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By Y Akiti, J Moller, E Esper, R Rugolo, A Pains

"Morro do Ouro Mine is a high tonnage/low-grade mine located in Paracatu, Minas Gerais State, Brazil. The mines move around 55 Mt of ore per year at an average grade of 0.4 g/t. The auriferous mineralisation of Morro do Ouro is related to hydrothermal fluids rich in arsenic (As), gold (Au), lead (Pb) and zinc (Zn). These percolated along favourable structures contained within phyllites of Upper Proterozoic age and defined a mineralised megaboudin which outcropped with 4 km extension and up to 2 km in width. The litologies in the interior of this structure are typically more deformed, sericitised and sulfidised, and exhibit the development of quartz boudins in the centre of the more deformed zones where are found the higher Au grades and the coarser sulfide crystals. Gold is preferentially associated with arsenopyrite, mainly occurring in fractures or aggregations of crystals and is rarely in solid solution or refractory. Over 90 per cent of the gold contained in the sulfide ore is free or extractable by cyanidisation. The current mineral reserve is 17.9 Mt at 0.403 g/t published at the end of 2012.In order to get a good grade estimation that represents the orebody more accurately a solids methodology was used to distinguish the different orebodies. Before 2011 the orebodies were worked with two domains relating to the weathered mantle. The B1 ore, which is oxidised, is located at the top of mineralisation, and is used to feed Plant 1. Underneath B2 ore, which is fresh sulfide bearing, represents over 30 years of production in Plant 2.In order to improve the predictability of gold grade estimation in geological modelling and to get a better predicting behaviour of each domain on the deposit, studies were carried out in which it was possible to show a correlation between elements and the mineralisation. One strong correlation and spatial distribution between Au and As, As and sulfur (S), Au and Pb, Au and Zn were found.Based on geochemistry, mineral correlations, amount of sulfide, structural deformation, texture of sulfides and the daily experience of the mine, it was possible to create solids that individualised bodies with similar mineralogical and chemical characteristics using the parameters listed above.After 2011, a new modelling concept was proposed and built with 11 different domains, compared with the previous, and with two more parameters: recovery acid neutralised capacity (ANC).Each of these bodies have different behaviours in mineral processing, like flotation and metallurgy. For example, bodies with pyrrhotite bring problems in the flotation, bodies with high arsenic do not recover well, bodies with high As with coarse texture have good recovery, bodies with fine texture do not have good adherence in production.In the present state of knowledge, protocols are being developed for bench testing to predict the recovery of each geochemical domain aiming to include these in the geological model for the parameter recovery. It is intended to create a field throughput in the model of ounces per hour, from each block of each domain to better predict the production, using the parameter recovery, Au and Bond Work Index (BWI).CITATION:Esper, E, Rugolo, R, Moller, J, Akiti, Y and Pains, A, 2013. Morro do Ouro geological model with a metallurgical view, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013, pp 67-74 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 29, 2013

By A N. Terblanche, D S. Smit

The paper discusses the improvements achieved after an external sparger flotation column, 1.42 m diameter by 9.5 m high, was installed as a re-recleaner unit at the Northam Platinum LtdÆs UG 2 plant in South Africa. The paper also evaluates the pilot plant data prior to the industrial size column installation as well as the accuracy of scale up from pilot to full-scale operation. Since the installation of the PrepQuip flotation column, the final concentrate upgrade ratio improved from 83 to 105, the 3PGM+Auå recovery improved from 79.7 per cent to 81 per cent and the Cr2O3 content in the final concentrate decreased from five per cent to 2.8 per cent. The upgrade ratio can be improved to 125 with an overall 3PGM+Au recovery of 80 per cent. Conventional mechanically agitated flotation cells achieved only 74 per cent recovery at an upgrade ratio of 125.

