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By R. Roufail

"Energy consumption in stirred mills has been studied, in the last couple of decades, on a macro scale. Effective operation and meeting particle size required for downstream operations used to be the main objectives behind energy utilization of stirred mills. In this paper, three energy terms are defined to assist in understanding the breakage mechanism for various types of minerals versus mill operation. The types of minerals studied had diverse physical and mechanical properties that are summarized as specific gravity, hardness and crystal structure. The minerals utilized in this study were quartz and galena. The effect of quartz and galena mix has been addressed as well as Lead-Zinc ore sample from SAG mill discharge. The energy input to the mill is function of the agitator speed, therefore three agitator speeds were evaluated, 1000, 1500 and 2000 RPM, respectively. The energy terms studied are specific energy (kWhr/ton). Effective energy is the ratio between net energy and total energy consumed by the mill. Last type of energy is the specific breakage energy, which is the net energy consumed by the mill per one-micron breakage. Results showed that specific energy and specific breakage rate are functions of mineral type, while effective energy is only function of mill input power (agitator speed).INTRODUCTIONGrinding is the largest energy consuming component of a mineral processing operation and typically consumes about 50% of the total energy used at a mining operation (Botin, 2009). Over the last two decades, stirred mills have been extensively utilized in mineral processing operations due to increased mineralogical complexity of ore bodies. Stirred mills grind particles to less than 10 µm by applying a high power intensity. The technology has been the focus of several research studies to investigate mill energy and grinding mechanisms. Becker, et. al. (2001) studied the relationship between different types of energy including input energy, specific energy, volume/mass specific energies, to stress intensity and final product particle size. Other studies such as by Kwade (1999), Kwade and Schwedes (2002), Blecher et al (1996), Partyka and Yan (2007), Stender et al (2004), focused on mill design and/or stress intensity distribution. Peukert (2004) studied the effect of mechanical properties of the grinding media and ground material on the comminution process."

Jan 1, 2016

By J. G. Stevens, S. W. Colley

"Selective separations of metals and ions in mineral extraction and refining are becoming more challenging as ore bodies become more complex and environmental pressures increase. The separation and containment of mercury produced in gold mining are a factor in the profitability and operability of mines. This paper will discuss the development and implementation of the Johnson Matthey HgFree selective mercury removal process. The process is designed to selectively recover co-leached mercury from either heap leach pregnant solutions at ambient temperature and low mercury concentrations, or electrowinning pregnant solutions at elevated temperature and high mercury concentration, without affecting gold or silver recovery. The process utilizes a highly selective adsorption-desorption step in which mercury is removed quantitatively by the HgFree adsorbent without adsorption of gold, silver or other metals present. Development of the original HgFree adsorbent has resulted in a process whereby mercury can be recovered as an inert salt and is never present as the free metal. The HgFree adsorbent can be regenerated and recycled in situ, and is capable of being reused multiple times. The overall process is compatible with existing gold mining and recovery practices and offers significant environmental and sustainability benefits, including reduction or elimination of the need to retort mercury with a subsequent reduction in potential mercury air emissions. Development of the HgFree adsorbent and process will be discussed along with a pilot operation at two operating mines.INTRODUCTIONMany gold ore bodies contain high concentrations of mercury which when extracted with cyanide, co-extract with the gold and other metals. This mercury is carried through the process with the gold, posing environmental and technical issues when it is separated from the doré. This paper describes a method to selectively adsorb mercury from the gold recovery circuit while it is in a soluble form, leaving gold to be processed as normal. The removal of mercury from the circuit eliminates the need for mercury retorting of doré and so reduces the potential environmental impact of fugitive emissions of elemental mercury."

