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By R. M. Beauchamp

Base metal processing operations often treat process tailings and acid mine drainage using a high density sludge (HDS) water treatment process. Lime is used in this process, which reacts with existing sulfates to form gypsum. When a recycle stream is incorporated in the process, gypsum levels in recirculating water may build up and cause high levels of gypsum supersaturation. Precipitation of gypsum from the supersaturated process water causes many problems. It is speculated that gypsum may precipitate on sulfide minerals and silica gangues in the flotation circuit, resulting in decreased selectivity and recovery. An understanding of the determinants and nature of precipitation may provide solutions to mitigate the formation of precipitates and improve flotation performance. This study showed that both sphalerite and silica exhibited gypsum- or calcium carbonate-like behavior in the respective supersaturated solutions, indicative of a coating of calcium species on the mineral particle surfaces. The addition of copper sulfate and/or potassium xanthate had little effect on the precipitation of gypsum or calcium carbonate on the mineral particles. Sodium carbonate is encouraging as a method to minimize calcium species interactions on sphalerite/silica surfaces.

Jan 1, 2006

By A. Staley, W. J. Cashwell, M. S. Moats

In the 1990’s, Técnicas Reunidas developed the Modified ZINCEX® Process to recover zinc from ores and secondary materials. The heart of this process was the use of solvent extraction to produce purified zinc electrolyte instead of traditional zinc dust cementation. This development was commercialized by Reunion Mining and Anglo American for primary ore at the Skorpion mine in Namibia with the first SHG zinc produced in May 2003. Horsehead Corporation through Horsehead Metal Products, Inc., its wholly owned subsidiary, is presently commercializing the MZP for the treatment of Waelz oxide. This paper will review open source information about the lessons learned and process modifications that have occurred at Skorpion over the past decade. It will also provide an update on Horsehead’s facility being constructed in Rutherford County, North Carolina.

Jan 1, 2014

By E. De Souza

Energy associated with ventilating an underground operation comprises a significant portion of a mine operation's base energy demand and is consequently responsible for a large percentage of the total operating costs. Ventilation systems may account from 25?40% of the total energy costs and 40?50% of the energy consumption of a mine operation. Fans are the most important mechanical devices used to ventilate underground mines and the total fan power installed in a single mine operation can easily exceed 10,000 kW. Investigations of a number of mine main fan installations have determined their assemblage to be, in general, very energy inefficient. The author has found that 40?80% of the energy consumed by a main fan is used to overcome the resistance of fan assemblage components. This paper presents how engineering design principles can be applied to improve the performance and efficiency of fan installations, resulting in substantial reductions in power consumption, operating cost and greenhouse gas emissions. A detailed case study is presented to demonstrate that, by designing fan assemblages using proper engineering concepts of fluid physics and industrial ventilation design, main fan systems will operate at efficiencies well above 80?90% (compared to common operating efficiencies of between 20 and 65%), resulting in a drastic reduction in a mine's overall costs and base electrical and energy loads.

Aug 1, 2013

By X. Cao

Friction stir processing (FSP) is used to produce wrought microstructures at the surface of sand-cast aerospace grade magnesium alloy ZE41A-T5. It is found that the microstructure is significantly refined in the stir zone and the flow arm. The stir zone is largely comprised of equiaxed magnesium grains of approximately 4.5 pm compared with about 50 µm in the base cast material. In the stir zone, however, abnormal growth of some grains is also observed. Vickers microindentation hardness tests indicated that the stir zone experiences some increases in hardness. Single surface passes with low distortion, lack of pores and cracks were successfully obtained indicating the great potential of the FSP technique for modifying, improving and repairing magnesium alloy castings. This will probably open new opportunities to apply magnesium alloys in aerospace industry.

