Search Documents

By Sage B. H., Lacey W. N., G. W. Billman

The composition of the coexisting phases in the methane-ethane-n-pentane system was determined at 100°F. This was accomplished by withdrawing samples of the coexisting phases under isobaric-isothermal conditions. The relative amount of each of the components present in the liquid and gas phases was determined by conventional analytical fractionation methods. The phase behavior of this system approximates that estimated from generalized correlations which take into account the influence of the nature and amount of each of the components present upon the equilibrium. It was found that for particular pressures and temperatures the equilibrium constant of each of the components was influenced significantly by the composition of the system and this effect was more pronounced at the lower pressures for methane than for the components of greater molecular weight. However, at the higher pressures approaching the maximum two-phase pressure for the system at this temperature the composition markedly influences the equilibrium constants of all the components at a particular pressure and temperature. The results of this study are presented in graphical and tabular form. Introduction The phase behavior of many of the binary systems containing parafin hydrocarbon components from methane through n-pentane has been investigated during recent years. In addition the compositions of the coexisting phases in mixtures of crude oil and natural gas have been studied.' However, these results do not establish the influence of the nature and amount of the other substances making up a multi-component system upon the gas-liquid equilibrium constant of any one component. A preliminary correlation on the basis of values for binary systems was made2 utilizing such experimental information as was available. However, there is need for much additional information regarding behavior in systems containing more than two components. Study of the phase behavior of ternary systems offers a feasible attack upon the determination of the influence of composition as well as of pressure and temperature upon the several equilibrium constants concerned. An investigation of the phase behavior of the methane-propane-n-pentane system at 100°, 160°, and 220°F was reported.".' This work served to illustrate the marked influence of concentration of the other components upon the equilibrium constants. Variations of as much as 50 pct in the equilibrium constants for methane for fixed temperature and pressure were observed in regions remote from the critical state. Likewise there was a marked variation in the equilibrium constants of propane and n-pentane as a result of changes in the composition. These results indicated the desirability of investigating additional ternary systems. The present paper deals with a study of the methane-ethane-n- pen-tane system at 100°F, which is similar in many respects to the work upon the meth-ane-propane-n-pentane system cited above.

Jan 1, 1948

By Sage B. H., G. W. Billman, Lacey W. N.

The composition of the coexisting phases in the methane-ethane-n-pentane system was determined at 100°F. This was accomplished by withdrawing samples of the coexisting phases under isobaric-isothermal conditions. The relative amount of each of the components present in the liquid and gas phases was determined by conventional analytical fractionation methods. The phase behavior of this system approximates that estimated from generalized correlations which take into account the influence of the nature and amount of each of the components present upon the equilibrium. It was found that for particular pressures and temperatures the equilibrium constant of each of the components was influenced significantly by the composition of the system and this effect was more pronounced at the lower pressures for methane than for the components of greater molecular weight. However, at the higher pressures approaching the maximum two-phase pressure for the system at this temperature the composition markedly influences the equilibrium constants of all the components at a particular pressure and temperature. The results of this study are presented in graphical and tabular form. Introduction The phase behavior of many of the binary systems containing parafin hydrocarbon components from methane through n-pentane has been investigated during recent years. In addition the compositions of the coexisting phases in mixtures of crude oil and natural gas have been studied.' However, these results do not establish the influence of the nature and amount of the other substances making up a multi-component system upon the gas-liquid equilibrium constant of any one component. A preliminary correlation on the basis of values for binary systems was made2 utilizing such experimental information as was available. However, there is need for much additional information regarding behavior in systems containing more than two components. Study of the phase behavior of ternary systems offers a feasible attack upon the determination of the influence of composition as well as of pressure and temperature upon the several equilibrium constants concerned. An investigation of the phase behavior of the methane-propane-n-pentane system at 100°, 160°, and 220°F was reported.".' This work served to illustrate the marked influence of concentration of the other components upon the equilibrium constants. Variations of as much as 50 pct in the equilibrium constants for methane for fixed temperature and pressure were observed in regions remote from the critical state. Likewise there was a marked variation in the equilibrium constants of propane and n-pentane as a result of changes in the composition. These results indicated the desirability of investigating additional ternary systems. The present paper deals with a study of the methane-ethane-n- pen-tane system at 100°F, which is similar in many respects to the work upon the meth-ane-propane-n-pentane system cited above.

