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By M. R. Shadnam

This contribution provides an assessment of research and development efforts to optimize SOx, NOx and mercury capture in flue gas. Coa, characteristics and combustion conditions in a power plant have an impact on the types and concentration of flue gas pollutants. These factors can also affect the amount of pollutant removed. This contribution would also provide a comparative study of the technologies that holistically aim remova, of SOx, NOx and mercury altogether in coal-fired power plants. A portion of this contribution provides background information on regulatory drivers.

Jan 1, 2010

By Patrick Laflamme, Jean-François Boulanger

Les minerais de cuivre sulfurés, qui représentent 80% de la production mondiale de cuivre, imposent une étape de concentration des minéraux, premièrement pour atteindre une teneur en cuivre minimale qui permette le traitement pyrométallurgique, mais aussi pour limiter la présence d’élément pénalisants (délétères). Cette introduction offre un survol des principes, limites et pistes d’améliorations touchant la concentration des minéraux de cuivre.

May 2, 2024

"In flotation research, relatively little attention has been paid to understanding particle-bubble detachment phenomena compared with attachment processes. With CFD models now incorporating attachment/detachment kinetics, it is important to obtain more accurate formulations for detachment probability. The formula most often used is due to Bloom and Heindel (2002) who proposed that the rate of detachment would equal the product of detachment frequency, as previously estimated by other authors, and probability of destabilization, as estimated previously by Schulze. These two factors both account for the balance between stabilization and destabilization forces, so the product accounts for this effect twice. An integrated procedure has been followed to estimate the overall detachment rate by re-analysing the process. In this analysis, detachment rate is calculated as the frequency of eddy-aggregate interactions (or “collisions”) sufficiently energetic to cause detachment. The Bond number analysis of Schulze has been incorporated into the turbulence frequency analysis of previous authors in an integrated way. The new formulation has essentially the same type of dependencies as the previous model, but gives a lower detachment frequency. Detachment frequency has been calculated using the new formula for conditions relevant to an industrial flotation cell. INTRODUCTIONIt is well known that the effectiveness of froth flotation for separating different minerals is limited to the particle size range of approximately 10–100 mm (Trahar & Warren, 1976; Trahar, 1981). Fine particles tend to follow fluid streamlines around bubbles limiting the likelihood of bubble–particle collision, while coarse particles can be more easily detached from bubbles before collection can be achieved.Phenomenological models have been developed to quantify the physico-chemical aspects of flotation in order to better understand factors affecting these limitations, and to suggest ways of broadening the window of feasible flotation. Koh and Schwarz (2008) have incorporated these models into computational fluid dynamics (CFD) models of flotation cells, which have then been used for design and scale-up purposes (Schwarz et al., 2015). The models are based on dividing the process of bubble–particle interaction into three subprocesses: collision, adhesion and detachment. Of these, the hydrodynamics of bubble–particle collision and the probability of adhesion have been studied most extensively, while the dynamics of detachment have received relatively little attention from investigators."

Jan 1, 2016

By Ji Wang

Reflective in-seam wave detection has the advantages of a far detection range and wide applicability. It has been successfully used in detection of many abnormal geological structures in work-faces, such as faults and collapse columns. However, a reflective in-seam wave is a dispersion wave. It has weak energy and is always covered by the direct in-seam wave. In the past, underground seismic explorations were not able to image the opposite roadway using reflective in-seam waves. To solve this problem, we propose a new method of reflective in-seam wave imaging based on adaptive dispersion filtering. This method processes the reflective in-seam wave using a filter with the parameter of transmission distance. The degree of similarity of the filtered and the explosion signal is used to estimate the transmission distance and image the reflective objects. We test and verify this method using real underground seismic data. This research is helpful for the detection of coal mine goafs and abandoned roadways in work-faces or in front of tunneling ends.

