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By H El-Shall, R Stana a

An innovative process for the separation of carbonaceous minerals from bulk ores is presented. In this process, the surface of carbonate minerals is reacted with acid used to nucleate CO2 bubbles at the particle solution interface. Entraining the liberated CO2 gas at the surface via coating agent renders the particle more buoyant providing for a selective separation from non-carbonate containing masses. Different surfactants were tested to stabilise the bubbles and float the particles. In this paper, separation of dolomite from apatite using PVA (polyvinyl alcohol) as a coating agent, is discussed. Interestingly, up to 10 mm particle sizes can be floated. Moreover, flotation of a phosphate and dolomite mixture was carried out and MgO content

Jan 1, 2005

The Warraua and Mount Poole Inliers form part of a discontinuous series of basement complexes in the northwestern corner of New South Wales. The Inliers comprise mainly clastic sediments of low metamorphic grade (Wonominta Beds) and minor sills, dykes and intrusives, particularly within the Mount Poole lnJier. The Warratta rnlier has received attention due to the occurrence of auriferous quartz-veins where reef mining activities havetaken place.The deformational history of the Warratta and Mount Poole Inljers is characterised by a continuous subhorizontally WSW-ENE directed compression. Deformation was associated with the development of NNW-trending and steeply west-dipping major faults, which bound or biscct the inliers. Chevron folds and a penetrative axial planar cleavage characterise the deformational architecture and document crustal shorterung of at least 40 per cent. In zones adjacent to the major faults and within pelitic and semi-pelitic uruts, a multiple deformational evolution becomes apparent, comprising two events (D1 and D2). Deformational structures considered significant in this study were the result of D1. Tight, northeast-vergent fold patterns FI' and associated axjal plane cleavage SI' and reverse dip-slip movements at major faults indicate early northeast-directed thrusting during D1. This was followed by dextral strike-slip deformation displayed by tight, recumbent folds, en-echelon fold patterns (F2'), a northeast trending crenulation cleavage (52'), and two sets of second order faults, the latter showing high angular relationship to the major faults. A final stage of the deformational history (D2) is represented by WSW-ENE trending kink folds (F2).Auriferous quartz veins, predominantly occurring within pelitic and semi-pelitic units, were generated syntectorucally during the early deformational event (D1) in the course of commencing development of cleavage (S2'). Vein textures point towards vein formation by repeated hydrauJjc fracturing and fracture healing (crack-seal process), and by simple accretionary vein growth. Folded pelite-dominated horizons, considered as low permeability units, are suggested preferential sites where migrating metamorphic Ouids pooled and were trapped, causing high fluid pressure.Hydraulic fracturing and vein precipitation was controlled by lithology and structural constraints such as cleavage.K-Ar dates of approximately 440 Ma (Benambran Orogeny) marking the peak of metamorphism, and coinciding with the development of cleavage S1', also indicate the time of auriferous quartz-vein formation. A period of deformation of at least 30 Ma is proposed for the development of cleavage S1', as constrained by K-Ar dating and the intrusion of a syntectonic granitoid, the Tibooburra Granodiorite.

Jan 1, 1992

By N DavT

Pyritic tailings from the Quirke mine waste management area in Elliot Lake, Ontario were subjected to long-term column leaching experiments in two PVC columns measuring 122 cm in height and 15.2 cm in diameter. At the end of the leaching experiments, the columns were taken apart and sampled at 5 cm intervals for quantitative mineralogical and geochemical characterisation. Each column is represented by a total of ten samples. Polished sections, prepared from the samples, were studied by optical microscopy, scanning electron microscopy, electron microprobe and X-ray diffraction techniques. Mineral quantities were determined based on linear mixing models of whole rock and mineral compositions. Pyrite particle sizes were measured by image analysis interfaced to an electron microprobe. The tailings are coarse-grained (ie 96 per cent passing 75 ¦m) and composed of quartz, K-feldspar, muscovite and pyrite. Pyrite is homogenous and occurs as liberated particles displaying angular to subangular boundaries with strong dissolution features at the end of the leaching experiments. Based on up to 3518 particles measured in a sample, pyrite particle sizes range from 1.7 to 78.6 ¦m. Pyrite concentrations vary from 0.1 to 7.8 wt per cent, depending upon their location from the top of the columns. These correspond to pyrite losses of up to 99 per cent from their original level of 7.2 wt per cent in the upper half of the columns. Pyrite oxidation rates in terms of moles of pyrite oxidised per mole of pyrite per square metre per second were calculated from the effluent data and the measured pyrite particle sizes. The rates vary from 1.71+10-12 to 5.78+10-10 mole+m-2+s-1 within the 1.5 to 3.5 pH range for 10 ¦m particles. These results are comparable with the published oxidation rates at pH 2 where the dissolved oxygen is the only oxidant.

