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By J. W. Chester

The rapid depletion of zinc-lead ore reserves and the rising costs of exploration have been major factors in the decline of mining activities and explorations for additional reserves in the Tri-State mining district. There is a need to develop new or adopt known, improved exploration techniques that will appreciably lower the costs of exploration. Demonstration of the practicability of using improved techniques to indicate, rapidly and cheaply, mineralized areas or geologic structures where more intensive explorations are justified could stimulate the search for and discovery of additional ore reserves. Various operators in the Tri-State district have used geophysical surveys to some extent since 1928 to guide exploratory drilling. Some geophysical investigations have also been made in the district by the State Geological Surveys of Kansas (11)3/ and Missouri (8, 13) and by Federal agencies (16), with the objective of directing exploratory drilling to areas where geologic conditions favored ore deposition. Many factual data obtained have not been published. The investigations generally have not been broad enough to permit conclusive evaluation of the usefulness of the geophysical techniques in all parts of the district.

Jan 1, 1959

By John M. Dale

Sulfur is a plentiful, low cost, unique material whose physical properties can be altered and employed in structural applications. This program was undertaken to develop an optimum sulfur based formulation for use as a coating to both seal and support mine walls. The initial effort in the program was devoted to a laboratory study of the physical and mechanical properties of a variety of sulfur base coatings that were specifically formulated for this application. Concurrent with formulation development, laboratory equipment and techniques were developed for spray applying the sulfur based coatings to the ceiling and walls of a structure that simulated the interior of a mine. Much of the formulation work was guided by the experiences encountered when attempting to spray the formulations overhead. One hundred parts of sulfur modified with 10 parts of talc, 3 parts of milled glass fiber, and 2 parts of dicyclopentadiene was found to be a fire retarded, low odor, low eye irritation, sprayable formulation for sealing and strengthening mini, walls. An invention disclosure on this formulation was submitted to the Bureau of Mines and a patent application was filed. Various mineral samples were obtained and adhesive strengths of the formulation to these samples in both the wet and dry state were measured. With the development of an attractive sulfur based coating material, attention was directed to the design, fabrication, and testing of a portable spray application unit so that coatings might be applied in the field to various rock surfaces and earth formations for further evaluation. The unit was fabricated in the Southwest Research Institute shop. Once operational, the unit's capabilities were field tested and demonstrated at three separate locations. Upon completion of the field testing, the unit was shipped to the Spokane Mining Research Center where Bureau personnel were instructed in the use of the unit.

Jan 1, 1972

By W. C. Sanborn

The Bureau of Mines program of investigation and development of domestic mineral deposits had as its wartime objective the most effective immediate utilization of these resources in the interest of National security. Since the war, the results of individual projects are being prepared for publication as rapidly as practicable. Numerous chromite deposits were examined, among them those of the French Hill Mine in northern California. Situated 16 miles east of Crescent City, 76 miles from the nearest railroad shipping point at Grants Pass, Oreg., this deposit had a recorded yield of about l4,000 tons of metallurgical-grade chromite to the end of 1943. By the end of 1946, total production was more than 25,000 tons, averaging 43 percent Cr2O3, with a chrome:iron ratio of about 2.5:1.

Jan 1, 1948

By L. C. George

Addition of an acid waste to an alkaline cyanide waste was investigated for five different combinations of electroplating wastes. At the optimum final pH values of the mixtures, metals and cyanides were almost quantita¬tively precipitated. No evolution of hydrogen cyanide was detected by a few additional processing steps, significant amounts of variable metals were recovered for recycling the waste-plus-Waste step is attractive because no reagents are required, metals arc concentrated, and a relatively harmless effluent that meets most water quality Standards for cyanide content is produced.

Jan 1, 1970

By Frank E. Cash

The information in this report covers the accident experience of the pebble-phosphate industry of Florida for 1935 and 1936, as well as the 5 years 1930-34, inclusive, statistics of which were published in Information Circular 69174/. The compilation and publication of such accident experience statistics enable the pebble-phosphate industry, as well as other industries, to consider relative hazards and to compare experience and thereby promote accident prevention.

