Search Documents

By V. C. Petersen

The titanium-rich end of the titanium-germanium system was investigated by x-ray and metallographic methods and verified by resistivity and dilatometer measurements. A constitution diagram is proposed. The titanium-rich portion of the phase diagram is characterized by eutectic and peritectic reactions. The eutectic composition is 19 percent germanium, and the eutectic temperature 1,360° C. The peritectic reaction occurs at 905° C. and 4 percent germanium. Germanium is soluble in alpha titanium to a maximum of 4 percent at 905° C. and in beta titanium to a maximum of 12.5 percent at 1,360° C. Both limits of solubility decrease with decreasing temperatures. Although substantial quantities of germanium are soluble in beta titanium, beta is not retained on quenching. The beta phase probably transforms to alpha by a martensitic reaction.

Jan 1, 1957

By R. V. Ramani, A. S. C. Owili-eger

A mass balance equation can be written for the unit block of Figure 7 for changes within the volume during time At as: [ ] where x and y are the coordinates; q is the flow across any surface; p is the density of the fluid flowing through the medium; qvol is the volumetric flowrate; @ is the medium porosity; and Ax and Ay are the dimensions of the block. The subscripts t and (t+At) denote time levels and At is the change in time. Writing this equation in nota- tional form and on rearranging, the following expression is obtained:

Jan 1, 1974

1. In 2001, a total of 7,131 sand and gravel mining operations reported employment statistics to the Mine Safety and Health Administration (MSHA). Sand and gravel mines comprised 48.8% of all mining operations, the largest percentage of all mining sectors. Sand and gravel mines are distributed throughout all 50 states. The median number of operator employees per sand and gravel mine was 3.0.

Jul 1, 2003

By Robert W. Ageton

The Bureau of Mines is currently conducting a comprehensive study to evaluate all aspects of recovering gold from large, low-grade deposits in the Golden Sunlight area, Whitehall mining district, Jefferson County, Mont. Prior to World War II this area produced significant quantities of gold. The study includes geologic mapping, diamond drilling, assaying, computer analysis of assay data, metallurgical research and ore testing, mine and mill planning, and an economic evaluation of all factors bearing on the establishment of a producing gold mine. Preliminary evaluation of the deposit indicates about 31 million tons of submarginal gold resources. American Exploration and Mining Co. (AMEX) has assisted the Bureau in this project by providing drill site preparation, control assays, and geological aid for the Bureau's exploration work and by furnishing comprehensive assay information of the property and copies of base and geologic maps. This report presents the geology and mining history of the area, together with a summary of Bureau work in progress.

Jan 1, 1969

By W. C. Phalen

"Tho the term “magnesite” is generally applied to the iron-bearing carbonate of magnesium, such as is found in Austria and Hungary, by some Austrian magnesite is referred to as bruennerite. The mineral bruennerite has become of commercial importance only in Austria. The important deposits are found in Styria, lower Austria and northern Hungary. It is of interest to know that the world's largest deposit of spathic iron ores or iron carbonate (FeCO3), occurs at Eisenerz, Styria, while the world's largest deposit of spathic bruennerite is found at Veitsch in the same province.The Styrian and lower Austrian deposits are located much nearer the Adriatic sea than are the deposits of northern Hungary; and it is from the former that most of the exported magnesite has come. They are located south-west of Vienna, and extend west from Semmering thru the Murz Valley to Tyrol. The chief deposits reckoning from east to west are those of Semmering, Veitsch, Breitenau, Trieben, Radenthein, and Dienten.The largest and most important deposit is that at Veitsch located near Mitterdorf, on the South Austrian railroad in the Murz Valley, Styria. Here the magnesite, which occurs in the form of a lens is quarried on the slope of a hill in a series of terraces about 50 feet apart. The entire work extends thru a vertical distance of 500 feet. The huge magnesite lens is nearly 4 of a mile long and over 1,000 feet in width, and probably extends to a considerable depth.The formation containing the magnesite extends eastward beyond Vienna into Northern Hungary where magnesite is quarried beyond Jolsva and Nyustya in the Gomor district. In spite of the remote location of these deposits as compared with those in Styria, magnesite was shipped from them before the war a distance of 360 miles to the port of Fiume for overseas shipments to other parts of Europe and to America.The average analysis showing the composition of the Austria-Hungary mineral is as follows:The magnesite occurs as lenticular masses in a belt of Carboniferous rocks consisting mainly of metamorphosed Shales, sandstones, conglomerates,,and limestone, It is grayish in color when fresh, and contains sufficient ferrous carbonate to blacken it when calcined. It turns brown owing to the oxide ion of the ferrous carbonate when exposed to the air. The quantity of carbonate of iron is ariable and different analyses show that it ranges up to 13 or 14%For the most part, only the sintered article has been imported into The United States. This material has achieved an enviable reputation for its uniformity both as to chemical and physical characteristics. The homogeneity of the sintered Austrian magnesite is doubtless due in part to the averaging effect of the different operations, such as crushing, dressing, sintering, And mixing, n effect which is not obtainable in mere hand samples.There is comparatively little variability in the sintered magnesite as marketed, and five analyses of this sintered magnesite as quoted by Cornu* are gas follows:"

