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By Fabio Terzi

In this investigation some preliminary results are reported about the electrochemical oxidation of CO using goldbased encapsulated nanoparticles grafted on conducting substrate. The investigation has been planned in four steps: 1. production of Au(111) substrate and modification with self assembled monolayers; 2. synthesis and embedding of nanoparticles; 3. grafting of encapsulated nanoparticles on electrode substrates; 4. investigation of CO electroxidation on the modified electrode. The systems were characterized by means of various techniques (spectroscopic, microscopic, and electrochemical methods), obtaining information about SAM's structure and morphology, size and composition of nanoparticles and electrochemical behavior of modified electrodes.

Oct 1, 2003

By Therese Schneck

The presence of xenon isotopes from in-situ spontaneous fission of short-lived Pu244 has been confirmed in Hadean detrital zircons from Western Australia. Hadean and meteoritic zircons can retain secondary overgrowths developed after primary cristalization at 3.97-3.94 Gyr. On the moon, the metal grain in sample 66095,78 is mantled by troilite, schreibersite and cohenite. High chlorine content FeCl2 is deposited around metallic FeNi. The magnitude of Pollonium-210 to Radon-222 on the Aristarchus plateau spectrum indicates a past greater activity. The Earth Moon system from Nb/Ta systematics is consistent with a Moon iron core delayed to 3,9 Gyr.

Aug 1, 2010

Iron control and iron residue management and disposal are significant issues in all zinc production processes. This paper briefly reviews the most important primary zinc production routes and discusses the challenges posed by iron control in each of them. The technologies and strategies that have proven successful in controlling and managing iron are discussed. SNC-Lavalin's experience in designing and commissioning zinc plants provides a unique perspective from which to review this aspect of zinc production.

Jan 1, 2006

By W. Hunka

PACIFIC PETROLEUMS, Ltd. first discovered commercial quantities of gas in the Peace River area in 1952. Development of gas wells in this area is quite ex-pensive due to low penetration rates. To improve the economics, the potential of the wells in many cases had to be increased. At that time, well stimulation was still in its infancy in Canada and in this area, in particular, no treatment of any consequence had been attempted. Therefore, trial-and-error was the only means available to determine the stimulating technique that would give optimum results. Various fluid treatments were available and these were used wherever the application was warrant-ed. This paper covers acid fracture and explosive treatments as carried out on various gas-bearing horizons.

Jan 1, 1958

By Egbert Burchardt

The challenge of "ore bodies getting steadily harder and lower in grade" was brought to light during the first oil crisis in the 70's. Shortly afterwards, HPGRs appeared on the scene with the promise of saving energy. This combined with developments in wear protection for the rolls ushered in a period of trade-off studies that considered the HPGR as an option to improve project economics or to even make projects feasible at all. Since then, applications of HPGRs at Cerro Verde (Freeport), PTFI Grasberg (Freeport), Mogalakwena (Anglo Platinum), Tarkwa (Goldfields), Boddington (Newmont), Penasquito (Goldcorp), and others have contributed to the creation of a formidable basket of operating experience. Collected through years of successful operation, this information has been used to validate design criteria, scale-up factors and establishing a clearer picture of what "to do" and what "not to do". This paper compares results from various mining operations using HPGRs in their processing plants. Some of the lessons learnt in different operating environments are reviewed in order to support proper implementation and operation of HPGR's. Some of the development programs that have been initiated to improve wear life of the tyres and to reduce overall operating costs are reviewed. It is timely to summarize today?s experience and analyse its implications for existing and new operations.

