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By A. Prokopiev

The biological stage of reclamation is the third final stage in remediation the damaged mining terrains, which is carried out following the completion of the mining technical stage. The biological stage of reclamation is carried out through restoration of the vegetation layer. The biological reclamation includes all activities related to the introduction into the terrain of vegetation, microorganisms, insects, and animals, with the acceleration of the succession and creating conditions for a sustainable ecosystem close to the natural one. It comprises of all anti erosion and other activities such as the preparation of the land for growing agricultural crops, sowing grass seeds, planting seedlings, amelioration of the soil and further care for the vegetation until its final place on the land. Mineral and organic-mineral ameliorants for biological reclamation were studied. The basic mineral ameliorant is Bulgarian natural zeolites. The zeolitic-rich tuff samples provided from Golobradovo deposit was characterized by their chemical and mineralogical composition and ion exchange properties and X ray analysis. The average content of clinoptilolite was found to be more than 80%. The materials had ion exchange capacity (NH4+) varying from 100 to 110 meq/100g. Chemical modifications of natural clinoptilolites were made in order to form active phases of nitrogen, phosphorus, potassium, and microelements. Slow-acting mineral ameliorant was developed. Organic-zeolite substrate for biological reclamation was developed. This new product is a mechanical mixture of organo-matter and modified zeolites. Agro-chemical parameters of new ameliorants were determined. The substrates including studied overburden dump soil and mineral or organo-mineral ameliorants are produced. The grass growth test was performed. Keywords: biological reclamation, ameliorants, damaged mining terrains

Sep 1, 2012

By A. Muhammad, A. Abdelaal, M. EL Salmawy

"Energy is vital for economic growth and sustainable development. Greater efforts are being devoted to developing unconventional energy resources such as oil shale as an alternative promising source of oil or solid fuel supplement. The main object of this contribution is to determine the upgrade potential of El-Nakheil oil shale using froth flotation. Samples were prepared by comminution followed by sieving into different size fractions. The flotation behavior of the material and extent of cleaning was studied with respect to nonionic and ionic collectors of anionic and cationic types. It was found that the organic rich portions could not be rendered sufficiently hydrophobic by the used collectors and selectivity towards surfactant was very low."

Jan 1, 2014

During incineration of municipal solid waste (MSW), some heavy metals and other environmentally harmful elements are liberated into bottom ash. The stricter environmental regulations require a higher immobilization efficiency of the ash before its safe disposal and application. Vitrification is one of the promising options, and has the advantages of high destruction efficiency of organics, high immobilization of heavy metals, and large volume reduction. The main components of the vitrified slag are SiO2, CaO, Al2O3, Fe2O3, Na2O and MgO, and the compositions have direct effect on the glass formation during vitrification, and further on the physical and mechanical properties of the slag. To provide essential data for the utilization of bottom ash as vitrified slag, the phase relations and thermodynamic properties of the oxide system need to be systematically investigated. In the present study, the liquidus temperature of the typical vitrified bottom ash slag was determined by using differential scanning calorimetry (DSC) measurement. High temperature equilibrium experiments were conducted to investigate the phase relations of the sub oxide system of CaO-SiO2-Na2O by means of Scanning Electron Microscopy (SEM), Electron Microprobe Analysis (EMPA) and X-ray Diffraction (XRD). The results show that the melting temperature of the vitrified bottom ash is around 930°C. In the CaO-SiO2-Na2O system with less than 50 mol% SiO2, the liquidus temperature de-creases with increasing amounts of Na2O along the tie-line of Na2O-Ca3Si2O7. Two compounds Na2Ca3Si2O8 and Na4Ca8Si5O20 are identified in the oxide system.