Jan 1, 1948

By J. Parke Channing

ALTHOUGH the original thought of investigating waste in industry came from a mining engineer, Herbert Hoover, and although the chairman of that committee was a mining engineer (although the real work was done by the vice-chairman, L. W. Wallace), it is an interesting commentary that when the report first saw light, at St. Louis, on the first of June, 1921, some people most violently went up in the air when it was submitted by the representatives of the mining engineers. At the time they resented most markedly the report of the committee that 50 per cent. of the waste in industry, or as Mr. Ingalls in his paper has properly said, inefficiency in industry, was to be laid upon management. The reason for that seems to have been that, as a whole, the mining industry is pretty well organized and is superior to a large number of manufacturing industries including those studied by the Report. However, this very meeting shows that even the min-ing engineers have finally realized that there is waste or inefficiency in mining and that a large proportion of it can, with propriety, be assessed against management.

Jan 3, 1922

By M. C. Manderson

The sharp drop in world phosphate demand that took place in 1975 due to temporarily high prices, now seems to be reversing itself. And prices for both phosphate rock and phosphate fertilizers, which declined dramatically from their 1975 highs, now appear to be bottoming out. This recent price weakness has delayed new mining ventures that had been planned for completion by around 1980. While there is ample capacity to supply near-term rock needs, the stage seems to be emerging for a better supply-demand and price environment in the late 1970's and early 1980's.

Jan 1, 1979

By R. M. Asimow, J. J. Svitak

Tile crilical resoll,r,d shear stress, CRSS, for slip of slow1y cooled Ag-All single crystals was measured at 201K. Tlze importance of short-range order and Suzuki sogregalion was inrestigated by deter~rlining llze ciic.cl of quenching on the CRSS. Thr obserz.ed rfrtenching effects were generally small and indicate that short-range ordcr and Slczuki srgregation do no1 account for n significant portion of the solid-solution strengthening in this system. However, all alloys slzozcwi yield drops ulhich rilere heat- lreat nrenl-sensiline THERE have been a number of mechanisms proposed to explain alloy strengthening in the Ag-Au system. The effectiveness of some of the proposed mechanisms, especially those that depend on Suzuki segregation1" or on short-range order,2-6 SRO? should be strongly dependent on heat treatment. Since internal friction investigations in this system indicate that there is stress-induced order,' we must also consider the possibility of local atomic rearrangement or short-range ordering in the stress field of a dislocation. There is not complete agreement whether these mechanisms should be most effective in raising the flow stress, in causing yield drops. or some combination of these two effects. This work was undertaken to determine the effects in the Ag-Au system of mechanisms that depend on segregation or order by using known but drastically different cooling rates following a high-temperature treatment. By comparing the critical resolved shear stress, CRSS, for slip measured after a very slow cool and again after a fast cool (quench) of the same crystal, it is possible to determine the effect of cooling rate on CRSS* and on yield drops. The single-crystal CRSS was determined at several compositions because there has been no data published across the phase field since the publication of room-temperature flow stress by Sachs and Weerts.' EXPERIMENTAL PROCEDURE Starting with materials of 99.999 pct purity, single-crystal specimens of random orientation 1.25 mm square by 4 cm long were prepared with 0, 10, 14, 25, 30. 50, 70. 75. 80, 90. and 100 at. pct Au. Crystals were grown in an inert atmosphere using a modified Bridgman technique with a growth rate of 1.5 cm per hr in a gradient of 3°C per cm. To obtain a maximum practical degree of SRO, the crystals were cooled at a rate of 275'C per hr to about 310°C and then cooled at 6°C per hr to approximately 200°C. Specimens were tested in tension immersed in an alcohol bath at -72°C (201°K) at a strain rate > = 0.003 mm"1 to determine the CRSS (7). The activation volume of several crystals was determined from the flow stress increment (72 - T1) for a tenfold increase in strain rate. The total shear strain varied from 0.05 to 2.3 pct but was generally less than 0.4 pct. After testing, each crystal was then held at 500°C for 10 min, quenched into brine at -35°C and. after storage at -71°C for 1 day, retested in tension using a procedure identical to that of the first test. The quenching apparatus, see Fig. 1, was designed to enable accurate temperature control and rapid quenching while preventing specimen contamination and accidental deformation. Test data from a specimen with a fine thermocouple spot-welded to it indicated a cooling rate of 104C per sec. The relatively low heat-treatment temperature was chosen to minimize quenching defects caused by a large vacancy

