time measured in milliseconds (ms)], the accuracy (the number of targets and objects missed), and the subjective discomfort rating of the glare experienced for each lighting combination. A secondary objective explored the effects of aging on visual performance. The results indicate that lighting combinations which consisted of LED area lights significantly improved visual performance for the detection of hazards found in the peripheral field of view, as well as those found on the ground. They furthermore, indicate that age plays a significant role in visual performance.

Jan 1, 2009

By Joan C. Biordi

The Bureau of Mines used molecular beam-mass spectrometry to determine the microstructure of a 10.1% CH4-2l.2% 02-67.6% Ar-1.1% CF3Br inhibited flame and its uninhibited analog, both stabilized at 32 torr on a cooled flat-flame burner. Composition profiles of atomic, radical, and stable species and temperature profiles for both flames were obtained and compared. Kinetic analyses of the profiles yielded values for the rate coefficients of several elementary methane flame reactions and information on the reactions of formation and decay of the observed halocarbon species. CF3Br is judged to decay by thermal decomposition as well as by abstraction reactions, and the fluorocarbon chemistry occurring in the inhibited flame is due primarily to CF2 radical reactions. Rate coefficients and mechanisms for reactions of the inhibitor-related species are given.

Jan 1, 1978

By E. G. King

Heats of formation of three crystalline oxides of rhenium (Re02, ReO3 and Re207) have been determined by the method of solution calorimetry, using an aqueous perchloric acid--ceric perchlorate solvent. Copper metal and cupric oxide were utilized as auxiliary substances. Heats were determined at 298' K for the reactions Re + 2CuO = Re02 + 2Cu, Re + 3CuO = ReO3 + 3Cu, and 2Re + 7CuO = Re207 + 7Cu. Standard heats of formation were derived using the value of -37.23 ±0,15 kcal/mole as the heat of formation of CuO. The standard molal heats of formation of the rhenium oxides were determined: Re02, -107.3 ±0.8 kcal; ReO3, -140.8 ±0.9 kcal; and Re207, -301.9 ±1.8 kcal.

Jan 1, 1969

By J. T. McCartney

Thin sections of coal have been prepared for many years either by cutting on a microtome (1,2)5 or by grinding and polishing (2,1). Specimens of most coals had to be demineralized in hydrofluoric acid and softened in caustic solutions before they could be successfully cut with a conventional microtome. Some lignites could be cut without pretreatment. Jeffrey (1) obtained sections from coals of all ranks, although long and tedious pretreatment was required for anthracite. His sections were less than 1 cm.2 in area (probably much less for high rank coals) and about 5 microns thick. Thiessen (2) also cut sections of softened coals, mostly of low rank. His sections were a few square millimeters in area and about 3 microns thick. However, Thiessen preferred ground and polished sections for detailed studies because they were larger and had not been chemically attacked by softening media. He prepared ground sections as large as 4 cm.2 in area and usually 5 to 10 microns thick. Thousands of such sections, covering complete column samples of many coal beds, were studied for a number of years (4). With the development of the electron microscope and increased interest in quantitative optical studies of coals, a need for much thinner sections arose. However, no suitable technique for preparing such sections was known until Fernández-Morán developed a diamond knife for cutting ultrathin sections of hard materials (5). Workers at the Centre d'Etudes et Recherches de Charbonnages de France applied this new tool to the cutting of coal sections and have recently described their technique to the Burg, of Mines. Using their methods, with some modifications, researchers of the Bureau of Mines have succeeded in cutting ultrathin sections of coals ranging in rank from lignite to

Jan 1, 1961

By T. G. Carnahan

The Federal Bureau of Mines investigated, on a laboratory scale, a technique for recovery of silver from pregnant solutions generated in the hydro-metallurgical treatment of complex base-metal sulfide concentrates with oxidizing chloride media. This technique provides a means for recovery and simplified reduction of accessory silver to metal from chloride solutions. The method consists of adding NaI or KI to the solution to precipitate AgI, which is then contacted with Na2S to produce Ag2S and to regenerate the iodide salt solution. Silver recoveries range from 99 pct with 20 pct excess iodide precipitant, to 92 pct when the theoretical stoichiometric amount of precipitant is employed. The Ag2S product can be reduced to silver metal by contact with aluminum chips in NaOH solution followed by purification with conventional fire refining techniques.