Jan 1, 2014

By Xinyang Xu, Chen Zhang, Lixia Li, Zhitao Yuan

"Density functional theory was employed to clarify the mechanisms of the activation of a quartz surface and its collection by the flotation method at the molecular level. The calculation results indicated that hydrogen bonds on the quartz surface (1 0 1) existed in pairs while in contact with water. The simulation was carried out to investigate the different effects of Ca2+ and Ca(OH)+ on a quartz surface with hydrogen bonds, and the results suggested that Ca(OH)+ most likely adsorbed onto and activated the quartz surface. Mulliken population analysis of the external oxygen atom of the quartz surface, calcium atom of Ca(OH)+, and the oxygen atom of oleate showed that there were electron transfer and the formation of a chemical bond between Ca1-O1 and Ca1-O3, which were indicative of strong interactions between the three atoms. In addition, the –OH of the Ca(OH)+ contributed to the activation, which suggested that the Ca(OH)+ group acted as a bridge between the surfaces of oleate and quartz.INTRODUCTIONFlotation is an effective separation method in mineral processing that takes advantage of the physicochemical differences between minerals and gangue, and the properties of the mineral surfaces play a key role in this process (Liu et al. 2016, Qin et al. 2017). In the reverse flotation process of iron ore, gangues are captured by cationic or anionic collectors and floated with air-bubbles as tailings, and the pre-depressed iron oxide minerals are left at the bottom as concentrates (Lima et al. 2013, Yianatos et al. 2015, Zhu et al. 2015). Quartz (SiO2) is one of the major gangues of hematite ores and cannot be easily removed. It is a naturally hydrophilic mineral, in which silicon is the cation in its crystal structure and has very limited solubility. Therefore, quartz must be activated, usually by metal ions, for its effective rejection as a float-product by reverse flotation (AIME. et al. 1976)."

Jan 1, 2018

By T. Shumba

The solvent extraction section of an old Uranium Plant in the Vaal River region produced a sub-stance called Crud (Chalk River Unidentified Deposit) that formed within the aqueous/organic interface of the settler of the solvent extraction circuit. The crud was deposited together with gold tailings to the tailings dam many years ago. Previous research done on the crud confirmed that ex-posed crud leaches Mn and Ni at concentrations that are well above their acceptable risk limits as well as Zn that leaches at concentrations that are slightly lower than its acceptable risk limit. Soil washing and bioremediation technologies were employed to treat the contaminated soil. Various laboratory test work and the pilot scale studies were conducted in parallel with each other and the results of the laboratory studies were used to determine critical parameters. Four lixiviants, i.e. sulphuric acid, acetic acid, oxalic acid and ethylene diamine acetic acid were tested at three concentration levels i.e. 0.001M, 0.0001M and 0.00001M, respectively. Column tests showed that the leaching of the heavy metals increases as the soil porosity increases. Silica sand was added to increase porosity of the contaminated soil. Highest Mn removal was achieved mainly by sulphuric and oxalic acid at 0.001M at all soil levels. EDTA was significantly efficient in the removal of Ni and Zn. The recovery of heavy metals, particularly Mn, decreased as the depth of sampling in-creased. Heterogeneous bacteria and filamentous organism plate counts were conducted to evaluate the growth of the bacteria and filamentous organisms in the soil. Results showed that more organism growth took place in the bioremediated soil with a fertilizer added to it. The leaching of metals from the soil that was bioremediated in the pilot study was generally higher than the extraction of the metals from the soil that was leached with no bioremediation carried out. The results from this study suggest that the leaching of heavy metals from the contaminated soil is to a large extent dependant on the pH of the leaching solution. By increasing the soil?s porosity and bioremediating the soil, higher extractions of metals were achieved.