Jan 1, 2012

By L. Voisin, K. Yamaguchi, D. G. Mendoza, K. Ltagaki

The behavior of arsenic and antimony in the Cu-0 system was thermodynamically investigated to understand their elimination during a blister-making stage in copper smelting. Firstly, the phase relations in a miscibility gap composed of the liquid slag and copper phases in the Cu-0-As and Cu-0-Sb systems at 1523 K were established by a quenching technique. It was found that arsenic and antimony distributed preferentially into the slag phase in the miscibility gap. Secondly, the activities of arsenic and antimony in the miscibility gap of these systems were determined at 1523 K by using a double Knudsen cell - mass spectrometer method. It was clarified that the activity of arsenic in the copper and slag phases showed the negative deviation from ideality while that of antimony in the copper phase a slightly positive deviation. These data obtained in this study suggest a possibility to eliminate arsenic and antimony by means of over-blowing in a converter after discharging the slag.

Jan 1, 2007

By M. Maleki-Moghaddam

At the concentration plant of the Gol-E-Gohar Iron Ore Company (Iran) three 9 m × 2.05 m AG mills (fixed speed) are used in parallel in a dry operation. The performance of AG mills has been lower than the target value indicated by an increase in the product size (P80) from 450 µm (target) to 515 µm and low power draw (50% of nominal). By simulation it was found that increasing the liner lifter face angle from 7 to 30o while keeping the original lifter height (i.e., 22.5 cm) could provide an appropriate charge trajectory. When the proposed liners installed in one of the AG mills, the throughput increased by 27%; when 5% (v/v) balls were added the throughput increased by 40%. The product size also decreased from 515 to 501 µm.

Jan 1, 2012

By R. H. Watson

A paper read by J. A. H. Church before the Northern Alberta Branch last February described a method of working thick inclined coal-seams from the dip upwards, with the view to preventing fire risk by using water for the stowage of waste workings, and extinguishing a conflagration should such break out, was favorably received; but there was some doubt as to the cost of such a method, as it involves a retreating system, which might prove too expensive for practical adoption. Let us consider a typical leasehold such as we are familiar with in the Rocky Mountains. The leasehold is crossed at one end by a mountain river, which is cut by the outcrop of a seam of coal, 30 feet in thickness, pitching as shown on the drawing herewith, which also shows the general line of the outcrop in elevation through the leasehold, which is two and a half miles long and contains 1,500 acres. The average lift is about 600 feet above river level and drilling has proved that the coalseam can be tapped at a depth of 1,500 feet, 2,000 feet down the pitch from the outcrop in the river, all as shown in the illustration, which is typical enough of our mountain conditions to serve the purposes of comparison of methods. We take up the leasehold and invest $30,000 to pay for drilling and prospecting; $30,000 more for the price of the lease to locator or holder, and say $100,000 to pay for a railway spur (it might cost twice this sum, but we are only comparing two methods in the same location) and "now we are ready to consider equipment and the cost of development.

Jan 1, 1924

By J. P. Piguet, A. Hosni, J. P. Josien, H. Baroudi, R. Hadadou

"The iron ore mines in the Lorraine region of north-eastern France cover a surface area of approximately 3,900 km2 and involve more than 150 cities. A total extraction method was usually used during exploitation, but this technique was sometimes replaced by the room and abandoned pillar technique when it was necessary to protect surface buildings and infrastructure. Rooms and abandoned pillars were initially designed to ensure long-term mine stability. However, this aim was not always reached and numerous collapses occurred in the Lorraine iron basin, either during production or several years after closure. Several subsidence events were identified during a period of one century; the most recent event occurred in 2012. Two groups of events were identified. The first group represents events characterized by sudden surface movement, and the second group includes event characterized by progressive subsidence.Numerous studies conducted during the last decade helped improve our understanding the origin mechanism of spontaneous or progressive (slow) events. These studies led to identifying long-term potentially unstable underground zones (hazard zones), particularly deep zones located under buildings and infrastructure. The latest are currently monitored by microseismic networks. A similar high requirement level is needed for unstable zones without taking into account the kinetics of the subsidence, which is very important for safety. Thus, GEODERIS initiated this study, primarily to acquire a better understanding of the kinetics of the progressive events group and identify the main parameters that could explain why some pillars zones developed a maximum amplitude subsidence on surface within a few hours or days, while it took several weeks to months for others. In practice, the results of this study will facilitate adapting the requirement level of microseismic monitoring system to the kinetics of pillar collapse.To retrieve the real kinetics for each event, historical and sparse documentation was used. Firstly, archives research was conducted, especially testimonies and newspaper articles published during the events. This work helped to gather useful information that sometimes contained a precise description of subsidence duration. The archives research helped to classify some progressive events according to the subsidence kinetics. Secondly, a diagnostic of geotechnical and geomechanical parameters of historic events was realized, combined with a cross analysis of the data. The analysis took into account dimensions of underground workings (e.g., pillar lengths, widths, heights, introduction of a “pillar shape factor”, and stress amount). An original expression was highlighted to connect the pillar geometry to the stress state. The kinetics expression was calibrated to classify the historic events taken into account according to the kinetics of movements. The kinetic criterion was applied to predict subsidence kinetics for the potential unstable zones currently monitored by a microseismic system."