Jan 1, 2007

By C. K. Wilton

"The Agnew Lake uranium deposits were discovered in 1953 following the discovery of the Elliot Lake deposits to the west. The original property was optioned to Kerr Addison Mines Limited who added additional claims by staking. Agnew Lake Mines Limited was incorporated in 1967 to develop the property and a shaft was sunk to 1040 metres and five levels developed before work was suspended due to low uranium prices at the end of1970.In 1974-75 the mine was dewatered and production started in 1977. By 1978 reserves were estimated at 10,000,000 tonnes averaging 0.35 kg. U10 , per tonne. Underground operations were terminated in 1980 although a uranium leaching operation was continued until early 1983.The deposits lie near the contact of Huronian metasediments with underlying Algoman granite. The sediments consist of arkose, conglomerate, argillite and quartzite with the uranium mineralogy mainly confined to oligomictic quartz pebble conglomerate. The higher uranium values are related to conglomerate with highest percentage of pebbles. The chief uranium minerals are uranothorite and monazite. It is of interest that the uranium thorium ratio differs appreciably from that of the Elliot Lake deposits. This fact along with the fact that the Elliot Lake sediments were deposited by paleocurrents from the northwest whereas the Agnew Lake sediments were deposited by paleocurrents from the northeast indicates widely separate sources for the deposits. It is suggested that the Agnew Lake uranium deposits are syngenetic placers deposited under anoxygenic atmospheric conditions."

Jan 1, 1986

By M. J. MONEA

Canada's only economic high-swelling bentonite deposit is mined in Wilcox, Saskatchewan, by A vonlea Mineral Industries Limited. The bentonite resulted from devitrified and altered volcanic ash released during the Laramide Orogeny. Volcanic ash was deposited in a pre-Cretaceous basin that was formed by salt solution collapse structures. Sedimentary rocks in the Wilcox area belong to the Snakebite Member of the Upper Cretaceous Bearpaw Formation. Bentonite beds are 61 cm, 46 cm and 30 cm thick; these are separated by 365 cm and 182 cm of shale respectively. Saskatchewan bentonite is used primarily in the oil well industry.

Jan 1, 1984

By K. M. Deen, E. Asselin

Hydrometallurgical processes, i.e., Cu extraction from a mineral concentrate and Zn electrowinning, are coupled in a battery-like system. A naturally-sourced CuFeS2 concentrate mixed with activated carbon is used as a positive slurry electrode separated by a membrane from the negative compartment. The Zn is deposited on the negative Al current collector from the circulating solution containing 100 g L–1 Zn2+ in 0.2 M H2SO4. In this battery-like system, both CuFeS2 oxidation and Zn deposition are possible during the charging cycle. The additional benefit of this setup is the energy storage if discharged by re-dissolving the Zn in the negative compartment. Cyclic charge/discharge testing revealed oxidation of the mineral concentrate supported by the Zn2+/Zn redox reaction. The coulombic and energy efficiencies increased monotonically to 95.6% and 43%, respectively, with approximately 7% Cu extraction during the first 10 charge/discharge cycles (completed in 2.4 hours). The discharge energy density also increased from 2.7 to 36.2 mWh L–1. In the following 90 cycles, the low energy (~14%) and coulombic (~33%) efficiencies that were obtained confirmed the progress of irreversible reactions e.g. Cu extraction from the mineral concentrate. Overall, approximately 16% Cu was extracted from the mineral concentrate over 100 charge/discharge cycles (or about 12.2 hours). INTRODUCTION Chalcopyrite (CuFeS2) is the main economic copper-bearing mineral, which is generally processed through pyro-metallurgical methods to produce Cu. However, environmental challenges with smelting, depletion of high-grade ores and a large number of impurities (some toxic) have resulted in continued research aimed at the development of hydrometallurgical technologies to process CuFeS2. There are a number of different proposed hydrometallurgical routes in the literature to treat CuFeS2 concentrates, but only a few have attained commercial acceptance (Dreisinger, 2006). Zn is another commercially important metal that is mainly produced via acid leaching of roasted sphalerite (ZnS). The pregnant leach solution is rigorously purified to remove all the soluble metal impurities, particularly those that are electrochemically more noble than Zn and present large kinetic activity towards H2 evolution (Hu & Piron, 1992; Mackinnon, Brannen, & Fenn, 1987; Mureşan, Maurin, Oniciu, & Gaga, 1996). Metal impurities such as Cu, Co, Ni, Cd, Pb, Sb, As, Ge and Fe etc., if they exist in the leach liquor beyond the tolerance limits, can decrease the current efficiency during electrowinning and deteriorate the deposit quality (Alfantazi & Dreisinger, 2001). A complete flow sheet, describing the process steps of Zn metal production from mine site to pure metal is presented elsewhere (Brown, Meisenhelder, & Yao, 1983).

