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By R. W. Smith

The Bureau of Mines is engaged in systematic evaluation of the thermodynamic properties of combustion gases. These studies are designed to provide basic thermodynamic information of high accuracy that will facilitate the theoretical study of flame and combustion phenomena. This report is the second of a series3/ presenting results of the study for particular fuel-oxidant sys tans. These calculations had as their objective evaluation of the constant pressure flame temperatures of methane-air and propane-air flames at atmospheric pressure as functions of the mixture ratio and inlet temperature of the fuel-air stream.

Jan 1, 1953

By E. G. King

Cerium and thorium sulfides have found use as crucible materials for melting certain radioactive metals. However, thermodynamic treatment of these sulfides has been hampered by lack of experimentally derived entropy values. This Bureau of Mines report describes heat-capacity measurements between 51° and 298° K, and entropy evaluations at 298.15° K, for cerium monosulfide (CeS), cerium sesquisulfide (Ce2S3), and thorium disulfide (THS2). The entropy values, with Literature results for the heats of formation, are used to obtain free energies of formation at 298.15°K. MATERIALS The samples used in this work were supplied by Prof, Leo Brewer of the Department of Chemistry, University of California. The methods of preparation and some of the physical and chemical properties of these sulfides were given by Eastman and coworkers.3 4/ Chemical analyses, conducted in our laboratory, gave the following results:

Jan 1, 1959

By Robert S. Sanford

The Broughton and Ring magnetite deposits in Essex County, N. Y., are thought to be in a mineralized belt that extends from the Lake Sanford mining district to Lake Champlain and passes through the Mineville district. The country rook is syenite-gneiss, similar to that in the Mineville area. The Bureau of Mines conducted a vertical magnetometer survey of the area. On the Broughton properties there are no indications, magnetically, of magnetite in any degree of concentration. 'On the ding properties a number of sharp, localized magnetic anomalies were observed. One core-drill hole was bored to a, depth of 48.3 feet, also, to test one of the strongest anomalies. The field work was in progress from December 1943 to July 1944. Although no iron ore was intersected by' the drill hole, it showed that the amphibolite rook, at a depth of 6 to 100 feet below the surface, contained enough magnetite and iron sulfides to account for the anomalies recorded by the magnetometer survey.

Jan 1, 1949

By D. S. DeLong, A. Giza, D. G. Fraser, V. A. Robinson, T. B. Whitmoyer, J. E. Sneckenberger

"A cotton dust animal exposure system has been modified to incorporate a microcomputer feedback loop to monitor particle concentrations. The loop's major components are a minature real-time aerosol monitor (miniram) to estimate concentrations and a microcomputer to read the miniram's data and to control a stepper motor that adjusts the amount of dilutant air mixing with respirable cotton dust. Ninety minute trials of this system indicate that the standard deviation of particle concentrations is within 0.68 Mg/m3 of the average concentration, insuring a near constant concentration of respirable dust throughout the exposure.INTRODUCTION Previous workWeyel et al. (1984) have determined that respirable cotton dust can be shaken from bulk cotton samples using acoustical energy. The particle generator designed to utilize this fact operates like a commercially available sonic sifter, but on a much larger scale.While this generator successfully resuspended trapped respirable cotton dust, the generator output concentration decreased exponentially with time. This disadvantage was solved by Frazer et al. (1986) by operating the generator with a sinusoidal voltage near the minimum resonance frequency of the generator. This adjustment enabled the generator to produce respirable cotton dust for six hours or longer.Frazer et al. (1987) utilized the modified acoustical generator to produce a cotton dust animal exposure system. The cotton dust concentrations were estimated by a miniram, a light scattering aerosol Monitor. The system operator used the miniram values to adjust the system's parameters to maintain the desired concentration level.PurposeThe objective of this study was to introduce a computerized feedback loop to the operator controlled cotton dust animal exposure system. The miniram's estimates were analyzed by a microcomputer to determine what adjustments in the flow of dilutant air were necessary to maintain the desired cotton dust concentration. These modifications were intended to improve system performance and ease the system operator's work burden."

Jan 1, 1988

By Thomas Varley

"Concentration, ore-dressing, or the dressing of minerals are common terms used in metallurgy and indicate processes of separating valuable minerals from worthless gangue. It is understood, of course, that the products from such processes, being separated from the various minerals and gangue, are ready for commercial sale or for further treatment by smelters and refineries.Gravity concentration takes advantage of the difference in specific gravity of the various constituent minerals and gangue of waste material in the ore. The two most common forms of concentration by this means are jigging and table concentration. Jigs usually are used in the separation of relatively coarse material and the tables for the finer material, the line of division in general being about 20 mesh.There are mar factors to be considered .before a decision can be made as to what method would be best adapted to the successful treatment of an ore and only by careful experiments can this be determined. Among the important factors to be considered are. The nature of the minerals present, their physical and chemical relations to the gangue material, and the gangue material itself. Perhaps the most important is the number of minerals present and their relation to each other.Metals exist in ores in three principal forms -- sulphides, oxides or carbonates, and native. Concentration by gravity methods is in general best suited to sulphide ores, although in some places considerable success has, been obtained in the concentration of oxide ores by gravity methods."