Jan 1, 2014

By Wei Sun, Chengwei Li, Zhiyong Gao, Yuehua Hu

"Grinding for mineral liberation is a prerequisite for a successful flotation separation. Different grinding media produce mineral particles with different morphologies and surface properties. In this study, the surface physicochemical properties of fluorite particles produced by ball and rod mills were systematically investigated through single mineral flotation experiment, wettability measurement, X-ray diffraction (XRD) test and scanning electron microscopy (SEM) observations. The XRD observations reveal that the surface exposure degree for both mill particles follows the order {111} > {110} > {100}. The difference lies in that the rod mill ones have a higher exposure of more reactive {110} and {100} surfaces, leading to a stronger interaction with the collector. The difference also leads to their higher elongation and lower roundness values of rod mill particles which are beneficial for the particle-bubble attachment by shorting the induction time. The wettability and flotation results show that the rod mill ones have a lower critical surface tension and a greater hydrophobicity when treated with the collector solution and accordingly perform a higher flotation recovery. This work, for the first time, revealed the importance of the exposure of crystal surfaces in determine the shape factors and reactivity of the mineral particles and will help provide guidance for optimizing flotation separation and particle surface modification. INTRODUCTIONFluorite (CaF2) is the most important source mineral for producing F-based chemicals and materials which are widely used in industrial, environmental, and medical fields [1, 2]. In ore deposit, there are two kinds of occurrence forms of fluorite mineral. Firstly, the fluorite mainly coexisted with the gangue minerals like calcite (CaCO3) and quartz (SiO2). Because of their similar density and fine-grained dissemination in ore deposit, ball mill grinding before flotation separation has been widely applied to produce relatively fine particles [3]. Secondly, the fluorite is often associated with other valuable minerals with higher relative density such as scheelite (CaWO4) and cassiterite (SnO2). Due to their obvious density differences and coarsely grained distribution in ore deposit, rod mill grinding before gravity separation has been usually used to produce more uniform particles and avoid over-grinding [4-6]. After the gravity separation, a flotation separation is also employed to beneficiate the fluorite [7]."

Jan 1, 2018

By Kozlov Andrey, Matveeva Tamara

"The results of mineralogical and technological studies of platiniferous dunites from Svetloborsky zonal massif (Urals platinum belt) are presented and the basic typomorphic signs of productive mineral assemblages are substantiated. The characteristic features of platinum ore mineralization are revealed: a wide range of iron-platinum alloys, enrichment of ore-formed system by the elements Os, Ir, Rh and activity of the S and As in it, intrusion of Fe-Ni sulfides in platinum and its fusion with magnetite. More than 80% of PGM mineral grains has size less than 100 microns, that determines the possibility of significant losses of platinum in the process of gravity separation and the need for additional recovery processes for small and fine fractions of platinum tailings and sludge products. Summarized results of laboratory tests of small-volume sample processing of platiniferous dunites are presented and the processing flow sheet is developed and tested. The flow sheet incorporates several stages, including stage-wise grinding and gravity separation of ore using the centrifugal concentrator Knelson KS-MD for differently sized material and flotation treatment of tailing products using new classes of reagents for additional recovery of PGM fines."

Jan 1, 2014

By Y. F. Guo

Among the different valences of vanadium, V (?) is insoluble in acid, V (?) and V (?) is in-soluble in water but soluble in acid. Vanadium mainly exists as V (?) in vanadium titanium-rich material obtained by reduction -milling-separation from vanadiferous titanomagnetite. Therefore, the vanadium titanium-rich material can not be used to extract vanadium by acid directly. In this paper, the vanadium leaching was studied by oxidation roasting and acid leaching. Through oxidation roasting, vanadium is transformed from the insoluble V (?) into V (?) or V (?) in order to improve the leaching of vanadium. The results show that vanadium leaching increases significantly by oxidation roasting-acid leaching. Leaching of vanadium is up to 70.18% under the optimized conditions of roasting temperature of 950 ?, roasting time of 40 min, sulfuric acid concentration of 40%, leaching time of 4h, leaching temperature of 95 ? and liquid to solid ratio of 4 : 1.

Jan 1, 2014

By E. Emelyanenko, P. Solozhenkin, J. Yagudina, O. Ibragimova

To recover tetrahedrite-tennantite series minerals from porphyry copper-pyrite ores by the froth flotation method, further research on thiol collectors is launched to promote the utilization efficiency of copper ores. In the present paper the adsorption mechanism of the collectors on tennantite surface has been investigated by computational modeling and FTIR-spectroscopic analysis, which have revealed that the decrease in prognosis of collector activity evaluation (PCAE) for tennantite is in the following order: BX (-0.34318), AEROPHINE 3418A (- 0.61756), AERO 5100 (-14.18857). The lower PCAE the stronger the ability of the collector to interact with the mineral surface of tennantite and form the stable complex. More kinetic reliable conditions to form suitable adsorption layer and rupture of the liquid interlayer with AERO 5100 have been observed by FTIR spectra due to decrease of the intensity and stretching and bending vibrations of water (less than 20 and 65%, respectively). In order to verify the feasibility of AERO 5100 as a collector the industrial flotation tests have been conducted. Flotation performance has improved significantly with the stadially grinding and preflotation of tennantite in intercycle copper flotation that allows to avoid desliming of the fragile mineral and minimize loss of Cu and As in tailings. The recovery of copper in copper concentrate increases by 3.9% with the grade maintained.