Jan 1, 2016

By H. J. McQueen

Friction stir welding (FSW) generates complex microstructures in the nugget and thermomechamically affected zones (TMAZ) that have led to diverse explanations. However, consideration as an extension of microstructure development in piercing/extrusion can lead to a better understanding of flow patterns and microstructures during FSW. Furthermore, the intense strains in the nugget/TMAZ can be interpreted by comparison with ultra-high strains in torsion that exhibit dynamic recovery as extending into regions with high angle boundaries strongly serrated with spacing near the subgrain size defined by the high temperature. The subgrain diameter and extrusion pressure have been shown to be dependent on the Zener-Hollomon parameter Z (=t exp(Q/RT), Q activation energy, R gas constant) combining temperature T and strain rate E in the same mariner as for torsion and compression. Moreover, such tests exhibited steady state stress os above a certain strain Es (rising as Z increases) in which T, , subgrain diameter and dislocation spacing remain constant. Due to the subgrain boundaries (SGB, low angle <5°, i.e.,LAB), continually rearranging by migration, decomposition and reformation, the subgrains remain equiaxed in elongating grains, whose boundaries (GB) become serrated as they migrate to absorb SGB. As confirmed by straining in torsion at constant T and Z. , more subgrains bordering the greater GB area have several high-angle facets (HAB) ; these small cellular regions with a mixture of HAB and LAB facets are designated HAB-subgrains. As serrations in neighboring grain boundaries impinge, the grains pinch off becoming shorter; this occurs at higher strains as subgrain size decreases with rising Z. The pinching-off makes the neighbors thicker so the grains never become thinner than about two subgrain diameters. In conjunction with such geometric dynamic recrystallization (gDRX), GB&apos;s undergo a net migration into grains with denser substructure, enlarging those with larger subgrains. Consequently a better name has been proposed: grain dimensioning dynamic recovery (gDRV).

Jan 1, 2007

By J. Beland

The Rimouski-Matapedia region is along the southwestern extension of the central Siluro-Devonian synclinorium of Gaspe Peninsula. As in Gaspe about 30,000 feet of Siluro-Devonian strata rest on a "basement" of tightly folded Ordovician rocks. The central synclinorium is divided up into two northeasterly trending belts each of which is characterized by distinctive lithologies and patterns of folding. The northwestern belt is gently to moderately folded and includes lithologies which point to a stable environment. The southeastern belt on the other hand is tightly folded and the lithologies indicate a less stable environment. A marked angular unconformity separates the basement from the Siluro-Devonian cover near the north-western margin of the northwestern belt. At the southeastern margin of the southeastern belt the relationship of cover to basement has not been as-certained because of a fault. The northwestern belt has several features significant in the search for petroleum; the Silurian strata are exposed in broad open anticlines

Jan 1, 1962

By K. Kryst, K. Elkayar

The increasing need to process lower grade contaminated copper concentrates and simultaneously produce higher purity copper cathodes necessitates a more diligent control in the electrorefining process. Ion exchange processes can be a powerful tool in controlling electrolyte impurities to ensure trouble free operation within the tankhouse and to help maintain cathode purity. In addition, some impurities can be recovered as a value added product. The use of a short bed ion exchange process provides a unique opportunity for impurity management in copper refineries. Several metals are discussed in this paper, including Sb, Bi, As and Ni and their methods of control and recovery within the copper electrolyte circuit. INTRODUCTION To produce a high purity copper product by electro-refining a copper electrolyte, it is important to control the concentration of impurities such as arsenic (As), bismuth (Bi), antimony (Sb), and nickel (Ni). These impurities are introduced into the electrolyte from the copper anode and can affect the copper product and the production operation. The presence of As in the copper product results in a lower electric conductivity and reduced workability of the copper. High levels of Bi in the electrolyte will result in a copper cathode product containing Bi. High Sb concentration will cause undesired floating slimes. A variety of methods have been developed to control the level of these impurities in the copper electrolyte including precipitation, liquid extraction, and ion exchange. These impurities can be recovered and used. This paper discusses novel methods that utilize short bed ion exchange technology to control these impurities. Also, the use of ion exchange to recover acid from the liberator cells bleed for reuse in the tankhouse is reviewed. SHORT BED ION EXCHANGE Short bed ion exchange technology has been employed extensively in the metal finishing industries for over forty years. Unlike conventional ion exchange, short beds are fixed beds without freeboard space. The application of short bed technology results in significant benefits when compared to conventional ion exchange. The resin used in this technology has a significantly smaller diameter than conventional ion exchange resin. As a result of the smaller resin size, exchange kinetics improves dramatically. This facilitates operation at higher flow rates and the use of smaller beds with a small mass transfer zone length. Smaller beds are especially important for applications that use chelating resins due to the high cost of the resin.

