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By Karl Dufresne

Blasting in geothermally high temperature ground and/or extremely reactive ground is an increasing common challenge for surface and underground mines. Many current PETN based non-electric and electronic detonators have manufacturer published in-hole temperature limits ranging from 55°C to 65°C (131°F to 150°F). When confronting blasthole temperatures above the manufacturer published limits, operations may request site-specific guidance and qualification for use. The advised safe loading window for in-hole PETN based detonators is often too short to be practicable for production blasting. To overcome limitations of PETN based initiation systems, surface mines with high temperature ground and/or reactive ground are known to load blastholes with a qualified high temperature bulk emulsion that are top primed with a cartridge of temperature qualified detonator sensitive emulsion plus an RDX detonating cord downline. As there is no in-hole delay detonator in this system, blasthole timing is accomplished with surface delays. Although this system is safe, top priming and surface delaying does influence floor quality and top size fragmentation, and safe loading windows times reduce blast block size and increase blasting frequency. A mining company with a site characterized by geothermally high temperature ground plus highly reactive ground employed a blasting system like the one described above. The site desires to improve blasting performance by moving to an in-hole delay initiation system that can withstand the site ground conditions. At the request of the mining house, DynaEnergetics developed an electronic initiation system for application in geothermally high temperature ground and/or extremely reactive ground conditions. The DynaEnergetics IGNEO high temperature electronic initiation system is rated for in-hole use in ground up to 150C (302°F) for 48 hours. The detonator consists of a high strength detonator with an HMX base charge and thermally resistant downline. To make up a primer, the detonator is inserted into a booster charge assembly that is fitted with a small HMX shape charge. This high energy primer is designed to be compatible and reliable for firing bulk emulsions, including those with high percentages of urea inhibition to combat reactive ground. Up to 1000 detonators may be programmed in 1ms increments up to 1500ms. The system is controlled by a digital firing panel that can be used with either a wired or wireless trigger.  The system enables high temperature and/or reactive ground sites to utilize in-hole delay initiation and realize the associated performance benefits. Conclusions and Future Work 1] The HMX based electronic initiation system permits bottom in-hole delaying in ground temperatures above 80°C (175°F). As compared to top priming and surface delaying, in-hole bottom delaying is known to improve floor quality, muckpile fragmentation uniformity and reduce oversize. 2] Field evaluation of the HMX initiation system at the Lihir Mine is continuing. 3] Work on the next generation of the HMX initiation system is underway and will bring with it expanded application range and flexibility. 

Oct 1, 2024

By Alfredo Bambaren

First Encounters between Communities and Mining 1. Importance, meaning and process 2. Antamina?s study case 3. ?Self-organization? theory (NLP) 4. The story we tell, the values we live 1. Importance, Meaning and Process ? First encounter stays in mind as a model. ? First encounter means foundation. ? First encounter builds the story.

May 1, 2010

By B. Dubreuil, J. -M. Lalancette, D. Lemieux, C. Chouinard

The extraction of gold and silver has been examined via the use of mixed halogens: chlorine and bromine. The reaction was performed in a brine of sodium chloride with a small amount of sodium bromide at 40-50°C, in an atmosphere of chlorine, at atmospheric pressure. The process takes advantage of the very high reactivity of bromine towards gold, while the higher oxidation capacity of chlorine leads to gold chloride as end product with recycling of bromine. Fast reaction rates are observed along with gold recovery at the level of 95%. Chlorine-consuming common elements are removed prior to chlorination.

Jan 1, 2011

By S. Khoshkhooei

In this research, the effects of rare earth elements addition on thermal fatigue behaviors of AZ91 alloy were studied. Repeated heating and cooling cycles were applied on the samples at 170°C and 210 °C to develop thermal fatigue cracks, Crack growth mechanisms and microstructural influences were investigated by optical and scanning electron microscopy (SEM) as well as energy dispersive X-ray spectroscopy (EDS), Thermal fatigue behaviors were improved successively by addition of up to 2-wt% RE, This improvement is attributed to consummation of the aluminum of the melt by precipitation of the needle shape Al 11 RE3 phases, This process reduces the volume of Mg17Al12 phases and consequently decreases the brittle Mg/Mg17Al12 interfaces which are the main reason of weak thermal properties of the alloy at rather high temperatures, Further additions of RE, however, reduced the thermal shock resistance of samples by increasing in the mean length of the brittle needle shape phases.