Jan 1, 1970

By K. Tangri, M. Chaturvedi

On water-quenching from within the (a + ß) phase region Zr-2.5 Nb and Zr-2.5 Nb-0.5 Cu alloys can undergo w transfirmation. This transformation has been attributed to the enrichment of ß Zr phase, at the solution-treatment temperature, by the solute atoms. The ß—w transformation is accompanied by a hardening 01 the alloys and in the optimum condition w-bearing specimens of the ternary alloy are about 14 pct harder than those bearing only a' phase. On aging crl reverls thermally to more stable phases, which results in a considerable softening of the specirnens, as follows: w quenched -waged + ß Zr (enriched) waged - a + ß Nb The high-temperature bcc ß Zr in certain zirconium alloys can transform to a metastable w phase which has a primitive hexagonal structure. In the Zr-Nb alloy system w phase has been observed in the composition range of 7 to 15 wt pct Nb by a number of investigators.'-' In this composition range w can form by water-quenching ß Zr or by aging. known as athermal and thermal w, respectively. Hatt and Roberts' have found that thermal w has a constant c/a ratio of 0.622 +0.002 regardless of the composition and tha: the lattice parameters are of the order of a = 5.02A and c = 3.0 ?. The actual lattice parameters depend upon composition and the temperature of aging. The lattice constants of athermal w. however, depend upon alloy composition.3 The presence of w phase in zirconium alloys can cause substantial strengthening which has been attributed as probably due to the coherency between w and parent ß Zr phase. Robinson et al.' found that the presence of w can raise the strength of Zr-5.0 Nb-2.0 Sn and Zr-5.0 Mo-2.0 Sn alloys to about 170.000 psi: however. the ductility is considerably reduced. With the growing use of Zr-2.5 Nb and Zr-2.5 Nb-0.5 Cu alloys in the nuclear reactors, and the significant effect of w transformation on the mechanical properties of zirconium alloys studies were undertaken to study the w transformation in Zr-2.5 Nb and Zr-2.5 Nb-0.5 Cu alloys. This paper is concerned with the formation and reversion of w phase in these alloys. 1) MATERIALS AND EXPERIMENTAL TECHNIQUES The following two alloys were studied: 1) Zr-2.5 Nb-0.5 Cu (referred to as the ternary alloy): 2) Zr-2.5 Nb (referred to as the binary alloy). The chemical analysis of the alloys is given in Table I. The alloys, in the form of 3/8-in.-diam rods and 1/8-in.-thick sheets, were supplied by the Chalk River Nuclear Laboratories of the A.E.C.L. Initial fabrication for preparation of various specimens was carried out by cold rolling and swaging with intermediate anneals at 1000°C. All the heat treatments were carried out after the specimens were wrapped in zirconium foils and encapsulated in silica tubes under a vacuum of 5 x 10-% m of Hg. For optical metallography and hardness measurements disc specimens + in. diam by + in. thick were used. After the required heat treatments the specimens were mechanically and then chemically polished in a 45 pct HNO3, 45 pct H20. and 10 pct HF solution. The hardness measurements on the chemically polished specimens were carried out on a Vickers hardness tester using a 10-kg load. For each specimen at least fifteen indentations were made in order to obtain a representative hardness value. The phase identification and structural analysis were carried out using X-rays and electron diffraction techniques. Wires of 1.5 mm diam reduced to 0.12 mm diam by chemical etching were used for making Debye-Scherrer powder patterns using copper K-a radiations in 114.6-mm-diam camera. Thin films for transmission electron microscopy were prepared by electropolishing heat-treated a by 7 by 0.005-in.-thick strips using a modified Bollmann-Window technique. The 10 pct perchloric acid-90 pct methyl alcohol electropolishing bath was kepl at -5OCC and polishing was done at 5 to 10 v. The thinned specimens were washed in ethyl alcohol at -30" to -40°C and dried between filter papers. The thin films

Jan 1, 1970

The following is an incomplete list of members and guests who called at Institute headquarters during the period Apr. 10, 1918 to May 10, 1915. Robert H. Chapman, Washington, D. C. Francis Nicholson, Charlotte Court House, G. A. Collins, Seattle, Wash. Va. W. N. Cummings, Orange, Cal. F. S. Platt, Australian Imperial Force. W. A. Deane, Summitville, N. Y. H. Rabling, Melbourne, Australia. H. W. Edmondson, Camp Lee, Va. James C. Ray, Palo Alto, Cal. H. F. E. Gamm, Rutherford, N. J. Jasper T. Robertson, Chicago, Ill. A. L. Gholz, Minneapolis, Minn. John A. Root, Kings Mills, Ohio. H. H. Hodgkinson, Dover, N. J. Robert H. Seip, Franklin, N. J. Norman L. Jenks, Marmato, Colombia, Trevor B. Simon, Morristown, N. J. South America. H. N. Stronck, Chicago, 111. Paul S. King, Wilmington, Del. Benjamin F. Tillson, Franklin, N. J. Ray G. Knickerbocker, Rolla, Mo. J. R. Underwood, Granby, Mo. Carl A. Lewis, Habana. Thor Warner, Phoenix, Ariz. Robert S. Lewis, Salt Lake City, Utah. G. B. Waterhouse, Buffalo, N. Y. Edmund Newton, Minneapolis, Minn. W. M. Weigel, Renfrew,. Ont., Canada. Alexander Nicholas, Australian Imperial Chas. F. Willis, Tucson, Ariz. Force. Ralph Arnold is devoting a part of his time to work as a member of the Board of Tax Reviewers in connection with the administration of the War Revenue Act.