Jan 1, 2019

By M. Jiang, X. Fan, W. X. Chen, Z. K. Guo, H. H. Zou

"Some improvements are carried out for elasto-plastic model by taking the shear dilation effects and relaxation effects of deep rocks into accounted. The high pressure equations of states with Mie-Grüneisen form are also introduced to describe the relation of pressure-volumetric strain. Numerical simulations of free field responses for deep underground explosions are conducted by using the user subroutines which compiled by means of the secondary development functions of LS-DYNA9703D codes. It is indicated that the dynamic responses of free field are well simulated based on this improved elasto-plastic model, and the analytical results are in good agreement with the data of U.S. Hardhat nuclear test.INTRODUCTIONDynamic behaviors of deep rocks for underground explosions are obviously different from that of shallow underground explosions and have aroused great attentions of international experts who work for rock engineering. The dynamic models of deep rocks could be roughly divided into classic elasto-plastic model and fracture damage model according to different theoretical foundation. M. E.Kipp and D. E.Grady et al. are the outstanding representatives who engaged in the researches of fracture damage mechanics. Researches of dynamic problems for geomaterials were carried out by C.C.Grigorian and the conclusion that incompressible elasto-plastic medium model could not be used to solve the problems of closed underground explosion was derived, and therefore C.C.Grigorian model was proposed. In this model, C.C.Grigorian assumed that the average hydrostatic pressures and the densities of medium had one to one relationship, and the path of loading or unloading is different from each other. For shear deformations, analytical solutions of the problems were derived according to the model which was slightly different from Prandtl-Reuss model, the constitutive equations were closed by Mises-Schleiher constitutive model. However, the analysis showed that there were two inadequacies in C.C.Grigorian model. Firstly, the shear dilation effects of fractured medium after wave front could not be considered. Secondly, the relaxation characteristics of the rocks in fractured region were not taken into account."

Jan 1, 2015

By M. Narita, S. Nakayama, M. Fujihara

Hibi Kyodo Smelting Co., Ltd. was founded in 1968 and celebrated its 50th anniversary in 2018. In 1972, we started producing copper cathode with a production capacity of 84 KTPY. Since the company founding, we have undertaken seven expansion projects, and our current copper-cathode production capacity is 290 KTPY. To increase our production efficiency, two tank houses were converted from Conventional process to ISA process in 2006 and 2014. In another investment, we equipped a continuous glue dosing system, which allowed for strict additive-concentration control, yielded quality improvements and reduced the power-consumption rate. Along with an increase in the production of copper cathode, the amount of impurities eluted from the anode increases. To solve this problem, the chelate-resin purification process that was introduced in 1983 was renovated, and impurities could be recovered more efficiently. In this paper, we report various improvements that have been implemented at the refinery since 2000. INTRODUCTION Tamano Smelter and Refinery of Hibi Kyodo Smelting Co., Ltd., founded in 1968, celebrated the 50th anniversary of its founding in 2018. The Tamano Smelter opened its No. 1 tankhouse in 1972, and began operating No. 2 tankhouse in 1984. Thereafter, with continuous production increases and technical improvements, electrolytic copper production was increased from 84 KTPY to 290 KTPY as shown in Figure 1. Table 1 shows the major operating facilities and operation data in 2017.In this paper, details of equipment introduced to continuously dissolve and add glue, various improvements made to the chelate resin process, enhancements made to the crude Ni sulfate process, and another vibrating screen introduced to the copper slime processing flow in accordance with the expansion of copper production capacity since 2000 are reported.

