Search Documents

By L. Chunpongtong

Compared to equipment used in hard rock mines, the lifespan of equipment deployed in oil sands operations tends to be shortened due to the abrasive nature of the material and soft ground conditions in which it operates. One of the challenges of oil sands mine planning is to determine the most cost-effective replacement time for aging equipment. For cost engineers dealing with aging equipment, the options become an economic trade-off between taking the chance of higher frame failure or buying new equipment. Therefore, the ultimate question is: “When is the best time to replace the equipment?”

Jan 1, 2012

By P. M. Shibley

"IntroductionMine drainage, surface. drainage and process liquors are the principal mine and mill effluents. The quantity and quality of these flows varies according to mineralogy, type and scale of mining, the process, tailing disposal, local ground conditions and climate.Typical contaminants remaining after solids sedimentation are colloidal or semi-colloidal particles, acids, alkalis, metals in solution, cyanides and thiosalts. Environmental regulations and guidelines have been issued in detail by the appropriate government agencies and will not be reviewed here. Revisions and additions are being made as our comprehension and abilities increase. Some contaminants of consequence have not been specifically regulated as practical treatment technology has not been identified. Thiosalts fall into that category as do the derivatives of the first stage of cyanide oxidation - cyanates.Most mining activities have present or foreseeable water treatment requirements. Because process economics can be adversely skewed by the environmental factor, the acknowledged objective of every operation must be to identify and anticipate those requirements.The evaluation and selection of water treatment techniques for mine-mill applications is complicated by the fact that most mine-mill effluents are high volume, dilute and chemically complex systems. Treatment processes applicable to most contaminants are: chemical or biological oxidation; neutralization and/or precipitation; liquid/solids separation. Other processes such as ion exchange, electro-deposition, foam fractionation, freeze crystallization and reverse osmosis offer the possibility of selective removal or concentration of contaminents. The latter tediniques, representing a slightly higher level of technology, are less suited to the large, low value flows usually encountered in the mine environment."

Jan 1, 1989

By Ray Mason

Marathon PGM Corporation?s PGM-Cu Project in Northwestern Ontario (Figure 1.0) serves as a case study to describe the process involved in advancing a deposit from grass roots exploration to the completion of several feasibility studies and the parallel commencement of environmental permitting. Through the following examination of historical exploration activities, it is clear that these activities are directly related to economic stimulus, mostly measured by downturns in the mineral industry. Other factors that influence the success of exploration advancing to feasibility and new mine development includes the ownership of the mineral claims, which also changes under these economic influences and the crucial role of interactions between the Company, the Crown and First Nations. The Marathon PGM-Cu deposit is hosted within the Eastern Gabbro Series of the Proterozoic Coldwell Complex, which intrudes and bisects the much older Archean Schreiber-Hemlo Greenstone Belt. The sub-circular complex has a diameter of 25 km and a surface area of 580 km2 and is the largest alkaline intrusive complex in North America (Walker et al., 1993). Mineralization at the Marathon PGM-Cu deposit is part of a very large magmatic system that consists of at least three cross-cutting intrusive olivine gabbro units that comprise the Eastern Gabbro Series of the Coldwell Complex (Figure 3.2.4-3). In order of intrusion, the three gabbroic units consist of (1) Layered Gabbro Series, (2) Layered Magnetite Olivine Cumulate (LMOC) and (3) Two Duck Lake (TDL) Gabbro. The relative size and abundance of the gabbroic units decrease in the order Layered Gabbro Series>TDL Gabbro>>LMOC. Late quartz syenite and augite syenite dikes cut all of the gabbros but form a minor component of the intrusive assemblage.