Aug 1, 1919

Roof screening for ground control originated with metal miners in the western United States. At first chain-link fence was used, but because it was so difficult to handle, the miners started installing a more rigid welded wire screen used in the concrete industry. Eventually coal mines in the west began to use screen, and now more and more coal operations, especially longwall mines, are installing roof screen on a regular basis. Screen use has recently increased in the Illinois basin and is now making its way to underground coal mines in the eastern U.S.

By B. Dimitriades

Data on smog-forming reactivities of exhaust aldehydes are scarce. Such data were obtained by irradiating in a smog chamber typical exhaust aldehydes, individually and in exhaustlike mixtures. Observed reactivity manifestations were rate of nitrogen dioxide formation (RNO2) and yields of oxidant, peroxyacetyl nitrate, and formaldehyde. Results showed that exhaust aldehydes vary widely in reactivity. Formaldehyde showed high RNO2 reactivity but low oxidant yield; benzaldehyde, [m]-, and [p]-tolualdehyde were totally unreactive when irradiated individually; [o]-tolualdehyde was reactive. In mixtures, benzaldehyde manifested reactivity in terms of peroxybenzoyl nitrate yield. Exhaust aldehydes as a group are judged to be as reactive as the exhaust olefin group. The importance of the aldehyde contribution to exhaust reactivity and methods for assessing such contribution are discussed.

Jan 1, 1971

By A. S. Prokopovitsh

A spectrophotometric method for the determination of small amounts of copper in tungsten metal powder using the principle of solvent extraction has been developed by the Federal Bureau of Mines. The metallic sample is dissolved in hydrogen peroxide, tartaric acid added, the pH adjusted, and the excess peroxide destroyed by boiling. Copper is reduced to the cuprous state, and the reagent neocuproine (2,9-dimethy1-1,10-phenanthroline) is added to form a colored complex with the copper. This colored complex is then extracted into chloroform and the absorbance of the separated chloroform layer measured on a spectrophotometer. Copper contents as low as 1 p.p.m. (parts per million) can be determined. The method is limited to finely divided tungsten powder. The interest of the Bureau of Mines in developing more sensitive methods for the determination of trace impurities in high-purity tungsten prompted an investigation of the possibility of using solvent extraction-colorimetric methods. The organic reagents now commercially available make possible many extremely sensitive colorimetric methods for the determination of metallic ions. Extraction of the colored complex into a small volume of organic phase can be used to further increase sensitivity (4) .4/ This general approach has the added advantage that no special equipment beyond that normally found in an analytical laboratory is required.