Jan 1, 2019

By E. R. Mitchell

When we grow up in an urban environment and choose to become a part of a way of life, it is sometimes difficult to appreciate the cost of this decision in terms of pollution. Explained in this article is our dependence on technology and the amount of pollution that technology produces. Inventories of air pollution on both a personal and a national basis are given so that the reader may judge the magnitude of the problem. In doing so, it is hoped that the reader will understand the need for a responsible attitude toward pollution by everyone and how he can make a personal contribution.

Jan 1, 1971

By R. Heikkilä

The utilization of Building Information Modeling (BIM) and model based 3-D control of work machines have increased a lot in new road construction in Finland as well as in other Nordic Countries. Up today, much less attention has been paid into the development of maintenance and rehabilitation processes. As a part of a large research and development program RYM PRE Infra FIN BIM in Finland, a focused research project of the BIM with experiments in total five (5) pilot projects has been performed. A main idea of the new BIM based process has been to utilize mobile laser scanning method for initial data acquirement, the use of novel 3-D analyze and modelling methods for point cloud processing, the use of new type optimization method for the planning of geometric and structural improvements needed for the existing uneven road surfaces, and further, through the creation of 3-D machine control models apply the newest 3- D machine control systems for continuous 3-D control of practical construction work using milling machine and asphalt paver. Finally, an evaluation is made between the new process model and the traditional way of working.

Aug 1, 2013

By P. Duran

The metallurgical gas handling system at Chagres Smelter, like that of many smelters, can be the limiting constraint to processing more concentrate through the smelter. Mass and energy balances for the metallurgical gas handling system processing off-gases from the flash furnace and Peirce-Smith converters have been used by both operations and process engineering groups to help evaluate different operational scenarios in which the use of the installed capacity could be maximized and/or an operational strategy can be change with the purpose of removing a bottleneck or justifying an investment to relieve a constraint in the gas handling system. The present work describes the development of these process balances that were carried out in Exce®. The results were validated with operational data and, subsequently, some cases of industrial interest were simulated, detecting some conditions that were limiting the operation due to the present installed capacity in the Chagres Smelter.

Jan 1, 2007

By P. R. G. Brandão, E. E. Ferreira

The presence of metallic cations in solution will affect the aggregation or dispersion of the fine hematite particles, depending on the type of cation adsorption: either specific or non specific adsorption. In this work, the zeta potential measurements were carried out on a sample of pure hematite as a function of pH and metallic cations concentration (Ca2, Mg2+, Mn2+, K+, Na+ and Al3+). The objective of these studies was to clarify the effect of these metallic cations on the surface chemical properties of pure hematite. The cations K+ and Na+ adsorbed as non-specific species and caused only the reduction on the values of zeta potential (in terms of absolute value) over the entire range of pH values tested. For the Al3+ cation, in the acidic pH range it adsorbed as a specific species and increased the zeta potential values. The cations Ca2+, Mg2+ and Mn2+, adsorbed as a non specific species at pH levels less than 6.0 and caused the reduction of zeta potential due to the compression of the electrical double layer. However, for pH values greater than 6.0, these cations adsorbed as a specific species causing the zeta potential to increase and became more positive as the pH value increased (alkaline). This effect could be due to the adsorption of some hidroxy complex species of these cations, which contributed to the positive charge. The effect of metallic cations (Ca2+, Mg2+ and Al3+ concentration, at pH 4.0, 7.0 and 10, showed the following results: a) at pH 4.0, increasing the concentrations of Ca2+ and Mg2+ resulted in on a small reduction in the value of the zeta potential. At this pH, increasing the concentration of A131 cations caused the zeta potential to increase due to specific adsorption of a negatively charged Al3+ hydroxy complex b) at pH 7 and 10, increasing the concentrations of Ca2+ and Mg2+ caused the zeta potential to change its charge from negative to positive.