Jan 6, 1918

Illustrated guidebooks treating in a popular descriptive way of the geology and other features of the Western United States have been issued by the U. S. Geological Survey. They will be of much interest to mem¬bers in connection with the Arizona Meeting of the Institute and espe¬cially the guidebook of the Santa Fe Route, with side trips to the Grand Canyon, containing as it does relief maps, topographical and geological maps, covering the entire route of the railroad, illustrations from photo¬graphs and other interesting descriptions of this great country. The method of treatment is adapted to the lay-reader, although it includes much valuable and interesting technical information concerning the geographical and other features. The books are well indexed. These volumes sell for 50 c. each and may be obtained from the Superintendent of Documents, Washington, D. C. These guidebooks originally sold for $1 each, but the reprint edition has been reduced to 50 c. A list of the different guidebooks follows: Bulletin 611. Guidebook of the Western United States, Part A, The Northern Pacific Route, with a Side Trip to Yellowstone Park, by M. R. Campbell, and others. 1915. 212 pages, 27 route maps, 27 plates, 39 text figures.

Jan 6, 1916

The following is a partial list of members and guests who called at Institute headquarters during the period July 10, 1917, to Aug. 10, 1917: G. A. Collins, Seattle, Wash. Norman Picot, Melbourne, Aust. A. D. R. Galloway, Komfrodua, W. Africa. W. E. Pomeroy, El Paso, Tex. F. Lynwood Garrison, Philadelphia,; Pa. Francis R. Pyne, Elizabeth, N. J. Geo. M. Henderson, Bland, N. M. W. L. Remick, W. Norfolk, Va. L. B. Herr, Jr., So, Bethlehem, Pa. M. F. Sayre, Schenectady, N. Y. Zay Jeffries, Cleveland, 0. Leighton Stewart, New York, N. Y. H. H. Lauer, Allentown, Pa. Randolph D. Talmage, Joplin, Mo. Wm. B. McKinlay, Yonkers, N. Y. H. J. Volker, Ossining, N. Y. A. N. Mackay, Republic of Colombia. Dwight E. Woodbridge, Duluth, Minn. Edmund Newton, Minneapolis, Minn. Kwong Wu, Peking, China. J. N. Acosta has resigned his position as mining engineer for the Shannon Copper Co., Gleeson, Ariz., and is now engaged as consulting engineer for Lower California, Mexico, with headquarters at San Diego, Cal. L. D. Albin, formerly assistant general sales manager of the Ingersoll-Rand Co., was appointed general sales manager on July 25,1917.

Jan 9, 1917

By E. R. Morgan, J. C. Shyne, V. F. Zackay

NITROGEN used as an alloying element in steel has received increased attention in recent years. Its merit as an austenite stabilizer and hot strengthener has long been recojinized, particularly by European investigators.' Recent work' indicates that nitrogen contents of 1/2 pet or more allow the addition of several percent of ferrite-forming hot strengtheners, such as molybdenum, without subsequent austenite decomposition at elevated temperatures. The room temperature properties of such alloys are characterized by high yield and tensile strengths with excellent ductility, even after cold working, as shown in Tables I and 11. The 1350°F creep-rupture properties of Cr-Mn-Mo-N steels are comparable to those of commercial alloys such as Timken's 16-25-6, containing 16 pct Cr, 25 pct Ni, and 6 pct Mo, as shown in Table 111. Cr-Mn steel containing 1/2 pet N must be made under pressure if ingot gassing is to be avoided. However, there are difficulties attendant to this practice. Pressure melting restricts the ingot size, and the equipment required is costlier and more complicated than comparable air melting facilities. An effort was made, therefore, to determine more economical methods of adding nitrogen. The pressures generated in centrifugal casting usually range from 5 to 10 atm and are sufficient to prevent the gassing of high nitrogen Cr-Mn steels. A centrifugal casting was made of an alloy containing 16 pct Cr, 18 pct Mn, 2 pct Mo, and 0.73 pct N. A risk, 8 in. diam and 11/2 in. thick, was cast at 1000 rpm. It has been calculated that a pressure of 9 atm was developed at the periphery of the disk at this speed. Metallographic inspection of specimens taken from the disk revealed no gas holes or other defects. The elevated temperature properties of radial and circumferential specimens taken from this casting are given in Table IV. The creep-rupture life of this cast nickel-free austenitic steel was equivalent to that of the wrought Cr-Mn-Mo-N steels. Although centrifugal casting appears to lend itself to the manufacture of high nitrogen austenitic steels, its applicability is limited to relatively small sizes. A process applicable to the production of large ingots of high nitrogen steels is suggested by low carbon rimming steel practice. Gas holes formed during ingot solidification are not detrimental so long as they weld shut during hot rolling. An economic advantage of gassing ingots is the increased ingot-to-slab yield, especially if the ingots are mechanically capped. Also, it is probable that higher nitrogen levels can be achieved with mechanically capped ingots than with hot-topped ingots. A series of gassy heats was made under both atmospheric and higher pressures, as indicated in Table V. Several of the air melted ingots were mechanically capped by chilling the molten ingot tops with a steel plate. The ingots were allowed to freeze in steel molds without hot-tops unless otherwise indicated. A comparison of Table 111 with Table V shows no significant difference in the creep-rupture properties of the gassy and the nongassy ingots after hot work- ing nor between the gassy ingots produced under different conditions. References 1 F. Rapatz: Application of Stainless and Heat Resisting Steels Alloyed with Nitrogen. Sinhl and Eisen ( 1941) 61, pp. 1073-1078. 'V. I?. Zackay, J. F. Carlson, and P. L. Jackson: High Nitrogen Austenltlc Cr-Mn Steels. Trans. ASM 119551 48, PP. 509-523.