Jan 1, 2015

By A. Alfantazi, M. Mahon

The current efficiency in zinc electrowinning is a key indicator of the performance in a cell house. This is typically measured by comparing the weight of the cathode to the electric current applied over the deposition period. This calculation can be cumbersome because the deposition history of each pulled set of cathodes will be unique. It will depend on the applied current and electrolyte conditions from onset of deposition until the cathode is removed and stripped. Not accounting for these can introduce errors to the calculated current efficiency. To track this history and reconcile the current efficiency, a time based computer process simulation was made of an industrial cell house. Two months of hourly recorded measurements from the cell house were input to the simulation, including current to the cell houses, concentrations, flow rate, and temperature of the purified leach solution. The simulation’s predictions of the concentration of zinc in the circulated, spent, and returned electrolyte all showed good agreement with the industrial data over the two months giving a validated zinc balance. The simulation was then tuned to predict the instantaneous current efficiency for all times, as well as the expected masses for the deposits given their deposition history.

Jan 1, 2014

By Dirige. A. P. E.

A study was conducted for an operating mine to determine the appropriateness of its tailings material to be used for the preparation of a low modulus, high density backfill. The research was initiated due to issues arising from increased observations of compressive failure of backfill placed in stopes and inconsistent backfill behaviour (i.e. increased backfill brittleness and modulus). Backfill materials investigated were classified tailings and de-slimed tailings. Characterization of the physical properties of the classified and de-slimed tailings materials was conducted to assess the effect that these material properties would have on the strength and deformation behaviour of high density backfill products made using them. Such behaviour was investigated to determine whether differences in tailings physical properties would influence the strength and modulus character of the backfill materials. Uniaxial (UCS) and consolidated-undrained triaxial compression strength tests were conducted to determine strength performance and deformation behaviour of backfill. This paper presents the results of the backfill material characterization study and how different particle size distributions affected the strength performance and deformation behaviour of the different backfill mixes. It also demonstrates how stress-strain curves generated from material strength tests were used to evaluate variation in high density backfill mix response when such materials were subjected to unconfined and confined (triaxial) compression loading.