Jan 1, 2004

By R W. Drybrough

The program to increase production at Sherritt Gordon's Lynn Lake property, which began in 1956, included increasing the rope speed and the horsepower of the ore hoist at the "A" shaft. Because of the limited power sup-ply from the two 7,000-hp. hydroelectric plants, and the ? 3,600 hp. predicted for the combined hoisting requirements of the three production shafts, it was considered desirable to lessen the impact of this type of load on the relatively small power system by equipping all future hoisting arrangements with Ward Leonard direct-current drives. The manually operated 8-by 4-ft. hoist at the "A" shaft had a rope speed of 1000 f.p.m., and was driven by a 385-hp., 380-r.p.m. wound rotor motor with liquid rheostat control. This A.C. drive was replaced by a semi-automatic Ward Leonard direct-current drive with a 515-hp., 566-r.p.m., shunt wound motor, providing a rope speed of 1,500 f.p.m. During several months preceding the con-version, all possible preparations were carried out to keep the changeover period to a minimum, and this resulted in a total shutdown time of twelve days. The capability of the "A" Shaft hoist was increased from 109 tons per hour to 134 tons per hour, and both mechanical and electrical maintenance were reduced considerably. The total cost of the conversion amounted to $130,000. The hoistmen who had been required for the manual A.C. drive were transferred to the new Farley shaft, and the reduction in operating labour costs of the "A" Shaft hoist

Jan 1, 1965

By J. Shahabpour

"Abstract - Breccias with angular and rounded clasts of a late-mineralization, ""barren"" hornblende porphyry dike set within a comminuted matrix consisting of rock fragments and quartz, cemented by quartz and K-feldspar of hydrothermal origin is observed in diamond drill cores from the Sar Cheshmeh porphyry copper deposit. Studies of age relationship between vein types, phyllic-altered clasts and the breccia groundmass suggest that the brecciation is a late event. The breccia clasts record evidence of hydrothermal reaction between the clasts and fluids responsible for the brecciation.Formation of bornite, in the breccia clasts of the originally barren hornblende porphyry dike, and in the breccia matrix, along with the scarcity of bornite in the Sar Cheshmeh deposit itself suggest involvement of fluids which are later and of different composition from the fluids responsible for the known mineralization at Sar Cheshmeh. These later fluids may be related to a later plutonic event and suggest the possibility of a later, and concealed deposit."

Jan 1, 1994

By Wencheng Gao

An attractive way to beneficiate magnesium chloride and aluminum chloride is to prepare Mg-Al spinel, an excellent refractory material. Mg4Al2(OH)14?3H2O, the precursor of spinel, can be prepared using a co-precipitate method from aqueous MgCl2-AlCl3 solutions. The co-precipitation process of magnesium-aluminum from acidified chloride solutions by using NaOH or NH4OH as base neutralization agent was studied. Co-precipitation was conducted from different mixed solutions ? at initial CAl=0.0625M and Mg/Al molar ratio from 0.5 to 10, the temperature range from 30 to 90 °C. The effect of other parameters, including base type, method of base addition, base addition rate, aging time, background electrolyte and concentration were also investigated. The co-precipitation process was monitored by potentionmetric(pH) measurements. The experimental pH curves were characterized by two platforms separated by a steep jump in pH at Mg/Al molar ratio 0.5~6. The first platform was centered at about a pH of 3.8 and the pH of second platform was varied with different conditions. When the Mg/Al molar ratio was up to 6~10, the first platform in pH was almost disappeared. Furthermore, the shapes of pH curves were also affected by base type, base addition rate and method of base addition. Experimental results showed that the first platform in pH was connected with Al precipitation, and the second platform was involved with Mg. The final co-precipitates were characterized by XRD, TGA-DTA, particle size analysis, SEM and TEM. We found both Mg/Al molar ratio and temperature proved to be the key parameters controlling the formation of Mg4Al2(OH)14?3H2O phase. At solution Mg/Al ratio=0.5~4, the main precipitate phase was Bayerite (Al(OH)3) admixed with Mg4Al2(OH)14?3H2O; at Mg/Al ratio=4~6, the main phase was Mg4Al2(OH)14?3H2O admixed with some Mg(OH)2; while from Mg/Al ratio=6~10, the systems were mixtures of Mg(OH)2 and Mg4Al2(OH)14?3H2O.

Oct 1, 2011

By M. Maley, S. Burling, R. Ring

ABSTRACT The numerous global uranium deposits vary significantly in mineralogy, grade, and textural characteristics; therefore, information from traditional (or conventional) sources on the fundamentals of leaching uranium and gangue minerals is not always applicable when studying particular ores. Empirical studies can be effective in understanding leach systems and can lead to improvements in process design but there remains a lack of fundamental understanding necessary for ongoing process optimization as ore bodies continue to vary. ANSTO Minerals has undertaken a work program to address several fundamental questions about uranium leaching, including the unexpected impact for some ore types of leaching at high oxidation potential.