Jan 1, 1961

By Paul R. Coyle, Anthony T. Iannacchione

A close look at the Loyalhanna Limestone of southwestern Pennsylvania reveals a complex structural environment. Most exposures of the Loyalhanna occur along Chestnut Ridge and LaurelHill within the Allegheny Mountain Section of the Appalachian Plateaus Province. Because the Loyalhanna is rated as a super-pavement aggregate by the Pennsylvania Department of Transportation and because of its proximity to the population centers of southwestern Pennsylvania, the Loyalhanna has been extensively mined along these prominent anticlinal structures. Geologic and engineering analyses were performed using gas well and core logs, outcrop examinations, underground observations, and mine maps. Strata exposures from both outcrops and quarries were used to construct geologic maps, stereo net, and rose diagram projections so that the Loyalhanna’s structural environment could be understood better. Many of these structural conditions cause ground control problems at local quarries. These problems ranged from small-to-moderate sized rock falls associated with roof jointing to pillar failures associated with dipping discontinuities. Stresses ranged from tensional on structural domes where weathering dominates, to high levels of compression within structural saddles. A greater understanding of these characteristics is a prerequisite to develop engineering controls, such as improved mine layouts, pillar sizes, etc., that lessen miner exposure to these hazards.

By M. M. Wong

A brief investigation was made to determine the feasibility of electro-refining beryllium in a KCI-LiCI-BeC12 bath. Thin, platelike crystals of beryllium metal were produced by electrolyzing technical-grade beryllium metal beads (about 94-percent purity) as the soluble anode. Operating cell conditions were: Temperatures of 450° to 600° C.; an inert atmosphere; bath compositions of (1) 38.1 mol. percent KC1, 54.8 mol. percent LiCl, and 7.1 mol. percent BeC12 and (2) 36.7 mol. percent KC1, 52.7 mol. percent LiCl, and 10.6 mol. percent BeC12; cell voltages of 0.30 to 0.80; and initial cathode current densities of 50 to 435 a./sq, ft. Current efficiencies ranging from 87 to 96 percent were obtained. Qualitative spectrographic analyses of the metal products indicated that impurities were reduced. This technique offers the possibility of producing a grade of beryllium purer than that now generally available, which may have better mechanical properties.

Jan 1, 1960

By Everett A. Sondreal

Data are presented on the characteristics of lignites with emphasis on the composition and fusion properties of the ash. Differences in the analyses of commercial-grade lignites are related primarily to variations in moisture and ash contents. Lignite ash is generally characterized by high concentra¬tions of alkaline earth oxides and a greater tendency for retention of sulfur in the ash than higher-rank coals. Composition of ash varies significantly within and between mines. The differences within mines are significant for short distances and may be eliminated under certain circumstances by normal mixing occurring during mining. The sulfur in lignite averages 0.6 percent and is found primarily in the organic or pyritic forms with only a trace of the sulfate. During the stan¬dard laboratory asking procedures, from 60 to 100 percent of the original sul¬fur is retained in the lignite ash. Trace elements, such as uranium and germanium, in the ash from commercial¬-grade lignites are present in low concentrations, but others, primarily copper and silver, are present in specific samples in concentrations approaching those found in some commercial ores.

Jan 1, 1968

A prototype EM Location System was fabricated and tested at the Geneva Mine near Dragerton, Utah. This system consisted of six manpack transmitters and six manpack receivers covering the frequency band from 900 Hz to 2900 Hz as well as a six channel receiver designed for use in a helicopter. Tests showed that EM signals from lightweight (314 lb) transmitters could be detected both on the surface and from a helicopter through -2 as much as 1650 ft of relatively high conductivity (2 X 10 mhos/m) over- burden. Furthermore, the resulting field strength profiles could be used to determine source location to within 150 ft of the actual surveyed location in the mine. Modifications were made to a Monitoring, Locating and Communications System being tested at the Bruceton Mine, Pittsburgh, Pennsylvania. These modifications have improved the performance and quality of the paging and voice telephony mode of the system. Subsurface receiver modifications have improved reception of voice downlink signals.

Jan 7, 1973

By Elaine T. Cullen, Albert H. Fein

Federal law mandates that all miners receive safety and health training when first entering the mining industry and at least 8 hours annually thereafter. Although the mining industry has historically relied on an experiential master-apprentice model for training new employees, the formal safety training provided to miners is generally done in a classroom, with mixed results. In a series of stakeholder meetings held by NIOSH across the West in 1997-2000, trainers identified significant gaps in materials that were available to teach new and experienced miners. They asked whether NIOSH could develop effective materials to fill these perceived gaps, as well as make training more effective for those who were required to attend, but who often refused to be attentive. Adult learning theories, social learning theories, mentoring, and storytelling were all employed in the development of a series of safety training videos that have become very popular in the mining industry. This Report of Investigations describes the theoretical frameworks that were used, the process that was developed to produce the videos, and the results of the evaluations as to whether or not they were effective in training new and experienced miners.