Aug 1, 2013

By M. Mahdi Aboutalebi, Roderick I. L. Guthrie, Mihaiela Isac

"A preliminary computational fluid flow model has been developed to simulate the flow field of liquid steel in the mold region of billet mold casting. This study reports the effect of different Submerged Entry Nozzles (SEN) on the fluid flow in round and square billet, curved mold, casters. In this study, ANSYS Fluent 14.5 software was used to model the 3-D turbulent flow of liquid steel. The standard k-0 model was used to simulate turbulence in the mold region. Similarly, the species transport equations were discretized to simulate the dye injection test into the mold cavity. The behavior of flow in the mold region was validated against previous experimental work. Predicted results showed that different nozzle types plus the slight curvatures in the molds can significantly influence the flow patterns generated within the mold region, and thereby affect the finished quality of the billet products.INTRODUCTIONConventional Continuous Casting (C.C) processes are presently used to solidify more than 95% of the 1.5 billion tons of steel now produced in the world annually (World Steel in Figure, 2014). This overwhelming contribution of C.C processes for steel production is the prime motivation for this study, in order to understand and optimize the casting processes and thereby reduce internal defects and minimize energy consumption. The primary objective of all C.C processes is to maintain liquid metal purity during the casting process and to create a uniform flow within the caster so as to avoid internal and external defects. In this regard, studying fluid flows in the mold region of continuous caster has attracted many research groups, in both academia and industry, in recent years. The mold region is one of the most critical parts of the C.C. process, in which the transport phenomena associated with this region can significantly affect the quality of the final products. Thus, proper control of fluid flows within this region can be expected to greatly decrease both internal and surface defects such as Oscillation Marks (OM), inclusion entrapment, and Mold Powder Entrapment (MPE). In the casting process, the fluid flow in the mold region can be affected by a number of variables, such as; the flow control system (stopper rod or slide gate), nozzle geometry, SEN (Submerged Entry Nozzle) depth, casting speed, mold dimensions, gas injection, and the application of electromagnetic fields. One of the most influential and easily-changed fluid flows are the jets of steel issuing from the SEN. Nozzle geometries are variable, consisting of a number of exit ports, different port angles, and/or port sizes, the bottom shape of the nozzle, and the SEN immersion depth (Thomas, 2001). The SEN characteristics can markedly affect meniscus surface velocities, surface level profiles, and turbulence levels that can vary in terms of the frequency and the magnitude of their fluctuations."

Jan 1, 2016

By Q. B. Li, B. Gonçalves da Silva, J. T. Germaine, H. H. Einstein, Z. Moradian

"Shale gas and oil production has grown rapidly in recent years, and consequently there are increasing demands to understand the mechanical and microseismic properties of shale. Acoustic emission (AE) monitoring provides useful information on the fracture mechanisms of shale rocks, and provides a basis for interpreting field seismic observations. While there have been attempts for microseismic monitoring of conventional hydrocarbon reservoirs, shale presents a large number of issues that require further investigation. For this purpose, experiments were conducted to understand the characteristics of the AE waveforms propagated through Opalinus shale rock in the time and frequency domains. Frequency range, arrival time, first arrival amplitude and other parameters such as counts, duration and energy of the waves generated from artificial and natural sources in the shale specimens were detected and compared with AE characteristics of granite, a brittle rock that has been extensively investigated. The experimental tests showed that there are some important factors that influence the analyses and interpretations of seismic surveys and microseismic monitoring of shale compared to granite. One of these factors is the anisotropic behavior of shale that causes the wave to propagate with different velocities in different directions. Also bedding planes and micro-discontinuities in the shale cause attenuation of the waves. Thus the AE waveforms that arrive at the sensor are a distorted and attenuated versions of the source waveform.INTRODUCTIONMonitoring microseismic activity from hydraulic fracturing of shale provides vital information for mapping injection paths and fluid migration in order to check the effectiveness of the hydraulic fracture stimulation. Analysis of microseismic source locations can be used to identify fracture networks induced or mobilized during the hydraulic fracturing operation (Rotherd and Shapiro, 2003). On the other hand, by monitoring and assessing detected signals from hydraulic fracturing one can evaluate the induced seismic impact of the stimulation operation.While there have been attempts to monitor microseismic events in conventional hydrocarbon reservoirs, shale presents a large number of issues that require further investigation. For this purpose, experiments were conducted on Opalinus shale to understand its acoustic emission (AE) characteristics in the time and frequency domains."

