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By Raymond W. Hiteshue, Sam Friedman, Robert Madden

Experiments were made in a semicontinuous unit to provide engineering data for designing experimental continuous systems . These systems would be used to study the hydrogasification of hvab coal and char (from lowtemperature carbonization ) to high - Btu gas . In experiments at 800 ° C and with a coal residence time of several seconds , yields of hydrocarbon gases increased from about 2,000 scf / ton of maf coal at 250 psig to 7,000 scf at 1,000 psig . With 15 minutes residence time , yields increased from 8,000 scf/ton of maf coal at 250 psig to 17,500 cubic feet at 1,000 psig . In all cases , small quantities of heavy oils were produced along with the gaseous hydrocarbons . Production of oils could be minimized with a corresponding increase in gaseous hydrocarbons by increasing the retention time of the volatiles within the hot zone . Yields of gaseous hydrocarbons from char were slightly greater than from coal under similar conditions . Although the hydrogasification reaction is very pressure dependent , substantial quantities of coal (40 to 60 percent ) could be reacted to gaseous hydrocarbons at pressures as low as 50 psig provided reaction temperatures were increased to 1,200 ° C. It was also demonstrated that a hvab coal could be hydrogasified continuously without incurring agglomeration . This was achieved by dispersing coal in a relatively large reactor with concurrent flow of hydrogen . At 1,000 psig and 800 ° C , it was possible to react about 35 percent of the coal and to produce a gas containing up to 52 percent methane .

Jan 1, 1964

By T. E. Swigart

In the production of oil end gas, engineering methods have been applied less than in any other branch of the oil industry. While refineries, gasoline plants, pipe-line and other transportation systems, and even drilling wells to a great extent, take advantage of engineering skill, the tendency has been to assume that the handling of producing wells is merely a mechanical and routine matter. At present few companies employ engineers to study oil and gas production methods with a view of increasing the general efficiency of recovery, but in vie, of the advancement in other lines of the petroleum industry by the application of engineering principles, does it not seem likely that the production branch may benefit also by engineering studies? Engineering applied to the handling of producing wells falls under two general headings, - first, the efficient handling of wells from the time of their inception in order to obtain the greatest possible ultimate production, and, second, the rehabilitation of old properties that have been handled carelessly in their early lives. To date, the engineering work that has been done on oil production problems falls mostly in the second class. For example, the use of vacuum and the application of compressed air have proved successful in some instances in stimulating wells of low gas pressure. These methods are costly to apply and are adapted to small wells in which the gas is almost exhausted, or in which the original gas pressure is negligible. The experiments described in this paper fall under the first heading, as they were made with an idea of learning toe probable extent to which the gas production of an oil well can be curtailed while gas in the sand is still plentiful, and thus saved for doing work during the later period of a well's life. Because of the scope of the experiments, this paper does not include a discussion of back pressure on flowing wells or for purposes other than cutting down the gas produced with each barrel of oil.

Jan 1, 1922

By L. Y. Sadler

The Bureau of Mines conducted a study Lo determine the loss in weight of silica (Si02) volatilization from low-alumina (A1203) refractories used as hot face liner materials in such process equipment as coal gasifiers, synthesis gas transfer lines, and ammonia plant secondary re-formers. Small specimens of 80-and 40-pct-A1203 brick and 95-pct-SiO2 brick were exposed to steam in high-pressure furnaces at pressures of up to 1,000 psig and temperatures up to 1,400° C for periods ranging up to 120 h. Weight losses from the 40-pct-A1203 brick after 40 h of exposure were highest, 2.75 pet at 1,400° C and 1,000 psig. The rate of weight loss had dropped to near zero after 80 h of exposure at all temperatures. No relationship between total silica content of the specimen and weight loss could be established nor did scanning electron microscopic examination of the specimens before and after exposure identify specific regions (e.g., surface) suffering a disproportionate share of the silica loss. It was concluded that minor silica volatilization is likely to occur, if at all, at temperatures of less than 1,000° C and pressures below 1,000 psig, and that low-alumina refractories should be used as dry-ash coal gasifier hot face linings.

Jan 1, 1986

By Carl Rampacek

The conversion of dilute sulfur dioxide gas into sulfuric acid by autoxidation in mechanical cells of the flotation or gas absorber types was investigated. Bench-scale tests were made with sulfur dioxide-air mixtures to determine the influence of several factors on autoxidation of sulfur dioxide, using iron and manganese salts as catalysts. The laboratory investigation subsequently was extended to pilot plant acid-making tests, using a modified turbomixer gas absorber having a 12-inch-diameter impeller. Sulfur dioxide gas was produced for the tests by roasting pyrite in a fluidized-bed reactor. In the better tests, made with manganese sulfate as the catalyst, the equivalent of 1,000 pounds of anhydrous H2SO4 was produced per 24 hours as a 10-percent solution; power consumption was 0.2 kwhr per pound of equivalent anhydrous acid synthesized. The batch and continuous tests demonstrated the technical feasibility of producing dilute sulfuric acid by autoxidation of sulfur dioxide gas in mechanical cells when converting pyrite roaster or waste smelter gases.