Jan 1, 2005

Since gold was first discovered, mining development in the West Australian goldfields has been heavily dependent on the location of groundwater both for potable and mineral processing supplies . The location of adequate and economic sources of water has been a constant challenge to both explorers and developers throughout the history of the goldfields. The provision of a piped supply from Mundaring in 1903 greatly alleviated pressure on scarce resources, lowered mining costs and permitted the orderly development of infrastructure. However, increases in the demand for water resulting from new mineral discoveries over the past three decades has led to renewed pressures for more local supplies to be established. Wide-ranging groundwater exploration took place in the late 1960's and early 1970's, also, more recently, in support of intensified gold exploration. The collation and interpretation of the hydrogeological data from the whole goldfields region indicates that despite a low mean annual rainfall of between 180 and 350 mm, quite marked differences exist between the rates of groundwater recharge in different parts of the area, In general, these can be shown to diminish in a southerly direction contrary to a trend towards increases in annual rainfall. Recharge rates are related mainly to differences in rock weathering pattern, geological structure and physiography. The same differences have controlled the pattern of groundwater salinity and the magnitude of groundwater storages associated with the palaeodrainages. In the vicinity of the northern and western watersheds with the Gascoyne, the superficial sediments tend to be thin, may have calcrete in the section and contain moderate storages of brackish or even fresh water. This contrasts with the lower regions of the palaeodrainages where calcrete is absent and deeper erosion has permitted the accumulation of relatively large thicknesses of fine-grained sediments which are saturated with hypersaline water and constitute substantial storages. Account must be taken of these characteristics if water supply sources are to be optimised to meet the growing demands for groundwater in the region.

Jan 1, 1988

By B P. Wrench, M J. Gowan, P J. Chapman

Embankment dams constructed mainly of sand or non-plastic fine soils are susceptible to liquefaction, particularly in high-rainfall, high-seismicity environments where there is sufficient water to saturate the materials and sufficient energy from an earthquake to cause liquefaction. This paper shows the process adopted to review the stability of an existing cross-valley, centreline-raised cyclone tailings sand embankment dam.The study showed that two-dimensional stability analyses did not sufficiently capture the potential for instability, overestimating the depth of the critical failure surface. Instead, three-dimensional modelling was required to provide a reasonable representation. Post-liquefaction stability analyses carried out using the three-dimensional model indicated an adequate factor of safety (FoS). The FoS under seismic conditions was still considered to be a concern based on pseudostatic analyses (but noting the limitations of the analysis method).Earthquake-induced settlements were estimated using an empirical approach based on case history records (Swaisgood, 2003). The post-earthquake event settlement was estimated to be in the order of 600 mm, which is considered to be acceptable for the embankment, taking account of the proposed long-term freeboard of more than 8 m under operating conditions and 2 m under the probable maximum flood condition.CITATION:Chapman, P J, Wrench, B P and Gowan, M J, 2015. Review of static and seismic stability of a cross-valley sand tailings embankment in a high-rainfall, high-seismicity setting, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 163–172 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

Gwalia Consolidated Ltd has been in the mining industry for about 15 years, yet its key wholly owned Greenbushes Mine has a history dating back to the last century. Similarly Gwalia Consolidated's associate, Sons of Gwalia Ltd owns the historic Sons of Gwalia and Marvel Loch Mines with Sons of Gwalia celebrating its centenary this year. This durability is a testament to the quality of the orebodies concerned and the massive technological achievements over this time which have enabled each of these mines to maintain their competitiveness. While Sons of Gwalia and Marvel Loch were and continue to be gold mines, the wholly owned Greenbushes Mine has survived and in fact prospered through the development of alternative products from its rich and unique pegmatite. Similarly, for Gwalia Consolidated to grow and prosper it will be necessary to expand the current portfolio of products and operations. The Greenbushes Mine has already given Gwalia world `No 1' status in both the supply of primary tantalite concentrates and lithium minerals (spodumene). The asset base contributed by Gwalia's gold investments assisted in the recapitalisation of the Greenbushes assets to fully develop their potential. Industrial minerals and strategic metals were of interest to Gwalia as these markets are relatively small and it is possible to develop an influential if not dominant position in the market with a quality asset. Capital expenditure to develop such projects are also usually in the order of $10 m to $20 m, a manageable range relative to Gwalia's size.