Jan 1, 2015

By Jean Robitaille

La découverte du gisement du puits Penna a nécessité une révision complète de tous les circuits du concentrateur Laronde pour permettre, premièrement, l?adaptation du procédé à la nouvelle minéralogie et deuxièmement, l'accroissement du tonnage de 1800* à 4500 t/j. Aux circuits existants de broyage, de flottation du cuivre, de cyanuration et du charbon en pulpe, les circuits suivants furent greffés : broyage semi-autogène, flottation du zinc, manutention des concentrés (épaississage, filtration, entreposage et chargement automatisé), décantation à contrecourant et précipitation au zinc, destruction des cyanures et remblai en pâte. Cet article se veut une revue des différentes étapes du projet d'agrandissement du concentrateur qui se sont effectuées par phases progressives de 1997 à 2000. De plus, une description des nouvelles technologies sélectionnées et implantées est présentée.

May 1, 2001

By P. Plante

Contaminated neutral drainage (CND) is characterized by the presence of metal concentrations above regulatory requirements at circumneutral pH in mine drainage. The generation of CND by tailings and waste rocks is a growing concern for the mining industry due to increasingly restrictive regulatory requirements. Difficulties in CND prediction arise from the low oxidation rates of sulfide minerals and from the metal retention potential within the wastes. In fact, sorption phenomena may induce an important delay in the development of CND. For now, it is not possible to adequately consider this delay using the prediction tools developed for acid-mine drainage, such as humidity cells, columns and lysimeters. This work aims to present the new approaches currently under study for CND prediction, particularly the use of a chelating agent in kinetic tests. The main challenge of CND prediction is to quantify the metal retention potential of mine wastes, especially when sorption phenomena are involved in metal retention. Three approaches are currently used to overcome this difficulty. Firstly, the sorption potential is estimated using batch sorption studies. The second approach consists of artificially saturating the sorption potential of the mine waste by contact with a contaminated leachate in sorption-enabling conditions until saturation of the retention potential. These approaches both require that the possible metals involved in CND are known (as well as their chemical speciation) prior to the tests, which require an exhaustive material characterization. Although the two methods enable a qualitative estimation of the retention potential of mine wastes, their results are difficult to scale up from the laboratory to the field since some important parameters are not taken into account. A third proposed approach consists of inhibiting metal sorption at the source using chelating agents. The hypothesis is that chelating the metals immediately upon their release from the oxidation of sulfide minerals will inhibit all geochemical interactions (sorption, complexation, secondary mineral precipitation, ion exchange, etc.) between the metal and its environment. The ideal chelating agent will inhibit geochemical interactions after metal release in the drainage waters without having any impact on the sulfide oxidation and acid neutralisation rates. These approaches were tested over a waste rock sample that is known to naturally generate CND after a few decades of weathering. Results show that kinetic testing (weathering cell, ± 70 g samples) using a chelating agent (EDTA) in the leaching water renders higher metal concentrations in the leachates than a control sample without EDTA, suggesting that sorption (and possibly other geochemical interactions) is inhibited. These results suggest that the combination of these approaches can be efficiently used for more precise CND prediction from mine wastes. Future work will be done using the chelating agent approach over larger scale tests such as columns (± 80 kg samples) and field cells (± 100 tons) in order to propose an integrated approach for CND prediction.

Aug 1, 2013

By D. L. Johnston

"Function and ApplicationsWater-only cyclones, (WOC) are a dynamic mineral separator which cause minerals to separate in a water medium by virtue of difference in specific gravity. Figure 1 shows diagramatic plan and sectional views of a water-only cyclone.A slurry of mineral matter and water is fed through the inlet opening under gravitational or pump pressure. The combined effect of centrifugal action and conical shape is to concentrate the heaviest fraction of mineral on the periphery and bottom of the cyclone. This layer of higher specific gravity particles increases in thickness and density between the cyclone inlet and apex. The action in the bed of higher gravity particles formed in the flattened portion of the cone surrounding the tip of the vortex finder deter;nines the specific gravity of separation or cut-point. Mineral particles of lower specific gravity flow with the bulk of the water, out the vortex finder. Mineral particles of higher specific gravity flow with little water out the apex. A more technically e:mct description of the functioning of the water-only cyclone can be found in previous publications noted in the references.The water-only cyclone was invented and refined by J. Vis man, formerly of the Canadian Mines Branch staff, between 1958 and 1965. The first industrial application noted in the literature was when it was introduced as a cleaner for fine coal in 1962. Since 1970 the water-only cyclone has become a common separation apparatus in many Canadian and foreign coal processing plants. The only other mineral industry application known to the author is in separation of gold bearing heavy minerals from sand<'>. The potential does exist for other applications and this area deserves to be investigated more thoroughly than it has been."