Aug 1, 2013

By S. Dominguez, E. Gebrehiwot, S. Richardson, S. Sandoval

Copper electrowinning/electrorefining (EW/ER) is powered by direct current (DC) rectifiers that typically generate 30,000 to 70,000 amps and a bus-bus voltage of 200 to 500 volts DC. Tankhouses are designed so that DC current flows through “cell lines” which contain individual EW/ER cells electrically connected in series. Electrolyte composed of copper sulfate and sulfuric acid in water forms the “liquid conductor” that connects the metallic conductors in this circuit. In this setting, stray current is a DC current that strays from and therefore bypasses the tankhouse circuit by finding a path to ground, often through the electrolyte in pipelines that feed into and discharge from the cells, or through dried electrolyte (i.e. sulfate), which is also electrically conductive. Tankhouse workers can be exposed to shock hazards if they become part of a stray current path to ground. This presentation details examples of stray current shock hazards in electrolytic tankhouses and provides voltage and amperage measurements associated with stray current in these examples. A review of critical safety controls in EW/ER tankhouses that will mitigate the risk of employee shock from stray current is also provided. INTRODUCTION Electrolytic tankhouses are designed to deliver relatively large amperages of DC current to a series of electrolytic cells in which copper is plated out of solution using the classic anode-cathode pair geometry within each cell. Electrolyte is the “liquid conductor” that transfers current in between the metallic conductors of the cell. The metallic conductors include inter-cell copper bus bars and the anodes and cathodes themselves. It is sometimes forgotten that electrolyte as a conductor is capable of delivering DC current outside the designed circuit of a tankhouse. Stray current is a DC current that strays from the tankhouse electrical circuit by finding a path to follow other than the designed path. Safety becomes a concern when there is a risk of an employee becoming part of an accidental stray current path, thereby suffering an electrical shock. In 2016, Freeport-McMoRan (FMI) suffered a fatality at one of its copper electrowinning tankhouses. The forensic analysis concluded that stray current from the tankhouse rectifier contributed to the fatality. An employee accidentally fell into contact with a metal flange at the end of an HDPE pipe that was collecting cell overflow electrolyte from the tankhouse. DC current passed through the employee to ground, creating a shock that was judged to contribute to his death. The situation was exasperated because the employee was unconscious, and therefore was exposed to the stray current for several minutes before being found. In addition, the employee’s clothing was saturated with liquid, and the employee was found kneeling in puddled liquid on the ground. FMI immediately began an investigation into the root cause of the stray current that was measured at the scene. Sufficient electrolyte had accumulated in the HDPE pipe such that a continuous path was formed between it and electrolyte that was continuously overflowing from energized electrowinning cells. The metal flange on the pipe was the metallic conductor that carried the current to the employee from the electrolyte inside the pipe. Current then flowed through the employee to ground. Because of this incident, FMI undertook an extensive review of the hazards of stray current in EW/ER. FMI’s tankhouse workforce received a Tankhouse Electrical Safety training course developed in- house to insure worker understanding of stray current hazards. Tankhouse design changes were implemented to better insulate workers from stray current. Personal protective equipment (PPE) standards were also reviewed and changes made.

Jan 1, 2019

By E. J. Schwarz, A. A. Winir

"Absolute magnetite contents were determined for asbestos specimens in various stages of milling by using a Faraday-type thermomagnetic balance. Comparison of these results with magnetic ratings (MR) supplied by the mining companies cooperating in this study reveals strong scatter. The main cause of this scatter is thought to be that the MR values were obtained in magnetic fields well below the saturating field of magnetite (5,000 oe). However, only the saturation moment is an intrinsic property and consequently must be used for the purpose of obtaining reliable estimates of the magnetite content. Curie points indicate that virtually pure magnetite and possibly Ni3Fe is present in all samples, and another phase, probably (Cr, Al) magnetite, is present in a few samples. The susceptibility in fields stronger than 5,000 oe is positive and falls in the normal paramagnetic range, whereas sy nthetic chrysotile exhibits weak diamagnetism. This suggests that, as a general rule, the least adulterated natural chrysotile concurs with the samples showing the smallest positive susceptibility above 5,000 oe. The magnetite appears to increase in quantity with a decrease in fibre length and to be somewhat more uniform in distribution for samples showing substantial fiberization (opening of the fibres)."

