Search Documents

By D. H. Baker

These investigations were conducted to determine the feasibility of molten salt electrorefining of zirconium scrap, offgrade sponge, and alloys under contract number AT(11-1)-475 between the Atomic Energy Commission and the Federal Bureau of Mines. Offgrade zirconium sponge having a Brinell hardness of 169 can be refined by this technique to produce metal having, consistently, a Brinell hardness of less than 90. Also, zirconium alloy scrap, approximating zircaloy-2 in composition, can be refined to recover zirconium metal with a Brinell hardness of less than 100 that is essentially free of the major alloying elements. Analysis showed that the quantities of these elements were decreased as follows: iron from 0.27 to 0.002, tin from 1.36 to 0.001, nickel from 0.02 to 0.001, and chromium from 0.12 to 0.002 percent.

Jan 1, 1961

By M. Howard Berliner

During the spring of 1944, the Bureau of Mines investigated the Crescent mine area near the village of Rewey, Iowa County, Wis., as part of a general investigation of the zinc-producing area of southwestern Wisconsin. The work was done when every effort was being made to increase the production of metals important to the Nation's war program. The Bureau of Mines completed 24 churn-drill holes in an area immediately to the west of a mineralized section which had been mined through shallow workings for lead and zinc more than 40 years earlier.

Jan 1, 1948

By J. S. Hansen

The U.S. Bureau of Mines developed a system for casting unique, slotted steel armor by modifying the conventional expendable pattern casting (EPC) process that is normally used for making aluminum castings. Three innovations were added to the EPC process to make the successful adaptation: (1) Vacuum was applied to sand molds, (2) continuous narrow-necked feeding systems were used to permit the casting of thin walls, and (3) fixtures were designed to prevent pattern damage and to hold critical casting tolerances, Potential problems and defects are described.

Jan 1, 2010

By Robert J. Willard

This chapter includes tables from 1983 that were not available in time for publication of the 1983 Minerals Yearbook, but does not include corresponding tables for 1984. The value of raw nonfuel minerals produced in the United States during 1984 was estimated at $23.2 billion, an increase of $2.1 billion over the value for 1983. This is the second consecutive year that the value has increased, and except for a decrease in 1982, the value for each year has increased since 1971, or 12 out of 13 years. In 1984, 16 out of 21 metal commodities increased in output while 5 metals decreased; 14 metals increased in value and 7 decreased. Of 46 nonmetal commodities. 37 increased in output while 7 decreased and 2 remained unchanged; 35 nonmetals increased in value and 11 decreased. These statistics are grounds for continuing the cautious economic optimism expressed in 1983. Despite the note of optimism, however, numerous problems plague the mining industry, weakening its stability and inhibiting its growth potential. The problems are a complex mix of international and domestic factors that have been building in the recent past, but have become even more troublesome in 1984.

Jan 1, 1985

By G. Nuñez, M. A. Pathak, C. F. Stanley

"Holographic interferometry is a non-destructive technique to detect small deformations1 of an object. It is a whole-field technique· with an accuracy of a few microns. An adaptation of holographic interferometry is time-averaged holographic interferometry which is particularly useful in detecting small vibration amplitudes of an object under investigation. Its application to biological tissue is especially difficult due to the combination of (a) the high sensitivity of the technique, and (b) the tendency of these objects to deform excessively, or move during the testing period. (This is also compounded by the changing moisture content of the tissue surface.)Ideally, a pulsed laser and fast-acting thermoplastic film camera could be chosen to overcome these difficulties, but the total equipment cost could exceed $75,000. In this paper we describe our relatively economical method to apply time· averaged holographic interferometry to an excised animal lung, utilizing holographic plates and a mechanically-shuttered continuous-wave Argon laser.EXPERIMENTAL METHODThe schematic of the experimental setup is shown in Fig. 1. The holographic equipment, including the laser, is fixed on a 3 ft x 6 ft x 4 in. honeycomb holographic table. This table is functionally similar to one described by Mark and Horsch2 which can be constructed for about one thousand dollars. The holographic table itself rests on six inner tubes to absorb floor vibrations. All unnecessary vibrations must be reduced to preserve the quality of the holograms. A laser beam from a 0.5-watt continuous-wave Argon laser is split by a circular variable beamsplitter (Newport Corporation Model 50GOOAV.1) into two beams, i.e., an object beam and a reference beam. The object beam is again split into two beams of equal intensity by a 50150 beamsplitter (Newport ·Corporation Model BS.1). These beams are optically filtered and expanded by spatial filters (Newport Corporation Model 910) to cover as much area of the object as possible. Soft biological tissues exhibit low reflectives, resulting in a relatively high reference to object beam ratio of roughly 5 : 1 at the holographic plate."

