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By N. J. Bolin

The Aitik copper mine is located in the north of Sweden and the concentrator at the mine started its operation in 1968 with a capacity of 2 Mton ore per year. Since then the operation has expanded several times, and today the capacity is 18 Mton ore per year. A new expansion plan was investigated in 2005, however the building of a new concentrator was found to be a better solution, giving a lower cost, a longer lifetime and more concentrates to the smelter at the coast. Several choices have been evaluated regarding the location of the concentrator?s crushing, grinding, dewatering, process control and water systems. The energy cost comparison has been an important factor when evaluating the various choices. The single most important decision has been in choosing the grinding system. Once again the fully autogenous grinding system, favoured by Boliden, has proven to be the best solution. The location of the mill, high and near the tailing pond, gives lower transportation costs for the ore and tailings, compared to other locations. A new water system will lower the pumping cost, give better control of water circulation to the plant and create fewer problems with permafrost in the tailings disposal area. Molybdenum recovery will be installed in the new plant using a separate circuit. A gold leaching plant was also investigated. Gold leaching is planned for the pyrite concentrate from the chalcopyrite/pyrite separation and the concentrate from the desulphurisation circuit that will be installed on the bulk flotation tailings.

Jan 1, 2014

According to the Darcy?s law, filtration rate should increase with increasing pressure drop (?P) across a filter cake. In centrifugal filtration, ?P is created by the free water present on the surface of a filter cake. Thus, ?P can become negative when the free water disappears from the cake surface, which makes it difficult to achieve low cake moistures. In the present work, we have developed methods of overcoming this problem by either increasing the air pressure inside or applying vacuum outside a centrifuge. Laboratory dewatering tests conducted using these provisions showed that the moistures of various minerals and coal fines can be reduced to the level that can obviate the need for thermal drying. The new concept has been successfully tested both at pilot- and full-scale, which lead to commercial deployment through Decanter Machine, Inc., under the trade name Centribaric® centrifuge. Keywords: dewatering, hyperbaric centrifuge, pressure drop, Darcy?s law, Centribaric® centrifuge

Sep 1, 2012

By J. Bhattacharya

In many different ways industrial raw materials resources industry as a whole has accepted the principles of sustainable development and has made a commitment to move toward this goal. The critical question now is ?how?? While many companies have adopted policies and are implementing community relations programs, sustainability is not always ?lived? throughout the organization. While traditional programs and commitment from the top are critical, employees within all functional areas can advance sustainability. Individuals can make difference at all organizational levels, and it is this collective action that is so critical for enhanced financial performance as well as the preservation of the industry. Keywords: value chains, sustainability, legislation, auditing process

Sep 1, 2012

By Maurício Torem, Gabriela Huaman, Antonio Merma

The purpose of this review paper is to succinctly present the most significant works related to Mineral Processing and Environmental Bioremediation and developed by the Mineral and Environmental Technology Group (METG) of the Materials Engineering Department of the Pontifical Catholic University of Rio de Janeiro (PUC-Rio). In mineral processing it was emphasized the use of the Rhodococcus opacus bacteria as a bioreagent in the bioflotation of some mineral samples (magnesite, calcite, hematite, quartz and apatite). The adsorption of the bacterial cells on the mineral surface can be due to specific and/or non-specific interactions, which will depend on several factors, as their surface charge and hydrophobic character. The zeta potential evaluation of the mineral particles before and after interaction with the R. opacus cells showed that the biomass modified the zeta potential profiles of the minerals, which confirm the adsorption of bacterial cells on the mineral surface. Moreover, the bacterial cells adsorbed caused a change in the mineral flotability which is related to a change in their hydrophobic character, thus, the mineral bioflotability was found to be dependent on the pH and the bacterial concentration. On the other hand, the environmental bioremetiation assessed the biosorption potential of three metal ions (lead, copper, and cobalt) by four different biomass Streptomyces lunalinharesii, Rhodococcus opacus, Rhodococcus ruber and coconut shell powder. For this purpose, biosorption process was characterized under different operating conditions such as initial pH and biosorbent dosage. The Freundlich and Langmuir isotherm models were applied to the equilibrium data obtained at different concentration.