Jan 1, 2019

By D. J. Lloyd

"Bending is involved in the forming of many sheet parts and it is important to understand the phenomena involved. In this paper the basic equations describing bending on a global scale are compared with strain measurements of bent sheet. The development of strain on a local, microstructural scale is also investigated, as is the general aspects of plasticity and the failure process. It is shown that the global equations can be used to estimate the strains involved and the local strains can be attributed to various aspects of the plasticity. The bendability can be related to the fracture strain of the sheet and the ability of a sheet alloy to accommodate the necessary bending to form the part can be assessed.INTRODUCTION The ability of a sheet alloy to undergo bending without failure is an important capability in the forming of many parts and it is useful to be able to assess the bendability of an alloy during its development. The basic mechanics of bending were developed in the 1950s (Lubhan & Sachs, 1950; Hoffman & Sachs, 1953). When a sheet is bent the upper bend surface is in tension, the lower surface in compression and at some point within the sheet there is a plane of zero strain which is referred to as the neutral axis. For sheet exhibiting limited plasticity the neutral axis is static and occurs at the mid-point of the sheet thickness but for sheet exhibiting extensive plasticity the neutral axis progresses deeper in to the sheet as bending progresses. This results in two expressions for the maximum strain at the upper bend surface depending on the motion of the neutral axis. For Al alloys such as AA6111, AA6016 and the like extensive plasticity occurs and the neutral axis is expected to move during bending. However, very few studies have examined how the neutral axis motion and the strains develop, compared with the mechanics analysis. Geist and Parker (1984) used hardness measurements to investigate neutral axis motion but these experiments did not have the resolution necessary to compare the results with experiment but did indicate neutral axis motion. To understand the nature of plasticity and failure during bending it is important to know the extent of neutral axis motion, the scale of strain gradients developed through the sheet and the maximum strains occurring at the bend surface, finally comparing experimental results with the theoretical predictions. The influence of microstructure on the evolution of strain and failure can then be considered in the context of these parameters. Recently, bending in some automotive Al alloys has been reported mainly from the microstructural perspective (Lloyd, 2000, Lloyd et al., 2002, Mattei et al., 2013) and FEM studies have also investigated the development of plasticity under bending, demonstrating the tendency for strain localization (Becker, 1992, Shi et al., 2014)."

Jan 1, 2018

By W. Abdellah

Underground mine developments, such as haulage drifts and cross cuts, play a vital role in providing access to ore extraction areas for mine production. The stability of mine developments is thus of crucial importance during the life of a mine plan. Many Canadian mines use longhole mining methods or one of its variants. These methods require access to the orebody through mine developments such as haulage drifts and cross cuts on multiple levels. This paper examines the stability of mine development access intersections with respect to the planned mining sequence. A case study, the #1 Shear East orebody at Vale?s Garson Mine in Sudbury, Ontario, is presented. A three-dimensional, elastoplastic, finite difference model (FLAC 3D) was created for a development intersection situated 1.5 km below ground surface. The stability, or performance of the intersection, is evaluated in terms of the strength-to-stress ratio. The ratio threshold is set at 1.4 for temporary openings. Unsatisfactory performance is defined as a strength-to-stress ratio less than this threshold value. The performance of the intersection stability is evaluated at various modelled mining stages and the probabilistic method of analysis is then invoked to study the probability of unsatisfactory performance of the intersection. The results are presented and categorized with respect to probability, instability, and mining stage.

Aug 1, 2013

By J. Budac, R. Kofluk, S. Mankasingh

Stainless steels such as 316L or 304 are normally relatively resistant to attack by nitric acid. However research at Sherritt International’s Fort Saskatchewan Operation reveals that when the stainless steel is immersed in an aqueous system in which nitric acid is used to dissolve metals such as cobalt or nickel, the steel can be seriously corroded. Sherritt is patenting a simple process for arresting the corrosion via the use of copper. This process is expected to substantially eliminate corrosion in processes where nitric acid is used to dissolve metals attached to a stainless steel substrate.