Jan 1, 1937

By Thomas W. Thompson

The Zebulon manganese deposit has been known for a number of years. It is situated about 3 miles east of Zebulon, Wake County, N. C., on the Avon, Privett property (fig. 1). The deposit outcrops as a vein, or dike averaging-16 to 20 feet in width. Drilling by the Bureau of Mines has shown that this outcrop results from consolidation of a number of small stringers near the surface. The surface width and the Percentage of manganese oxides (resulting from. weathering) diminish with depth. Below 50 to 80 feet, the vein material is mainly quartz and spessartite garnet. The deposit was first examined by W. T. Benson, a Bureau of Mines engineer, in 1941. The Bureau conducted a diamond-drilling exploratory program an the property from November 7, 1944, to January 25, 1945. A. total of 2,508.5 feet was drilled in 14 holes along the strike of the deposit.

Jan 1, 1950

By Irving Hartmann

The record of safety in the use of permissible explosives in United States coal mines has been excellent, due in great measure to the persistence with which research has been carried on in the Bureau of Mines, to the development of permissible explosives, and to the cooperation of mine operators and workers in using permissibles in a recommended manner and in the effective though gradual replacement of black powder and other nonpermissibles. The demand for increased rate of coal production, changes in mining conditions and minim methods, and introduction of new mining machinery have resulted in modified or new blasting practices. To keep abreast of these developments the Bureau of Mines conducts investigations under actual mining conditions at the Experimental coal mine near Pittsburgh, Pa. Several years ago an extensive study was complete to determine conditions under which the allowable charge limit for permissible explosives per shot hole might be raised from 1.5 to 3 pounds without undue risk of gas or coal-dust ignitions. As a result of the study, this increase in the charge limit was authorized under certain specified conditions in 1948,5/ greatly facilitating production schedules.

Jan 1, 1954

By E. S. Shedd

The Bureau of Mines investigated electrowinning and tapping lanthanum metal from lanthanum oxide in a fluoride bath. The electrolyte was composed of LaF3, BaF2, and LiF. Metal containing 0.2 percent impurities was produced at a rate of over 2 pounds per hour. Principal impurities were carbon, aluminum, and silicon. Low-carbon metal was produced by continually discharging the carbon oxide gases and maintaining 0.1-atmosphere pressure. Anode reactions and cell design were found to be important factors in cell operation. Both frozen electrolyte skulls and tungsten metal crucibles proved satisfactory for collecting the metal and did not react with the molten lanthanum.

Jan 1, 1966

By Abdo F. Bayazeed

A survey of the underground injection of steel processing waste pickle liquor (WPL) was made by Bureau of Mines engineers. Hydrochloric and sulfuric acids WPL are being injected into deep wells completed in the Cambrian age Mt. Simon Sandstone Formation in Illinois and Indiana. The Mt. Simon Formation ranges up to 1,800 feet in thickness. The average depth of WPL injection wells is 4,000 feet, and injection is mostly by gravity flow at rates as high as 4,000 barrels per day. The details of the design and operating history of a WPL well located near Gary, Ind., are discussed. Laboratory tests showed that the Mt. Simon Sandstone is sensitive to fresh water. The adsorption of iron and neutralization of acids by sandstone cores from deep wells and an outcrop were determined.