Jan 1, 2005

By C. Denis Thibodeau

Outline Introduction 402 OB Mining Sequence Trial to Verify Sequence Change Monitoring Observations Numerical Modelling Conclusion

May 1, 2013

By A. Golpaygan

Application of Computational Fluid Dynamics (CFD) modeling for simulation of fluid flow and combustion in industrial scale electric furnace is presented. Poor combustion efficiency, roof and/or side wall overheating, carry over to off-gas system and non-ideal radiative heat transfer to processes or cooling systems have been common limiting factors causing inadequate process performance of the furnace, operational problems, and safety hazards. This paper describes how CFD analysis can be used to obtain a better understanding of commonly observed problems associated with freeboard combustion. Examples are presented to describe using combustion CFD modeling to understand requirements to diagnose a problem with furnace design including required freeboard volume or possible roof/side wall overheating.

Jan 1, 2011

By P. Ramirez

"To achieve an optimal metallurgical performance in the flotation process the bubble diameter should be between 0.5 and 2.5 mm. To control bubble size, frothers are added, reducing bubble size and conferring bubble stability against coalescence. However, the bubble generation mechanism determines predominantly the bubble size distribution produced. In mechanical flotation cells, bubbles are produced by the shear stress generated by a rotating blade on a gas stream. This mechanism produces a log normal bubble size distribution. In contrast, in column flotation, jetting gas injectors are commonly used in Chile and the bubble size distribution is bimodal with small and large bubbles. Bubbles larger than 2.5 mm mean a loss in surface area, while bubbles smaller than 0.5 mm move with the pulp stream and therefore collide less frequently with particles. In this paper, a new device based on a jetting sparger and a deflector disc (impinging jetting) is evaluated as an alternative sparger for column flotation.The new device was tested in a rectangular acrylic cell 1 m × 0.5 m × 3 m. High-speed cinematography was used to compare bubble generation with jetting and impinging jetting at different gas velocity in the nozzle (5–50 m/s). From the image analysis, it was observed that the deflector induces a shear stress, in analogy to a rotating blade but in this case the shear results from a high velocity gas hitting a static surface. The device was evaluated in a 0.5 m diameter 3 m high column. The McGill bubble viewer technique was used to compare the bubble size generated by jetting and impinging jetting. It was found that the Sauter mean bubble diameter reduced from 7.4 mm to 2.8 mm, when the jetting sparger was modified with the deflector. In the case of the impinging jetting sparger, 70% of the bubbles were in the effective range for flotation, while for the jetting sparger, only 10% were in the effective range."

Jan 1, 2016

By Brian Lewis

"IntroductionThe leaching method selected for the dissolving of uranium ore depends in part on the physical characteristics of the ore, as well as the uranium mineralization. There are two main methods of leaching employed in uranium circuits in North America, one being ""Carbonate Leaching"" on sandstone, and pitchblende type ores, and ""Acid Leaching"", on quartzite type ores.This chapter deals with the acid leaching of uranium ores found in the Elliot Lake area, using sulphuric acid, for the leaching reagent, and ""pachucas"" for the contactor.The basic leaching process involves the pregrinding of the ore and the mixing of the ore with hot sulphuric acid, the mixture is air agitated, the air being used to oxidize the ore as well as produce agitation. The chemical reaction is as follows: Uranium Oxide + Sulphuric Acid = Uranyl SulphateThe following equations show the actual dissolution of the ""Hexavalent Uranium"", which show that more than one ion or complex of uranium is possible.Uranium DissolutionsI. UO, + 2H-(UOJ + H,O2. (UO,) + SO, = -UO, SO, (Uranyl Sulphate)3. UO, + SO,-(UO, (SO,),)=4. (UO, (SO,),)= -(UO, (SO,),)'Test work carried out in the laboratory as well as in the plants has determined the most efficient methods of extracting the uranium from the ore. A very important factor that has to be determined during initial test work are the amount of acid consumers in the ore. Within the Elliot Lake orebodies are minerals such as chlorite schist, diabase, and basement material, all very high acid consumers, consuming up to 1000 lbs. of acid per ton of ore. Of these minerals only the chlorite schist contain any uranium at all.The following are the operating parameters that have to be controlled in the plant:I. sulphuric acid concentration2. temperature of the mixture3. agitation4. liquid solid ratio5. reaction time6. particle size of ground ore"