Jan 1, 2014

By Yu Chen, Charlie C. Li

The application of rock bolts for the stabilisation of underground openings needs a good understanding of the response of the bolts during rock excavation. The pull-and-shear performance of two types of rock bolts—that is, the fully encapsulated rebar and the D-Bolt—has been studied both experimentally and numerically. The rock bolts were tested under a pull-and-shear load at five displacing angles (i.e., 0°, 20°, 40°, 60°, and 90°), and at the same time, the strains on the bolts were monitored during testing. The two types of rock bolts have similar loading capacities, while the loading angle has obvious influence on the deformation capacity of the D-Bolt. The ultimate total displacement of the D-Bolt decreases from 140 mm under pure pull loading to 70 mm under shearing. The displacement capacity of the rebar is not significantly influenced by the loading angle but remains at a quite low level from 29 to 53 mm. The D-Bolt yielded in a longer section the rebar bolt under pure shear. A trilinear material model was used to simulate the strain hardening behaviour of the bolt steels in the numerical code FLAC3D. The numerical results show that the axial load in the bolt decreases exponentially with the distance from the loading position for the rebar bolts, but it remains constant in the bolt sections between the anchor positions for the D-Bolts. When the bolt is subjected to a lateral load, shear stresses are created on the D-Bolt surface within a short distance from the loading position.

Jan 1, 2015

By Yvon Trudeau, Deni Raymond

"The Orion gold mine, located 7 Ian northeast of the town of Malartic, Quebec, was discovered in mid-1985. Underground exploration was undertaken in 1986 leading to commercial production in 1988. The upper part of the orebody was exploited above the 125 m level and a total of 131 090 t at an average grade of 5.31 g/t gold were extracted.This paper describes the authors&apos; current knowledge and interpretation of the geology, gold distribution, and structure of the Orion No.8 ore zone deposit. The deposit is an epigenetic lode gold occurrence somewhat unique in that both quartz-vein type and pyritic type of gold ore occur side-by-side. It is located within the Marban-Noriartic Deformation Corridor (MNDC) formed during a first deformation stage (D1) The MNDC is a well-defined regional structural feature in the Val d&apos;Or - Malartic mining camp. Primary gold mineralization is associated with the D1 event and is represented by pyritized, silicified and brecciated basaltic lavas enclosed by ultramafic flow units. The ore zone is concordant with the MNDC. Felsic intrusions are spatially related with the ore zone, but their role in the genesis of the ore has yet to be dermed.A second deformation event (D2) resulted in local folding, a second schistosity (S2) and reverse faulting. Gold remobilization, the formation of the gold-bearing quartz breccia and the emplacement of the main quartz vein at the No. 8 zone deposit were associated with this event."

Jan 1, 1992

By E. V. Manlapig, M. A. Hampton, M. E. Holuszko

Methanol treatment of ZnS particles has been found to remove slimes and facilitate flotation. The removal of slimes renders the ZnS surface more hydrophobic, resulting in an increase in the hydrophobic attractive force between the particle and bubble. Hallimond tube flotation, induction time measurement and particle-bubble force analysis with the atomic force microscope (AFM) was undertaken to link the beneficial effect of methanol treatment of ZnS particles to their increased floatability.

Jan 1, 2009

By G. S. Hume

"THERE HAS BEEN a marked growth in the petroleum industry in Canada since the end of the war. The rate of growth in the demand for oil products has exceeded that in United States, although the per capita consumption is still less. Estimates of the consumption of petroleum and petroleum products in Canada in 1951 are approximately 154,000,000 barrels, which is slightly more than 11 •barrels per capita, whereas the estimated consumption in United States for the same period, according to World Petroleum, is placed at 2,619,- 970,000 barrels. This, on the basis of a population of 154,000,000, would be equivalent to 17 barrels per capita. The increase in consumption of the petroleum and products is world wide. World production in 1951 has been estimated (Oil and Gas Journal) at 11,700,000 barrels a day or more than 41;4, billion barrels for the year. United States production increased 13.7 per cent to 6,143,000 •barrels a day and Canada'.s ,, total production increased about 65 per cent from a total of 29,091,235 •barrels in 1950 to an estimated (Dominion Bureau of Statistics) 48,096,800 barrels in 1951.The trend to use increased amounts of petroleum and petroleum products, particularly in the United States and Canada, has also been supplemented by increased use of natural gas. The rate of expansion of the consumption of natural gas in United States in the past few years has been very rapid, increasing from 2,600 billion cubic feet in 1940 to 5,975 billion in 1950, with the proven reserves in the same period increasing from 85,000 billion to 186,000 billion cubic feet."