Jan 1, 1973

By G. S. Scott. R. L. Grant

Ammonium nitrate (NH4NO3), a white crystalline chemical compound composed of 35 percent nitrogen, 60 percent oxygen, and 5 percent hydrogen, has again attracted attention, due largely to the recent catastrophe on April 16 and 17, 1947, at Texas City, Tex. The fire and subsequent explosion on the steamship Ocean Liberty, outside the harbor of Brest, France, on July 28, 1947, has fur- ther increased the interest in the properties of ammonium nitrate. As a result of the Texas City disaster, several laboratories have undertaken research to determine more certainly what causes ammonium nitrate to detonate and under what circumstances. This is not the first time that ammonium nitrate has been involved in a disaster, and its properties reviewed from the standpoint of safety. The disaster at Oppau, Germany, in 1921, which involved an equimolec- ular mixture of ammonium nitrate and ammonium sulfate, prompted an intensive study in Europe and in America. In the United States the properties of am- monium nitrate are now of especial concern because very large quantites are being manufactured and shipped in interstate commerce and abroad. Many an- monium nitrate factories, which were built during the war, will manufacture increasing amounts of this compound for use as a fertilizer. It is the purpose of this report to present a brief summary and biblio- graphy of the published experimental facts about the properties and behavior of ammonium nitrate. The reader is referred to original publications for greater details of the investigative work, and for theoretical discussions. This report also includes a survey of ammonium nitrate fertilizer of the type involved in the Texas City explosions. In the past, authorities have not always agreed on the degree of hazard involved in the manufacture and handling of ammonium nitrate, as the following quotations from the literature indicate: Munroe (82) quoted the following from Turner's Chemistry (a book pub- lished in 1835): "When this salt is exposed to fire, it liquefies, emits aqueous vapor, dries and detonates." Berthelot (14) in his book, Explosives and Their Power, 1983, wrote: "Ammonium nitrate from the point of view of its volatility, and cn account of many considerations, may be regarded as a typical explosive substance."

Jun 1, 1948

By G. H. Keith

The Bureau of Mines determined the mechanism(s) involved in observed anomalous changes in mechanical properties of vanadium-base alloys. Tensile properties of electrorefined and commercial-purity vanadium-base alloys containing up to 5 atomic percent molybdenum or titanium were measured between 77° and 673° K. Snoek oxygen and nitrogen peak heights were measured to determine the changes in dissolved interstitial content caused by increasing quantities of solute. In addition, changes in lattice parameter were followed wit: precision X-ray techniques. Softening, observed in alloys containing titanium, is explained by the formation of a second-phase titanium compound with oxygen or nitrogen. However, because of partitioning of titanium between compound formation and solid solution formation, about five times the stoichiometric amount was required for complete reaction. Addition of 1 percent titanium drastically lowered the strengthening due to strain aging, at 673° K, and 2 percent titanium essentially eliminated it. All alloys were ductile at 77° K. Variations in the tensile properties of the molybdenum-containing alloys are explained by variations in the amounts of interstitial impurities present. The molybdenum did not react with these impurities and had no effect on strengthening due to strain aging. Commercial-purity vanadium alloys containing more than 2 percent molybdenum were brittle at 77° K.

Jan 1, 1969

By Patricia J. Leonard - Mayer

A Bureau of Mines surface resistivity method has been used to determine the joint strike and coefficient of anisotropy of jointed , nearsurface formations at five study areas . The field studies demonstrate the use of rotated , or azimuthal , Wenner-Lee arrays for determining the strike of predominant joint sets . The results of the field studies include the following : in a formation having a predominant , vertical joint set , the maximum value of the apparent resistivity ( pa ) occurs in the same direction ( azimuth ) as the joint strike ; the polar coordinate graph of pa for such a formation is approximately elliptical ; the coefficient of anisotropy ( ^ ) can be calculated from the field data , and values of λ for jointed formations are in the same range of values reported for layered formations ; values of λ are higher at mined sites than at unmined sites . The azimuthal resistivity method and horizontal profiling were used at a site in Pennsylvania to delineate a zone of intensely jointed and fractured bedrock that provided a flow path from a surface stream to a mine . Analysis of the data has been based on a simple model of a jointed formation having a single joint set ; the success achieved to date indicates the need for a more complex model and additional field data .