Jan 1, 1957

By R. Shuttleworth, R. Smith

A Knudsen effusion tnethod I~as been used lo measure the vapor pressure of pure iron in the temperature range 1000° to 1500°C. Neutron-irradiated , natural iron was used and the Mn'~proclzdced by the (n, p) reaction removed by evaporation at high temperature. The results can be represented by the equation: where pM - 1.088 x 107 atm and T, = 20,890°K. A value of 100.2 kcal per g- atom was obtained for AH;. THE vapor pressure of pure iron in the temperature range 1000" to 1500°C has been measured. Radioactive iron and a Knudsen cell technique were used and the Mn' produced by an (n, p) reaction removed by evaporation at high temperature. From the variation of vapor pressure with temperature values of the enthalpy and entropy of solid iron have been found. Previous workers2 used a Lang-muir method and measurements were made over a smaller temperature range than that in this work. EXPERIMENTAL The apparatus used was similar to that of Pyle and Shuttleworth, and McLellan and Shuttle worth. However, because of the higher temperatures the Knudsen cell was machined from tungsten bar and the flanged furnace tube was beryllia. Heating was by passing a high current (70 amp at 7 v for 1500°K) through a strip of tantalum foil laid across the top of the cell and through a turn of molybdenum wire around the furnace tube. This method of heating ensured that the top of the cell was slightly hotter than the base and prevented condensation and re-evaporation from the orifice. The temperature was measured by means of a pt/Pt 13 pct Rh thermocouple spot-welded to the base of the crucible. To ensure accurate temperature measurement the iron was in the form of a thin disc (0.75 cm diam by 0.075 cm) which lay on the base of the cell. The high-purity iron was irradiated in the Harwell pile for a week at a neutron flux of 1.2 X 10" neutrons per sq cm per sec. The isotopes fe'~ and Fe" are produced by (n! y) reactions but only Fe", half-life 45.1 days, is a emitter; Mn which is also a y emitter, half-life 300 days, is produced simultaneously by an (n,p) reaction.' Immediately after irradiation of natural iron the ratio of ~e" to Mn y activity was 100:l. However, manganese is very much more volatile than iron and almost all the y activity of the condensate is due to Mn'~. Thus it was essential to eliminate all the manganeses before any measurement of the vapor pressure of iron was made and this was done by preliminary heating for 20 hr at 1400°C. For each determination the iron was dissolved from the target with acid and the y activity compared to a known weight of iron. By means of a y-ray spectrometer the y-activity measurements were made at the 1.09-mev peak of the 17e5' spectrum where the background was of the order of 3 cpm. Despite the low specific activity of ~e" a mass of 10- " g of iron could be determined corresponding to a vapor pressure of about l0-'' atm. RESULTS The vapor pressures were calculated from the equation: Where m is the mass of iron effusing in a time t through an orifice of area a2, r is the radius of the target, Z is the distance from the orifice to the