Jan 1, 1952

By L. H. Smith, D. S. Taylor

"AbstractSherritt has been applying hydraulic drives to concentrator equipment since 1967. The initial application was made on a bank of 5- by 5-in. slurry pumps. This has now been extended to all slurry pumps requiring less than 40 hp and several conveyors which require variable-speed or low-speed/high-torque characteristics. The pump motors are directly connected through a flexible coupling, whereas the conveyor systems are directly mounted onto the head-pulley shaft extension.The different applications and design concepts will be described, with outlines of the operating and maintenance advantages and disadvantages and costs. The paper also outlines future possible applications, together with the limiting conditions, of such systems.IntroductionSHERRITT GORDON MINES LIMITED has been operating a mining division in Northern Manitoba for almost 50 years. The original mining operation was at Sherridon, Manitoba and was a copper-zinc producer. This mine was exhausted in 1948 and the mining plant was moved north to its present location at Lynn Lake, Manitoba. The Lynn Lake Mine is a nickel-copper producer. Since 1960, two new mines have been discovered and brought into production in the general vicinity of Lynn Lake. The first of these was the Fox Mine, a copper-zinc property operating at 3,000 tons per day from an underground operation. This mine started production in May 1970."

Jan 1, 1977

By W. H. Zieman

NORMAN WEISS, Milling Engineer, American Smelting• and Refining Company: The subject of the Forum on Rod and Ball Mill Liners is very fascinating, and there is no end of discussion when operators get together on grinding. However, the hypotheses and suppositions easily outrun the facts, especially when we •consider the inaccuracy of many reported observations. Still surprisingly small is the number of concentrators even reasonably well equipped to measure power consumption of each grinding mill, together with running time, so that data on this tangible factor, at least, can be obtained with precision. While the more elaborate devices of this nature, producing for each 24-hour period the total power consumption, average kilowatt hours per hour, short-term demand chart, instantaneous demand, and print-out, may cost in the neighbourhood of $2,500 per mill and may be difficult to justify, the combination of an ammeter, watthour meter, and running-time meter will cost only a few hundred dollars, so there appears to be little reason not to in-stall them in view of their numerous advantages.

Jan 1, 1959

By Russell McIntosh

"The Madsen mine is in the southeastern part of Baird township, in Red Lake area, Ontario. It lies about 6 miles southwest of the town of Red Lake, with which it is connected by an all-weather road.The Madsen Red Lake Gold Mines Company was formed in March, 1935, to take over the holdings of the Falcon Gold and Jomac Gold syndicates. During 1935 an4 the early part of 1936 No. 1 shaft was sunk and drifts driven on four levels, all on a narrow quartz vein in a granite dyke.In July, 1936, the Austin zone was discovered about half a mile north of No. 1 shaft by Austin McVeigh, a prospector employed by the Company. Diamond drilling showed that the zone included an orebody worth development, and in 1937 No. 2 shaft was sunk, three levels opened up and sufficient ore outlined to justify the installation of a mill. Milling commenced in August, 1938, at the rate of 300 tons a day, which was later increased to 400 tons a day.The total production from 1938 to 1946 was 1,116,307 tons from which gold and silver having a value of $9,949,010 were recovered. The gold produced ranged from a minimum of 0.1910 oz. a ton in 1939 to a maximum of 0.2827 oz. in 1944. The average grade in 1946 was 0.2345 oz. to the ton."