Jan 1, 1996

By J Heyes, G A. Maddocks, R J. Stewart, G D. Corder

Mining is an international business and vital contributor to national and global economies. It depends on the trust and confidence of investors and stakeholders for its financial and operational well-being (Committee for Mineral Reserves International Reporting Standards (CRIRSCO), 2016). The Social Licence to Operate (SLTO) is an increasingly multifaceted and multistakeholder risk that can impact investment decisions. Community challenges to broader political and economic decisions have given rise to protest delaying or stopping projects or closing mines and has led to loss of life (Ernst and Young, 2016). Some governments are now giving greater powers to stakeholders to make the final decision on approving mining and metals activities (EY, 2016). With billions of dollars in project investment at stake, ongoing engagement, collaboration and effective communication with stakeholders is crucial and mutually beneficial solutions are increasingly expected (EY, 2016). It is therefore essential that the industry communicates the risks (and opportunities) associated with investment effectively and transparently in order to earn the necessary level of trust with investors and stakeholders to underpin its activities (CRIRSCO, 2016). Despite this need, investor and stakeholder trust in the sector has eroded in recent years.CITATION:Maddocks, G A, Corder, G D, Heyes, J and Stewart, R J, 2016. The social licence to operate and drivers for change – resource reporting and mine material characterisation, in Proceedings Life-of-Mine 2016 Conference, pp 183–187 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 28, 2016

By I Zulkarnain, H Permana, R A. Binns

Through an ambitious but relatively low-cost program of marine fieldwork, laboratory investigations and technology-transfer and training activities, three Indonesia-Australia-led marine expeditions were undertaken aboard KR Baruna Jaya VIII between 2001 and 2003. These IASSHA (Indonesia-Australia Survey for Submarine Hydrothermal Activity) cruises have sought to discover and investigate a variety of potential ore forming hydrothermal systems in a range of tectonic settings. All cruises have been successful, both scientifically and from the point of view of training, creation of capabilities and capacity building for such research in Indonesia. Over 60 scientists and technicians from Indonesian and Australian institutions and agencies have been involved. Three new sites and a possible fourth site of hydrothermal activity were discovered in the Sangihe arc in northern Sulawesi. Surveys in the Tomini basin tested a hypothesis based on previous data which suggested this might be an isolated anoxic, brine-filled basin over 2000 m deep where igneous heat sources existed to generate hydrothermal mineralisation. The bay, however, was found to be open to adjacent deep ocean circulation, and there was no evidence of massive base metal sulfides. Subdued evidence of hydrothermal activity was found in the Sunda Strait associated with the famous Krakatau volcano and the extension of the seismically active Semangko Fault. The BANDAMIN program (Indonesia-Germany) covered a portion of the Banda arc in eastern Indonesia, and also found evidence of recent hydrothermal activity and epithermal sulfide mineralisation.

Jan 1, 2004

A series of petrological studies were carried out on the characteristics of alteration and mineralisation in mainly structural-controlled (Deep Star, Meikle, Deep Post) and predominantly lithological-controlled (Post-Betze-Screamer and West Leeville) gold deposits in the northern district of the Carlin trend, Nevada. Alteration and mineralisation in these deposits are hosted in a sequence of calcareous clastic units of the Devonian Popovich Formation, into which have been emplaced a number of Jurassic intrusions, and syn- to post-mineral Eocene dikes. Four hydrothermal events have been recognised in these deposits: an initial Devonian base metal system and early diagenesis; a Mississippian stage of alteration in conjunction with burial metamorphism; contact and hydrothermal alteration and base metal-gold mineralisation associated with the emplacement of the Jurassic intrusions; and a Carlin-style gold system related to Eocene magmatism.

Jan 1, 2004

By I Jabouri

There are many physical factors that can affect the self-heating rate of coal. The presence of seam gas has often been referred to as inhibiting coal self-heating due to the limited access of oxidation sites created by the presence of the gas adsorbed on the coal pores. Similarly, the presence of bed moisture in the coal also acts as an inhibitor of oxidation by blocking access of air into the pores. Gas drainage of a coal seam prior to mining removes both gas and moisture from the seam. Bulk coal self-heating tests in a two-metre column on both gassy, as-mined and gas-drained, dried high volatile bituminous coal show that removal of gas and moisture from the coal accelerates the rate of self-heating to thermal runaway from 8.5 days to 4.25 days, from a start temperature of 30¦C, with an airflow of 0.25 L/min. The corresponding gas evolution pattern for each of these situations is different. Therefore, it is necessary to take this change in coal condition into consideration when developing a spontaneous combustion management plan.