Jan 1, 2014

By A. V. Faiberg

Currently, the interest to conditioning of cyanide-bearing recycled solutions with high-grade of base metals, in particular, copper has significantly grown. This can be explained by two major factors. Firstly, there are strict regulations on cyanides amount in tails and higher cost of detoxification processes. This problem can be easily solved during the ore treatment using the conditioning of solutions and water recycling. Secondly, the presence of other metals minerals which react with cyanide during gold leaching resulting in high cyanide consumption. The presence of copper is a major problem. Many copper minerals react with cyanide with the formation of cyanide complexes-Cu(CN)2-, Cu(CN)32- and Cu(CN)43-. One mole of copper consumes 2-4 moles of free cyanide. Availability of cyanide-soluble copper minerals has deleterious effect on gold leaching (gold recovery, cyanide consumption, tails detoxification, efficiency of gold elution and electrowinning). The precipitation of copper from the solutions improves gold recovery by CIL. The removal and recycling of cyanide allowed the reduction of cyanide addition to the process. The recycling of spent cyanide-bearing solutions based on the removal of copper and the return of cyanide bound in complex compounds for leaching process is an optimal way of solving the problem of gold-bearing copper ores treatment. By using the technology, an adverse impact onto gold recovery process is eliminated and at the same time reducing the cyanide consumption. Today, processes and methods of high-grade copper leaching solutions conditioning before and after gold recovery have been developed, which combine two ways of copper recovery: as a saleable product and cyanide to recover gold and reduce total operating costs. They are Cutech, MNR, SART, Cyanomet, AuGment, Vitrokele, Hannah and Cyanisorb. At the same time, these technologies have not been studied enough and described in literature. Data on parameters and operating conditions as well as introduction is not available. The conditioning technology of recycled solutions developed by IRGIREDMET JSC allows copper to be recovered as high quality concentrate and at the same time free cyanide regeneration in the recycled solution which is amenable to gold leaching. This technology was commercialized at a mine in Kazakhstan in 2008. The removal and recycling of cyanide does not require additional cyanide and is cost-effective. More cost-efficiency is achievable through selling copper concentrates, closed water cycle without the detoxification of effluents and enhanced gold recovery by CIL and cathode quality.

Sep 1, 2012

By S. Cagirici, Z. Öztürk, A. Hassanzadeh

Many flotation kinetics models have been studied in the literature. Their applicability was extensively investigated and argued in detail. However, model selection criteria were not adequately discussed from the statistical points of view. In this investigation, the kinetic behavior of a complex copper sulfide ore was studied in a mechanical Denver flotation cell focusing on flotation kinetics of chalcopyrite, pyrite and molybdenite. Different flotation kinetics models including nine common empirical models and four mathematical models namely Hill, Chapman (Sigmodial function), single rectangular (Hyperbola equation) and exponential were applied to the experimental data. In addition to assessment of the goodness of fit criterion for each model, a factor of model complexity was considered using information criteria (IC) (i.e. Bayesian information (BIC), low of iterated logarithm (LILC) and Akaike information (AIC) indices). The obtained results showed that the IC indices could simply manifest the best-fitted model to the experimental data. Whereas, the coefficient of determination values (R2) were relatively same for all models. By taking the R2 and model complexity criteria into account, the exponential model was chosen as the best representative mathematical model to demonstrate chalcopyrite kinetic behavior. However, Chapman model was selected as the best one for the flotation of pyrite and molybdenite. In case of the common first-order flotation kinetics models, fast and slow flotation kinetic model (Kelsall) was reasonably fitted the best to the given data of chalcopyrite. However, the gas/solid kinetics adsorption model was chosen as the best-fitted one for pyrite and molybdenite. Furthermore, it was found that mathematical models represent better results in association with flotation kinetic behavior of chalcopyrite, pyrite and molybdenite due to the consideration of more parameters in modeling. Finally, it was concluded that the IC indices must be applied to the process of model selection due to consideration of goodness of fit, complexity of a model and model consistency.