Jan 8, 2005

By Brian G. White

Two examples of en echelon mining-induced fractures seen in hard-rock mines provided a basis for inferring that fracture zones and bedding plane separations immediately surrounding mine openings are promoted by oblique shear into the openings. It is hypothesized that initial fractures or separations form at the corners of openings as a result of high stress and physical constraint on the rock's ability to deform elastically toward the opening. These conditions result in a locally preferred direction of shearing. The shearing, in turn, generates tensile stress that initiates a progression of systematically offset fractures approximately parallel to the direction of greatest compressive stress. The fractures or bedding separations create tabular rock layers that amplify shearing displacement through bending and dilation. Such shearing effectively reduces and redistributes the compressive stress, but significant dilation is an inevitable consequence. The combination of dilation and shearing and the progressive development of fracture zones have important implications with respect to ground support. The concept of mining-induced fractures forming as a result of shear is illustrated by two examples from coal mines. First, fractures seen at longwall faces probably result from shear associated with subsidence. The fracture zone that develops approximates or possibly defines the draw angle of subsidence. As the face advances, fractures extend downward along the lower edge of the fracture zone, while upper extensions of the fractures are pressed closed. Fracture zones in entry roofs provide a second practical example. Here, mining-induced fractures typically follow bedding planes. The shear zone model suggests that the first bedding separations develop near the edges of the roof and successive separations progress upward and toward the center. However, if the direction of greatest stress is inclined with respect to the roof, a fracture or bedding separation zone may propagate from one side only and also extend higher. Because coal ahead of the face provides some support against lateral shear deformation, bedding separation is inhibited near the face. Rock bolts installed close to the face ultimately become more strained and bent than bolts installed a few meters from the face, and bolts installed through the more remote part of a separation zone may ultimately experience the greatest tensile and bending strains. This model is supported by field data documenting progressive bolt failures that rapidly propagated downward across the roof during face advance.

By C. Ortuglio

The effect of cracking by increasing the free space above the charge on the composition and yields of the volatile products from carbonization of Pittsburgh-bed coal and one industrially used blend from Eastern United States and one from Western United States was investigated with the BM-AGA carbonization apparatus. Increasing the free space above the charge from 1 inch to 3 inches, to 6 inches, and to 9 inches resulted in lower tar yields and increased gas and light oil yields. Anthracene and naphthalene yields were increased; quinoline and benzene insoluble fractions of both the tar and pitch increased considerably with increased free space, although the carbon content of the tars and pitches increased only slightly. Increased cracking, occasioned by the increase in free space, resulted in a decrease in the yields of tar acids, tar bases, neutral oils, olefins, aromatics, and paraffins and naphthenes. Gas composition was relatively constant; hydrogen and methane tended to increase and ethane decrease. Results of the investigation are being used to design a unit to upgrade the volatile products of carbonization by cracking the hot products as they leave the carbonization chamber.

Jan 1, 1970

By L. B. Pankratz

High-temperature heat-content values of gallium and scandium sesquioxides were measured over the temperature range from 298° to 1,800° K. The results fill gaps in the thermodynamic information for these compounds; no previous similar data existed. The heat-content values were combined with heats and entropies of formation to obtain free energies of formation of gallium and scandium sesquioxides to 2,000° K. The thermodynamic stabilities of the sesquioxides of aluminum, gallium, scandim, and yttrium were compared.