Jan 1, 1989

By K. Blower

"Since there was no representative from Wesfrob Mines Limited, the information on their infra-red concentrate drying operation, which had been prepared by Mr. K. Blower, was presented by Mr, Dorland. Mr. Blower, in submitting the information, emphasized that their objectives in this operation were (a) to guarantee less than 90%, of flow-moisture in their copper concentrates and thus satisfy marine shipping regulation• and (b) to minimize capital costs, The infra-red dryers have satisfied these objectives.To control final moisture in the copper concentrate, current practice is to preheat the filter cake with steam in the disc filter hood and then conveyor-0r7 the concentrate with infra-red calrod heaters. The application of steam aids the system as follows:1) Improves vacuum pump efficiency.2) Lowers viscosity of filtrate (increased temperature},3) Preheats the cake prior to radiant heating. (150°F)The hot cake discharging from the filter ranges from 10.6 to 10.9% moisture. After radiant heating the moisture level is reduced to 8.5% - 9.7% depending on production rate. Further moisture loss occurs during conveying and transferring to the stockpile for a final shipment moisture ranging from 8.1% to 9.5%. Production rate is frail J to 5 dry short tons per hour.1) #23 Conveyor 18"" flat belt covered from filter discharge to transfer point with 7 heaters end-to-end. Drive - Reeves Vari-Speed, 31:4 ratio, type 332-10-18, class ""D"", driving through a 24:1 ratio Dodge reducer. Speed of Conveyor - 3,9 feet per minute to 19.6 feet per minute. (Speed has been established and is not changed as a rule from the present level of a1:out 15.)2) #23 Conveyor 24"" wide, 20° troughed belt covered with 21 heaters, end-to-end from loading point, Speed - Constant at 54,2 feet per minute."

Jan 1, 1972

By Andrea R. Gerson, Roger St. C. Smart, Russell Schumann, Joan E. Thomas, Warwick Stewart, Stuart Miller

Sequential Net Acid Generation (NAG) accelerated oxidation testing using peroxide was carried out on single sulfide mineral samples. The calculation of the nett acid production potential (NAPP) assumes that all the sulfide is present as pyrite and that dissolution results in a 2:1 ratio of H+:SO42-. NAPP as kg H2SO4/t is calculated as 30.6 x wt.% S present. To test whether this calculation is valid a NAPP* value was defined in which instead of using the wt.% S present for the calculation the wt.% S dissolved is used. Stoichiometric analysis of the dissolution products of the sulfide minerals as they would occur at pH 7 indicates, that in all cases, the ratio of H+:SO42- of 2:1 is viable. The NAG to pH 7 and NAPP* closely coincided for pyrite, bornite, chalcocite and covellite. For the three Cu-containing minerals, the NAG to pH 4.5 value was 0 as is predicted on the basis of the speciation likely to be present at pH 4.5. Acid generation is due to hydroxylation of the dissolved Cu between pH 4.5 and 7.0. The NAG to pH 7 and NAPP* values for chalcopyrite, arsenopyrite and pyrrhotite were in reasonable agreement but were not for either sphalerite or galena. Zn is not completely hydroxylated at pH 7 as is assumed by the calculation. For galena, surface analysis identified polysulfide formation on of the leach residue polysulfide. The formation of polysulfide is an acid consuming reaction. Therefore under conditions of accelerated oxidation the NAPP value is a reasonable estimate of the possible acid production in all cases except for sphalerite and galena. However, under conditions of less intense oxidation, for instance in columns, waste rock and tailings dumps, the formation of polysulfides is likely to be more widespread thus reducing the correlation between NAPP and the maximum possible acid production.