Jan 1, 2018

By A. Lewis

"Thiol collectors including the xanthates and dithiophosphates have dominated the sulfide mineral processing industry for over a century. Tecflote represents completely different chemistry, without sulfur or phosphorus, and will float all sulfides and associated precious metals. As these collectors are surfactant in nature, they comprise a head group which binds to mineral surfaces, a spacer and a long hydrophobic tail. The modification of the spacer behind the head group allows for collector optimisation for different sulfide ore types and process conditions.The Tecflote surfactants have been designed to be either very selective against pyrite at the natural pH of the ore (pH 7-9) or to float all sulfides including pyrite. Depending on the ore type and the process flow sheet, the use of lime can be maintained, reduced or completely eliminated.Tecflote can be used either as a rougher collector giving good recovery and grade for the sulfide minerals or it can be used to target valuable minerals after regrind and through cleaner flotation. It has repeatedly shown to be very effective at holding onto gold through the cleaner steps. The low solubility has a significant impact on the mechanism and surface activity of the collector, resulting in a very different flotation response compared to conventional thiol collectors.INTRODUCTIONXanthate was first made in 1882 by Zeise and first used in flotation in 1924 (Keller, 2018). In 1946 Keller patented thionocarbamate as a collector, which was produced by Dow Chemicals (Keller, 2018). Later it was replaced by Dow product Z-200, while dialkylthionocarbamate was discovered by Harris et al. (Harris, 1954. No significant chemistry change to collectors has occurred since they were introduced in the mid-20th century and now that the feed grades have been declining over the last decades creating a need to find more selective collectors to extract difficult and complex ores and pushing the industry to look at other reagents."

Jan 1, 2018

By R. L. Pascual, W. J. Whiten

"The froth flotation process is not well understood. Both flotation models, and the parameters used to describe the stream flows are not well defined. They in fact vary considerably in different applications. This creates difficulties is designing a simulation program suitable for use by plant personnel, consultants, and researchers. In addition to simulation, an effective simulation program can be expected to provide a range of other services.This paper shows how a process circuit simulator can be designed with sufficient flexibility to satisfy these needs, and discusses some of the additional services."

Jan 1, 2003

By P. Spolaore

In the frame of Bioshale FP6 project, the bioprocessing of a polymetallic and polymineral concentrate produced in an industrial operation in Lubin, Poland, was assessed. Following successful batch culture tests, processing in continuous conditions was tested to determine the main specifications for the application of the stirred-tank technology to this sulphide concentrate from black shale ores. The experimental work was carried out in a laboratory-scale unit consisting of 3 stirred tanks (50L or 20L) using an acidophilic and moderate thermophilic bacterial population. Different configurations of the unit and key operating parameters were tested (nutrient medium composition, solids concentration, rates of agitation and aeration). Scientific and technical approaches, such as bacterial community structure and mineralogical analysis were implemented in order to better understand the chemical and biochemical reactions occurring in the system. Using the data produced during the continuous operation, downstream processing assessment for both copper and silver recovery was also carried out. The best copper recovery obtained in the continuous operation was 92% and a hot brine leaching of the bioleach residue (PLINT process) allowed to recover 92% of the silver. A preliminary tech-no-economic evaluation of Lubin concentrate bioprocessing including bioleaching, copper and silver recoveries demonstrated the potential economic feasibility. Recovery of silver plays an important role in the economy of the process. This study presents promising values to further investigate this bioprocessing option.

Jan 1, 2014

By F. Waanders, Campbell. Q.

This project was specifically aimed at using increased acceleration separation, as a method to optimize the recovery of gold in an ore body mainly consisting of hematite where the specific gravity of gold is much higher in comparison to the carrying material, making it possible to separate gold from other materials like silica, base metals and their oxides, usually associated with gravitation-gold-recovery-processes. The ore body investigated in this project originated from a gold reef containing a large portion of gold locked inside the gold pyrite complexes, which was mined and treated in a conventional way. After gold extraction, the material was pumped to a tailings dump and the gold extraction of this dump was investigated. In order to assemble a concentration plant setup, the head grade and size distribution of the dump and bulk sample were determined accurately. Chemical analysis and mineralogical examination were done on a representative sample of the bulk sample, to determine the chemical composition of the material. The results obtained thereof were evaluated and a pilot plant was configured. A bulk sample was processed in the pilot plant and the results were evaluated. The results at optimum acceleration forces applied, resulted in a recovery of 5% of the mass, with a gold concentrate of 90 g/t Au, which represented 58% recovery of the gold. The hematite with high specific gravity as main phase positively influenced the high acceleration separation process. It proved that if the specific gravity of particles in a suspension were increased, high acceleration separation could be applied effectively to separate much smaller particle sizes.