Jan 1, 2003

By C A Heinrich, Morse M. P, Cruickshank B. I, Pyke J. G, Whitaker A

Very little public domain information is available on the exploration signature of the Coronation Hill Au+Pd+Pt deposit. From 1987 to 1990 the BMR (now AGSO) carried out geological, geophysical and geochemical (whole-rock, stream, soil and rock chip) surveys within the South Alligator and Kakadu Conservation Zones and defined several key parameters useful for exploration programs. The essential geological ingredients for the style of Coronation Hill Au+Pd+Pt¦U deposit are oxidised, low pH fluids, dilatant fault structures, a thick neutral to oxidised cover sequence and chemical traps in the basement. In geophysical data, the areas surrounding the mineralisation can be detected by airborne magnetics as major lows in magnetite-rich rocks, whereas in airborne gamma-ray spectrometry data, imaged spectrometric channel ratios such as U2/I'h and U2/K highlighted alteration surrounding the deposits. Three types of stream-sediment and soil samples were taken from each site: (1) -1 mm mesh, 5 kg sample for bulk cyanide leach (BCL) analysis for Au, Pd, and Pt; (2) 1 kg sample of -1 mm mesh sediment for fire assay/ICPMS analysis for Au, Pt and Pd; and (3) 50 g - 180¦ mesh sample for a variety of trace element analyses, including Au, Pd and Pt. Techniques 2 and 3 gave similar results for Au, Pt and Pd, while the recovery rates for Pd and Pt from the BCL samples were considerably lower. Other trace elements did not define unique indicators for Pt or Pd mineralisation, as each sample reflected the dominant lithology in the drainage basin. Rock chip surveys were useful in determining which faults were associated with the ore fluid in regions of multiple fracturing. Results from these exploration-style surveys also confirmed that the Coronation Hill deposit is a variant of the unconformity-style of mineralisation, as all significant geochemical and/or geophysical results occur at or below the unconformity.

Jan 1, 1994

By R Smart

This paper examines the longer-term predictive capacity of the GAMSPATH computer program (developed by the Alberta Research Council) for a waste rock (sample MS) obtained from the Kaltim Prima Coal (KPC) mine, Kalimantan that contained significant framboidal pyrite. The model was refined by comparison with the net acid generation (NAG) and column leach tests to provide a basis for calibration of the model for both short term and longer-term reaction trends. The oxidation of pyrite during the kinetic NAG test using H2O2 provides oxygen directly at the mineral surface, generating a measured oxidation rate for pyrite of 1.16 + 10-6 mol m-2 s-1, whereas the oxygen diffusion limited rate in the leach column air equilibrated reaction was of the order 10-8 mol m-2 s-1 as calculated from the GAMSPATH thermodynamic database. Results indicated that the oxygen derived from hydrogen peroxide had to be included as a reactant (eg a reacting mineral) in the simulation to account for the direct availability of oxygen at the sulfide mineral surfaces. Optical investigations identified the proportion, particle size, and surface area, of framboidal and euhedral pyrite in sample MS. The reactive surface areas of the two morphologies were very different (eg ratio: 5:1). To manage these two different pyrite morphologies the GAMSPATH thermodynamic database was updated to include framboidal pyrite, with similar thermodynamic properties and oxidation rate to euhedral pyrite but with a particle size based on the size of the individual internal framboid microcrysts. This modification, with framboidal pyrite reaction based on the size of its microcrysts produced results that correlated well with the kinetic NAG and column leach test results when the measured (kinetic NAG test rate) and calculated (column test rate) pyrite oxidation rates were employed. This provided some confidence that the model could be extrapolated to indicate longer-term geochemical reaction trends.