Jan 1, 1989

By James A. Powell

The theory of electromagnetic fields indicates such fields could be used to detect and locate trapped miners. To be useful, the hardware of the system must meet a number of requirements, including small size, intrinsic safety, and rugged construction. Such hardware has been built, and the system has been tested by the Bureau of Mines and its contractors. These tests indicate that the electromagnetic method provides a practical means to locate miners in emergencies.

Jan 1, 1976

To expediate the transfer of technology from Bureau laboratories into new products and processes that enhance the economic competitiveness of the U.S. mining and minerals industry in world markets. Background The U.S. Bureau of Mines and various members of the industry are concerned about the current technology challenge to the minerals industry in the United States. They arc working together to delineate ways of enhancing the mineral industry's technology base. More emphasis is being placed on collaboration between the government, academia, and industry to formulate the innovative revolutions needed to maintain our technology edge. Through these partnerships, real issues and problems can be identified, the industry's needs as customers can be defined, and research and development activities can be tailored to meet these needs. Now is an especially exciting time in research because some special opportunities exist to encourage private industry to capitalize on Federal laboratory research and development. These opportunities arc called CRADA's. What Is A CRADA? The Congress recently enacted a mechanism that enhances collaboration between industry and government through the Technology Transfer Act of 1986. A key lea lure of this Act is a provision through which Cooperative Research and Development Agreements or CRADA's can be developed to encourage industry and government to work together and stretch their research budgets. By entering into a CRADA, a private, non-Federal company can cost-effectively perform research by sharing the costs of this research with the Federal Government. The agree¬ment involves no transfer of funds from the Government. The Government agrees to provide personnel, services, facilities, equipment or other resources (but nut funds) and the non-Federal party agrees to provide funds, personnel, services, facilities, equipment, or other resources needed to conduct a specific research or development effort.

Jan 1, 1992

By V. A. Nieberlein

Problems of design involving the high-temperature characteristics of materials of construction have focused attention on tungsten, the metal with the highest melting point. To study the properties of this metal a method was needed to produce tungsten of high purity easily and consistently. The Bureau of Mines has made tungsten metal in massive form on a laboratory scale by hydrogen reduction of tungsten hexafluoride (WF6). Metal made in this manner had a purity of 99.99 percent or better, with reference to all detectable impurities, including gases. The process tolerated a wide variation in operating conditions, and the results with respect to total impurities as low as 0.01 percent were reproducible.

Jan 1, 1959

By K. O. Bennington

[Thermodynamic properties of two amphibole asbestos minerals were determined by the Bureau of Mines. The enthalpies of formation were determined by the hydrofluoric acid solution calorimetry method. Heat capacity measurements were made with an adiabatic calorimeter over the range of 5 to 315 K. High-temperature enthalpies above 298 K were determined with a copper-block drop calorimeter to 852 K for amosite and to 902 K for crocidolite. Thermodynamic data determined for amosite of the composition Fe5+2.2766Mg1.5209 Fe+03.12Mn0.0825) Si7.9163Al0.0837022.0363)(OH)1.9637 are: S°298 = 168.8 ± 5 cal/deg-mole; ?Hf°298-15 (elements) = -2419.24 ± 2.95 kcal/mole; ?Hf298.15 (oxides) = -30.92 ± 2.47 kcal/mole; and ?Gf° -2260.1 kcal. Corresponding data found for s3 ,1s = crocidolite of the composition (Na1.9Ca0.1)(Fe2+.024Fe2.5 01Mg0.475) (Si7.9713024Fe+2 2.501Mg0.475) (Si7.971 Al0.029022.095) (OH)1.905 are: S2.98-15 - 161.1 ± 4 cal/deg-mole; ?Rf° 2 298.15 (elements) = -2433.56 ± 2.99 kcal/mole, 10298.1s (oxides) = -87.69 1.70 kcal/mole, and ?Gf°298.15 = -2269.8 kcal.] Calorimetric values from this investigation were combined with other data from the literature to calculate the Gibbs energies of formation and equilibrium constants of formation over the temperature range of the measurements. Tables of enthalpies of formation and Gibbs energies of formation are given as a function of temperature both from the elements and the constituent oxides.