Jan 1, 1989

By G. Morin, G. Marin, M. C. Parr, J. Carignan

"Investment casting offers many advantages for the near net shape production of complex geometries, however, molten titanium reacts with most of the refractories used in investment casting shelling systems, which leads to the formation of an oxygen contaminated surface layer. This layer, called alpha case, is 0.1 to 0.6 millimeters in thickness according to the casting section size and must be removed either by mechanical or chemical milling processes. Alpha case removal processes affect casting tolerances and may contaminate the part intended for medical applications (e.g. embedding of abrasive grit media in the alloy). A shelling system based on an yttria prime slurry has been developed and was found to almost suppress the mold metal reaction. Yttria is an expensive refractory, but slurry life was found acceptable for small castings using a closed container and flow coating process instead of conventional pattern dipping. Alpha case depth has been determined for Ti6Al4V by metallographic techniques and microhardness measurements on different step block casting cross sections. Alumina and yttria second prime stuccos were evaluated in this study. The shelling system minimizes finishing operations in the production of casting for medical applications.INTRODUCTIONTitanium investment castings have been in the commercial market since the beginning of the titanium era in the mid 50’s. Investment casting is a cost effective way to produce complex parts for medical, aerospace and chemical processes applications. Investment casting of titanium is difficult due to the high reactivity of titanium with air and refractories used for shell mold building especially for the face coat. Melting is done under vacuum and no shelling system has been proven effective to suppress the mold-metal reaction yet. The main issue with the mold-metal reaction is the formation of an oxygen enriched zone at the surface of the castings named alpha case (Frueh et al., 1997; Kim, 2002; Saha, 1986). The alpha case is brittle, reduce the fatigue life in service of the parts and must be removed by chemical milling.For industrial purposes, calcia partially stabilized zirconia based slurries have become widely used in titanium investment casting for primary coats due to a combination of limited metal shell reaction. Calcia stabilized zirconia slurries have an acceptable shelf life and offer an interesting production window. Our experience shows that a resulting alpha case depth is 280 micrometers for a casting section of 6.35 mm in thickness is typical with such a shelling system (Morin, 2013)."

Jan 1, 2016

By P. L. Wright

"This is a brief history of the development of the mining project, with a description of the proven geology. The paper describes how the experiences gained progressively demanded change in the mine design. The equipment used is described, together with methods of working. Interesting facts have been proved regarding gas emissions and roof. supi;iort. The. working cycles evolved are completely flexible m operation and lend themselves to maximum utilization of the most productive units. The two underground mines are compared, showing the variance in conditions already experienced. Programs currently in operation to improve standards and production are: the training of miners, maintenance men and officials; experiments in floor consolidation and continuing roof support trials; and the effect of comparative stability of working crews on the performance of the operation."

Jan 1, 1973

By Kevin Azocar, Jim Hazzard

"Slope stability analysis is performed most commonly using limit equilibrium calculations or numerical models assuming a two-dimensional slice through an infinitely long slope surface. In areas such as open pit mining, where most slope surfaces are not planar, the importance of curvature becomes important due to the economic gains associated with creating a steeper slope. With advances in computing capabilities within the last decade, three-dimensional slope analysis can be performed within reasonable time frames. Some work has been done on the potential importance of curvature on slope stability, mainly assuming homogenous materials with a circular shear-failure mechanism. However, many open pit mines are excavated in jointed rock mass where a completely different set of failure mechanisms can be seen. Depending on the geometry and radius of the pit, the curved geometry may influence the factor of safety and failure behaviour compared to a two-dimensional slice.A series of numerical analyses were performed to investigate the effect of curvature on jointed rock slope stability compared to an equivalent two-dimensional slope analysis. By using discrete element method models, the influence of joint planes and interaction between distinct blocks can be seen. With a three-dimensional model, the effect of curvature can be combined with multiple joint sets at any orientation, which cannot be seen in a single slice. Numerous three-dimensional models are created, along with an equivalent unit-thick slice. The effect of curvature on a variety of different types of failure mechanisms is observed, and graphical relationships are created to quantify the difference between the three-dimensional factor of safety and the two-dimensional factor of safety based on the degree of curvature."