Jan 1, 2018

By A. V. Neretin

This paper is a continuation and extention of the previous paper on energy-efficient placer mining methods which was presented in 2007 at the World Gold Conference in Cairns, Australia (Nere-tin, 2007a). The paper reports the results only on gravel processing as they were not fully discussed in the previous paper. It is common knowledge that placer gold mining requires processing of large tonnages of gold-bearing gravels by wash plants of different types. In Russia, gold-bearing gravels are mostly disintegrated and screened by the following types of wash plants: a water canon, a derocker or a scrubber trommel. Gold-bearing gravel processing is regarded as highly energy-intensive due to high energy consumption for transportation of large tonnage of material and high pressure water flow rate. The industries requiring a significant expenditure of energy normally estimate the process efficiency by energy consumption per product unit. In order to obtain quantitative data on energy consumption for gravel processing and to estimate placer mining costs, in 2003~2006 four placer gold mines located in the Irkutsk Region were thoroughly investigated through time and motion studies. At all these placer mines gravels were processed by a water canon, a derocker or a scrubber trommel. The objective of the study was to investigate the following parameters: ? wash plant throughput rate per hour; ? hourly diesel fuel and power consumption per cubic meter of gravel processed; ? volume per cent and shape of oversize material; ? different combinations of gravel processing methods. The results from this study were as follows: ? specific energy consumption per cubic metre of gravel processed for different combinations of gravel processing methods was estimated; ? a correlation between energy consumption and unit cost of gravel processing was determined; ? effect of yield and shape of oversize material on wash plant throughput rate per hour was de-fined; ? energy-efficient gravel processing methods were developed. Based on these results, an improved method of gold-bearing gravel processing was proposed. Implementation of this method at a placer mine saved US$ 123 000 in operating expenses only during a short-time Siberian placer mining season. At the same time, this method improved gravel disintegration, screening and processing operations used at the mine. Another advantage of the pro-posed method was higher gold recovery due to reduced yield of undersize material. In order to improve efficiency of gravel processing, a wash system including a derocker for primary gravel processing and a lightweight scrubber trommel was developed. There are two economic benefits of replacing water cannons with the proposed wash system. The first benefit includes lower operating costs for gravel processing due to lower specific energy consumption, while the second benefit is lower gold losses during slurrifying (disintegration and screening) and sluicing of the undersize material.

Jan 1, 2014

By Xuliang Yang, Yuemin Zhao, Bo Zhang, Liang Dong, Cheng Sheng, Gongmin Li, Zhenfu Luo, Yaqun He, Chenlong Duan

Coal plays an important role in the primary energy consumption of all over the world. In 2012, coal reached the highest share (29.9%) of global primary energy consumption since 1970. Coal burning mainly contributes to the emission of SO2, NOX, Hg and other impurities that jeopardize the future of environment. . Beneficiation before coal utilization is the most economical and effective technology for removing the hazardous material and gangue. In this paper, a novel process of dry beneficiation based on gas-solid two-phase flow composed of the compound dry cleaning separator (FGX), the air dense medium fluidized bed separator (ADMFB) and the vibrated fluidized bed with autogenous medium (VFB) is proposed. The main equipment and the flowsheet of the united system are described in detail. Separating principle of the FGX, ADMFB and VFB devices are all based on gas-solid two-phase flow. In FGX, gassolid suspension is composed of continuous gas flow and coal powder in feed coal. Large size coal (+6- 80mm) can be pre-separated effectively, and large size gangue can be removed effectively. Moreover, - 6mm particles fed serve as autogenous medium in FGX. The probable E value is 0.13 for -80 mm raw coal. In ADMFB, magnetic powder with -0.3 + 0.045 mm size fraction and coal powder in feed coal are compound medium solids. The separation density can be adjusted and controlled according to properties of raw coal. -50 + 6 mm raw coal can be cleaned efficiently, the probable E value is 0.05. In VFB, -6 + 1 mm coal can be separated. Generally, -80 mm raw coal can be cleaned efficiently in the united system based on gas-solid two-phase flow.