May 1, 2010

By Yves Caron

Résumédes travaux effectués De septembre 2009 àmai 2011 ? Plus de 21 000 m de forages complétés en avril 2011 et près de 9 000 échantillons ? 2,7 km de décapage, 52 tranchées et 852 m de rainures ? Estiméde ressources 28 mai 2010 (SGS Géostat) ? Essais métallurgiques en laboratoire (automne 2010) ? Étude économique préliminaire (janvier 2011)

May 1, 2011

Particles for heap leaching in conventional circuits are prepared using Cone crushers. Cone crushers are used to crush the ore to the size range between 12-25 mm for heap leaching operations. Leaching from these relatively coarse particles occurs only at the surface and in subsurface regions, which are accessible from the surface by cracks and pores. Since leaching is active in accessible areas, the method of comminution that forms multiple cracks and pores would offer an advantage for heap leach. An investigation was performed in this study to assess if the HPGR forms more cracks and pores than a Cone crusher. X-ray computed tomography (CT) was used to characterize the degree of cracks and pores formed by these two comminution devices that can be used for heap leaching feed preparation. In order to compare the effect of the comminution method on crack network generation, a bulk sample of the zinc ore was crushed by the HPGR at three different pressure settings (45, 95 and 120 bar), the sample ore was also crushed with a Cone crusher for comparison purposes. Products from the Cone crusher and HPGR experiment were then screened into five size fractions ((-25 +19), (-19+16), (-16+9.5), (-9.5+5), (-5+4.75) mm), Subsamples from the ((-25 +19), (-16+9.5), (-5+4.75) mm) size fractions were analysed. The spatial distribution of the crack network of sphalerite particles was characterized using a highresolution industrial X-ray CT system. This paper describes the use of image analysis techniques including image segmentation, which uses a combination of thresholding and other methods to characterize and quantify crack and mineral dissemination in the sphalerite particles after comminution with the HPGR and Cone crusher. The results are validated with those obtained using traditional techniques such as physical gas (with N2) adsorption, mercury intrusion porosimetry, SEM and QEMSCAN.

Jan 1, 2012

By L. A. Homeniuk, R. Bonnar

"The Fond-du-Lac uranium deposit is located on the northern rim of the Athabasca Basin. The uranium mineralization is, for the most part, confined to the Athabasca Group, which is underlain by pre-Helikian metamorphic rocks of the Western Craton.The deposit is characterized by a remarkable train of mineralized glacial erratics which led to the original discovery. The mineralization is present as a ""high-grade"" core and a diffuse ""low-grade"" aureole. The ""high-grade"" core occurs as a stockwork of steeply dipping pitchblende veins which strike N 50°E. Hematite, siderite and secondary silicate are also abundant. The ""low-grade"" aureole contains uraniferous goethite, argillaceous material and rare carbon buttons. Recent alteration to coffinite has taken place along the margins of pre-existing ore minerals.The ""high-grade"" core is 390 m long and 10 to 40 m wide, and is surrounded by an irregularly shaped zone of ""low-grade"" mineralization with a similar length and a width of up to 350 m.Comparing the Fond-du-Lac deposit to other unconformity-type deposits, several important differences can be noted:1. Ninety per cent of the ore is above the unconformity, in the Athabasca sandstone.2. The deposit is not associated with underlying graphitic rocks or a major structure.3. The clay-rich alteration zone is not extensive around the Fond-du-Lac deposit.Although there are differences with other Athabasca unconformity-type deposits, the high-grade portion below the unconformity suggests a common origin.The ore deposit is postulated to have been formed from uranium-bearing solutions which entered the stockwork of fractures. Following the reduction in part of these solutions by pre-existing carbonaceous matter and pyrite and/or chemical reaction with pre-existing hematite, deposition continued as a result of decreasing temperature and pressure. Subsequently, minor supergene redistribution of the uranium has taken place."