Jan 1, 2014

By O. N. Mohanty, S. Mohan Rao, N. D. Rao, T. Mukherjee, P. V. T. Rao

"Tata Steel has its captive chromite resources at Sukinda, Orissa. They contain two ore types, i.e. (i) Ferruginous and (ii) Siliceous. The generation of off-grade ores is an increasing trend and simultaneously customer quality requirements are becoming ever more stringent. The ferruginous type ore also contains a considerable quantity of in-situ fines (~20% particles below 0.5 mm) that compound the beneficiation problem.In this paper, new strategies are discussed for producing additional value.added products after evaluating the present beneficiation practice in terms of changing market scenario, processing capability of the plant and ore characteristic. They would entail use of MGS - an enhanced gravity separator, for recovering additional products from plant tailings; production of ferruginous coarse concentrates (-3+0.5 mm with ~46% Cr2O3) using jigs; production of marketable grade lumpy (-40+10 mm size) concentrates from low grade siliceous ore using jigs and >2.8 Cr/Fe ratio siliceous ore fines treated in the Chrome Ore Beneficiation plant gravity circuit units and low intensity magnetic separator. The studies indicate that it is possible to recover 79-80% of the chromite, against a theoretical maximum of 82% from both the ore types, in the form of several marketable grade concentrates that would also include refractory grade."

Jan 1, 2003

By Carlos Rabanal, Levi Guzmán

"The concern regarding grinding media consumption rates is as old as the invention of the tumbling mill. Over the years many materials and grinding media shapes have been tested. Through all this, steel grinding balls have proved to be the most effective media for comminution in tumbling mills. There have been several approaches to be able to the wear of the ball charge in any given mill, all of them based on limited empirical evidence. The mining industry still utilizes the Bond Abrasion test that was developed in the 1960´s. As shown later in this publication, this approach shows error greater than 60%. More recently, in 2007, Radziszewski from Mc Gill University has proposed a different total grinding media wear model; this model is based on decoupling the effects of the abrasion, corrosion and impact wear mechanisms. Also in 2007, Benavente, at the time with Moly-Cop Peru, presented an empirical model relating both ore properties and operational conditions that would affect the wear performance of the grinding media. For the database referred in this article, Benavente’s model shows an average error of ± 12% which represents a higher degree of improvement in comparison with previous approaches. The current paper presents recent research conducted by Moly-Cop Peru to further improve the capability of the empirical model originally developed by Benavente to estimate grinding media wear rates. The work performed included extensive determinations of the Bond Abrasion Index for different types of ores, collected at industrial grinding applications where the corresponding operational information was made available. The results of the research enabled us to build a more robust and confident model for estimating the grinding media wear rate. The average error of this new model is in the order of ± 9% which is a significant improvement over the models previously described."

Jan 1, 2014

By B. Y. Tuo

This article presents results of studies performed to determine the feasibility of using low-grade limonite ores from Yunnan deposit. Laboratory tests and commercial trials have shown that the magnetic separation can be performed with a high high-grade concentrates. The quality of the preparation concentration meets the requirements for blast-furnace smelting. The results as a whole demonstrate the feasibility of utilizing bank limonite ore. Yunnan limonite?s magnetic separation, roasting magnetic separation and flotation experimental study shows that grade of the ore grade can been from 32.91% heighten to 58.64%, a recovery of iron is 90.87%, productive rate is 51% through orthogonal test optimization; roasting magnetic separation can obtain that the grade of iron preparation concentrate is 61.16%, recovery is 67.39%, productive rate is 36%. As far as economy and enviormental protection is concerned, strong mag-netic suggested a more appropriate process. Keywords: Limonite; Roast; Magnetic separation

Jan 1, 2014

By O. A. Bascur

It is difficult to analyse the economics without an integrated view of mine transactions, stockpile inventories, process flows and assays. The lack of integration of mining and metallurgical information with sufficient detail to analyse and act is a problem. However, to take action requires real time information from manufacturing assets, corrected for gross errors from trucks, shovels, conveyors, faulty sensors, bad instrument calibration. Validation methods use process models to identify inconsistent information in the case of corrupt actionable information. This paper presents new strategies that transform the data into business information for continuous improvement and optimization. This technical presentation will review recent implementations enabling large metallurgical complexes to improve their data quality for overall production and energy management. A competence center emerges as an enabler for implementing operational intelligence. The evolution of Web services to troubleshoot plant information and to collaborate at the enterprise level is presented.