Jan 1, 1965

By R. E. Gilchrist, R. R. Harvey, M. R. Dean

A simple and rapid three-component analysis procedure has been developed for use in fluid-flow studies. The method is based on refractive index measurements, combined with refractive dispersion measured between the Ha and H wave lengths. The procedure requires. calibration curves for the three-fluid system. The only restriction on the fluids employed is that only one be an aromatzc or olefinic compound. Individual sample measurements require only a few minutes. Composition results within the limits of accuracy required for fluid-flow analog studies are obtained. INTRODUCTION The simultaneous analysis of three-component mixtures is a problem often encountered in fluid-flow analog systems. In petroleum production research, the problem is usually encountered in experiments on the displacement of fluid from a porous medium. In the case of immiscible displacement, simple volumetric measurements of the produced fluids are usually sufficient, the analog fluids often being the actual reservoir fluids themselves — oil, water and gas. However, modern secondary recovery of petroleum sometimes involves production under miscible conditions, in which the oil is displaced by liquefied petroleum gas which, in turn, is displaced by dry gas. Since this type of displacement is done under conditions of pressure and temperature that are not easily reproduced in the laboratory, studies are often performed with analog fluids at essentially atmospheric pressure. Since the number of samples taken during one of these experiments is usually quite large, the time required for analysis becomes an important factor. In the past, the difficulty of conventional analysis has been avoided by the addition of various tracers to one or more of the components, or by the use of a tracer fluid as one of the components. With these techniques, a relatively large amount of analytical time is still required. Moreover, in the case of added tracers, the tracer material may migrate in part to one of the other fluids, may be adsorbed on the solid surfaces of the model, or may introduce side effects not characteristic of the prototype fluid. The substitution of a tracer fluid for one of the components can severely limit the choice of analog fluids. Optical refractometry provides a rapid and economical method of analysis of two-fluid systems or of monitoring small changes in composition of an essentially one-component system. Refractometric methods are capable of high degrees of accuracy, require only very small samples and can easily be adapted to automatic methods. They are not generally applicable, however, where three or more fluids are present over wide ranges of concentration. The method of three-component analysis described here has three essential characteristics. 1. It is based on refractometric measurements and thus preserves all of these desirable properties. 2. It does not make any stringent demands on the choice of fluids that can be analyzed. 3. It is capable of accuracy sufficient for fluid-flow analog studies. THEORETICAL The difference in the refractive index of a substance at two different wave lengths of light is known as its dispersivity. When the difference is taken between the specific refractions at the two wave lengths, the quantity is referred to as the specific dispersivity. Specific refraction was defined empirically by Gladstone and Dale1 as r = n-1/d....[1] where n is the index of refraction and d is the density. The definition is given more correctly by the expression r =n2-1/n2+1 1/d..........(2) 1References given at end of paper. MICIFTV OF PETROLEUM ENGINEER JOURNAL.

THE strike and dip of bedded formations is readily determined by trigonometry if some marker horizon is intercepted by three holes. If no marker can be identified and if orientation of the cores is unknown, as is the usual case in diamond drilling, the determination still can be made readily by the use of a stereonet if the bearing, inclination, and angle the bedding makes with the core axis is known for each of the three holes. Such determination, valid only if the bedding orientation is fairly uniform within the area drilled, is considered simpler, faster, and more effective than any solution previously published. Method: The steps of this procedure are as follows: 1) Mark north and south poles on tracing paper placed over stereonet.* 2) Plot the three diamond drillholes by drawing a line from the center of the net in the direction of the bearings of the holes. Then rotate the paper until each line, in turn, lies along the equatorial diameter of the net; the end of each line is determined by the inclination of the hole measured in degrees from the periphery toward the center of the net along the equatorial diameter. Fig. 1 illustrates a vertical hole and a hole inclined at —23" due east. 3) With the projection of one diamond drillhole along the equatorial diameter, measure from the end of the hole, to the east and then to the west, a dis- tance in degrees equal to the core axis-bedding plane angle. Find two more points by measuring the same number of degrees north then south along the great circle from the end of the drillhole. Draw a circle, the center somewhere along the direction of the projection of the drillhole, to connect these four points. Draw circles for the other two diamond drillholes in the same manner. See Fig. 1 for two circles representing core axis-bedding plane angles of 35" and 23" and Fig. 2 for these plus a third circle representing a core axis-bedding angle of 42" in a hole bearing S 50 W inclined at —52". 4) Rotate the tracing paper until one great circle on the stereonet is found which is tangent to all three of the circles or parts of circles derived in the previous step. Trace this great circle on the paper and join its ends with a straight line passing through the center of the net. The bearing of this line is the strike of the bedding. In Fig. 2 the bedding strikes N 77 E. 5) Rotate the paper until the strike is along the polar diameter of the net. The dip of the bedding is determined by measuring along the equatorial diameter the distance in degrees from the periphery of the net to the great circle derived in step 4. The dip of plane illustrated in Fig. 2 is 55" to the N 13 W. Fig. 3 indicates the solution for three holes whose bearings and inclinations are N 20 W and —43o, due E and —30°, S 30 W and 23" with core axis-bedding angles of 30°, 50°, and 43" respectively. The bedding (stippled area) strikes N 44 W and dips 70" to the southwest.