Jan 1, 2014

By Z. H. Wang

The internal parameters of ball mill are very important in the grinding process and have significant impact on the grinding results. Accurate measurement of the internal parameters of ball mill is crucial and indispensable for optimization and control of grinding process. In this paper, a novel tri-sensor measurement method was used to measure the external signals (i.e., bearing pressure, sound intensity and power consumption) of ball mill. Mathematical models, which link the external signals of ball mill with its internal parameters, were established to predict the internal parameters of ball mill. Experimental results showed that the mathematical models could directly predict the internal parameters of ball mill once the external signals were obtained. The tri-sensor measurement method and the mathematical models proposed in this paper provided a new way and solid basis for optimization and control of ball milling.

Jan 1, 2014

By Alexander V. Epiforov, Stanislav V. Balikov

This paper describes of processing tests of 8 flotation concentrates containing precious and base metals by pressure oxidation (POX) method. Concentrates 1 and 2 were gold-copper concentrates. Zinc and silver were by-products in these concentrates. These concentrates were processed by POX with following cyanidation of POX solid residues, copper solvent extraction and zinc carbonate precipitation. The recoveries of gold, copper, silver and zinc from these concentrate were 98, 99, 30 and 99%, respectively. Concentrates 3 and 4 were lead-zinc concentrates. Silver was by-product in concentrate 3. Gold, silver and copper were by-products in concentrate 4. Concentrate 3 was processed by POX with following reduction smelting of POX cakes for primary lead recovery and zinc carbonate precipitation from POX solution. The recoveries of lead and silver into ingot were 96 and 98%, respectively. The recovery of zinc was 99%. Concentrate 4 was processed by POX with following zinc carbonate precipitation and reduction smelting of POX cakes. Copper was precipitated from the POX solution using sodium sulphide prior zinc precipitation. The recovery of zinc into carbonate concentrate was 99%. The recoveries of lead, gold and silver into lead bullion were 95, 99 and 98% respectively. The recovery of copper into sulphide concentrate was 99%. Concentrate 5 was gold-pyrite concentrate, and concentrates 6-8 were double refractory gold-arsenopyrite concentrates. Silver was by-product in these concentrates. These concentrates processed by POX and CIL. The recovery of gold from concentrate 5 was 98%, and from concentrates 6-8 was 85-90. Low gold recovery from concentrates 6-8 was associated with preg-robbing factor. The recovery of silver from gold-sulphide concentrates did not exceed 10-20%. The low silver recovery was associated with argentojarosite formation that is resistant to cyanidation. The flowsheets for complex processing of precious and base metals sulphide flotation concentrates based on this test work results were proposed.

Jan 1, 2018

By A. E. Sobolev

The kinetics of hydrochemical oxidation of antimonite in solutions of nitric acid was studied using the rotating disk method and the factor experiment design. The dependences of the antimonite?s oxidation rate on concentration of nitric acid solutions, temperature, disk rotation frequency, and duration of interaction were determined. The adequate kinetic models allowing calculating the specific oxidation rate at any combination of the values of the influencing factors were obtained. The oxidation process is found to proceed in a mixed mode, close to chemically controlled. Gradually, as the sediments of elemental sulphur and Sb2O5 accumulate on the disk surface, the process becomes controlled by internal diffusion. The observed high (more than second) order of the oxidation rate with respect to the concentration of nitric acid was explained by the autocatalytic action of the acid reduction products. The apparent activation energy depends on the stage of interaction. At the initial stage (in a mixed mode of the process proceeding), it depends on nitric acid concentration and varies from 31.5 kJ?mol?1 (in 2 M HNO3) to 36.1 kJ?mol?1 (in 10 M HNO3). This trend indicates the weakening of diffusion limitations with a nitric acid concentration increase. When the process is controlled by internal diffusion, the apparent activation energy was found to be 14.5 kJ?mol?1. The obtained kinetic characteristics enlarge the database on hydrochemical oxidation kinetics of sulphides and can be used for the elaboration of the recommendations for the effective comprehensive exploitation of antimony-bearing ores and concentrates.