Jan 1, 1982

By L. A. Homeniuk, R. Bonnar

"The Fond-du-Lac uranium deposit is located on the northern rim of the Athabasca Basin. The uranium mineralization is, for the most part, confined to the Athabasca Group, which is underlain by pre-Helikian metamorphic rocks of the Western Craton.The deposit is characterized by a remarkable train of mineralized glacial erratics which led to the original discovery. The mineralization is present as a ""high-grade"" core and a diffuse ""low-grade"" aureole. The ""high-grade"" core occurs as a stockwork of steeply dipping pitchblende veins which strike N 50°E. Hematite, siderite and secondary silicate are also abundant. The ""low-grade"" aureole contains uraniferous goethite, argillaceous material and rare carbon buttons. Recent alteration to coffinite has taken place along the margins of pre-existing ore minerals.The ""high-grade"" core is 390 m long and 10 to 40 m wide, and is surrounded by an irregularly shaped zone of ""low-grade"" mineralization with a similar length and a width of up to 350 m.Comparing the Fond-du-Lac deposit to other unconformity-type deposits, several important differences can be noted:1. Ninety per cent of the ore is above the unconformity, in the Athabasca sandstone.2. The deposit is not associated with underlying graphitic rocks or a major structure.3. The clay-rich alteration zone is not extensive around the Fond-du-Lac deposit.Although there are differences with other Athabasca unconformity-type deposits, the high-grade portion below the unconformity suggests a common origin.The ore deposit is postulated to have been formed from uranium-bearing solutions which entered the stockwork of fractures. Following the reduction in part of these solutions by pre-existing carbonaceous matter and pyrite and/or chemical reaction with pre-existing hematite, deposition continued as a result of decreasing temperature and pressure. Subsequently, minor supergene redistribution of the uranium has taken place."

Jan 1, 1982

By Bordeaux Sciences Agro-INRA UMR 1065 SAVE, S. Piutti, E. Benizri, S. Lopez

Ultramafic soils display high concentrations of nickel (Ni) and a number of nutrient deficiencies (e.g. N, K, P). Ni-hyperaccumulator plants have evolved on such environments, developed specific metal homeostasis showing concentrations of Ni sometimes above 1% in their aerial biomass (Baker & Brooks 1989). Alyssum murale, a Ni-hyperaccumulator, is commonly found around the Mediterranean but can grow on non-ultramafic soils as well, with an altitudinal extension ranging from sea level to 2000 m.a.s.l. Rhizosphere bacterial communities associated with Ni-hyperaccumulator plants can differ from those of non-accumulating plants growing at the same site. Among edaphic factors that could influence the phylogenetic structure of the bacterial communities, altitude and metal-bioavailability and in particular nickel could be significant. However, most studies have focused on analyzing soils with techniques that provide little detail about the phylogenetic structure of these bacterial communities present in ultramafic soils. The objectives of this study were to understand the specific changes in the structure of A. murale rhizosphere bacterial community that occur across two gradients: 1°) elevation and 2°) Ni geochemistry, using pyrosequencing technique (454-pyrosequencing of 16S rRNA gene). It was found that the higher the soil chemically-available Ni contents, the higher the relative abundance of Proteobacteria and Actinobacteria. On the contrary, the abundance of TM7 decreased with increasing levels of available Ni. Moreover, Chloroflexi was present with 53 to 77% of relative abundance. These results demonstrate that soil chemically-available Ni drives the bacterial community diversity in the rhizosphere of Alyssum murale regardless the elevation gradient and other different soil physicochemical parameters. These results should now be confirmed in different ultramafic edaphic environments worldwide (e.g. ultramafic lateritic covers) and in the rhizosphere of different hyperaccumulator taxa.

Jan 1, 2016

"As part of a series describing the nickel operations of Vale Canada (formerly known as Inco), this paper focuses on the 1973 to current operations of the Copper Cliff nickel refinery in Ontario, Canada. The process used there employs the formation of Ni tetracarbonyl at high CO (gas) pressure and its subsequent decomposition at somewhat elevated temperatures to produce highly pure Ni pellets and powders. Personal sampling of workplace aerosol dusts is reported, with information on specific Ni compounds in the aerosols.RÉSUMÉ Dans le cadre de la série d’articles décrivant les opérations de nickel chez Vale Canada (anciennement Inco), le présent article cible les opérations de 1973 à ce jour à l’affinerie de nickel de Copper Cliff en Ontario, Canada. Le procédé utilisé à cette usine est la formation de tétracarbonylnickel sous une pression élevée de CO (gaz) et sa décomposition subséquente à des températures plutôt élevées pour produire des granules et des poudres de Ni pur. Un échantillonnage par l’auteur des poussières en aérosol est présenté ainsi que de l’information sur les composés spécifiques de Ni dans les aérosols."