Jan 1, 2005

By W Potma, C Brauhart, S Halley, S Urbisinov, A Scogings

Truly integrated, quantitative, 3D GEOmetallurgical (or mineral system) characterisation, classification and 3D modelling should provide a cradle to grave unifying link across the exploration and mining value chain. All too often, spatially representative (quantitative) characterisation and modelling of a mineral system is delayed until feasibility stage, incurring a significant opportunity cost. The application of robust GEOmet characterisation methods early in the project lifecycle (at exploration stage) improves ground selection, exploration, and Mineral Resource estimation outcomes, long before there is a need for metallurgical test work. The value of this early provision of quantitative 3D mineralogy models is compounded at project feasibility stage, and continues to accrue over the entire project lifecycle, delivering cost savings, improved decision making and early warning of issues and opportunities.CITATION: Potma, W, Halley, S, Scogings, A, Urbisinov, S and Brauhart, C, 2018. Putting the ‘GEO’ back in front of GEOmetallurgy: importance of early implementation of quantitative mineral system characterisation, classification and modelling, in Proceedings Complex Orebodies Conference 2018, pp 55–57 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

Alfred Nobel first invented a practical detonator in 1863 and then the blasting cap in 1865. At that time the detonator was used on the end of a length of safety fuse to initiate nitroglycerine-based explosives. Since then the detonator has gone through a number of changes. The instantaneous electric detonator was the first to allow remote firing. The electric delay detonator followed and allowed for timing between holes. In the mid 1970s the NONEL« Tube was invented. This tube combined with NONEL« detonators meant that many of the safety issues, such as stray current and radio frequency, associated with electric delay detonators were eliminated. This system gave the mining industry a reliable and fairly accurate system with which to detonate shots of any size. Since the early 1980s a large amount of research and development work has been done around the world to create a more accurate detonator for the mining and quarrying industry. After years of research, electronic detonators have emerged as the most accurate and precise initiation system available to the mining and quarry industry today. Electronics provide the user with millisecond timing accuracy. The improved level of timing control allows operations to improve fragmentation, throw and reduce vibration levels. There are now a number of different electronic detonator suppliers on the market today. In 2004 Dyno Nobel formed a joint venture called DetNet with AECI. DetNet has a suite of electronic detonators: DigiDet«, HotShot« and QuickShot«. This paper will focus on the HotShot« system, the first of the three new initiation systems to be released to the market in Australia by Dyno Nobel.

Jan 1, 2005

Declines for both access and rock haulage are replacing shafts for mining relatively shallow deposits of down to 1000 m below surface. Where the orebody does not outcrop and where surface access may be restricted, it is often necessary to drive long dead end headings before a connection can be made back to surface and a ventilation circuit created. In hot tropical areas and where large diesel powered equipment is used for mining, heat may also be a problem at these relatively shallow depths. The normal design criteria based on statutory limits and good practice used to evaluate ventilation and cooling requirements in terms of air velocity, dust, gases, diesel exhaust dilution, re-entry after blasting and heat stress are described in this paper. These are then used to design and cost alternative auxiliary ventilation systems that include leakage based on general fan performance curves and typical duct systems. The implications of the current European Community recommendations regarding nitrous fumes are also briefly considered. The actual problem relates to a 2100 m long decline that may have to be extended to 3000 m long without a connection to surface or through ventilation and is located in a hot tropical area where the surface wet bulb temperatures may exceed 25¦C for more than a third of the summer period. Once the preliminary ventilation design is completed, the auxiliary ventilation system can be modelled and simulations undertaken that incorporate heat and moisture transfer routines with the objective of determining the cooling load and amount of refrigeration required. Cognisance is taken of cyclic diesel operations and the thermal flywheel effect of the surrounding rock on the wet and dry bulb temperatures resulting from these operations.A suitable modular cooling system located at the portal is described and optimised with capital and operating costs of both the ventilation and cooling systems provided.