Jan 1, 1954

By L. Zeng, Q. Feng, Z. Qiu, L. Ou, Central South University

It is well-known that the use of nanobubbles can significantly improve the flotation efficiency of ultra-fine particles. However, this is mainly focused on coal and phosphate rock flotation. In the field of nonferrous metal processing, the related research is few. In this paper, a small laboratory mechanical cell associated with a specially-designed nanobubbles generator was used to investigate the effects of nanobubbles on enhancing ultra-fine scheelite flotation. Nanobubbles were created and based on the hydrodynamic cavitation principle through Venturi tubes. Comparative flotation tests were performed using different tubes to evaluate the nanobubbles impact on the ultra-fine scheelite particle flotation recovery. In order to better understand the nanobubbles enhanced ultra-fine scheelite flotation, nanobubbles potential and size distribution were measured. The effect of nanobubbles on the particle aggregation and scheelite particles potential were also studied through the turbidity tests, microscope tests and zeta potential measurements. According to the results, the mean size of nanobubbles was about several hundred nanometers, and the surface of nanobubbles was of highly negative charge in alkaline conditions. The flotation recovery of ultra-fine scheelite particles was increased in the presence of nanobubbles. The zeta potential measurements indicated that the repulsive forces between scheelite particles decreased when nanobubbles existed. Through the turbidity tests and microscope tests, the promotion effect of nanobubbles on particle coagulation could be verified more directly. The existence of nanobubbles in flotation system promotes the particle aggregation, thus increasing particles apparent size and particles capture by bubbles, which may be the fundamental reason why nanobubbles enhance ultra-fine scheelite flotation.

Jan 1, 2016

By A. H. Lang

"The great interest taken in uranium in Canada during the past few years has resulted in the discovery of a very large number of occurrences, and in much research that has added to the knowledge of the mineralogy and geology of uranium deposits. The object of this paper is to present that information in condensed form. Some of it has been published before, but the writer has been asked to bring it together and to add more recent, unpublished data. The paper therefore contains short accounts of the mineralogy of uranium and of the types and distribution of occurrences; brief regional descriptions, including information on some of the characteristic deposits; and conclusions regarding prospecting and development possibilities.The writer has access to much confidential information supplied in compliance with regulations of the Atomic Energy Control Board. He has used this only for making broad generalizations that could not affect individual interests, and only where the owners of properties have agreed to its use.Much of the information on mineralogy and geology is derived from the work of others. The writer is particularly indebted to M. H. Haycock and S. Kaiman of the Mines Branch; H. V. Ellsworth, S. C. Robinson, E. J. Brooker, H. R. Steacy, W. E. Hale, and A. M. Christie of the Geological Survey; and E.W. Nuffield, J. S. Stevenson, and other officers of provincial Departments of Mines. For information and many courtesies he is greatly indebted to so many officers of Eldorado. Mining and Refining (1944), Limited, and owners and staffs of private properties, that it is impossible to mention them individually."

Jan 1, 1950

By S. J. Laskowski

In potash ore flotation, carried out in NaCI-KCI saturated brine (about 6-7 molar KC1 and NaCI solution), long-chain primary amines are used as flotation collectors. Long-chain primary amines are poorly soluble in water and their solubility further decreases at high electrolyte concentration. For ionic surfactants there is a characteristic temperature (Krafft Point, KP) below which their solubility is too low for micellization. In a previous study, the effect of pH on the KP of dodecylammonium chloride in water was determined [Q. Dai and J.S. Laskowski, Langmuir, 7, 1361-1365 (1991)]. This paper deals with the effect of electrolyte concentration on the KP of dodecylammonium chloride. The derived theoretical relationship between the KP and the critical micelle concentration (CMC) for dodecylamine can be used to calculate the KP for electrolyte concentrations of up to 0.5 mol/L (about 8% NaCI-KCI brine). A simple experimental procedure for the determination of the KP for higher electrolyte concentrations is also described. The results show that the Krafft point of dodecylamine increases from about 17-18°C (in distilled water) to about 80°C at 16% brine saturation.

Jan 1, 2006