Jan 1, 2012

By Glen Robertson, Jeff McLaughlin

"The Clarabelle Mill rock tailings have the potential to generate sulphuric acid through chemical and biological oxidation of sulphide minerals. Current rock tailings assay between 0.80 -1.40 %S, with sulphur occurring principally as coarse pyrrhotite. Acid generation within the tailings area can be substantially reduced by segregating pyrrhotite rich tailings in a submerged storage area and by depositing only low sulphur rock tailings in exposed areas. Laboratory tests confirmed that low sulphur tailings could be produced by flotation at reduced pH with a small xanthate addition. A plant test was conducted to evaluate the production of low sulphur tailings in conjunction with INCO's continuing commitment to environmental protection and progressive decommissioning of the metallurgical site.During the plant evaluation, approximately 5% of the mill rock tailings were reprocessed in a line of 100 tt3 Denver flotation cells. Tailing grades below 0.40% S were easily achieved through operation at pH 6 -7, with xanthate addition (dosages up to 0.02 lb/ton) and 10 -15 minutes of nominal retention time. Froth depths between 1 -3 inches combined with relatively liberal amounts of frother were required to pull the lightly mineralized froth into the concentrate which averaged 11% sulphur and less than 5% mass recovery. In addition, three field lysimeters were each filled with two hundred.ton bulk samples of low sulphur tails (0.35% S), standard rock tailings (0.98% S), and mill total tailings (2.30% S) for long term monitoring. The implications for full scale plant design, tailings area decommissioning, the possibility of increased nickel recovery and preliminary field lysimeter data are discussed."

Jan 1, 1994

By Michael S. Moats, Prashant Bagri

"In recent years with increasing concerns about energy consumption in hydrometallurgical processing, there is an ongoing attempt to use Catalytic Titanium Anodes (CTAs) for copper electrowinning. For this work, anodes with IrO2 - Ta2O5 coatings were prepared in the laboratory with the same total coating loading but varying the number of layers by changing the speed of withdrawal in dip coating. A second set of CTAs were fabricated on niobium, Ti Grade 1, Ti Grade 7 and Ti Grade 36 metal substrates. All the anodes prepared in the laboratory were characterized using standard electrochemical techniques and subjected to accelerated life testing. It was found that the coating would not adhere to the niobium substrate, the grade of titanium had a minimal to no effect on the life of the anode, and it is observed that as the coating speed slows, there is an increase in the electrochemically active surface area of the coating which seems to directly contribute to an increase in the Tafel slope of the anodes. There was inconclusive evidence on the effect of coating speed on anode lifetime.INTRODUCTIONLarge scale hydrometallurgical extraction of copper has become widely practiced over the last 40+ years. The hydrometallurgical route entails leaching, solvent extraction and electrowinning. With the increasing desire to process refractory sulphides like enargite and chalcopyrite through the hydrometallurgical route, use of hydro-processing of copper is expected to remain high.In conventional electrowinning, copper is deposited on the cathode and an inert anode is used for oxygen evolution. Presently, the most common anode material is rolled lead-calcium-tin and the cathode is 316L stainless steel (Robinson et al., 2013). This lead alloy is fairly inexpensive and is robust, providing lifetimes typically of 4+ years. The main drawbacks of lead alloys are their relatively high oxygen evolution overpotential, the need for cobalt in the electrolyte to reduce their corrosion, the contamination of cathode product by lead, and the generation of harzardous by-products (Hiskey, 1999)."

Jan 1, 2016

By M. Maldonado

This work details the application of a decentralized control strategy to a pilot flotation column working with a two-phase system (water-air). The process is represented by a multivariable system composed of three inputs and three outputs. The selected control variables are the froth depth, the air hold-up and the bias rate, whereas the corresponding manipulated variables are the set-points of the local flow controllers of tailings, air and wash water. All controlled variables are estimated using electrical conductivity based techniques. In particular, the results of a new method for estimating the bias rate, based on the measurement of the volumetric fraction of wash water under the interface, is presented. This method reduces the coupling problem associated to the bias estimation as a difference between feed and tailing water rates. Moreover, the nominal system transfer matrix can be represented by an upper triangular matrix, in such a way that the closed-loop system stability reduces to the stability of the independent control loops. The experimental results show that the closed-loop system performance, particularly that of the bias rate loop, is strongly dependent on the air flow rate, reaching in some cases the saturation point of the controller.