Jan 1, 2005

By P A. Montoya

La Colosa is a world-class porphyry Au project located in Colombia, currently undergoing prefeasibility analysis. As part of collaboration between AngloGold Ashanti and the AMIRA P843A GeMIII Project, the application of emerging geometallurgical characterisation testing and modelling tools has been incorporated in early stages of project development. The aim of the geometallurgical study is to map inherent comminution variability across the La Colosa deposit providing information critical for mine/mill design and optimisation. In this study, site-based data incorporating multi-element assays, quantitative analyse X-ray difraction QXRD bulk mineralogy measurements, EQUOtip rebound hardness data, and routine geological logging information from 59 diamond drill holes has been integrated with a range of geometallurgically specific comminution test (ie GeMCi, A × b, BMWi). The work in this paper demonstrates the integration techniques used at La Colosa to link routine data acquisition methods with comminution test results through the development of proxy support models. The integration incorporates a range of statistical techniques including principal component analysis and regression modelling. By creating proxy models, comminution index estimates can be propagated into the geological database enabling comminution processing domains to be defined. These domains provide the first spatial representation of comminution performance and variability at La Colosa and can be compared against traditional geological domains. This study provides the foundation for ongoing comminution characterisation as the La Colosa project evolves through project cycles into an operational mine.

Sep 5, 2011

By D Xiong, G Xu, L Yao, F Wang, Y Duan

The goal of this project has been to digitise and use drill parameter data from rotary drilling (measurement while drilling; MWD) for a more effective planning of the blasting process in surface mines. A more accurate and reliable digital drilling and automatic hardness identification technology was developed, which includes both a hardware and software system. In the aspect of hardware, we designed a positioning, navigation and hardness perception terminal system which consists of a global positioning system original equipment manufacturer board, programmable logic controller and sensors of measuring major parameters, and a wireless data transmission system which combines digital blasting platform and wireless transmission facilities. In the aspect of software, we developed the navigation software of locating blastholes using LabVIEW and C++, and the blasthole design software using AutoCAD ActiveX (C#) technologies. This new technology is applied at Jiangxi Dexing Copper Mine, and initially realising the digitisation of drilling and hardness identification in blasting zone.CITATION:Duan, Y, Xiong, D, Yao, L, Wang, F and Xu, G, 2015. Advanced technology for setting out of blastholes and measurement while drilling, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 593–598 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By S Casas Castellanos

"Tyres consumption is one of the costliest branches of the operation in a truck-based haulage mine. Off-the-road (OTR) tyres working within undesirable conditions have a considerable negative impact on the whole mine’s productivity. Only the rolling resistance due to underinflated tyres could increase truck fuel consumption by 15 per cent. The impact of other conditions such as road surface quality and temperature are difficult to estimate. Tyre management is a demanding activity that requires a high level of coordination between maintenance and production departments.The project is aimed to develop a smart decision tool to assist mine managers to optimise tyre resources. By identifying factors that have significant impact on tyres, managers are able to take timely action to mitigate undesirable working conditions.The proposed model utilises real-time tyre measurement of pressure, temperature, speed, load, deformation and surface profile to report tyre performance in terms of tonne-kilometre-per-hour (TKPH) and tyre longevity. Both indicators are permanently monitored in order to trigger a warning system designed to keep tyres under optimal working conditions.An interactive database ‘Octo-Mine’ wirelessly receives records from a programmable logic controller (PLC) deployed on the truck. PLC records are the integration of multiple sensor signals with a time stamp. Octo-Mine utilises real-time and historical tyre records to generate online performance and longevity reports, as well as preventative and corrective tyre maintenance scheduling, by comparing current tyre status with established standards.To validate the model, the prototype database was populated with hypothetical data to simulate ideal working conditions subject to comparison with real field observations. Additionally, a laser-based technology prototype device successfully measured a new 9 mm tyre tread and a 60 000 km rolled tyre tread in the laboratory.In conclusion, optimal tyre management contributes not only to reduction of tyre waste but also to truck energy efficiency. This project is a first step in proving these benefits under real field conditions. It suggests that further development of sensor equipment and its integration with a communication system is a worthwhile focus for future research.Citation:Casas Castellanos, S, 2016. Optimum Management of Truck Tyres in a Mine, in Proceedings Ninth AusIMM Open Pit Operators' Conference 2016, pp 212–228 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 15, 2016