Jan 1, 1980

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

APPENDIX E EQUIPMENT USED FOR FIELD TESTING OF MINE SEALING SYSTEM I. Drilling Operation - Equipment supplied by local drilling contractor 1. Mobile drill rig. 2. Flat bed truck, containing 20 lengths of drill pipe. 3. Auxiliary compressor. 4. Pickup truck for small parts and supply of diesel fuel. 5. Bulldozer. 6. Water supply, in this case the nearby stream. 7. Supply of casing, positioned next to the drill rig. 8. Ready mixed cement grout. 9. Drill bits, stabilizer units, cutting and welding equipment, other miscellaneous tools and supplies. II. Sonar Probing Operation 1. 25 foot tower with pulley mounted atop. - FMA 2. Electric winch with 100 feet of 1/4-inch cable, Model No. 100A, City Engineering Co. , Indianapolis, Indiana. 3. 400 feet of 1-1/2-inch-diameter aluminum pipe with alignment holes and coupling grooves. - FMA*

Jan 1, 1973

By R. V. Ramani, J. Qin

"In this paper, the results of a research study on airborne dust transport in a full scale simulated longwall face are presented. The simulated longwall face was set up in the Lake Lynn Laboratory mine of the U.S. Bureau of Mines to conduct experiments under controlled conditions. The controlled parameters in the experiments were the dust dispersion rate, dust size distribution, density of the dust, air velocity, and the rate of travel of the dust generating source. The analyses of the experimental results on mass concentrations, particle size distributions, and real-time respirable dust concentrations are discussed. There are definite spatio-temporal trends between the location of the shearer, the concentration at any location in the face, and the dust generation rates. The size-consist and density characteristics of the source dust, the air velocity in the face, and the air leakage into the gobs all affect the concentration. INTRODUCTIONA detailed experimental study on the characteristics of longwall dust cloud in operating longwall faces has been reported by Ramani, Qin, and Jankowski (1991). The study indicated that there are several important factors whose effects on dust transport in longwall faces need to be further investigated. In an operating longwall face, the effect of these parameters could not be easily isolated as control over the affecting parameters is not readily possible. In a simulated longwall face, however, these parameters can be controlled. Therefore, as a follow-up to the field study, a series of controlled experiments were conducted in a full scale simulated longwall face in the Lake Lynn Laboratory mine of the U.S. Bureau of Mines [Qin, 1992]. Specific aspects which were addressed during the experimental design phase included determining the types of samples to be collected, selecting proper instruments to collect these samples, and developing detailed sampling and time-study plans to correlate the dust concentrations with face activities. Two types of dust--anthracite and bituminous--were used. Dust dispersion rate into the air as well as the source dust particle size distribution were documented. Control was exercised over both air velocity at the face and air leakage along the longwall face. During experiments, the dust source was moved to simulate the shearer movement at operating longwall faces. Detailed descriptions of the design of experiments, experimental results, and data analyses follow in the subsequent sections."

Dec 1, 1996

By Bruce D. Hanson

The Bureau of Mines conducted a series of experiments using four different coal types to determine the effect of attack angle and symmetric bit wear on airborne respirable dust (ARD) generated by point-attack bits and in energy consumption. Neither had a significant effect on ARD at the 95-pct confidence level, but bit wear had a significant effect (95 pct confidence) on specific energy (energy per gram of cut coal) for three coal types, Depth of cut was the most significant factor affecting ARD and specific energy.