Jan 1, 2015

By Fidelis T. Suorineni

HydraboltTM is a Swellex-type dowel support element developed and manufactured by New Concept Mining in South Africa. Like Swellex, the HydraboltTM is a folded tube which can be inserted into a larger diameter hole without pushing. It is then activated by injection of high pressure water which inflates the folded tube to intimate contact with the walls of the borehole at a set pressure, normally 25 MPa. Unlike Swellex however, the set water pressure at the end of the inflation is maintained throughout the life of the dowel. An integral non-return valve makes this possible. The HydraboltTM is being investigated as a possible stress change measuring cell. This paper presents the results of closed form solutions, numerical modeling and laboratory test to date. Preliminary results indicate that the HydraboltTM can be used as a stress change monitoring cell in addition to its conventional role as a rock mass reinforcing element. If successful, the HydraboltTM will supplement microseismic monitoring systems in rockburst-prone ground conditions where they will give quantitative stress change data for both mine design model calibrations and means for proactive safety measures.

Oct 1, 2010

By R. Roufail

Mineral liberation is accomplished by comminution and is the first step towards achieving successful downstream processes such as flotation or leaching. In metal mining, one of the most effective comminution methods that is used to grind particles below 10 microns is stirred milling. In this paper the study of particle breakage mode vs. mill operating parameters is addressed. Stirred mills&apos; grinding action is mainly attrition, but operation can be manipulated to include breakage by compression or impact loading. Macro and micro analysis of particle breakage and grinding mechanisms are correlated. Macro analyses convey information that relates grinding mechanism to particle size and shape. It is speculated that the breakage mechanism in the horizontal stirred mills is massive fracture for the coarsest particles and attrition (abrasion) close to the grinding limit where the size reduction ratio approaches 1.0. For micro analysis, the particle breakage mode has a direct impact on fracture type either transgranular or intergranular. Intergranular particle breakage leads to higher mineral liberation compared to transgranular breakage. Similar minerals would have more homogeneous properties that convey a stronger bond compared to dissimilar, heterogeneous mineral bonds. Transgranular fracture requires higher energy than inter granular fracture; trans granular fracture toughness of pure single phase mineral is about 10-14 % higher than the intergranular fracture toughness. This communication presents the results of an investigation to assess how operating conditions can affect trans- vs. inter-granular breakage.

Jan 1, 2009

By R. U. Seneviratne, B. K. Ahlgren

In this paper we follow various technological discoveries and developments in the purification of minerals and metals in the mining industry by ion exchange. For approximately 100 years, ion exchange has been a known and variously applied purification and separation technology used by scientists and producers. It would seem obvious that the producer’s objectives have always been to achieve the highest quality products and the lowest operation costs, but also with the least amount of technological complexity. As a strategy to reach these goals, much effort has been expended in the quest to improve continuous ion exchange (CIX) systems by reducing utility needs and resin degradation or loss while at the same time improving productivity and reliability. Recent developments from a number of companies have pushed equipment boundaries, resulting in a variety of unique commercial equipment designs each with a varying degree of success. The challenge set forth for all new designs has been a truly continuous process with no sacrifice in the afore mentioned benefits. One very recent equipment design based on system symmetry appears to meet many of these objectives with greater flexibility and less complexity resulting in better economics for the producer.

Jan 1, 2014

By I. Pérez-Rey, J. Arzúa, L. R. Alejano

"The decrease in strength with increasing rock specimen size is usually associated to the increase in the number of defects inside the specimens at small scale (centimeters) but also to the role of the rock mass structure at the rock mass scale (meters to decimeters).This matter of concern was particularly focused when determining the size of pillars in underground mines. Some formulae regarding strength of pillars have been proposed but they usually consider only the size and shape of the pillars and the strength of the intact rock. The structure tends to be overlooked or hidden behind the scale, but it is probably very relevant. For standard tunnel design, the approach by Hoek and Brown (1997), taking the structure into account in terms of the GSI, is commonly used. However, this approach does not specifically consider the size of the tunnel. Thus, a size larger than the so-called representative elementary volume is implicitly contemplated.The authors have recently performed a lab study on the effect of the structure in the strength, deformability and post-failure characteristics of granite at lab scale (NX size) extended here. This experimental program included intact and artificially jointed rock specimens. Obtained results permit to observe the changes in strength, deformability and post-failure behavior of this “small scale rock masses”, associating the role of the structure to the observed complete stress-strain response of the specimen, which can improve our understanding of the actual complete mechanical response of rock masses."