By Canterford J. H, Sparrow G. J, Dyson N. F

Pressure leaching of a bulk flotation concentrate prepared from a complex Cu-Pb-Zn sulphide ore was carried out at 150 and 190¦C under 1050 kPa oxygen overpressure in 1 L and 4 L titanium autoclaves to extract zinc, and to obtain residues for smelting tests and leach liquors for purification and recovery of the zinc by electrowinning. Dissolution of 95% of the zinc was achieved at both temperatures. Copper and iron dissolution and the degree of oxidation of the sulphide sulphur to elemental sulphur or sulphate depended on the temperature of the leach. At 190¦C, a jarosite (a basic iron sulphate) was the major iron-containing material in a residue that contained 17% total sulphur. Its formation was associated with dissolution of 18% of the iron. At 150¦C, oxidation of the sulphide sulphur and dissolution of the iron were significantly less. Only 7% of the iron was dissolved and a residue containing 25% total sulphur, present as a lead jarosite, lead sulphate, and elemental sulphur, was obtained. The formation of small pellets of unreacted sulphides coated with elemental sulphur caused problems during the leaching at 150¦C, and also during scale-up from the 1 L to the 4 L autoclave at 190¦C. At 150¦C the concentrate required two stages of leaching to achieve dissolution of over 90% of the zinc. These problems are discussed.

Jan 1, 1989

By M Berndt

Four siltite-argillite rock samples were characterised (particle size, chemistry, mineralogy) and subjected to laboratory dissolution testing for 36 to 298 weeks. In two samples sulfur (0.99, 1.69 wt per cent) occurred largely as pyrite, and in the other two samples sulfur (0.96, 1.93 wt per cent) occurred predominately as potassium jarosite. The observed rate of sulfate release from the pyritic samples was one to two orders of magnitude greater than that from samples containing potassium jarosite. Drainage pH values from the pyritic samples were one to two units lower and acidities were ten to 70 times higher than associated values from the potassium jarosite samples. Geochemical modelling supported the hypothesis that pH and concentrations of sulfate and potassium in drainage from the potassium jarosite samples were controlled by the limited solubility of potassium jarosite. This dissolution produced an iron-dominated mineral phase, but iron concentrations in the drainage were well below those predicted by ferrihydrite solubility.

Jan 1, 2003

By J Webb

The mining industry is relatively niche and complex compared to other global industries in its safety and operating environment. Whilst some of the technology required to decarbonise the mining industry will emerge from the mass market (eg batteries, energy storage solutions and renewable power generation) where exogeneous external investment and innovation will drive supply, bespoke applications such as material movement will be constrained by industry limitations. Underground load and haul equipment burns the majority portion of underground mine diesel, and typically 25 per cent of scope one and two emissions. Transitioning away from incumbent diesel engines offers a considerable health benefit to all mine workers, as well as decarbonisation achievements, and through trials there is emerging evidence of more productive equipment and realistic expectations of lower operating costs of fleet. However, new equipment and material movement systems that support these industry goals are currently approached with caution due to the pivotal role they play in delivering productivity goals, and the lack of experiential data and certainty to mitigate the supplier development risk during this technology transition period, where all resources are required to meet a booming industry. A group of mining companies and suppliers have the aligned aim to accelerate the understanding and availability of heavy haulage mobile equipment through collaboratively piloting equipment and working with suppliers and each other to aggregate market demand, encourage investment and resolve the mine design and technology choices through their involvement in the Electric Mine Consortium (EMC). This paper will outline the major challenges the industry must overcome in sourcing and adopting a zero-diesel particulate and zero-emission mine, drawn from cases and insights across ten EMC mining company members.