Jan 1, 2015

By A. Gillis, J. Keyes

"This is a prelirr1inary report on automatic control at East Malartic Gold Mines.After installation of the cyclones in the East Malartic grinding circuit, the interest was aroused in the automatic control system for the circuit. Investigations were made as to the possibilities of such an installation. This resulted in a preliminary survey of the circuit by Milltronics Ltd and an analysis of the circuit by Mines Branch personnel. A study of the investigation and analysis indicated that a cost reduction and improved efficiency could be expected by the installation of an automatic control system in the grinding circuit. It was also indicated tl1at such installation should pay for itself within a year. This was the point that sold management on such installation. The need of three operators was expected to be eliminated .The installation was to consist of a central control panel, microphoncs on each mill, regulation of feed rate, pneumatic valves for addition of solt1tions, density control of the cyclone overflow, which is a grinding circuit product, rod mill feed box plugging detector and a conveyer weightometer for tonnage indication and control.As well as the elimination of one man per sl1ift, other benefits which were to be received but unable to estimate were: 1) More tonnage per clay by operation of the mills at the proper capacities. 2) Lower grinding costs. Less under-loading should result in less steel wear and lower pumping cost. In the condition of overloading, a coarser grind is obtained resulting in greater impeller and liner wear. The overloading and underloading showed up on the n1icropl1oncs. 3) An improvement in the recovery as a result of less over-load. The tailings loss from a coarser grind are not as frequent."

Jan 1, 1965

By Robert D. Brown, Robert B. Parsons

"Careful tax planning and proper attention to the regulations can result in an optimum deduction ""of the 25% federal resource allowance. Introduced in the Income Tax Act in1976, in part to compensate for the disallowance of provincial mining taxes and royalties. the 25% ""resource allowance"" is a permitted deduction in computing taxable income from mining and petroleum. However, the rules relating to the deduction are complex, and the importance of the deduction which can readily exceed 25% of net income- is frequently underestimated. This month, Tax Notes discusses the basic rules of calculating the resource allowance, and suggests some tax planning aspects which may warrant consideration.May 6, 1974 - "" .. . our provinces have adjusted royalties, mining taxes and other arrangements to derive what they perceive to be a fair share for the benefit of their people. However, a provincial resource is also a national resource... I am proposing that revenues derived by provincial governments in respect of production from a… mineral resource should no longer be.\ deductible in computing the income of the operator. .. I am proposing that. .. there be an extra abatement from federal income tax in respect of taxable production income.. .fifteen points in the case of mineral profits. .. "" - The Honourable John N. Turner, Minister of Finance. June 23, 1975-"" '"" to meet, at least in part, the request for some form of deductibility in the tax system for provincial resource levies... to offer more incentive to those who explore and develop in Canada. .. I am now proposing, the extra fifteen point abatement of federal taxes would be withdrawn... at the same time, I am introducing a new resource allowance, which would be an extra deduction from income equal to 250/0 of production income.. ."" - The Honourable John N. Turner, Minister of Finance."