Jan 1, 2015

By A. Zangooi, J. A. Finch

Flotation is a separation process based on the collection of particles on the surface of bubbles. Flotation machines disperse air into bubbles using a variety of techniques. The characteristics of the bubble population are strongly affected by the selection of frother type and concentration. As metallurgical results depend on the bubble distribution, the measurement of frother concentration is vital to understand and control performance. A previously developed colorimetric technique was refined to work with low solubility frothers and to increase daily analysis rate. Field-testing demonstrated that the method is robust, reliable and accurate. As well as relating frother concentration to gas dispersion measurements, the results can be used to answer operational questions including: how well a frother dissolves, how reliable and stable frother delivery is, how evenly frother is distributed down a bank, and whether frother distributes between the pulp and froth zones. Some of these points are illustrated from plant experiences. Advances in Mineral Processing Science and Technology Proceedings of the 48th Annual Conference of Metallurgists ofCIM Sudbury, Ontario, Canada Edited by

Jan 1, 2009

By Youngsoo Song, Hyunjung Kim, Junhyun Choi, Siyoung Q. Choi, Gahee Kim

In this study, for the first time, to confirm the effect of bacterial growth phase on the malachite flotation were investigated in a well-controlled Hallimond tube system. The test results showed that the bacteria in the stationary phase exhibit two-fold greater floatability than those in mid-exponential phase. To understand the observed flotation behavior, complementary cell characterization tests and cell attachment tests were conducted. Interestingly, the bacteria at both phases exhibited similar surface properties as well as almost identical amount of cells attached onto the malachite, suggesting that the growth phasedependent flotation behavior cannot be attributed to the variation of cell surface properties and the extent of cell adsorption. On the other hand, cell detachment tests revealed that the amount of cells detached from the malachite surface is greater for the mid-exponential phase than the stationary phase due to the higher fluid drag applied to the cells at the mid-exponential phase, which was explained by the differences in the size and shape of attached bacteria onto the malachite surface. These morphological characteristics were found to cause the bacteria of mid-exponential phase to be separated highly sensitive and easy from malachite surface due to the fluid flow. Second, scale-up selective bioflotation tests were carried out in a 1 L Denver cell in malachite–silica binary mixture systems. Through the tests, we optimized the cell concentration and the malachite fraction in the feed. Overall, high malachite selectively was observed under optimized conditions (both recovery and grade showed more than 90%). The trend was in agreement with classical DLVO interaction energy profiles, which show the relative magnitudes of the adhesive forces between the mineral and the attached cell under equal hydrodynamic conditions.

Jan 1, 2016

By Kimberly M. Curran

The path by which hydrogen supply is provided to any end use application will have a strong effect on the specific economics and price stability for the product supply and the flexibility with which it can be used. The objective of this paper is to present those variables which play a significant role in the selection of the hydrogen production technology, with a particular focus on several typical mining applications. The variables examined include gas requirements in terms of flow-rate and demand profile, overall volumetric consumption, level of interruption tolerable, gas pressure and quality needs. Also examined are the effects of geography in terms of primary energy supply available as well as existing hydrogen sources, developed or not. The role of these factors in the selection of an appropriate supply chain capable of supporting mining applications that use hydrogen as an energy carrier will be illustrated with a typical mining application scenario drawn upon in the form of a case study.

May 1, 2007

By Tetsuya Yumoto, Toshikazu Shiratori

Information on the elements contained in E-Waste is important from the viewpoint of recycling. We analyzed several components of waste electrical and electronic equipment (WEEE) collected from citizens. The distributions of the minor metals in WEEE were determined with elemental mapping and chemical analyses. The annual change in elemental composition was investigated by analyzing equipment manufactured in different years. The information will be of use for separation techniques required for future advanced recycling.

Jan 1, 2011