Mar 29, 2023

By A Gerson, S Miller, R Smart, J Thomas

Environmental Geochemistry International (EGi) and the Ian Wark Research Institute (IWRI) collaborated in a three-year Australian Minerals Industry Research Association (AMIRA) research project (Project Number P387A) focussed on the prediction and kinetic control of acid mine drainage. As part of this project, single addition, and sequential net acid generation (NAG) testing was carried out on sulfide mineral samples. The test samples comprised a range of synthetic waste materials prepared using a quartz bulk and controlled quantities of the commonly occurring sulfide minerals; pyrite (FeS2), pyrrhotite (Fe7S8), arsenopyrite (AsFeS), chalcopyrite (CuFeS2), chalcocite (Cu2S), covellite (CuS), bornite (Cu5FeS4), galena (PbS) and sphalerite (ZnS). NAG test results clearly show that there are significant differences between the acid forming potential of sulfide minerals. The NAG test results for each mineral were compared with theoretical acidity values (NAPP*). The NAPP* calculation was based on stoichiometric oxidation reactions assumed for each of the sulfide minerals. Sequential NAG values for pyrite corresponds closely to predicted NAPP* values, confirming the assumption that pyrite oxidation occurs according to the stoichiometry assumed. For the pyrite sample with 5 wt per cent S, two NAG stages were sufficient for all of the sulfur to be released to solution. Since sulfides in waste materials will generally be dominated by pyrite, results also confirm the validity of including NAG testing for ARD evaluation of most waste rock. NAG testing confirms that of the sulfide minerals examined, only pyrite, pyrrhotite, arsenopyrite and chalcopyrite are acid producing, ie able to produce leachate with a pH less than 4.5. In the case of sphalerite, galena, bornite, chalcocite and covellite the pH of the final NAG solution was greater than 4.5. The significant differences between the acid forming potential of different sulfide minerals could lead to overestimation of acid producing potentials based on NAPP values calculated from total per cent S alone, ie assuming all S is present as pyrite. The oxidation of galena during the NAG test resulted in the consumption of acid. The examination of the galena surface by X-ray photoelectron spectroscopy (XPS) after oxidation in peroxide solution indicated the presence of polysulfide. The reaction of sulfide to polysulfide is acid consuming, thus explaining the net acid consuming behaviour of galena in the NAG test. This reaction pathway may provide a possible explanation for the lower than expected acid production observed for some of the other sulfide minerals examined.

Jan 1, 2003

By M Dusci, A Trueman, S Poos, R Baumgartner, M Brittan

The Canahuire epithermal Au-Cu-Ag deposit in southern Peru is a complex and challenging deposit for metallurgical studies. It has issues of gold locking in sulfides and non-sulfides, deleterious elements and acid rock drainage (ARD). From scoping study to feasibility study, there has been considerable improvement in the understanding of the important geometallurgical characteristics that need to be measured and modelled. This paper presents the current understanding and the requirements to continue to provide optimal models for mining studies.Significant effort has been put into understanding the genesis of the deposit. Improved spatial and temporal understanding of lithology, alteration, structure and mineralogy was used to build a geological and alteration model of the deposit.Early metallurgical programs quantified the effect of head grade on process plant recoveries, but the geometallurgical and statistical analyses did not identify other physical characteristics that influence these recoveries. The studies improved the understanding of the nature of locked gold which can occur as minute inclusions (< 5 ¦m) in sulfides (primarily pyrite with lesser arsenopyrite, pyrite being 100 times more abundant than arsenopyrite) and gangue minerals (quartz and carbonates) as well as solid solution in arsenopyrite and pyrite.The presence of pyrite and the limited buffering capacity of waste rocks increases the potential ARD, which will require mitigation costs before, during and after operations. Waste rock ARD potential has been classified and incorporated in the geometallurgical model. The current classification of waste rock at Canahuire, using international classification standards, is limited due to the complexity of the deposit.Complex deposit metallurgy necessitates a complex process flow sheet, including flotation and cyanidation. Economic recovery will be constrained by the relationships between economic variable grade, other elements and mineralogy. These constraints and inter-relationships are difficult to establish throughout the deposit with a single test. A follow-up geometallurgical program is under investigation and will attempt, with the help of additional test work, to map areas of higher and lower recoveries. It is hoped that metallurgical response can be linked to measurable parameters other than head grade. If this is possible, these factors can be incorporated into future geometallurgical models.CITATION:Baumgartner, R, Dusci, M, Trueman, A, Brittan, M and Poos, S, 2013. Building a geometallurgical model for the Canahuire Epithermal Au-Cu-Ag Deposit, Southern Peru - past, present and future, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 51-58 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013