Jan 1, 1963

This surveillance report summarizes data on work-related fatal and nonfatal injuries, illnesses, and hazardous exposures in the mining industry for the 10-year period 1986-1995. The term ?surveillance,? as used in public health, may be new to many readers of this report. With regard to occupational safety and health, the goal of surveillance is to describe the occurrence of work-related injuries, illnesses, and known hazardous exposures; to identify new hazards that may occur due to the introduction of new technology or other factors; and to assess the effects of preventive measures designed to improve worker safety and health. Surveillance provides an overall picture, which can be used to focus resources on areas most in need of prevention programs or further research. Surveillance generally requires the use of multiple sources of data, all of which have their own strengths and limitations. Surveillance in the U.S. mining industry is complicated by the fact that U.S. national data systems that provide information on mining are based on two different definitions of the mining industry. One is established by the Mine Safety and Health Administration (MSHA), the other by the Standard Industrial Classification (SIC) System [Office of Management and Budget 1987] and the 1980 U.S. Bureau of the Census (BOC) Classification System [U.S. Bureau of the Census 1982].

Jan 1, 2000

By John W. Buch

"INTRODUCTION The Ruhr coal basin is estimated to cover an area of more than 1,000 square miles. Here, the total thickness of the coal bearing formation (Carboniferous) is 10,500 feet, and drilling-hole have revealed 92 coal beds with a total thickness of 262 feet. 6/ Beds pitch from 0 to 90 degrees and about 70 percent of the wartime production came from beds that pitched less than 30 decrees. 5/For example at the Minisiter Stein mine, there are 24 minable coal beds ranging from 80 centimeters. (2 ft., 7 1/2 in.) to 250 centimeters (8 2 1/2 in.). The vertical thickness of the measures is 1,000 meters (3,200 ft.), and at this mine the deposits are covered with 150 meters (500 ft.) of surface wash. The cross section (fig, 1) at Fritz mine; Hoesch, A.G., Essen, Ruhr, is characteristic, The mines have been developed and worked to vertical depths of 2,000 to 2,500 feet by vertical shafts; main-level intervals are 500 to 700 feet apart. Haulage roads are straight, driven in rock, and centered as nearly as practical between property boundaries. Levels are sectionalized by driving crosscuts at right angles to the main haulage road on 800- to 900-foot centers. The roads are the main transportation arteries for the use of trolley or Diesel locomotives. A plan of the sixth main level (fig. 2) at the Bruchstrasse mine; Gelsenkirchener A.G., Bochum, illustrates main-level development and,sectionalizing with crosscuts. The cross section in figure 3 is that of the fourth crosscut west at the same mine."

Oct 1, 1946

By John Ward Smith

Methods for estimating the amounts of nahcolite, dawsonite, and the sum of these two sodium carbonate minerals from oil-yield assay data are developed and evaluated for Green River Formation oil shales from the saline section of Colorado's Piceance Creek Basin. Derived statistically, these estimation methods depend on the fact that these minerals yield water and gas measured during oil-yield assay. The estimation procedures yield values for nahcolite and nahcolite-plus-dawsonite of sufficient accuracy for stratigraphic plotting and correlation, whereas estimates for dawsonite are more generalized. However, resource estimates and reserve computations for both nahcolite and dawsonite accurate within 10 percent of the real value are readily available by summing the mineral amounts calculated by the procedures presented. These estimation procedures are applicable to oil-yield assay data on core samples from more than 30 coreholes which have penetrated the saline section of the Green River Formation in Colorado.

Jan 1, 1972

By T. A. Lang

The objective was to develop a Program Plan of analytical studies and tests for determining (1) the optimum installation tension of a coal mine roof bolt, (2) the most valid bolt support theory or theories, and (3) the most valid roof failure theory or theories. On this basis a comprehensive literature search was made and significant material dealing with coal mine roof behavior, roof bolting and roof support was collected, reviewed, classified and analyzed. Emphasis was given to the influence of rock reinforcement on the control of deformation, stress field modification and mine roof stability. An assessment was made of the effect of various parameters including bolt tension, bolt pattern and time of installation, on the effectiveness of rock reinforcement systems, and equations developed for bolt tension as a function of these parameters, and rock properties. From these studies, a major program plan of tests and studies was developed for verifying and validating the most tenable theories of roof behavior and roof support and for determining optimum bolt installation tension.

Jan 1, 1979