Jan 1, 1956

CONTENTS PAGE INTRODUCTION AND ACKNOWLEDGMENTS. By George M. Fowler 2 Question 1-Is Structural Deformation of Some Character Always Necessary for the Migration of Mineralizing Solutions, Especially in Limestone or Other Dense Rock? DISCUSSION by: A. M. Bateman 10 S. F. Kelly 15 C. H. Behre, Jr 8, 13 G. B. Langford 13 T. M. Broderick 11 H. E. McKinstry 6 R. H. Clarke 13 D. H. McLaughlin 8 J. D. Forrester for M. H. Gidel . . . 4 W. H. Newhouse 13 G. M. Fowler 2, 6, 11 R. H. Sales 6 L. C. Graton 11 Edward Sampson 12 R. D. Hoffman 10 J. S. Stevenson 7 I. B. Joralemon 11 L. B. Wright 2 Question 2-What Are Some of the Chemical and Physical Characteristics in Cer¬tain Beds within a Limestone Formation that Determine Their Favorable or Unfavorable Aspects as Reservoirs for Ore and Other Introduced Minerals? DISCUSSION by: G. W. Bain 17 G. M. Fowler 21 C. H. Behre, Jr 21 L. C. Graton 18 J. S. Brown 16 G. F. Loughlin 18 E. L. Bruce 19 R. H. Sales 19 R. H. Clarke 20 A. K. Snelgrove 20 Question 3-Are There Any Criteria by Which One Can Determine When Min¬ing Operations Have Reached the Roots of an Ore Deposit? DISCUSSION by: J. M. Boutwell 29 G. B. Langford 29 T. M. Broderick 28 G. F. Loughlin 25 E. Y. Dougherty 27 R. H. Sales 24 G. M. Fowler 22 F. A. Thomson 26 I. B. Joralemon 22 Edward Wisser 30 General S. F. Kelly 35 References 36

Jan 1, 1940

PERSONAL (Members are urged to send in for this column any notes of interest concerning themselves or their fellow-members.) Members and guests who registered at Institute headquarters during the period Oct. 10 to Nov. 10, 1914: Jintaro Kojima, Ashio, Japan. E. R. Hinckley, Seoul, Korea. J. Homer Stover, Trenton, N. J. S. A. Taylor, Pittsburgh, Pa. Kirby Thomas, New York, N. Y. Lawrence Addicks, Douglas, Ariz. Keijiro Nishio, Tokyo, Japan. Noel Cunningham, Bethlehem, Pa. Alexander K. Hamilton, Chicago, Ill. E. C. Vigeon, London, England. Harold N. Lawrie, Portland, Ore. S. E. Fairchild, Jr., Philadelphia, Pa. C. Spence Thomas, Cardiff, Wales. W. C. Schmidt, Jr., New York, N. Y. Henry Tackmann, New York, N. Y. Kenneth C. Browne, New York, N. Y. Dr. David T. Day has resigned his position with the U. S. Geological Survey and opened an office at 1331 F Street, N. W., Washington, D. C., for practice as a consulting engineer.

Jan 12, 1914

Albin, B. R Billings, Mont. '28 Amster, Nathan L 25 Broad St., New York, N. Y. '28 Bache, Jules S 42 Broadway, New York, N. Y. '28 Barrett, C. P 5338 Harper Ave., Chicago, 111. '28 Bayless, William S Russ Bldg., San Francisco, Cal. '28 Bean, Louis, H 60 E. 42nd St., New York, N. Y. '28 Beatty, Ross J Room 604, 6 N. Clark St., Chicago, III. '28 Benwell, Oswald F Hold Mags. '28 Beymer, Albert S., V.P., Keystone National Bank Pittsburgh, Pa. '28 Blumenthal, Hugo 44 Pine St., New York, N. Y. '28 Boettcher. Charles Ideal Cement Bldg., Denver, Colo. '28 Bowlus, Thomas H., Banker, Pres., Allen County State Bank Iola, Ran. '28 Brown, Colvin B Chamber of Commerce, Washington, D. C. '28 Burt, Maxwell Struthers Southern Pines, N. C. '28

Jan 1, 1934

By AIME AIME

Council.* PRESIDENT OF THE COUNCIL. ROBERT Wm. HUNT CHICAGO, ILL. (Term expires February, 1907.) VICE-PRESIDENTS OF THE COUNCIL. WILLIAM P. BLAKE TUCSON, ARIZ. THOMAS F. COLE DULUTH, MINN. IRVING A. STEARNS WILKES-BARRE, PA. (Term expires February, 1907.) HENRY M . HOWE NEW YORK, N. Y. J. B. GRANT DENVER, COLO. JAMES D. HAGUE NEW YORK, N. Y. (Term expires February, 1909.) COUNCILORS. F. L. GRAMMER BALTIMORE, MD. JOSEPH HARTSHORNE POTTSTOWN, PA. CHARLES H. SNOW NEW YORK, N. Y. (Term expires February, 1907.) A. A. BLOW WASHINGTON, D. C. FRANK LYMAN NEW YORK, N. Y. T. A. RICKARD SAN FRANCISCO, CAL. (Term expires February, 1908.) THEODORE DWIGHT NEW YORK, N. Y. WALTER WOOD PHILADELPHIA, PA. WM. FLEET ROBERTSON VICTORIA, B. C., CAN. (Term expires February, 1903.) SECRETARY OF THE COUNCIL. R. W. RAYMOND, No. 99 John Street NEW YORK, N. Y. (Term expires February, 1907.) ASSISTANT SECRETARY AND EDITOR. JOSEPH STRUTHERS NEW YORK, N. Y.