Jan 1, 1979

By W. W. Weller

Heat-capacity measurements of sodium dimolybdate (Na2Mo207) and sodium ditungstate (Na2W207) were conducted over the temperature range from 51° to 298° K. The entropies of the two compounds at 298.15° K were calculated from the heat-capacity values and were used, in conjunction with other entropy data, to evaluate the entropies of formation of the compounds from their constituent elements and oxides.

Jan 1, 1963

By W. S. Sanner

Grinding experiments were conducted to determine the finest anthracite particles that could be produced in a ball mill. Continuous and batch tests were run in a dry-grinding ball mill. Batch grinding produced the finest coal particles. They averaged 2.2 microns in diameter and were 99.0 percent smaller than 37 microns. Continuous grinding yielded a product 6.1 microns in diameter, with 96 percent smaller than 37 microns.

Jan 1, 1968

By Seth C. Schaefer

The Bureau of Mines investigated thermodynamic properties of Mn304 (manganomanganic oxide) and Mn203 (manganese sesquioxide). The standard Gibbs energies of formation (?Gf°) of Mn304 and Mn203 from their lower oxides were determined with high-temperature galvanic cells using stabilized Zr02 (zirconia) as the electrolyte. Potential measurements were obtained for the cell Pt, MnO, Mn304//Zr0 2//02(g, 0.0112 atm), Pt, with the overall cell reaction 6Mn0(c) + 02(g, 0.0112 atm) = 2Mn304(c), where- 02 refers to indicated partial pressure of oxygen at the reference electrode. Similar measurements were obtained for the cell Pt, Mn304, Mn203//ZrO2//02(g, 0.0115 atm), Pt, with the overall cell reaction 4Mn304(c) + 02(g, 0.0115 atm) = 6Mn203(c). Equilibrium oxygen pressures for the Mn0-Mn304-02 and Mn304-Mn203-02 systems were measured and may be expressed for the respective systems as [23,400 109 P02 T + 11.91 (764.9 - 1,208.6 K) and log p02 = - 11,957 + 9.66 T (968.6 - 1,208.2 K),] where pressure (p02) is in atmospheres and temperature (T) is in kelvins. Standard thermodynamic properties of Mn304 and Mn203 were derived from these measurements and auxiliary thermodynamic data from the literature.

Jan 1, 1982

By L. W. Brandt

As part of its objective to expand the body of mineral information as a basis for new technology, the Bureau of Mines conducted research on the fundamental behavior exhibited by phosphate clay waste in settling ponds. A semiempirical equation used to describe the compaction of ceramic powders in a single-acting die was applied to aqueous phosphatic clay waste and attapulgite slurries. This equation, [*V = a1 e ?k1/P + a2e ? k2/P] was found to describe the compaction of an attapulgite gel and a phosphate slime gel by a moving screen. [*V] is the ratio of the compaction achieved at a given pressure, P, to the compaction achieved at a pres-sure sufficient to remove all space between particles. The constant al represents the fraction of compaction achieved at low pressure by rearrangement of floes to higher packing density, and a2 represents the fraction of compaction achieved at higher pressure resulting from removal of voids within floes. K1 and K2 are constants determined from the experimental data. Both the low-pressure and high-pressure compaction mechanisms were observed in the compaction of the clays. These two compaction mechanisms offer an explanation for the observation that impounded slimes initially dewater rapidly and then dewater at a much slower rate.

Jan 1, 1982

By R. F. Abernethy

A chemical method of determining microgram quantities of arsenic in coal was investigated by the Bureau of Mines to supplement a semiquantitative spectrographic method of determining arsenic in coal ash. In accordance with a method recommended by the International Organization for Standardization, 1-gram samples of coal are decomposed by wet oxidation with boiling sulfuric acid (H2S04) and nitric acid (HN03) to remove the organic matter. After heating to fumes of SO3 to remove HN03, the arsenic is separated as arsine by the action of zinc in H2S04 solution. The arsine is absorbed in dilute iodine solution in which the arsenic is determined colorimetrically by the molybdenum-blue reaction. Two modifications of the method for obtaining the arsenic in solution, in addition to the wet oxidation method, give satisfactory results. The modifications are (1) furnace ashing with MgO added to the coal, followed by treatment with H2S04, and (2) extraction of arsenic from the coal by dilute HNO3 without ashing. Float-and sink-tests show that arsenic is associated mainly with mineral matter in the three coals examined. High-temperature ashing tests show that very little arsenic is volatilized from coal ash below 1,000° C, but it is virtually all removed from the ash at 1,300° C.