Jan 1, 1980

By Roger C. Parsons

"The problems presented by ice formation and interference with processes, structures and mechanical operations in the mining industry can be expected to increase sharply as more of our mineraI needs are supplied from the far north. A process of rapid ice destruction is presented which lends itself to the effective removal or penetration of ice. Suggestions are offered for applying the system to problems related to mining activity in cold environments. The system can be readily adapted to large-scale operation, the reactant components being transported in crystalline form and volatilized on site.IntroductionThe number of operational mines in northern environments, relative to the number of mines in the temperate zone, will increase in the years ahead. This is not surprising, because:(a) in the past, those mines closest to centres of commerce had minimum transport charges and hence were more economic to develop;(b) great centres of commerce were far removed from northern environments;(c) the exhaustion of ores and lowering of grades in temperate zones now offset to some degree the extra transport costs applied to northern ores;(d) the abundance of excess energy in the north in the form of oil, gas and hydropower attracts mining as a means to justify its development; (e) assuming that the frequency of mineral occurrence north of the 52° N latitude is no different than south of it, there are many deposits waiting to be developed.As a result of current and projected activity in northern environments, we are faced today, and will be increasingly so in the future, with mining problems rarely encountered before-problems related to below-freezing temperatures. Engineering activity in permafrost regions will increase as new mining ventures are developed north of the 52° N latitude, roughly coinciding with the -1.1 ° C isotherm in Labrador, the upper temperature boundary for permafrost."

Jan 1, 1982

By W. A. Alexander

Introduction In the course of a programme of research on beryllium in progress in these laboratories, knowledge of the recrystallization temperature became necessary. As the information is not available in the literature, the determination of this temperature for metallic beryllium was undertaken. By the reduction of grain size through working and recrystallization and the probable simultaneous induction of preferred orientation, it was hoped to improve the working properties of beryllium at lower temperatures. The recrystallization temperature is usually determined by observing the lowest temperature of annealing at which new crystals are formed in severely cold-worked metal or alloys. This temperature is profoundly influenced by the following factors: the purity of the metal, in the case of an element, or the composition of the alloy; the degree of straining or working; the temperature of straining; the original grain size; and the time held at the annealing temperature. The observed temperature is lowered by higher purity, more severe straining, lower temperature of working, smaller original grain size, and longer time of annealing. Beryllium presents special difficulties in that the percent elongation in tension is effectively zero, so that ordinary squeezing or rolling was not possible. A possible means of straining was suggested by the fact that indentation hardness tests could be made. It was known from earlier work that the metal could be worked at elevated temperatures, so that working at the lowest feasible temperature and quenching might also be a means of producing strain. The purity of the metal is also a point of some uncertainty in the case of beryllium. Losano has prepared 99.96% Be which appears to be the best reported. Distilled metal used in the present work approached this purity. However, by analogy with other metals, residual impurities may have a pronounced effect on the recrystallization. Further purification of beryllium would evidently entail considerable difficulties due to the highly reactive nature of the metal, and was not attempted.

Jan 1, 1947

By P. R. A. Andrews

"A sample of flotation feed from Bakertalc Inc., High water, Quebec was subjected to flotation evaluation to improve the recovery of talc. A number of alternative frother/collectors and depressants as well as flotation parameters including pH, conditioning time, frother/collector concentration and pulp density were assessed. In addition, the possibility of using a size coarser than that currently employed for flotation (95% minus 50 um) was investigated.As far as possible, a laboratory duplication of the present circuit arrangement was folio wed so as to minimize the cost of any changes. The best results obtained were a concentrate analyzing 95.96% acid insol for a recovery of 65.98% after four stages of cleaning. With recirculation of cleaner tailings, the recovery would be higher.The possibility of using an alternative method, based on the natural ability of talc to float unaided by a frother/collector, was briefly explored with encouraging results.IntroductionBakertalc lnc ., located in the eastern townships at Highwater, Quebec, Is approximately 140 km east of Montreal near the Vermont, U.S. border. Originally called Baker Mining and Milling Co. Ltd., it has produced pulverized talc products since 1938(1 ), although records show that talc was mined in the area as early as 1871(2). Feed to the mill originally was obtained from local deposits, but since 1952 the van Reet mine near south Bolton, approximately 25 km from Highwater, has been the source of ore .In 1957 a Raymond high -side roller mill was installed which enabled production of a greater range of talc products and, in 1960, new crushing equipment and a dryer were added. Other additions to the mill were the introduction of wet magnetic separation, although this was later discontinued, and flotation to produce high-grade talc concentrates."