Jan 1, 2003

By M Kuruppu

The paper explores the sustainability of the Australian mining industry, and the potential for application of a substitute fuel into existing mining operations. This alternative fuel biodiesel is produced from biological oils and not from refined hydrocarbons like the transport fuel diesel (petrodiesel). The fuel is compatible with all current diesel equipment with little to no modification and has many superior properties. As biodiesel is derived from biological sources it is æcarbon neutralÆ meaning there is no net carbon addition to the atmosphere when the fuel is burned. The current fuel, petrodiesel releases long stored carbon dioxide (CO2) and is of concern to Australian government targets which seek to reduce these emissions. The mining industryÆs unique reliance on petrodiesel is of particular interest when assessing the substitution of biodiesel into underground and open cut operations. The underground benefits of biodiesel see a reduction in the noxious emissions of carbon monoxide and diesel particulate matter, both contaminants which require extensive diluting ventilation to ensure safe levels. As biodiesel is both safer to store due to its higher flash point and produces less exhaust emissions, its occupational health and safety benefits in underground mines is clear. The use of biodiesel in open cut mines benefits the environmental sustainability aspects of the project. The formulation of national targets relating to carbon dioxide emission reductions promotes any measure to reduce CO2 within the mining environment. As the diesel engine is one of the least emission efficient (kWh/tonne CO2) energy sources on-site, its potential for reduction in CO2 at minimal cost is the greatest. By substituting the fuel, significant quantities of site emissions are reduced, thereby achieving the goals of improved site sustainability and the governmentÆs targets to reduce emissions. This aspect of gauging mutually beneficial relationship regarding government interests and mining industry profitability is the underlying outcome for this paper.

Jan 1, 2009

By M Ben, P de Donato, M Kongolo

The extensive literature on sulfide flotation indicates that pyrite poorly floats under alkaline condition. Xanthate concentration has a positive effect on pyrite flotation, but above a pH of 11, pyrite seems to be strongly depressed, independently of the concentration in xanthate. In this investigation, aeration and xanthate concentration effects were studied for pyrite flotation conditioned at pH 11 with lime. Results presented in this paper include surface infrared analyses and pulp chemistry measurements which have showed that aeration had a dual effect on pyrite flotation. It induced pyrite surface activation by oxygen, and oxidation of ferrous iron to ferric hydroxides or oxyhydroxides species. It also favoured dissolution of CO2, leading to calcium carbonate precipitation and adsorption onto pyrite surface. Both CO2 dissolution and ferrous oxidation generated protons and decreased pulp pH. Pyrite flotation was observed to be effective with a statistical monolayer of xanthate that could be adsorbed as mixture of dixanthogen and metal-xanthate complex. Non-floated fractions showed high amounts of carbonate, and presence of hydroxyl iron sulfate (Fen(OH)m(SO4)p, xH2O) which have inhibited the hydrophobicity effect of adsorbed xanthate. Environmental desulfurisation could be improved by aeration control causing pyrite oxidation and pH decrease to reach optimal flotation condition with a relatively low xanthate concentration.

Jan 1, 2005

By R Fleming, G Jones

An ocean outfall is currently under construction in Christchurch, New Zealand to transfer treated wastewater from the existing treatment ponds at the city wastewater treatment plant to diffusers located 3 km offshore. The New Zealand $85 million project comprises a new pump station and 5 km of 1800 mm diameter pipeline with a design capacity of 6.0 cumecs. The pipeline comprises 2.3 km of concrete pipe installed by microtunnelling and 2.7 km of polyethene marine pipe installed by dredge and lay. This paper describes the consent process, key environmental and community constraints, the tender process, risk provisions included in the contract, the type of contract, partnering provisions, geotechnical design issues and the pipejacking construction activities and issues.

Jan 1, 2008

By E S. Souza, H Delboni Jr, M F. Calixto

This paper aims at presenting the results of laboratory, pilot plant and simulation studies for the design of the grinding circuit for the beneficiation of compact itabirites from the Conceitpo mine. Two alternatives were investigated, both utilising the current crushing circuit up to tertiary crushing. Under alternative #1, quaternary crushing was considered to produce the feed of the ball mill; under alternative #2, high pressure grinding rolls were selected to prepare the ball mill circuit feed. Pilot scale studies pointed towards the use of high pressure grinding rolls (HPGR). The circuit design was based on a throughput of 720 t/h, representing a nominal solids flow rate of 600 t/h, considering a design factor of 1.2, and P80 of 95 ¦m.