Jan 1, 1968

By J. H. East

Potash is one of the essential chemicals used in fertilizing soil deficient in natural minerals . Europe uses a large tonnage of potash in the form of easily soluble salts , and this is particularly true of those countries where the natural minerals in the soil have been exhausted owing to intensive cropping of the land . The application of potash to the soil in these countries is essential if normal crops are to be obtained ; during the war , some European countries were unable to obtain sufficient potash , and productivity of the farming areas declined seriously . • The largest -known deposits of potash in the world ; with the possible. exception of Russia , occur in Germany , and the German output of processed salts constituted about 65 percent of world production prior to the war . The German potash-plant installations are large , modern , brick and steel construction and apparently built for a planned operation of many years . Two districts produced approximately 80 percent of the German potash; the Werra -Fulda district , near Vacha , had the largest production , and the Sudharz district , near Nordhausen and Sonderhausen , was second . (Fig . 1. ) Hannover and Stassfurt were two smaller producers . Potash fertilizers are rated in terms of potassium oxide (K20 ) . The usual basis for calculation of production or application of the salt is to reduce the potash content to 40 percent K₂0 .

May 1, 1947

By Larry J. Nicks

The Bureau of Mines is investigating the catalytic activity of rare-earth compounds to develop a catalyst for the cathode reaction of a hydrogen-oxygen fuel cell. This report presents the results of studies of the catalytic activities of lanthanide oxides for the oxidation of hydrogen at 150° to 250° C. Preliminary activity tests were made with approximately stoichiometric mixtures of hydrogen and oxygen diluted with helium. A series of tests was also run under oxygen-rich conditions in which specific rate constants and activation energies were determined. Variations in rate constants up to 2,000 times were observed for the various lanthanide oxides. The three most active catalysts were oxides of Ce, Pr, and Eu, having specific activities of 6.93 X 10-7, 4.88 X 10-7, and 4.06 X 10-7 moles H2.sec-1.m-2, respectively, at 200° C.

Jan 1, 1973

By L. C. IlsLey, E. J. Gleim, F. CRAVEN

Electrical apparatus and circuits began to be used in mines about 50 years ago. A search of the literature on mining reveals that in 1882, umping was being done by electricity in some aines of England. One account tells of a small electric locomotive being used in 1882 "to drive eight corves loaded with coal" in a mine near Dresden. In an account of his visit to some English mines, en American in 1892 mentions that he saw underground electric signals, lights, pumps, hoists, and one revolving- cutter-bar 19wall mining machine,. Among the carl electrical installa- tions in the United States was an electric locomotive in the Lykens Valley Coal Co. mine at Lykens Valley, Pa., in 1887. In 1889 the Sperry electric coal digger was being tried out. Tarce mining machines were placed in the Prospect mine, East Palestine, Ohio, in 1890. An electrical pumping plant was put in oneration during 1892 in the Woodward mine of the Delaware, Lacka- rahma & Western Railroad Co. Thus we Almost coincident with the proposed use of this new servant in under- ground workings, came the thought of making it safe in gassy mines. find an account of a design for a protected stationary electric mine lamp proposed by Edison in 1831. Enclosed-type motors rere developed in the United States and shiped to English collieries about 1903. From those early beginnings there has been continuous progress until to-day one finds hundreds of pieces of specially designed electrical apparatus distributed in American coal mines and in mines of nearly all important coal-producing countries. Along with introduction of this equipment grew the idea of the necessi- ty of government aid, in standardization. In most coal-mining countries to- day the governments either directly or indirectly have a considerable in- fluence in guiding the design of electrical equipment intended for use in Pasay mine