Jan 1, 1971

By F. A. Forward

"NINETEEN sixty-six is a year of unusual significance in our Institute and in our country. It marks two-thirds of a century of service by the Institute to the people of the mineral industry and two-thirds of the century that Sir Wilfred Laurier said ""belongs to Canada."" As we meet here today within the historic walls of Canada's oldest city, a city that looks back on three hundred and fifty years of progress, I am reminded that it is almost a third of a century ago -in April, 1934 -that here in Quebec I first attended an Annual General Meeting of the Institute. It occurred to me that it might be appropriate to examine briefly the change that the middle third of this century has brought in the affairs of the mineral industry and, with some trepidation, to consider the prospect for the third that lies ahead.Opinions differ as to the relative importance of factors that have been responsible for the expansion and growth of Canada in its first hundred years. Some will say that it has been due to the abundance and fertility of agricultural land, others to the early enterprise of the railroads, and financiers believe that the banking system has been a major factor; -the fisherman -the forester -the teacher -each has his own view. I suspect, however, that most of us here would subscribe to the thesis of T. A. Rickard -miner, author, imperialist -who wrote, a gene-ration ago, ""Trade follows the flag, but the flag follows the pick,"" and thus agree that the finest contribution to progress, to wealth, to extension of frontiers and to inter-national trade has been provided by the mineral industry."

Jan 1, 1966

By J. D. Wright

This paper describes current milling practice at Endako Mines Ltd., a molybdenum producer in central British Columbia. The various steps in the crushing, grinding and flotation of the ore are outlined, with emphasis on the metallurgy of the latter operation. Tailings disposal and concentrate assaying methods are also described.

Jan 1, 1969

By R. Plassart, F. Laigle

"As a powerhouse, a transformer or a valve chamber, large underground caverns are a major element of hydropower plant. On the contrary to galleries and shafts which are linear and long underground structures, large caverns are designed with often complex geometries and large spans. Moreover, as these caverns are generally located on the foot of the hydraulic scheme, the high overburden is often responsible of a high stress state. Thanks to current experiences in France and around the world, the Hydro Engineering Centre (CIH) of EDF has defined great principles in the design of caverns leading to a more general methodology. The project of Tehri in India is an example of difficult ground, with in the same time a high overburden, a ductile material and an important schistosity. These physical realities are attempted to be approached in numerical modelling thanks to a constitutive law with softening behaviour and an oriented criterion integrated in the continuum model. As a result, a flexible support is advised, based on a high density bolt system and a thin lay of shotcrete. This methodology has been developed in the case of Gilboa in Israel, except the schistosity which has not been observed in situ. At last, the example of Gavet (France) illustrates a discontinuous case of numerical modelling for a good quality but fractured rock mass.PRINCIPES ET METHODES DE CONCEPTION DE GRANDES CAVERNESHYDROELECTRIQUES SOUTERRAINESRESUME Les grandes cavernes souterraines abritant les turbines, les transformateurs et certaines vannes sont des ouvrages majeurs dans les aménagements hydroélectriques. A la différence des galeries et des puits qui présentent de longs linéaires, les grandes cavernes sont des structures à la géométrie souvent complexe et avec des portées conséquentes. De plus, ces cavernes étant généralement situées en pied du circuit hydraulique, la grande couverture rocheuse peut se traduire par un état de contraintes important. Forte de ses expériences récentes en France et dans le monde, le Centre d’Ingénierie Hydraulique d’EDF a identifié de grands principes de conception des cavernes permettant l’élaboration d’une méthodologie plus générale. Le projet de Tehri en Inde est un exemple de terrain difficile, présentant à la fois une forte couverture, un matériau ductile et une schistosité marquée. Ces réalités physiques sont approchées au mieux grâce à la prise en compte dans les modélisations numériques d’une loi de comportement radoucissante avec un critère orienté intégré dans un modèle continu. Les résultats ont conduit à privilégier un soutènement souple basé sur un boulonnage systématique relativement dense associé à une fine couche de béton projeté. Cette méthodologie a ensuite été reprise pour le projet de Gilboa en Israël, exception faite de la schistosité puisque non observée sur site. L’exemple de Gavet (France) enfin permet d’illustrer un cas de modélisation numérique discontinue d’un massif rocheux de bonne qualité mais fracturé."