Jan 1, 2014

By V. G. Minenko, V. A. Chanturiya, A. L. Samusev

Eudialyte is one of perspective resources of zirconium and other rare earth elements (REEs). Large reserves of eudialyte concentrated in the Murmansk region of the Russian Federation. Usually, technologies of REE treatment include the decomposition of eudialyte concentrate in different acidic, extraction and utilization of all components. The main problems in the leaching of eudialyte include are: the formation of an unfiltered silicon-containing gel; low recovery of REE; difficulty extraction of metals from the productive solution; high aggressiveness of the reagents. One of the promising trends of intensification of the processing of hard-to-degrease rare metal raw materials is the use of energy methods for affecting mineral suspensions. These methods make it possible to increase the efficiency of break up fine-dispersed mineral complexes and extracting micro- and nanoparticles of a valuable component in subsequent deep processing. The purpose of this work is to investigate the effect of energy impacts on the nitric acid leaching of eudialyte concentrate. Experimental studies were carried out in a developed laboratory facility that makes it possible to evaluate the effect of electrochemical, ultrasonic and combined effects on the leaching of zirconium and REE from eudialyte concentrate. The studies carried out on the samples of eudialyte concentrate with the size class of -0.315 + 0.063 mm showed that the use of electrochemical and acoustic effects increases the extraction of ZrO2 in the production solution in 1.6 - 2.5 times, REE in 1.3 - 2.2 times, respectively. An analysis of the microstructure and phase composition of the surface of the eudialyte concentrate showed that the intensification of the leaching process is due to surface cleaning from the silicon-containing gel, as well as the opening of capillary channels and microcracks, which accelerates mass-transfer processes. The results obtained open wide opportunities for creation of modern and effective technology of processing of eudialyte concentrate, producing high-quality zirconium products and REE.

Jan 1, 2018

By Kazutoshi Haga, Batnasan Altansukh, Shirchinnamjil Nyamdelger, Atsushi Shibayama, Narankhuu Ariunbolor, Gunchin Burmaa

In this study, the authors investigated the capability of an acidic thiourea solution and silicon-organic polymers (PSTM-3c, PSTM-3T) as ion-exchange resins to recover of gold from gold-bearing ore concentrates. Firstly, elemental gold present in flotation concentrates was dissolved by leaching with a solution of nitric acid and thiourea under the optimized conditions. The best result on gold thiourea leaching was obtained under a nitric acid concentration of 2 N, thiourea concentration of 2 %, and oxidant (Fe2(SO4)3) concentration of 3 %, solid:liquid ratio (S:L) of 1:20, leaching time of 6 hours at 20 °C with a gold recovery of 93.7 % for a gold flotation (unroasted) concentrate. For the roasted gold concentrate, the dissolution of gold was 94.8% under the optimized leaching condition as nitric acid concentration of 0.5 N, thiourea concentration of 2 %, and the oxidant concentration of 1 %, S:L ratio of 1:10, leaching time of 4 hours at 50 °C. Secondly, a series of sorption tests was carried out on a pregnant leach solution containing gold complex Au[S=C(NH2)2]2+ using silicon-organic polymers (PSTM-3c and PSTM-3T), respectively. The effects of solution pH, adsorption time and temperature in the sorption process are also studied. As the results, the PSTM-3c and PSTM-3T polymers were adsorbed about 94.4 % and 95.1 % gold from the pregnant leach solutions under the optimum sorption conditions, respectively. It was found that the both PSTM-3c and PSTM-3T polymers were effective for the recovery of gold from the pregnant leach solution of thiourea. Adsorption activity of the PSTM-3c and PSTM-3T polymers was confirmed by new peaks near 1700 cm-1 in the FT-IR spectrum of the gold-adsorbed polymers, respectively.