Jan 1, 1933

By J. S. Tosh

An equilibrium study of the system potassium carbonate, potassium bicarbonate, carbon dioxide, and water has been conducted with solutions of 20-, 30-, and 40-percent equivalent potassium carboaate concentrations. These equilibrium data cover the operating range of the hot carbonate scrubbing system for removing carbon dioxide from gas mixtures. Such data are necessary to establish the limits of purification and are used to design absorption and regeneration towers. Values of K in the relationship K = (KHCO3)2/(K2CO3)PCO2 were determined for higher temperatures of 70" to 140° C. and greater concentrations, I 20 to 40 percent, than employed by previous investigators. For the 20- and 30-percent concentrations, K is constant at a given temperature; thus, once K has been determined the equilibrium pressure of carbon dioxide can be calculated for any conversion. Variation of & values with changing conversion was observed with the 40-percent solutions, so that equilibrium calculated pressures are less reliable from average K values.

Jan 1, 1959

By D. J. MacDonald

The Bureau of Mines has carried out investigations on a method for producing zirconyl sulfate solution from zircon sand, comprising (1) reacting zircon sand with molten NaOH, (2) leaching the resultant fusion frit with water to remove sodium silicate and to convert sodium zircon-ate to hydrous zirconium oxide, and (3) leaching the hydrous zirconium oxide from unreacted sand with hot, dilute H2S04 to produce crude zirconyl sulfate solution. The following conditions were found to be suitable: reacting 0.6 kg of NaOH per kilogram of zircon sand for 10 min at 600° C; leaching the frit with 3 to 4 liters of water per kilogram of solids; leaching the residue with 5.1 liters of water and 1.25 liters of 98-pct H2S04 per kilogram of original solids for 10 min at 90° C; and filtering or decanting to recover unreacted zircon sand. A preliminary cost estimate is included.

Jan 1, 1982

By P. R. Bremner

In keeping with its mission to maximize mineral and metal recovery from domestic sources, the Bureau of Mines investigated a method to extract silver from tailings not amenable to cyanidation. Results of a laboratory study on the recovery of silver from cyanide tailings containing 1.7 ounces of silver per ton by leaching with an acidic ferrous chloride-sodium chloride solution are presented. The effects of reagent concentration and reaction time on the leaching of silver were investigated. A leaching solution containing 5 wt-pct NaCI, 2.5 wt-pct FeCI2, and 1.2 wt-pct HCI (for acidity) extracted 82 pct of the silver from the tailings during a 24-hour leach. The amount of HCI consumed during the leach was 46 pounds of HCI per ton of feed. Only 23 pct of the silver was extracted by conventional cyanidation. Ninety-nine percent of the silver was recovered from the pregnant solution by cementation onto iron powder.

Jan 1, 1982

By P. R. Bremner

The United States is more than 90 pct dependent on imported bauxite a source for aluminum, but it has vast nonbauxitic aluminum resources, such as kaolinite, anorthosite, alunite, etc. As part of a program to devise processes for treating these resources, the Bureau of Mines investigated a bench-scale leaching process using hydrochloric acid (HC1) and fluoride to extract aluminum from Wyoming anorthosite. HC1 and fluoride-to-aluminum (F/Al) mole ratios were studied with respect to aluminum extraction for single-stage, cocurrent, and countercurrent leaching modes. Using 95 pct stoichiometric HC1 and a F/Al mole ratio of 0.27, 90 pct of the aluminum was extracted by countercurrent leaching. Single-stage leaching with the same amount of acid and fluoride extracted 48 pct of the aluminum. Three fluoride sources, CaF2, Na2SiF6, and H2SiF6, were used and gave similar results on aluminum extractions.

Jan 1, 1982