Jan 1, 2004

By Richard C. Williams, Herman Pieterse, Ken Thomas, K. S. Fraser, Ron H. Colquhoun

"The Banick Goldstrike Mines Inc. (Goldstrike) operation is located in Eureka County in north-central Nevada on the Carlin geological trend. Gold in the sulphide mill feed, occurs primarily as submicroscopic inclusions or possibly solid solution in a pyrite and marcasite matrix. Sulphide mill feed is pretreated in a pressure oxidation plant allowing gold recoveries of 90 per cent and greater to be achieved. Anticipated 1994 gold production for the sulphide gold facility is approximately 1,500,000 ounces.In January 1989 American Banick Resources Corporation (Banick) announced the US$365 million Betze Development Plan for the Goldstrike property. The Betze plan was based on a three (3) staged expansion of the original 4,500 STPD oxide gold plant. This expansion would involve addition of ore and gold processing capacity and the total conversion of all ore handling facilities to treating Betze sulphide ores.Phase 1 of the Betze Development Plan involved the construction of a pressure oxidation circuit, including a single autoclave and supporting ancillary services. The pressure oxidation circuit was commissioned in February 1990. Currently a throughput of 2,000 STPD is being achieved.Phase II of the Betze Development Plan, commissioned throughout April and May 1992, included the expansion of grinding, leaching, and gold recovery facilities enabling the treatment of combined oxide, and sulphide ore. Pressure oxidation capacity was increased by the addition of two (2) autoclave circuits each treating 2,600 STPD of sulphide ore and other required ancillary services. By June 1992, the Phase II gold facility had achieved a combined throughput of 15,000 STPD of oxide and sulphide ore.Phase Ill, the final stage of the Betze Development Plan, was successfully commissioned in February and March 1993. This final stage of development increased the design throughput of the pressure oxidation plant to 15,000 STPD by the addition of three (3) autoclave circuits with combined capacity of 7,800 STPD."

Jan 1, 1994

By C. Barnett

"The mill at Noranda Mines Limited, Geco Division in Manitouwadge, Ontario went into production in 1957 treating 3,500 tons per day of copper, zinc, silver, lead ore. It was not until 1964, however, that the zinc concentrate drying plant was constructed. In 1970, milling capacity was increased from 4,000 to 5,000 tons per day. The zinc content of the ore is quite variable so that the tonnage of zinc concentrate dried varies from 200 to 650 tons per day.The drying plant was designed to dry 25 tons of zinc concentrate, dry basis, per hour from an initial moisture of 8.5% to a final moisture of 2%. Major components were selected so that capacity could be increased to 35 tons per hour with minor modifications.The rotary dryer is a Hardinge type ""XH-12"" with a diameter of 80"" and a length of 50 feet. The all welded construction shell is 1/2 inch thick mild steel plate with 3/4"" thick reinforcing bands under the tires arranged for operation at a slope of 1/2 inch to the foot. The 3/8"" x 12"" radial flights are welded to the shell. There are no flights in the last ten feet of the shell in order to reduce dusting. This unit is driven by a 50 HP motor through a Hamilton type CD250 double reduction helical gear speed reducer. The shell speed is 5.8 RPM.The standard Peabody horizontal air heater has a rated capacity of 10,000,000 B.T.U. 's/Hr. The combustion chamber is lined with high temperature refractory brick and is air cooled. The conical outlet section of the air heater is lined with insulating fire-brick. The burner is a type AT wide range mechanical atomizer fired by a type ""CR"" gas-electric ignitor.The Bunker ""C"" fuel is supplied by a Compower duplex pumping, heating and straining unit, including tank hotwell, Powertronic oil line heating system with a 550/24 volt transformer."