Jan 1, 2007

The laboratory-scale reduction of fixed beds of iron ore pellets has been investigated over a range of experimental conditions. The effects of reduction temperatures, gas compos- itions and flowrates on 1) the rate of reduction and 2) the physical properties of the metallized products after reduction are being studied as part of a general programme aimed at the evaluation of the use of gaseous reductants for the direct reduction of Australian iron ores. This paper deals primar- ily with the effects of temperature on the rate of reduction using a H2/CO gas mixture. The physical properties of the metallized products such as strength after reduction, abrasion resistance and porosity are presented as functions of the reducing temperature.

Jan 1, 1974

By Ciminelli VST

Thiourea leaching has been applied to a refractory gold concentrate previously treated by bacterial oxidation. Following the bio-oxidation, gold has been leached in acidic thiourea solutions, under different pH(1 - 2.4), thiourea concentrations (2 - 15 g/1), ferric ion concentrations (0.04 - 3 g/1) and temperatures (298 - 333 K). Through this procedure, it was possible to increase gold extraction from 40 to 77 per cent. The increase in temperature raised gold extraction and reduced reagent consumption. Sodium sulphite addition was also very effective in lowering thiourea consumption. Staged leaching operations with interstage acid washing and carbon-in-leach experiments were tested, in an attempt to increase gold extraction. The results of thiourea leaching were compared with those obtained with cyanidation.

Jan 1, 1993

By Wenya X, Bingchen C

About 60 per cent of magnesite ores of Haicheng Magnesium Mine, due to their low grade, are not currently commercially exploitable. In this paper, the flotabilities of the main component minerals of the ores were studied in detail with ether amine as collector. Based on. these, a new technique of reverse-direct flotation with single etheramine as collector for the beneficiation of the ores was developed. It gave highly satisfactory results. On the basis of the calculation by means of CNDO/2 method, of the studies of the solution chemistry of magnesite and of the adsorption tests and Zeta-potential measurements, the key mechanism in the new technique about activating effect of Ca2+ on the flotation of magnesite was suggested.

Jan 1, 1993

By Kaji S

The Tsugaru Tunnel, located on the Honshu island approach to the Seikan Tunnel, is 5,880 m long and has a "Shinkansen" cross section of 90 m2 area. The geological formation through which the tunnel passes consists of very soft rock most of which is unsolidified sandstone belonging to the Neogen. The permeability coefficient is in the range of 10-2 to 10-4 cm/s and being water bearing with a high ground water level, the ground is unstable and subject to soil outflow phenomenon. Kajima Corporation, undertaking the Futamata Construction Section (1,420 m long), excavated the tunnel by the upper half heading method with side pilots employing the following countermeasures to cope with these severe conditions.

Jan 1, 1987

Mount Isa mine is the largest underground mine in Australia and is located 2,000 kilometres north-west of Brisbane. This mine has been in continuous operation since 1931 and in 1986/87 the silver/lead/zinc stream achieved the peak annual mining rate of 4.7 million tonnes. At present about fifteen different steeply dipping stratiform orebodies are being mined to maintain an annual production rate of around 3.0 million tonnes. Out of these, only two orebodies (2 & 5) are amenable to sub level open stoping (SLOS) type bulk mining methods. This year only 150,000 tonnes are scheduled from pillars and remnant areas but in future, more sources will be required to meet the budget production targets.

Jan 1, 1990

By M Chappell

This paper describes the design of the steel fibre reinforced precast concrete (SFRC) segmental lining for the intake and discharge tunnels for the Gold Coast desalination plant in Queensland. In addition, the key design requirements and design methods for the lining of these 2 km long, 2.8 m internal diameter tunnels, including structural, durability and maintenance requirements are discussed. Details of the segment configuration and erection process are presented along with information on the manufacture and trial testing of the concrete for the segments. The paper also gives a brief introduction to steel fibre reinforced concrete behaviour. Construction of the tunnels commenced in April 2007, and the authors believe this is the first application of this technology in Australia.