Jan 1, 1978

By A. L. Engel

The sample of ore on which the work described in this paper was done came from Mina Oriente, Carrizal Bajo, Provincia de Atacama, Chile, South America, and was sent at the request of the Chil.ean Government through the Foreign Minerals Division of the Bureau of Mines. This ore had been tested locally for treatment by flotation and cyanidation without satisfactory results. An additional difficulty was the absence of water near the ore deposits, so that in any treatment method considered the water requirements would have to be very low. It was desired to develop a practical method of recovering the gold and, if possible, the copper in the area. No data of previous investigations were made available. The sample received was mostly quartz, highly brecciated, with limonite and hematite in the fractures. Copper occurred as malachite and azurite, also in the fracture s and to a slight extent as a stain in the quartz. Some fine-grained pyrite with a little arsenopyrite occurred within the quartz. An occasional grain of chalcopyrite was observed. No free gold was seen during examinations of the ore, but amalgamation indicated that some was present.

Jan 1, 1949

By H. Kim, R. W. Plummer, T. J. Stobbe

"The probability of developing coal workers' pneumoconiosis (CWP) varies among miners in different geographic areas, coal seams, and jobs. Many studies have revealed the correlation between mineral content and the frequency and severity of CWP development still remains controversial. Furthermore, the mineral content and its variability in different areas is unknown.Since mineral content is expected to vary from location to location within a mine, between mines, between coal seams, and over time, this information will be valuable in understanding the variations in CWP incidence, as well as in establishing the appropriate kinds of dust to use in toxicological research programs studying CWP.Size-selective airborne dust samples were collected using 4-stage cassette impactors at 9 different locations in each of five coal seams. These coal seams were the Upper Freeport, Pittsburgh, Kittaning, Coal Burg, and Pocahontas. Mineralogical analyses were done by a x-ray powder diffraction photographic technique.Common minerals found in coal mine dust were illite, calcite, kaolinite, quartz, siderite, dolomite, gypsum, anhydrite, and pyrite. The distribution of minerals in interand intra location samples will be reported. Early results on the mineral content show wide variations between locations.in a mine and between coal seams, and small, but significant, variations between particle sizes.INTRODUCTIONIn spite of its long history of incidence, and the large amount of research conducted on it, coal workers' pneumoconiosis (CWP) is still prevalent among coal miners and needs further research to develop effective preventive and remedial measures. Although the dose-response relationship between simple CWP and coal mine dust has been established (1), the causal agent(s) and the mechanism(s) involved in the progression of simple to complicated CWP are not yet defined. Many plausible hypotheses have been made to explain the mechanisms involved in the disease progression however none of them is satisfactory. In addition, the source of variation in occurrence of CWP among miners in different geographic areas (2), rank of coal seam (3,4), and job (5) remain unsolved."

Jan 1, 1988

By Neil B. Young

Carbonate minerals constitute a major fraction of the oil shale in Colorado's Green River Formation. Quantification of carbonate minerals is important for the characterization of oil shale, particularly because of their thermal activity in production of oil from shale. The carbonate minerals found in this oil shale are nahcolite (NaHCO3), dawsonite [NaA1(OH)2CO3], dolomite [(Mg1-xFx)Ca(CO3)2], calcite (CaCO3), and ferroan [(Mg1-xFex)CO3]. Although carbonate minerals can be removed by acid extraction from the balance of the oil shale, direct determination of carbonate minerals is complicated by the occurrence of the same cations in more than one mineral. A method for assigning the acid-soluble cations to the individual carbonate minerals was developed from two assumptions based on oil shale geochemistry: (1) Calcite and ferroan do not occur together, and (2) the ratio of iron and magnesium is the same in dolomite and ferroan. These assumptions were tested by the Bureau of Mines by applying the technique for assigning cations to 219 samples from the saline section of the formation. The reported carbonate mineral amounts were compared statistically with X-ray diffraction peak heights, verifying the cation assignment method.