Jan 1, 1972

By H. Sano

Most of the dust generated from the copper smelting process in Chile has been stored after the stabilization by hydrometallurgical process because it contains high concentrations of arsenic. However, in recent years, the dust generation has increased because of degrading the quality of concentrate. In addition, the environmental regulations become stricter. On the other hand, valuable metals such as copper and zinc are contained in the dust at high concentrations and it is desirable to recover them. In this study, the effect of dust recirculation to the smelting process was examined in order not only to decrease the amount of dust but also to recover copper. Dust generation and the distribution of arsenic, lead, zinc etc. among the matte, slag and gas phases were evaluated as a function of the amount of recirculated dust, partial pressure of oxygen and temperature. It was found that the direct dust return to the smelting process was quite effective for the recovery of copper and the reduction of dust generation, but the acceptable dust amount was limited by the produced matte quality.

Jan 1, 2007

By C. Hari Manoj Simha, J. Gholipour, M. J. Worswick

Due to the high pressures involved in the hydroforming process, friction and lubrication play an important role and can affect formability of the material. Tubes of A1Mg3.5Mn aluminum alloy, of 76.2 mm (3 inch) outside diameter and 2-mm thickness were considered in this study. Three kinds of lubricants, Al070, Hydrodraw711 and water, were applied to the tubes and tubes were hydroformed to burst in a square shape die cavity. The key process parameters were recorded during the tests. An in-house Gurson-Tvergaard-Needleman (GTN) damage-based material model, implemented in LS-DYNA, was used to model the process and predict the formability of this material. The applied axial loads and internal pressures recorded during the tests were used in the computations. The effect of different types of elements (solid and shell) with different constitutive models (von Mises and GTN models) in predicting the strain distribution is studied. The GTN damage-based material showed a good ability to capture necking and displacement histories in this process. Both predicted and measured results showed that the lubricant with lower coefficient of friction can effectively increase the comer expansion.

Jan 1, 2006

By P. Au, P. Patnaik, H. Saari, D. Y. Seo, S. Bulmer

Ti-48Al-2Cr-2Nb-xW (where x = 0, 0.5, and 1 at. %) powders were consolidated by hot isostatic pressing (HIP). The consolidated samples were solution heat treated above the a-transus followed by stepped cooling to room temperature. Selected samples were subsequently aged at 950 °C for up to 72 hours. The post-heat treatment microstructure was examined by optical and electron microscopy. It was found that increasing holding time above the a-transus generated a more homogenous microstructure. Utilizing the stepped cooling sequence, especially with a transition temperature of 1270 °C, massively transformed gamma (Ym) was diminished. Aging caused coarsening of the fully lamellar microstructure in the 0%W and 0.5%W samples while almost no coarsening occurred in the 1 % W sample. Precipitates began to form during aging in samples containing W. The precipitates at the lamellar interfaces are fine and have a needle like shape, while precipitates at the lamellar grain boundaries are coarse and circular in shape. The size and number of the precipitates depend on aging time and the level ofW content.

Jan 1, 2006

By H. Hao

This paper outlines the development of a 2-D axisymmetric mathematical model to predict the evolution of temperature during the Direct Chill (DC) casting of AZ31 magnesium billets. Model predictions of temperature have been compared to measurements made on an industrial DC casting machine at Timminco Ltd, in Haley, Ontario. These measurements have been used to fine-tune the thermal boundary conditions employed in the mathematical model, The model, which is based on the commercial finite-element code ABAQUS, has been developed as part of a strategic project aimed at improving the DC casting process for light metals through a reduction in casting related defects and increased productivity.