Jan 1, 2015

By J. J. Quinn

Several mineral flotation plants utilize process water with high soluble salt content. The processing of semi-soluble minerals, the use of recycle streams, sea or well water give rise to this situation. It is unclear as to the overall effect on flotation response though there does seem to be evidence of bubble size reduction, increased froth stability and reduced reagent dosage. The present work aims to quantify the effects of salts present in process water on gas dispersion (bubble size and gas holdup) and froth properties. The salts examined were NaCI, CaCl2, Na2SO4, Na2S2O3 and Al2(SO4)3. Tests were conducted to determine the effects of salt type and concentration on gas holdup and bubble size distribution. The salts containing multivalent ions had a greater impact than the monovalent ions, in keeping with the literature. A relationship between gas holdup and ionic strength was established. The concentration of frother (methyl isobutyl carbinol, MIBC) giving equivalent gas holdup was determined. The effect of salt and frother combinations was also explored.Proposed mechanisms for coalescence inhibition in salt solutions are briefly reviewed in light of the current findings.

Jan 1, 2006

By Maxim Martel, Karolan Tremblay

Westwood Mine has experienced several episodes of increased seismic activity. While current geotechnical characterizations such as RMR, GSI, and Q' index can identify the general rock quality and zones at risk of convergence, they fail in identifying zones at risk of seismic activity. Previous research at Westwood Mine has shown a correlation between seismicity and areas with strong rheology contrasts. To characterize this contrast, 300 UCS tests were analyzed with their associated geochemical data, and statistical analysis and regression were performed using IOGAS software to establish a relationship between resistance and geochemistry. UCS-generated data with XRF results were transferred to Leapfrog Geo to create a block model of intact rock strength. This block model dataset was used to perform a competency contrast block model, and back-analysis of specific seismic sectors at Westwood Mine were conducted to validate the model. The purpose is to develop an established geomechanical tool capable in identifying areas with greater seismic risk associated to a change in the rock strength characteristics. By identifying those areas, mitigation measures can be implemented to minimize impact of seismicity on the operation.

Jan 1, 2023

By E. Dernedde

Industrial plants located in the province of Quebec, Canada, are subjected to large variations of the ambient air temperature, Building ventilation systems of these plants must have some flexibility in order to meet industrial hygiene standards (TLV for chemical substances, heat stress and cold stress) at any time of the year, The building ventilation of a bath treatment plant of an aluminium smelter in Quebec was examined under summer and winter conditions, Part of the plant has periodic emissions of hydrogen fluoride gas and heat from hot anode butts, CFD modeling was used to optimise the building ventilation of the bath treatment plant, The present study proposes a modified building ventilation system, which improves the internal environment, complies with industrial hygiene standards and also reduces heating costs by 20 % during winter.

Jan 1, 2005

By lchimura. R. .

Japan Oil, Gas and Metals National Corporation (JOGMEC) and Centro de Investigation Minera y Metalurgica (CIMM) commenced a five year project from 2001 to modify the treatment of the furnace dust from Teniente converter containing harmful elements like arsenic and lead. The project was supported by Japanese and Chilean governments, and a demonstration plant was installed and operated at Las Ventanas Smelter and Refinery (Division Ventanas CODELCO). The basic and detailed engineering was made by Mitsui Mining and Smelting Co., Ltd (MMS) based on the joint study among JOGMEC, CIMM and Division Ventanas CODELCO. Arsenic in flue dust is lixiviated by sulfuric acid and fixed as crystalline ferric arsenate, where leachability of arsenic will be lower enough than the regulation, 5mg/I by TCLP (Toxicity Charactaristic Leaching Procedure) of USEPA. On the other hand, the recovered copper from the dust will be fed to the copper production process at Las Ventanas Smelter and Refinery, while zinc will be recovered as the exportable product. As introducing the crystallization and growing stage, the stable crystalline ferric arsenate formation can be achieved under the normal pressure.

Jan 1, 2007