Jan 1, 1963

By D. S. Kingery

Investigations over several years have disclosed that the principal manners of occurrence of shuttle-car injuries are in order: 1. Victims in contact with roof or crossbars. 2. Victims in contact with ribs or timber legs. 3. Victims falling from, or jerked from, shuttle cars. 4. Victims in contact with overhanging brows or protruding pine for pin timbers, or water lines. 5. Contact with persons or collisions with parked equipment. 6. Victims injured by roof falls or falling timbers caused by knocking out roof supports with shuttle cars. 7. Victims injured by runaway shuttle cars. 8. Victims injured while loading or unloading timbers or other materials from shuttle cars. These recurring types of shuttle-car accidents reflect the physical conditions of the working sections, certain safety deficiencies in shuttle-car maintenance and design, and unsafe practices by operators.

Jan 1, 1952

By John R. Bradley

The available supply of fuel and power is a subject of importance at all times and particularly at this time. The following brief survey of fuel and power in the United States appraises the extent of the several primary sources of energy the approximate monthly demand, 1929-40; the chief centers of production and consumption; and shifts in the principal uses from 1929 to recent years. The period covers the boom year 1929, the years of the great depression, the more normal year 1937, the recession in 1938, the year 1939, and 1940 (which was affected by armament programs). In some instances, the data for 1939 and 1940 are preliminary. The four primary sources of fuel and power are coal, petroleum, natural gas, and water power. Wood fuel, important in some regions, and foreign trade in natural gas and hydroelectricity represent a relatively small part of the energy supply and are not considered in this study. The tonnages shown are in terms of coal, based upon the calorific or B. t. u. equivalents of the several sources of power. In practice, the usable heat or energy varies according to the type of equipment available for its use. For example, the efficiency of turbine water wheels and internal-combustion engines is much higher than that of steam plants and household-heating devices.

Jan 1, 1941

By Stephen D. Cramer

A nondestructive procedure for measuring electrodeposit porosity has been developed which records the location and number of deposit defects including pores, pits, and voids. The procedure involves the passage of an X-ray beam through the deposit-substrate system onto suitable film. The defects are recorded as images on the film. Variables studied included intensity and spectra of the X-ray beam, composition and thickness of deposit and substrate, film type and developing procedure, and limits for detecting defects. At an X-ray tube voltage of 40 kv, pores several mils thick were easily detected in copper-nickel specimens more than 20 mils thick. To illustrate the utility of the procedure, the effect of substrate oxidation and of current density on electrodeposit porosity was briefly studied.

Jan 1, 1970

By Douglas A. Elkins

The unique characteristics of plasmas, their current applications, and ongoing research into new applications are described. Major technical and economic problems in application of plasma technology are discussed. Examples of potential applications of plasma in extractive metallurgy are described and evaluated. The report includes a selected bibliography of articles on plasma and related high-temperature technology.

Jan 1, 1969

By L. J. E. Hofer

The Bureau of Mines determined rates of adsorption and desorption of methane as a function of particle size and temperature, using coals from the Pocahontas No.3 seam (lvb) from the Bishop mine of western Virginia, and the Pittsburgh seam (hvab) from the Pursglove No. 15 mine of northern West Virginia. For a given coal sample and temperature, the rate curves for adsorption and desorption are essentially the same when expressed on a fractional approach to equilibrium basis. The rates of adsorption and desorption increased eightfold as the particle size was decreased from 6-8 to 270-325 mesh per inch. The adsorption process appears to be diffusion controlled. Rate of sorption processes increased with increasing temperature; however, the amount adsorbed at equilibrium decreased.

Jan 1, 1966

By G. M. Kintz, E. H. Denny

Although some engineering colleges recognize the importance of instructing young engineers in industrial safety , the different institutions handle this instruction in various ways . It is believed that a recent industrial safety course , conducted at the Colorado School of Mines through the cooperation of this school and the Bureau of Mines , U. S. Department of Commerce , presents some unusual features that are of interest to other schools and to the mining public .