Jan 1, 2004

By J. B. Hamilton

The advantages of generating and distributing electrical energy direct from the coal-fields so closely affects the mining industry that a few remarks on the unbalanced phases of coal distribution is worthy of attention. The value of coal imported into Canada from 1912 to 1921 exceeded the sum of $580,000,000. In 1922 Ontario imported 1,640,000 tons of anthracite and 9,440,000 tons of bituminous coal. I submit that the use of Saskatchewan lignite in an electrical super-power plant equipped for the carbonizing of coal, and disposal of excess gases would be the commencement of a solution of the fuel shortage in Ontario. As Saskatchewan becomes more and more populated and manufacturing increases, the amount of by-product carbonized fuel available for shipment to Ontario will increase, and its shipment to that province would decrease the trade deficit of the national balance sheet. If and when this is carried out it will mean a better and wider market for Alberta fuels in Saskatchewan and Manitoba.

Jan 1, 1924

By Jianhong Xu, Hailong Hou, Yu Jing, Yundong Wang

Microcapsules containing extractants have been applied to the extraction of metal ions, organic acid, pesticide, and herbicide. The difficulties of conventional liquid-liquid extraction in phase mixing and phase separation (e.g. high energy consumption, emulsification phenomenon, and large equipment requiring housing) could be overcome in a liquid-solid system by using microcapsules. Even some extractants with high viscosity and poison can be encapsulated conveniently into microcapsules. In the work described in this paper, polysulfone microcapsules containing 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (P507) were successfully prepared. Then, the extraction rate of lanthanum, samarium, and erbium in dilute solution into the microcapsules containing P507 was studied. An extraction kinetic model is proposed based on the interfacial reaction model accompanied by intraparticle diffusion expressed by Fick’s law. The extraction efficiency was obtained by using the kinetic model with the separately determined complex formation rate constant and the intraparticle diffusion coefficient. From the results, it was confirmed that the kinetic model could predict the experiment in a microcapsule system over a wide concentration range of lanthanide solution. In the future, the model could provide good guidance for the design and application in extraction of lanthanides.

Jan 1, 2014

By W. R. Richmond, T. S. Li, D. Ilievski

The reactive precipitation of ferrihydrite was studied in a laboratory semi-batch precipitator, where a highly concentrated sodium hydroxide solution was fed into an iron nitrate solution. Instantaneous hydrolysis of iron[III] takes place when the two reagents are mixed generating supersaturation, and leading to immediate precipitation of ferrihydrite via a primary nucleation mechanism then followed by limited crystallite growth to 3 to 7nm. A mathematical model of the semi-batch laboratory precipitator was used to simulate the pH responses during the precipitation of ferrihydrite at different reagent feed rates. The model comprised of interconnected compartments of averaged hydrodynamic conditions, incorporating physically meaningful turbulent mixing time constants. The precipitation process is described by the solute concentration conservation equation incorporating a postulated ferrihydrite primary nucleation model. It was found that the semi-batch precipitator model predicted the experimental pH response reasonably well. The experimental results demonstrated that the reagent feed rate has a critical effect on the course of the precipitation of ferrihydrite, i.e. it is a rate determining step given the fast hydrolysis and precipitation kinetics.

Jan 1, 2005

By K. Karan

Oxygen reduction reaction in PEM fuel cell cathodes involves participation of three reactants - oxygen, hydrogen ions, and electrons. Electrochemical reaction in the catalyst layer is, therefore, influenced by how these species are transported to the reaction site. The two-phase boundary locations at which percolating networks of ionically conducting electrolyte and electronically conducting Pt/C meet are feasible reaction sites. The electrolyte phase also provides pathway for the transport of dissolved oxygen. Most of the 3-D models describe the catalyst layer as an ultra-thin layer, thereby, losing useful information on the distribution of electrochemical reaction rate. In this paper, we extend our previous work on 2-D cross-the-channel modeling of PEMFC cathode based on agglomerate catalyst layer. In particular, we take a closer look at the influence of proton conductivity on the reaction rate distribution in the catalyst layer. As well, we re-examine the role of anisotropic transport coefficient of the porous transport layer (PTL), commonly known as the gas diffusion layer, on the current density distribution under the channel and the rib of the flow-field plates. Results from both a 2¬D and a 3-D models will be presented.

Jan 1, 2005