Jan 1, 1983

By D. E. Anders

Saturated hydrocarbons from 60 selected samples of a 2,300-foot Green River Formation oil-shale core (Piceance Creek Basin, Colo.) were analyzed by gas-liquid chromatography techniques. Emphasis was placed upon the distribution of normal alkanes and 15 key-branched and cyclic alkanes. The latter compounds consisted of the C15, C16, C18, C19, and C20 chain isoprenoids, the 5-a and 5-ß C27, C28, and C29 steranes, three C30 pentacyclic triterpanes, and perhydro-ß-carotene. The results showed definite evidence of maturation of both the n-alkanes and the branched and cyclic alkanes; however, most if not all of the changes were limited to the indigenous soluble extract and were not the result of additional soluble extract generation from the insoluble kerogen. Source material and environmental variations were important factors in some of the observed differences in the branched plus cyclic alkane compositions.

Jan 1, 1973

By E. J. Gleim

[of- ac tore affecting the e -success of recent conveyor miningsystems forLt. extraction. 1 GL C ,_tfreedom shoot &apos;_)`u 2--ethe.1 is coal while e en othershot firers re:7 t _e&apos; _U-tin , w J, e coal .Z- 311.ing States conveyors because ;-.;lax .ca requires thatblasting be limited to when c .. men os. _o tend neces¬sary officials 1 s . re out c-z ,r 7t ...y e:e l z<: woes no t a -¬#to 1 C" such restriction on blasting conveyor miningbeen extendedWhere ere t ere. re no _ c: t&apos;_ _c tit-----! . kind cutlasting;,1CL?; C&apos;. _ z)carried anI-7LC. AT continuouslyHowever, unless et._&apos;0:, precations are taken under r&apos;t e , accidents, n is or such, as111 electricity r 1C- from.J--_,._.1t ,° =&apos;1?without usingholes, as well as numerous-o _&apos;1&apos;-1 -= e troublehe record of mineexplosions (some of themSo so _C&apos;_ °:&apos;,v 0f rock- dusting]

Jan 1, 1941

By D. A. Hill

This volume contains a summary of the results of past analyses on U.S. Bureau of Mines Contract No. H0122061 which are relevant to electromagnetic location in mine rescue situations. The analytical results indicated that detection of a trapped miner equipped with a special transmitter is feasible in most situations. Location of the miner by surface measurements is also generally feasible within certain errors. The feasibility of miner detection and the accuracy of miner location have been examined theoretically for a wide variety of situations. Agreement with experimental results is generally good in cases where measurements are available.

By B. W. Gandrud

In 1927 Coghill showed that there is considerable liberation of the iron oxide mineral from gangue when the Alabama red iron ores are ground to a size suitable for classification and tabling but that there is not sufficient to make possible a high extraction and a high grade of concentrate. Coghill states: High extraction and &apos;high grade of concentrate cannot be obtained without grinding to a size comparable with flotation or cyanide practice. If grade of concentrate be sacrificed the grinding need not be so severe. These ores slime readily during grinding, and in most instances the slimes are only slightly higher grade than the original ore. Not only do they carry a considerable percentage of the total iron in the ore, so that to reject them as tailings would result in prohibitively low extraction, but they are too fine to be amenable to ordinary methods of gravity concentration. In 1929 the Bureau of Mines published results showing that certain Alabama oolitic iron ores could be concentrated by classification and tabling after grinding, with rubber-covered rods. This selective grinding produced slimes of much higher grade than the original ore, and they were considered part of the final concentrate.

Jan 1, 1934

This is the second of a series of reports on properties of commercial motor fuels made pursuant to a cooperative agreement between the Cooperative Fuel Research (C.F.R.) Committee and the Bureau of Mines of the Department of the Interior. The first report gave data oil motor gasolines sold during the minter of 1935-36.3/ These gasoline surveys report results of inspections, in oil-company laboratories, of samples of gasoline obtained by representatives of oil companies from service-station pumps in marketing areas throughout the country. In the present survey are presented inspection data on 239 samples of regular- price gasoline, 166 samples of premium-price gasoline, and 157 samples of third-grade gasoline, a total of 562 samples collected during the summer of 1936.