Sep 1, 1930

By D. Harrington

Advocates of health and safety in mining have found themselves confronted in recent years with what might appear to be contradictory procedures with regard to dust occurrence in mines and what appear to be suitable methods or measures to give the mines and mine workers a maximum measure of protection against dust. A concerted and relatively effective drive has been made to introduce rock dust into bituminous and lignitic coal mines to prevent or limit explosion and fire disasters, while an equally determined effort has been and is now being made to curb rock dust or to eliminate it from air in metal mines to prevent or at least limit the occurrence of miners' consumption and other diseases. Both procedures are logical even though the efforts appear to be of an opposing nature. While rock dusting has not been applied in coal mines nearly as universally or as effectively as could and should be done, nevertheless a careful analysis of the record of the past 10 years indicates that the amount of rock dusting that has been done has resulted in the saving of a minimum? of 200 lives annually certainly no small achievement. Largely but by no means wholly due to the use of rock dusting, the number of fatalities from explosions and fires in our coal mines in the last 4 years haw been reduced more than 75 percent as compared with the 4-year period 1911-15, the first years of the existence of the United States Bureau of Mines, which was brought into existence in 1910 largely to try to do something about reducing the disgracefully high fatality occurrence from explosion disasters in our coal mines. Hence, rock dusting has been given at least a. trial and has proved its effectiveness definitely.

Jan 1, 1937

By D. R. Brooks

The Bureau of Mines has tested a dewatering technique for phosphatic clay waste. The technique utilizes a flocculant, polyethylene oxide (PEO), that forms strong, stable flocs that can be dewatered on a static screen followed by further dewatering on a rotary screen or trommel. In field tests conducted in central Florida, clay wastes containing approximately 4 pct solids have been consolidated to greater than 20 pct solids. The rate at which PEO-treated material continues to dewater in a mine cut also was monitored. Preliminary results indicate that PEO-treated material will dewater to 30 pct solids in 80 days. Pretreatment of phosphatic clay waste with lime lowers the PEO dosage required for dewatering.

Jan 1, 1986

By T. T. Campbell

Studies were conducted by the Bureau of Mines to develop a process for preparing thorium-magnesium master alloys or pure thorium metal by magnesium reduction of thorium tetrachloride in a semicontinuous reactor. Thorium tetrachloride was prepared in a fluidized-bed reactor by chlorination of thorium oxide or thorium oxalate. Conditions were established for producing a suitable thorium oxide feed for a fluidized-bed reactor. Thorium tetra-chloride was purified by vacuum sublimation and subsequently reduced by magnesium in a semicontinuous reactor to form thorium-magnesium alloys. Relatively pure thorium was produced by removing magnesium from the alloys by vacuum sublimation. Close to 100 percent of the thorium fed into the reactor was recovered either as metal (~93 percent) or as thorium oxide (~7 percent). The oxide can be recycled directly into the process.

Jan 1, 1971

By Kathleen M. PH. D. Kowalski

This paper discusses human judgment and decision-making under stress. The authors review selected recent literature across various disciplines and suggest a definition of stress within the context of decision-making during the management of emergencies. They also discuss fieldwork by the Pittsburgh Research Laboratory, NIOSH, which explores traumatic incident stress, the relationship between previous training and performance under stressful conditions, and human behavior in underground mine fires. The authors assert that stress is one of the factors that decision-makers must contend with in most life-or-death situations. They suggest that a better understanding of individual's judgment and decision-making activities while under stress would yield a better understanding of how people reach the choices they make in emergencies. This enhanced understanding would be of enormous value to emergency managers, researchers, and policymakers.

Jan 1, 2008

By Ned H. Snyder

In recent years the Government and other large consumers of coal have appreciated more and more the desirability of definitely determining by chemical analysis and test the character and quality of the coal they purchase. Higher prices for coal point forcibly to the need of giving more study to engine room and boiler room efficiencies and economies; this implies an intimate knowledge of the character and quality of the fuel used. Analyses and tests of delivered coal furnish data whereby power plant results can be comprehensively studied and a continuous check maintained on the coal and on the conditions of plant operation. Under authority of acts of Congress making appropriations for technologic investigation of fuels and the analyzing and testing of fuels belonging to or for the use of the United States Government, a laboratory is maintained at the Pittsburgh station of the Bureau of Mines, where samples representing deliveries of coal purchased for Government use are analyzed and tested. The Bureau of Mines has been active in promoting the purchase of coal by the Government under specifications/ that is, by contracts that make definite requirements regarding the heating value of the coal, expressed in British thermal units, and the composition as shown by proximate analysis. Under many of these specification contracts the bidders guarantee the quality of the coal offered, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled and analyzed to determine whether the coal is of the quality guaranteed by the contractor, and if it is not, the price to be paid is decreased in proportion; but if the coal is of higher quality, the price is proportionately increased. The known analyses of coals or the guaranteed analyses offered by the bidders may sometimes be used for determining the award of a contract, but if the coals offered differ widely in characteristics, it may be difficult to determine which would prove the cheapest fuel without data on their relative evaporative efficiencies. Hence, the making of evaporative tests under service conditions may be necessary in order to determine which coal is particularly adapted for successful and economical use in a certain plant. Once a particular coal is selected, however, regardless of the procedure of determining the award of a contract, then the greatest advantage of the specification method is realized, for it guarantees the purchaser receiving coal of uniform character and quality, thereby insuring the best results in the plant. The success of the specification method for the purchase of coal and the reliability of analysis now rests largely on sampling.3 Improper sampling leads to controversies, with resulting condemnation of the specification method in general and of the value of laboratory analyses and tests in particular.