Jan 1, 2007

By N. Maleki

In recent years, research and development of magnesium alloys have been greatly promoted by the lightweight requirements in critical industries. The use of these alloys, however, has been restricted by their limited mechanical properties especially at high temperatures. The disadvantages can be overcome by producing Mg matrix composites. The Mg?Si alloys containing in situ Mg2Si particles have found a great potential as structural materials. Unfortunately, Mg2Si compounds are prone to form undesirable coarse Chinese script morphologies, which would deteriorate the properties of the materials. Refinement of microstructure is performed for improvement of wear and corrosion resistance. This paper investigates the microstructure and corrosion behavior of pure magnesium, unmodified and modified magnesium matrix composites reinforced with Mg2Si particles. The Mg2Si/Mg composite was prepared via a normal cast route, and then various amount of zinc was added to melt in order to modify the Mg2Si reinforcement particle morphologies. The microstrucrures were characterized by optical and scanning electron microscopy followed by EDX analysis. The corrosion behavior of Mg/Mg2Si composite was investigated by using potentiodynamic polarization measurements. The results showed that by addition of zinc, the average size of the primary Mg2Si became significantly decreased from about 100µm to about 20µm, as well as its morphology changed from dendritic to a polyhedral shape. However, by adding extra amount of zinc many primary Mg2Si particles become coarse again. It was also found proper amount Zn addition increased the corrosion resistance of Mg/Mg2Si composite.

Oct 1, 2011

By C. S. Touchard, F. Bourgeois, L. Cassayre, Julcour-Lebigue C.

Developing a hydrometallurgical process that can overcome the refractory nature of chalcopyrite (CuFeS2) to leaching still eludes the minerals industry, despite major research efforts spanning decades. The several leaching experiments of this ore in sulfuric acid tend toward the same conclusion that the precipitation of elemental sulfur or iron containing species are the main dissolution inhibitors. Describing both the electrolyte composition and the various solid phases in equilibrium for the Fe-H2SO4-H2O system is essential to overcome this issue and to find an operating window. According to the thermodynamic models and to the thermodynamic data, we demonstrate, in this study, the need to use the Specific ion Interactive Theory (SIT) model to describe complex electrolytic systems through a limited number of parameters. Hence, the binary interactions for our case study have to be defined and estimated. This work develops a methodology to determine these parameters of the SIT model up to 90°C and an acid concentration of 1 mol/kg from published data for H2SO4-H2O and Fe(II)-H2SO4-H2O sub-systems or from new experimental data for the Fe(III)-H2SO4-H2O one. This method will eventually be applied to copper systems to lead to a thermodynamic description of the complete CuFeS2-H2SO4-H2O system. INTRODUCTION A leaching process consists in the dissolution of a solid phase into an aqueous medium in order to extract compounds of interest. It is a key step in the hydrometallurgical processes used in the primary production and recycling of metal components. One of the main leaching issues is the formation of passivating layers on the surface of solid particles, whose consequence is a partial or total hindrance of the dissolution. The leaching of chalcopyrite (CuFeS2) in sulfuric acid is a prime example. No industrial solution for the atmospheric pressure leaching of this ore has been developed to date because of passivation phenomena caused by the formation of elemental sulfur or iron-containing precipitates on the surface of the particles (Li, Kawashima, Li, Chandra, & Gerson, 2013). In the 1970s, the Pourbaix diagrams established for the Cu-Fe-S-H2O system at 25°C for low concentrated solutions (Garrels & Christ, 1965; Peters, 1976) agreed that copper and iron are fully dissolved at high potential and in acidic medium (pH < 4). However, they neglected the many stable solid phases that can form in these conditions. In addition, the Pourbaix diagrams of chalcopyrite in water, calculated with two recent databases (FactPS and Thermoddem 2017) associated to FactSage and PhreeqC softwares respectively, show large discrepancies at 75°C (Figure 1). Indeed, at high potential, FactSage predicts the formation of goethite FeOOH at a pH value of 1, while PhreeqC predicts the formation of jarosite (H3O)[Fe3(SO4)2(OH)6] for pH greater than 2.5.

Jan 1, 2019