Jan 1, 1937

This is the second of a series of reports on properties of commercial motor fuels made pursuant to a cooperative agreement between the Cooperative Fuel Research (C.F.R.) Committee and the Bureau of Mines of the Department of the Interior. The first report gave data on motor gasolines sold during the winter of 1935-36.3/ These gasoline surveys report results of inspections, in oil-company laboratories, of samples of gasoline obtained by representatives of oil companies from service-station pumps in marketing areas throughout the country. In the present survey are presented inspection data on 239 samples of regular-price gasoline, 166 samples of premium-price gasoline, and 157 samples of third-grade gasoline, a total of 562 samples collected during the summer of 1936.

Jan 1, 1937

By Clarence Karr

In 1955 the Federal Bureau of Mines established a low-temperature tar laboratory at its new Appalachian Experiment Station in Morgantown, W. Va. The objective of the laboratory is to investigate the yields and chemical and physical properties of tars from low-temperature carbonization of coal, to investigate means of economically upgrading these tars, and to make available to industry and the public essential data for increasing coal utilization through the establishment of a new coal-chemical industry, based on the utilization of low-temperature tars. Because of the obvious economic significance of phenols, as well as the relative ease with which they can be separated and analyzed, initial research has centered mainly around this class of tar constituents. It was realized early that no listing of phenols and their physical properties existed that included enough compounds to be practicable. The purpose of this paper is to make such a compilation available.

Jan 1, 1957

By L. H. McGuire, L. B. Berger

"During the period October 31 to November 4, 1944, tests were conducted by the Bureau of Mines in the Cascade Tunnel of the Great Northern Railway Cc. to determine the effects upon the tunnel atmosphere of the use of a Diesel freight locomotive through the tunnel. These tests were conducted at the request of the company to ascertain whether undesirable conditions might be caused by the discharge of Diesel engine exhaust gas in the tunnel, which was constructed for an electric haulage system and is not provided with equipment for mechanical ventilation. The use of Diesel locomotives on the division that includes the Cascade Tunnel was under consideration as a means of augmenting haulage facilities for the abnormal freight tonnage that must be handled during wartime.As the Bureau of Mines has received requests for information on the extent of contamination of the air of railroad tunnels by Diesel locomotives, this report was prepared to make available for general information the data obtained during the tests in the Cascade Tunnel. As the test locomotive is of a type used on other railroads, and as the bore and grade of the tunnel and the tonnages moved are comparable to such factors on other roads, the data should be sufficiently representative to be of general interest. The exceptional length of the Cascade Tunnel made it an excellent location for obtaining information on the composition of the tunnel air and on the movement of air induced in the tunnel by the passage of trains.The writers are indebted to C. O. Jenks, vice president of the Great Northern Railway Co., who arranged for the tests, and to the following personnel of the railroad who cooperated in the conduct of the tests: I. E. Clary, superintendent, Spokane Division, J. L. Robson, superintendent of motive power, oil and gas equipment, J. F. N. Gaynor, superintendent of electric operations, William Lowney, master mechanic, Spokane Division, and D. F. Marston and Verne Nelson, assistant superintendents of electric operations.The Cascade Tunnel is on the Spokane Division of the Great Northern Railway and pierces the Cascade Mountains some 49 miles west of Wenatchee, Wash. The west end of this division is electrified from Appleyard Station, 2 miles east of Wenatchee, to Skykomish, Wash., a distance of 73 miles. Until the described tests, only electric haulage had been employed through the tunnel since it was first opened to traffic in January 1929.The Cascade is the longest railroad tunnel in the United States - 7.79 miles. The tunnel is single-track, perfectly straight, concrete-lined, and is on an essentially uniform grade of 1.56 percent, ascending from west to east. The cross-sectional area of the tunnel is 314 square feet, the dimensions being shown in figure 1. Elevation of the east portal is 2,880 feet and of the west portal, 2,240 feet."

Jun 1, 1946