Jan 1, 1975

By Stephen C. Tadolini, Thomas M. Barczak

Western mines have had limited choices for standing support. Wood cribs were often too soft and unstable. The introduction of the Can support in the early 1990’s provided a very effective alternative and remains the dominant form of tailgate support. Water-filled prestressing cells are now used to cap the Can and preload it to provide an active roof load. The Cluster Prop, consisting of three timber wedge props bundled together, provides more capacity than an equivalent sized Can support and improves transport efficiency. However, the Cluster Prop is less stable and does not maintain a consistent load throughout its loading profile. Pumpable roof supports are another alternative support, but they have not been proven in high deformation environments. Alternative supports are also being used in longwall recovery operations. These include the Rocprop and Omni Prop, which are extendable support systems. They also provide active roof loading which can be beneficial in these applications. Specialty supports, such as the Sand Prop and Spider Prop, have also been introduced into western longwall operations. This paper compares the performance characteristics of these various support systems.

By L. C. IlsLey

Cooperation between the United States Bureau of Mines and the Safety in Mines Research Board of Great Britain, continuous since 1924, has made possible this and other papers on safety subjects. Grateful acknowledgment is made to representatives of the Safety in Mines Research Board of the Mines Department for their assistance in arranging visits to several mine safety stations, and to F. R. Wynne, Deputy Chief Inspector of Mines, Great Britain, for arranging visits to mines in Great Britain, Belgium, Germany, and France. During the summer of 1927 the writer had the privilege of visiting the mine safety testing stations in Great Britain, Belgium, Germany, and France, in the order named. All of these countries have large coal mines, many of which are rated as gassy. Therefore, when installation of electrical equipment is contemplated, each of these countries is confronted with the same safety problem as is the United States - the development of electrical equipment that will not ignite gassy mine atmospheres which might, through neglect or accident surround the equipment. The means used by these countries in safeguarding gassy mines should therefore be of general interest to safety engineers of American coal mines, and it is proposed to give a brief survey for each of the four countries mentioned. This paper presents the second of these surveys, which covers conditions in Belgium.

Jan 1, 1929

By Sidney Katell

Continuing the series of cost bibliographies which was initiated with the publication of Information Circular 7516 in October 1949, the present report covers the period from January 1959 through December 1959. The abstracted articles, concerned with all facets of cost engineering in the field of petroleum and chemical plants and related facilities, were obtained from the following sources: 1. Bureau of Mines Information Circulars. 2. Bureau of Mines Report of Investigations. 3. Chemical Engineering. 4. Chemical Engineering Progress. 5. Chemical Week. 6. Coal Age. 7. Coal Utilization. 8. Cost Engineering. 9. Industrial and Engineering Chemistry. 10. Nucleonics. 11. Oil and Gas Journal. 12. Petroleum Engineering. 13. Petroleum Refiner. 14. World Oil. On Oct. 16, 1959 a cooperative agreement between the Bureau of Mines and the American Association of Cost Engineers became effective. This agreement provides for the publication of the annual bibliography under the sponsorship of both groups with the work load involved in the preparation divided equally between the two. As a result, the present report partially reflects the efforts of the members of the Association.

Jan 1, 1960

By J. P. Coughlin

Gypsum plaster is calcium sulfate hemihydrate (CaS04-1/2H2O). There are two varieties, commonly designated as a and ß. The hydration setting) of this plaster involves the chemical reaction: CaS04?1/2H20(c) + 3/2H20(l) = CaSO4?2H20(c); that is, the hemihydrate combines with water to form the dihydrate. Many substances, when present as impurities, either in the hemihydrate or the water have influenced the rate of the hydration reaction. The objective of the Bureau of Mines work described in this report was to investigate the accelerating or retarding effects of small amounts of dissolved substances and to attempt to classify these effects upon a chemical basis. To eliminate competing effects, the work was conducted separately on the two varieties of hemihydrate; both were in highly pure form. (Commercial plasters usually are a mixture of the hemihydrates, with other substances present as impurities.) As the hydration reaction of each variety of hemihydrate evolves heat in amounts known from previous work, 5,6/ the authors decided to use calorimetric methods to follow the extent of the hydration reaction as a function of time. Two calorimetric methods were employed. One was designed to study the hydration reaction with a large water to plaster ratio and the other with a small water to plaster ratio (to simulate commercial practice in utilizing plaster).