Jan 1, 1922

By G. E. McElroy

Ventilation-pressure surveys are required to determine the rates of pressure losses in various parts of mine-airway systems. These may be determined directly by differential pressure measurements or deduced from absolute pressure measurements, Despite the confusion caused by its inverted nonlinear scale, the altimeter has special application to pressure surveys in mines in which only small differences in elevation are involved, as is true for most of our large bituminous-coal mines in these, the judicious use of information obtained by pressure surveying can result in greatly improved working conditions as regards health and safety and, in many instances, can yield large financial returns. The main purposes of this report are to discuss methods of using altimeters for pressure surveys and to present the particular methods of making surveys and calculating the results of surveys used by the Mine Ventilation Section of the Bureau of Mines.

Jan 1, 1957

By M. M. Wong

Electrolysis of titanium carbide and a material consisting of titanium, carbon, nitrogen, and oxygen as soluble anodes in Used electrolytes was investigated by the Bureau of Mines for the preparation of crude titanium metal. Tests made in all-chloride electrolytes showed only a low recovery of titanium as well as a substantial volatilization of titanium trichloride (TiC13) when present in the electrolyte. Electrolysis at 750° to 850° C in a mixture containing 85 percent NaC1-15 percent potassium floutitanate (K2TiF6) yielded as high as 91 percent recovery of titanium from titanium carbide and 62 percent recovery of titanium from the titanium-carbon-nitrogen-oxygen material. Problems associated with the preparation of crude metal by fused-salt electrolysis are discussed. The crude metals produced from both anode materials were electrorefined in a sodium chloride-titanium chloride (NaCl-TiC12) electrolyte, and ductile titanium metal was obtained.

Jan 1, 1963

By W. G. Pariseau

The U.S. Bureau of Mines has been conducting a series of rock mechanics investigations at the Lucky Friday Mine in the Coeur d'Alene Mining District of northern Idaho. The present study uses rock deformation measurements to validate and calibrate a geomechanical model of the experimental Lucky Friday underhand longwall (LFUL) stope on the 5,100-ft level of the Lucky Friday Mine, Mullan, ID. The calibrated three-dimensional, finite-element model and measurements of rock mass displacement show a correlation of 0.795. The calibration reduces rock mass modulus to 14 to 17 pet of laboratory values and rock mass strength (with an energy rule) to 37 to 41 pet of laboratory values. This model suggested that stress-related ground control problems would be encountered west of the stope where the vein makes a right-angle turn and then splits. Rock burst activity was concentrated in this area during mining of the LFUL stope.

Jan 1, 2010

By R. E. Morgan

[IN COMPILING the table of analyses of this bulletin every available source of information was studied. These sources, as listed at the end of the table, were many and varied, and it believed that the tabulation gives the best general information obtainable. However, its known accuracy and completeness of coverage necessarily fall far short of published data on coals of the United States. A table of world production of coal and lignite, as and published by the Bureau of Mine, of world resources of coals, brown coal, and lignite, as published in the Yearbook of the World Power Conference, 1948, are included for convenience of the reader. The six continental maps at the end of the bulletin show the general location of the principal coal fields.]

Jan 1, 1952

By Margaret R. Egan

The U.S. Bureau of Mines conducted experiments in the intermediate-scale fire tunnel to assess the influence of air velocity on the gas production and smoke characteristics during smoldering and flaming combustion of Pittsburgh seam coal and its impact on the detection of the combustion products. On-line determinations of mass and number of smoke particles, light transmission, and various gas concentrations were made. From these experimental values, generation rates, heat-release rates, production constants, particle sizes, obscuration rates, and optical densities were calculated. Ventilation has a direct effect on fire detection and development. The results indicate that, in general, increased air velocity lengthened the onset of smoke and flaming ignition, increased the fire intensity, but decreased the gas and smoke concentrations. Increased air velocity also lengthened the response times of all the fire sensors tested. Rapid and reliable detector response at this most crucial stage of fire development can increase the possibility that appropriate miner response (fire suppression tactics or evacuation) can be completed before toxic smoke spreads throughout the mine.

Jan 1, 2010