Jan 1, 2014

By X. Y. Zeng

Most Chinese titanium bearing minerals are the composition of magnetite vanadium and ilmenite. All of such mineral processing plants use low intensity magnetic separators to recover magnetite and vanadium goes with magnetite. In the past years most of the plant tails containing about 10% TiO2 were abandoned. Now many of these plants use SLon magnetic separators to recover ilmenite in the roughing stage, which can throw away most of the gangs and slimes with very low cost. The new development of applications of SLon magnetic separators in Chinese ilmenite processing industry is introduced in the paper.

Jan 1, 2014

By R. Singh

The paper presents the results of characterization and beneficiation studies carried out on a lean grade tungsten ore sample from Degana, India. Basically, three different routes, involving gravity separation, magnetic separation, and froth flotation were studied for concentration of the sample by physical and physico-chemical methods. Considering the low recovery by physical methods, efforts were put in to produce a tungsten concentrate by physical methods suitable for subsequent hydrometallurgical recovery of tungsten as ammonium para-tungstate. This strategy proved quite helpful in minimizing the losses of tungsten in tailings. Based upon these studies a novel integrated technological process flow-sheet was developed for the exploitation of lean grade tungsten ore deposit of Degana, India. Keywords: lean tungsten ore, characterization, beneficiation, gravity and magnetic separation, hydrometallurgical extraction, integrated process route

Sep 1, 2012

By E. Emelyanenko, P. Solozhenkin, J. Yagudina, O. Ibragimova

"To recover tetrahedrite-tennantite series minerals from porphyry copper-pyrite ores by the froth flotation method, further research on thiol collectors is launched to promote the utilization efficiency of copper ores. In the present paper the adsorption mechanism of the collectors on tennantite surface has been investigated by computational modeling and FTIR-spectroscopic analysis, which have revealed that the decrease in prognosis of collector activity evaluation (PCAE) for tennantite is in the following order: BX (-0.34318), AEROPHINE 3418A (- 0.61756), AERO 5100 (-14.18857). The lower PCAE the stronger the ability of the collector to interact with the mineral surface of tennantite and form the stable complex. More kinetic reliable conditions to form suitable adsorption layer and rupture of the liquid interlayer with AERO 5100 have been observed by FTIR spectra due to decrease of the intensity and stretching and bending vibrations of water (less than 20 and 65%, respectively). In order to verify the feasibility of AERO 5100 as a collector the industrial flotation tests have been conducted. Flotation performance has improved significantly with the stadially grinding and preflotation of tennantite in intercycle copper flotation that allows to avoid desliming of the fragile mineral and minimize loss of Cu and As in tailings. The recovery of copper in copper concentrate increases by 3.9% with the grade maintained.INTRODUCTIONCopper is one of the first metals extracted and the main material of choice for different high-technology applications today. Currently 80% of the world's copper comes from copper sulfide ores. However, due to the depletion of high-grade copper ores in the world and constantly growing demand for copper, the need to develop processes and technologies to treat copper resources from additional sources such as mine tailings, low grade deposits, industrial wastes and deposits with high impurity levels such as As and Sb will continue to increase (Miller and Craig, 1983). The beneficiation processes of copper-pyrite ores consisting of tennantite-tetrahedrite series minerals are generally complex. Tetrahedrite-tennantite minerals occur as fine anhedral grains intermixed with grains of galena, sphalerite, chalcopyrite, pyrite and other sulfides (Saharova, 1966). The mineralized zones of Southern Urals, Russia deposits correspond with these ore types but tennantite-tetrahedrite series are more abundant in ores at the Uzelginskoye deposit, some samples of which contain 70% of copper in tennantite form (Seravkin et al., 1994). This deposit differs from other similar copper-pyrite ores by thin mutual ""germinating"" minerals and higher content of arsenic (up to 0.8-1 %) which create additional considerable problems in enrichment (Solozhenkin et al., 2016)."