Jan 1, 1985

By A. J. Sinclair

"Abstract-Geology contributes essential information toward obtaining high-quality resource/reserve estimates. In this context, geology can be considered under the following overlapping topics: regional geology, detailed (deposit) geology, mineralogy, ore deposit models and continuity, with geological mapping being fundamental to all. Each of these topics is considered here in terms of potential contributions to "improved" mineral inventory estimation. Some of the principal conclusions are:1. Regional geological relations must be consistent with deposit geology. It is common that important geological relations are more clearly evident in various regional locales than in highly altered and/or highly deformed mineralized areas containing mineral deposit.2. Detailed geology provides information for a geometric model of a deposit, a model that serves as a basis for mine planning. It is important to distinguish fact from interpretation in such models. Substantial effort is required to characterize the geometric margins of a deposit and the relation of these margins to the simplistic geometric form that normally emerges as an interpretation.3. Mineralogical studies relate to many aspects of deposit evaluation including abundance of ore and deleterious minerals, spatial distribution of ore and deleterious minerals, grain size characteristics of important minerals, mill design, etc.4. Ore deposit models contribute substantially to confidence in developing a three-dimensional geometric model of a deposit for mine planning. Specifically, they are a basis on which to develop rules for interpolation and extrapolation of ore, and they contribute to recognition of domains, each with its own characteristic continuity and margin character.5. Continuity is dependent on mineralization style and may be controlled structurally and/or chemically. It is important to distinguish geological continuity and value continuity. A wide range of classical geological methods are useful in examining geological continuity; value continuity is best viewed as a statistical characteristic that is quantified by any of several measures of autocorrelation."

Jan 1, 1998

By Rodney G. Orr, Phil Robertshaw, Roland Loewer, Klau Lehnert-Thiel

This paper documents the 1988 discovery and subsequent evaluation (to 1991) of diamond bearing kimberlites in the Fort à la Corne area, Saskatchewan, by Uranerz Exploration and Mining Limited. Cameco Corporation began participating as a joint venture partner (50%) in mid-1989. The first indications that kimberlite-type intrusions might exist in the area carne from Geological Survey of Canada aeromagnetic maps. Because of the overburden thickness (over 100 m), magnetometer surveys continue to be the main exploration tool in defining pipe locations and sizes. Magnetometer surveys in varying levels of detail have outlined one main cluster and two sub-clusters, the main group being some 10 km by 50 km in size. In excess of 70 individual targets have been interpreted from the magnetics as probably representing kimberlites. The size range of the individual magnetically-defined bodies is between 1 ha and 74 ha. Proof that the magnetic anomalies were kimberlite intrusions carne in 1989 when each of seven test holes, all drilled on different targets, intersected the potential diamond host rock. The majority of the targets tested were diamond-bearing, with the indicator mineral chemistries suggesting that both peridotitic and ecIogitic diamond parageneses could be expected. To date, 18 individual kimberlite bodies have been drill-tested. A total of 39 bulk samples, amounting to 186 t (representing 360 t of theoretical sample recoveries) were processed in 1990 and 1991. One hundred and sixty diamonds were recovered, averaging 0.04 carats in weight, the largest being 0.6 carats. Most of the bulk sample grades are less than 2 carats/loo t; only three bulk samples have higher grades, the best being approximately 10.5 carats/l00 1. The diamonds are predominantly gem-quality stones.

Jan 1, 1992

By G. V. Poropat

Roughness of a discontinuity may be an important factor influencing shear strength of the discontinuity. Traditionally, determining the roughness of a discontinuity surface and providing a numerical measure of the roughness has required considerable effort or specialised equipment. The development of new 3D imaging tools that are easy to use has provided effective fast and accurate means of creating 3D surface models from which roughness measurements can be readily obtained. These new techniques are versatile enabling a user to measure roughness along any desired profile and at any resolution up to the limit of the spatial subtense of a measurement on the discontinuity surface. This paper primarily reviews extensions to the use of 3D imaging that enable the measurement of roughness. Additionally we provide some examples of the measurements and examine some of the issues associated with extracting measures from the spatial data that will support estimation of shear strength.