Mar 1, 1906

By G. E. Warner

This paper presents a review and analysis of a highly stratified Burbank sand waterflooding project in Osage County, Okla. Permeability values in this reservoir range from less than 0.1 md to nearly 3 darcys, and 90 percent of the permeability capacity is contained in approximately 26 percent of the reservoir volume. To date, the project has recovered 103 bbl/flood-acre-ft since waterflood initiation, which represents 50 percent of the total preflood cumulative and 12 percent of the original stock-tank oil in place (OSTOIP). The outstanding feature of this project has been the economical recovery of a sizable quantity of oil at water-oil ratios higher than those normally considered prohibitive. Nearly 70 percent of the recovery to date has been achieved at water-cut values greater than 95 percent. An ultimate waterflood recovery of 138 bbl/flood-acre-ft, or 67 percent of the preflood recovery and 16 percent of the OSTOIP, is predicted. The ultimate primary and secondary recovery will be 302 bbl/acre-ft and approximutely 40 percent of the OSTOIP. The actual performance is compared with the predicted performance by both the Stiles and the Dykstra-Parsons methods, and applicabiliry of these methods to this particular reservoir is evaluated. The performance of this project indicafes highly stratified reservoirs can be successfully and economically waterflooded when either reservoir or economic conditions preclude the use of mechanical and chemical means of mdbility control. Introduction The concept of the stratified reservoir has been used by reservoir engineers for many years to describe the vertical variations in permeability within a reservoir. Numerous techniques have been advanced to predict the expected waterflood performance of the stratified reservoir, and in most cases they prove reasonably accurate. The advisability of undertaking a prospective waterflooding project is determined, based on these predictions. This paper presents a review of a waterflood project in a highly stratified reservoir that normally would be considered a marginal prospect, at best, when evaluated with any prediction technique properly adjusted for reservoir conditions. This kind of project can be successful if the predictions are used to design a waterflooding system capable of economically recovering an oil cut of 1 to 2 percent. Experience gained in the early stages of the project's development was profitably applied in the later development of the entire reservoir and could prove beneficial to other projects with similar reservoir stratification or fracture characteristics. The East Burbank pool waterflooding operations have been developed in three separate stages, each of which has been a separate project: Mid-Burbank Unit, Flood A, and Stanley Waterflood. When referred to collectively, these projects will be called the Composite Project. The Skelly Oil Co.'s Barber lease — the only portion of the pool not included in the three projects — is operated as a separate facility with a cooperative injection-well agreement. It contains less than 80 productive acres and would not significantly affect the over-all performance picture.

Jan 1, 1969

By Ellsworth Daggett

Jan 1, 1879

By Paul Beck

WHILE the recrystallization properties of most of the practically important metals are known in considerable detail, those of lead are still relatively little known in spite of some valuable contributions in recent years. This condition probably is due to the difficulties involved in applying the usual methods of investigation. The microscopic method of discriminating between the elongated deformed grains of the familiar lenticular shape and the equiaxed recrys-tallized grains is not successful with fully refined lead: lenticular grains cannot be seen under the microscope with any amount of deformation whatever. The probable cause of this phenomenon was recognized long ago. With large deformation the time of recrystallization at room tem-perature is shorter than the period of preparation of the specimen for microscopic examination; with small deformation the deformed grains are not noticeably elongated in the first place. However, with small deformation the migration of the grain boundaries can be observed. The only systematic investigations yet published on the recrystallization of lead, those by R. S. Russell,1-3 make use of the conditions just described. Russell considered recrystallization completed when no further migration of boundaries could be observed. A serious objection to this method arises from the fact that there is no evidence to support the view that grain-boundary migration results only from recrystallization. If such migration does result from other sources after recrystallization is com-pleted-after the deformed grains have been replaced by new unde-formed grains-the "time of recrystallization" as determined by Russell may be too long. Furthermore, the method is subject to the above-mentioned limitation because of the unavoidable period of preparation of the sample. According to Russell, even with the fastest technique 5 min. elapsed before the deformed samples were ready for examination, and consequently no recrystallization time shorter than 5 min. could be measured.

Jan 1, 1939