Jan 1, 2014

By Áureo Del Vecchio, Lídia Dely Alves de Sousa, José Pereira

The potassium demand for agriculture purposes has increased in Brazil, which has great deficit of internal demands. Potassium-rich rocks have been used as fertilizers as technological alternatives for agriculture aimed to reduce the amount of chemicals and the sector dependence for such products. Vermiculite tailings from União Brasileira de Mineração - UBM, at Santa Luzia - PB, was studied aiming their application in agriculture by potassium release. The sample was analyzed by XRF and XRD; studies on release kinetic with particles smaller than 2 mm added of organic acids (citric and oxalic) at 10-2 mol/L concentration; samples were analyzed by XRD after kinetic assays. The work was conducted using a shaker incubator at 300-rpm agitation and time variation to better understand the potassium availability in the ground. Results show the presence of K2O at 3.46% concentration. Citric and oxalic acids increased the release speed to almost the same level with speed coefficients (k) of 2.61x10-2 h-1/2 and 2.55x10-2 h-1/2 respectively. In statistical terms for both acids, the linear equation represents more than 99.0% of the experimental assays. Stonemeal was applied to banana seedlings in experiment conducted in a greenhouse. The use of vermiculite tailings in banana seedlings promoted potassium absorption, which influenced its growth. The amount of potassium liberated from vermiculite tailings could be used as a long-term alternative to fertilizers in agriculture cultures.

Jan 1, 2014

By P. Harris, D Bradshaw

"Comparison of the two most commonly used classes of depressant in the South African platinum industry is complicated by the fact that these polymers induce different effects on the surfaces onto which they adsorb. The use of carboxymethyl cellulose (CMC), which is ionically charged in solution, can lead to increased particle dispersion in addition to the effect of reduced surface hydrophobicity (depression). Guar is typically only slightly charged in solution. Comparison of these two depressants is complicated since it is uncertain whether differences in their action is a result of either depression of dispersion effects.This work investigates the role of dispersion independently to that of depression in the batch flotation of a platinum bearing ore. An inorganic dispersant, sodium hexametaphosphate (NaHMP) was added in parallel to the uncharged guar depressant to simulate the action of depressants with varying degrees of dispersion. By distinguishing between the material recovered by entrainment and the floatable gangue and by including the effects of froth stability it was possible to decouple the effects of dispersion and depression.The results show that both dispersion and depression led to increased grade of the sulphide minerals. Depression leads to a decreased recovery of floatable gangue minerals. Dispersion leads to an increased recovery rate of these minerals and an accompanying decrease in froth stability."

Jan 1, 2003

By G. Zaitsev

In mining and mineral processing, ammonium and nitrate from residues of explosives and other sources are discharged to the aquatic environment. Nitrogenous compounds in mine water can adversely affect the aquatic environment. The aim of this work was to study the biological removal of nitrate from cold inorganic mine water at the pilot-scale in an operating underground mine. Seven-months pilot testing on biological removal of nitrate from inorganic mine water was successfully performed in denitrifying fixed-bed biofilm reactors. The feed to denitrification bioreactors contained 11 mg NO3--N/L. Methanol was added as an external carbon source to the denitrifying bio-reactor since the inorganic mine water contained only traces of organic compounds (<CODCr (50 mgO2/L). Nitrate removal reached 75 g NO3--N/m3/d with removal efficiencies above 95% at temperature below 4°C. Thus, removal of explosives-residues from cold inorganic mine water was shown in pilot-scale biofilm reactors.

Jan 1, 2014

By Vladimir G. Kochnev

An innovative AG and SAG technology aimed to be applied in grinding of ores and in the production of construction materials is described. A novel design of a cantilever-type mill capable to operate in autogenous, semi-autogenous and ball grinding mode ensures easy delivery and installation even in remote areas, and low capital and operating costs. Results of the tests of the new heel-shaped liners performed by TTD jointly with ALROSA, MINTEK and Anglo-American Corporation are reported. The approach includes also a novel discharge grid design and a technique of treating the material of critical size. These innovations make grinding in AG and SAG mills dramatically more effective, with an increase in the throughput rate and a reduction in power consumption ranging from 1.5 to 2 times.

Jan 1, 2003