Jan 1, 2018

By Kwang Soon Moon

Liquid ? liquid reactions such as solvent extraction in hydrometallurgy and BTX extraction in petrochemical industry has long suffered from the long retention time mainly due to the limited interfacial area caused by the immiscibility between water and oil phase, requiring typically very large perfect mixer type reactors and tall adsorption towers. A novel spray reactor for immiscible liquids; that is the KISEI Nozzle Reactor (KNR) was introduced, enabling the drastic increase in the interfacial area between the reacting immiscible liquids. Various spray mechanisms were applied in materials processing, e.g. spray drying, powder metallurgy, and aerosol industry, but not in hydrometallurgy. The KISEI Nozzle Reactor(KNR) was fully developed and used in production of biodiesel from the immiscible triglycerides and methanol. An experience with a full production plant facility is briefly discussed in the current paper. With the fog-like methanol spray in oil medium, the trans esterification reaction was almost instantaneous, and transformed the traditional batch trans esterification process into a continuous production process. And above all, with no moving parts in the KISEI Nozzle Reactor (KNR), the process requires minimal operation and maintenance costs. Keywords: immiscible liquids reaction, nozzle spray reactor, continuous biodiesel reactor, hydrometallurgy, organic extraction, micro emulsion

Sep 1, 2012

By V. Buddhiraju

Liberation of valuable minerals from low-grade ores is an important challenge faced by the minerals industry. It is necessary to grind the ore to extremely fine size in order to liberate the mineral from such ores. As it is generally difficult to produce ultra-fine particles of diameter less than 1-10 mm using traditional grinding equipment such as the ball mill and the rod mill, several new types of grinding equipment are being explored to produce ultra-fine particles. The planetary ball mill is promising in that it makes grinding to submicron sizes possible by imparting high energy to the ground powder. It consists of four pots mounted on a disc. The pots and the disc rotate in opposite directions. The high-speed rotation of the pots and the disc makes the grinding media move at high centrifugal velocities leading to high impact energy and thus improving the grinding performance. The planetary mill is currently being explored for its capability to produce ultra-fine particles on a large scale. In this context, there is a need to understand the dynamics of the ultra-fine grinding process within the planetary ball mill. Here, we address this need by studying the movement of media inside the pots and the grinding kinetics, employing both experimental and modeling techniques. The experiments were conducted on a laboratory scale planetary ball mill. The particle size distribution of the powder was monitored to allow an estimate of the grinding kinetics to be made while video images of the media profiles inside the pots were taken to allow quantification of the media movement as a function of process variables such as the media size, percent loading, etc. The population balance modeling (PBM) framework was used to simulate the kinetics of grinding while the discrete element modeling (DEM) approach was utilized to simulate the media motion. The parameters in the population balance model, namely, the specific breakage rate and the breakage distribution function were determined by fitting the batch grinding equation to the experimental data. The predicted powder size distributions were found to be in good agreement with the experimental data. The experimental results have shown that the mean size of product powder decreases as the size of the grinding media decreases. Keywords: population balance modeling, grinding, planetary mill, grinding media, grinding equation

Sep 1, 2012

By A. K. Mukherjee

In this apparatus closed sized particles are placed in a container and then fluidized by passing water through the load of particles. Water flow is adjusted to deposit particles in one or more layers depending on the specific gravity of each of the particles, after which the deposited particles are separated in portions of different specific gravity. The obtained portions represent different ore content of the closed sized fraction. The process is repeated for all other size fractions to generate washability curve of the feed. Three different types of iron ores and one coal sample are tested in this equipment. The theoretical yield-grade curve generated for iron ore feed is unique in absence of any such practice for ore minerals. Similar curve is generated for coal and it is compared with washability curve, an existing practice followed worldwide. This comparison validates the performance of the process and the equipment.

Sep 1, 2012