Jan 1, 1959

By George A. Morgan

Mineral production was confined to out-put of cement and gravel. However, exploration was being conducted by the U.S.S.R. and the United Nations Development Program. Development of a domestic limestone deposit and crude oil from an offshore oilfield was underway. Benin's currency remained fixed to the French franc. The gross domestic product (GDP) was $977 million in 1981, the latest year for which information was available. 2 COMMODITY REVIEW Cement.-Construction of a cement plant with 500,000 tons per year capacity neared completion at Pobé. The operator of the plant, using locally produced limestone, was the Societe des Ciments d'Onigbolo, a joint venture between Benin and Nigeria. Nigeria was expected to utilize most of the cement produced. Equipment for the plant included a 1,600-ton-per-day, oil-fired pre-heater.

Jan 1, 1984

By George S. Koch

Several methods of calculating ore grades by diamond-drill sampling in the Homestake mine, Lead, S. Dak., have been evaluated by statistical analyses of assay data. The natural distribution of gold particles, partly masked through sampling and assaying procedures, is probably lognormal. As a consequence of the gold particles being clustered rather than randomly distributed within the ore bodies, (1) more mine samples are needed to obtain a specified precision of mean grade than the number predicted by the standard-error-of-the-mean law; (2) the variance of gold values is not inversely proportional to sample volume, and, therefore, small-diameter drill core yields samples nearly as good as larger diameter core; and (3) sampling at 5-foot intervals provides nearly as good results as sampling at shorter intervals.

Jan 1, 1971

By P. M. Gruzensky

In view of some of the outstanding properties of chromium, considerable effort has been made in recent years to prepare the high-purity metal in ductile form. The object of this investigation was to obtain such metal by electrolysis of chromic acid solutions and to determine the conditions that yield optimum results. The apparatus is described, as well as the parameters that received consideration. Ion-exchange resins were employed to remove cation impurities from the electrolyte. Tensile specimens prepared from the electrodeposits by arc melting, press forging, swaging, and drawing, were ductile at room temperature. INTRODUCTION Metallic chromium displays an exceptionally high resistance to corrosion, oxidation, and wear at elevated temperatures. Although these properties are utilized to some extent when chromium is alloyed with other metals, such as in stainless steels, high-chromium alloys and pure chromium are not employed as engineering materials because of a serious lack of ductility and impact resistance at room temperature. Because high-chromium alloys appear promising as refractory metals for applications such as in gas turbines, much interest has been shown recently in the preparation of uniformly ductile chromium and in determining which factors contribute to its brittleness.

Jan 1, 1957

By Robert E. Wood

[The temperature dependency of the low-density thermal conductivity coefficients, ?°T, of nitrogen, 100° to 1,200° K, is correlated with the Keyes' equation, ?T ½ -1 -12/T) WT = aT+ bT 10 The equation ?T,P = ?°T +a[ ]ß represented 509 experimental higher V pressure thermal conductivities in the temperature range 131.2° to 973.15° K for pressures to 500 atmospheres, with a mean absolute deviation of 2.35 percent. This equation was used to compute thermal conductivities of gaseous nitrogen for 47 pressures, 1 to 240 atmospheres, and 110 temperatures, 133° to 740° K, which are common to conditions encountered in Bureau of Mines helium purification processes. Isobaric heat capacities, CP, and viscosities, ?T,P, from previous work were combined with the present thermal conductivities, ?T,P, to compute Prandl1 numbers, C?T P / ?T ,P, of nitrogen. Tabular values of Prandtl num¬bers are presented for 49 pressures, 1 to 240 atmospheres, and 75 temperatures, 133° to 740° K. Estimated uncertainties are ±5 percent in the tabulated thermal conductivities and ±15 percent for the computed Prandtl numbers. However, the uncertainty may rise to ±10 percent for thermal conductivities and to ±30 percent for Prandtl numbers as the critical conditions of nitrogen are approached.]

Jan 1, 1971