Jan 1, 2008

The Escondida Porphyry Copper Deposit, located in Chile's II Region 160 Km to the southeast of the city of Antofagasta, is currently owned by Minera Escondida Limitada, a company comprising The Broken Hill Proprietary (57.5%), Rio Tinto Zinc (30%) a group of Japanese companies represented by Mitsubishi Corporation (10%), and the International Financing Corporation of the World Bank (2.5%) (Fig.l)By 1983, most of the reconnaissance drilling was completed and prefeasibility studies were regularly updated as new drilling results were reported and project concepts re-evaluated (Fig.2). In October 1982 the project was transferred from Exploration Management to Operations. By the end of 1984 project pre-development activities, including inpit development drilling, geological exploration, water resource definition, an underground bulk sampling program and the initial project feasibility report, were completed.

Jan 1, 1990

By Johnstone RD, Rattenbury MS

RACE Quartz-calcite veins containing Au, As, W, Cu, Pb, Zn and Fe cross-cut Alpine Fault- related structures in the Alpine Schist of South Island, New Zealand. These veins, and some other related veins have been deposited by metamorphic fluids at 250¦C to >320¦C at pressures of a few hundred bars. The fluids were very variable in composition, with 0 to 50 mole % CO2 and 2 to 18 wt. % NaCl equivalent. Penetration of hot metamorphic fluids to shallow levels in the crust was facilitated by rapid uplift of hot rocks at a compressive plate margin. Fluid immiscibility at shallow levels caused concentration of salts and metals into the aqueous phase. Gold precipitation was caused by reduction by pelitic country rock and/nr dluILion by other aqueous fluids.

Jan 1, 1987

Pan Australian Mining lid installed a milling and gold leaching plant designed to process 2 million tonnes per annum of breccia sulphide ore. This plant was commissioned in January 1989. Since commissioning, increased ore reserves have been established and the plant has been expanded by the addition of one ball mill and several tanks to increase the design capacity to 3 million tonnes per annum. This additional plant was commissioned in May 1990, bringing the total number of mills up to three, each 4.5 m diameter x 7 m long. The paper details how milling rates have been increased at the expense of grind size to increase the capacity of the original plant from 2 million to 3.1 million tonne per year rate before the additional ball mill was Commissioned.

Jan 1, 1991

By J Finlay, P Betts, D Milton, H Williams

The aim of this paper is to present an innovative method to help delineate potential target volumes for haematite-goethite mineralisation as opposed to more magnetic ores. This is achieved through interpretation and modelling (2.5D and 3D inversions) of ground magnetics and gravity surveys over the Koolanooka South prospect in Western Australia. The targets are assumed to be dense and weakly magnetic and hosted within banded iron formation (BIF) horizons. Geophysical interpretation (2D map) was performed using a variety of processed magnetic and gravity images (Betts et al, 2007) to determine the distribution of lithologies, to understand the structural architecture and to map out any anomalous areas of excess density (possibly indicating goethite alteration). The created geological map is used to build geological cross-sections (geometrically consistent) that were modelled (in 2.5 D) against both potential field datasets. The crosssections are consequently used as the framework to build a 3D geological model. The model defines 3D volumes of rocks including several BIF horizons. The distribution of densities and magnetic susceptibilities of the BIFs is inverted within the GOCAD«-VPmg environment to reduce the misfit between the response of the model and the observed gravity and magnetics. By combining the results of both petrophysical property distribution it is possible to map out (using classical GIS type queries in 3D) volumes of higher density and lower magnetic susceptibility.

Jan 1, 2009

By B Oostendorp, R van der Merwe, P

In order to assess whether polysaccharide depressants are strongly or weakly and reversibly bound to the surface of talc, a series of experiments was conducted on New York talc in which the floatability of the talc in a microflotation cell was determined. The talc was conditioned in solutions of carboxymethyl cellulose (CMC) or guar gum in 10-2 ionic strength Ca(NO3)2 or Mg(NO3)2. The talc was then washed with four successive aliquots of water, or cation solution, to try to remove the polymer and the flotation response of the talc was assessed. CMCs of different charge (DS) were used to assess the effect of charge on the strength of bonding. The results show that CMC and guar gum could be removed to a large extent from the talc surface by washing with water (the floatability was restored), however very little could be removed from the surface by washing with cation solution. The higher charge CMC was easier to remove from the talc planes in the absence of cations than the lower charge CMC. Thus CMC bonding to talc has been shown to be irreversible or very slowly reversible only if cations are present, implying that cations are necessary to keep the polymer bound to the surface of the planes to effect depression. The presence of ions in solution also had the effect of maintaining surface coverage of the talc by guar gum.

Jan 1, 2005