May 1, 2009

By H. Clare Horwood

"Two structures, a fracture zone and a shear zone, contained the two orebodies that yielded all the ore mined at the Gold Eagle mine. The orebodies are known as the Gold Eagle vein and the No. 1 shear zone. Both structures occur close to contacts between Timiskaming sediments, Algoman diorite, and later Algoman granite-granodiorite. The structures were produced by compressive forces from a south direction acting in the southern part of the McKenzie-Gold Eagle stock and in a cylindrically shaped inclusion of Timiskaming sediments.The mine, which exhausted its ore reserves and ceased operations in September of 1941, is on the east side of Mackenzie island, in the centre of Dome township in the Red Lake area.The Gold Eagle vein was located during the summer of 1933 by a surface exploration programme carried out under the direction of Alex Gillies. Sub-· sequent diamond drilling and underground exploration led to the installation of a mill, which came into production in October of 1937. The No. 1 shear zone was discovered and explored later from a drive on the 500-foot level. The mine produced a total of 40,204 oz. gold and 19,157 oz. silver from 223,628 tons of ore hoisted (180,095 tons milled) during its 4 years of mill operation.GENERAL GEOLOGYThe ore-bearing structures trend S.61°E. across Timiskaming greywacke, Algoman diorite, and later Algoman granite-granodiorite. The greywacke is a large, cylindrically shaped mass that is separated from the mai~ mass by the later intrusives. It is a massive, light-coloured, quartzose variety that has been recrystallized by the enclosing granite. The diorite and the granite-granodiorite are early and late components of the McKenzie-Gold Eagle stock. The diorite, which is a porphyritic rock containing large crystals of andesine-labradorite surrounded by hornblende, was injected early in the Algoman period. It was intruded and in large measure surrounded by the later granite-granodiorite. This rock varies from a granodiorite near the mine to a granite in the centre of the stock. All three intrusions are massive and homogeneous."

Jan 1, 1954

By D. H. Schwarz

The performance of proton exchange membrane (PEM) fuel cells depends on catalyst layer composition and structure. Experimental observations reveal that state-of-the-art catalyst layers consist of microporous agglomerates of carbon-supported catalyst sites bound together by polymer electrolyte. In between the agglomerates are macropores which provide pathways for the transport of gaseous reactants. In this work, three-dimensional, multicomponent and multiphase transport computations are performed using a computational fluid dynamics (CFD) code (FLUENTTM) with a new PEM fuel cell module, which has been further improved by taking into account the detailed composition and structure of the catalyst layers using a multiple thin-film agglomerate model. In this model, it is assumed that thin films of polymer electrolyte and liquid water surround the catalyst sites. The results of CFD computations show that transport limitations associated with the thin film of polymer electrolyte and the presence of liquid water in the catalyst and gas diffusion layers have substantial negative effects on PEM fuel cell performance. Also, the results of computations with variable distributions for a given precious metal loading show that, in general, uniform catalyst loading provides the best fuel cell performance.

Jan 1, 2005

By K. Adham

Iron chloride pyrohydrolysis (ICP) is used as an efficient way to fix iron as an oxide, for sale as a by-product or for safe disposal. Iron chloride is reacted with water at elevated temperatures to yield iron oxide and hydrogen chloride. Both the steel industry and synthetic rutile producers make extensive use of ICP. Two technologies are available for ICP: fluidized bed (FB) and spray roaster (SR). Both technologies are energy intensive. Here, fluid beds and spray roasters are compared with respect to their fuel and electrical energy consumptions. Roaster size and oxide product characteristics are also considered. Process models are prepared, using the METSIM® software, and specific energy consumptions are compared. The results will help the industry decide which technology best suits its goals and at what energy cost.

Jan 1, 2006