Apr 1, 1920

By H. J. Fissan, G. Ananth, K. Rubow, V. Marple

"INTRODUCTION Over the past several years a new type of cascade impactor that utilizes small nozzle diameters (micro-orifice nozzles) has been under development (Kuhlmey et al., 1981; Marple et al., 1981). The small nozzle dimensions allow for particles to be collected as small as 0.024 µm aerodynamic diameter on the last stage of the impactor. To obtain a reasonable flow rate of 30 I min - i through the impactor, a large number of nozzles (up to 2000) are required per stage.Furthermore, by locating the nozzles of multi-nozzle stages in a prescribed manner (described in detail by Marple et al., 1981) and rotating the impaction plates relative to the nozzle plates, uniform deposits can be achieved on the impaction plates. As described by Marple et al. (1981), the advantages of a uniform deposit impactor over the conventional impactor that collects particles only beneath stationary nozzles are: (1) maximum use of the impaction substrate surface, reducing both particle bounce (if substrates are greased) and tare weights of the substrates (if particle mass is measured gravimetrically); (2) deposited particles can be analyzed for elemental composition by X-ray fluorescence (Dzubay and Rieke!, 1978); and (3) the pressure in the impactor can be kept relatively high compared to low pressure impactors that depend on a large slip correction to achieve small particle collection (some types of particles may evaporate at low pressures). The work described in this paper investigates two additional advantages of a uniform deposit impactor. These are: (1) the possibility of collecting two separate deposits at one time on one stage for two types of analysis techniques, and (2) the possibility of utilizing piezoelectric quartz crystal impaction plates more effectively by eliminating the deposit location sensitivity nature of the crystals (Schulze-Frohlich, 1981 ).MICRO-ORIFICE UNIFORM DEPOSIT IMPACTOR (MOUDI)A photograph of an eight-stage MOUDI is shown in Fig. 1. Each stage body of the impactor supports the impaction plate for the stage above and the nozzle plate for the stage below as shown in Fig. 2. By rotating alternate stage bodies, while holding the other stage bodies stationary, the impaction plates (or nozzle plates) will be rotated relative to the nozzle plates (or impaction plates).Rotation of the alternate stage bodies is achieved by gears on these bodies that mesh with gears on an electrically driven drive shaft of a rotating mechanism (Fig. 1 ). The alternate stage bodies are restrained from rotation by pins that rest on the drive shaft."

Mar 1, 1989

By John Nagy

This circular has been prepared for the guidance of safety engineers, shot firers, and coal-mine inspectors concerning multiple blasting with short-delay (millisecond-delay) detonators. These special precautions are suggested in addition to those normally followed in blasting, as outlined in the Federal Mine Safety Codes 5 6/ and in Miners' Circular 58.7/ INTRODUCTION The use of short-delay blasting has been proposed for promoting safety and increasing the rate of production in coal mining. Ideally, short-delay blasting, as compared with equivalent single-shot blasting, reduces exposure of the shot firer to dust, fumes, and weakened roof; as compared with equivalent simultaneous blasting, it reduces roof disturbance.

Jan 1, 1959

By Spencer P. Hwell, Charles E. Munroe

"Among the surplus explosives left on band with the War Department was a quantity of that styled Trojan Grenade Powder, which was especially designed during the war for use as a bursting charge in grenades and for which naturally there would be very little military use in time of peace. With a view to its disposal through use in civil projects a quantity was sent to the Bureau of Minas explosives experiment station, where analysis showed that its characteristic explosive ingredient was nitrostarcn and that the powder bad the following composition:Trojan Grenade Powder appears as a dark gray granular substance, part of which is slightly pulverulent. The granules fairly hard. The explosive is not at all dusty, and has the consistency of granulated sugar.Nitrostarch is a substance produced by treating starch with nitric and sulphuric acids and in appearance it looks very little different from powdered starch. It resembles nitrocellulose and nitroglycerin in its constitution and explosive properties and has been longer known than either, it having been prepared by Braconnet in 1833. Nitrostarch explosives have in recent years been developed for industrial use in this country, they having been used to an extent in blasting in the Canal Zone, yet as this grenade powder was a special composition it seemed desirable that a complete series of tests should be run upon it. This was done, and the results are reported in the following table in comparison with those previously obtained in testing ammonia dynamite."

Jun 1, 1920

By J. W. Paul

This paper deals with the second phase of an extensive research on coal-mine ventilation factors. A comprehensive report of the entire work is in course of preparation, but abstracts of the various chapters are being prepared in order to make the results public as rapidly as possible. Part 1 dealt with the resistance of unobstructed entries and was issued as Serial 2621 of the Bureau of Mines, in July 1924. Description of tests. After the resistance of an unobstructed entry to flow of air had been determined by tests in the Experiment mine, mine cars were; run into the test section in various arrangements and the increase in resistance was determined. The cars used were of the wooden type with loose end gate, and would hold about one ton of coal, level full. They were 7 feet long. 4 feet 2 inches wide above the wheels, 3 feet high, and had a cross-sectional area of approximately 10 square feet. The average area of the entry was about 57 square feet, the ratio of unobstructed to total area being about 17.6 per cent. The track gage was 42 inches and the wheel-base 20 inches.

Jan 1, 1924

By F. E. Armstrong

The Bureau of Mines has conducted a research program to systematize the art of locating uncharted and lost oil and gas wells that penetrate coal seams; this publication presents a preliminary summary of its findings. Although no method or combination of methods will guarantee finding all uncharted and abandoned wells in a particular area, at least 75 percent of such wells can be located by compiling and applying all available information and using modern metal detectors.

Jan 1, 1973

Provide a low-cost, low-maintenance method for im¬proving mine water quality on abandoned mine land (AML) sites. Approach A model (figure 1) is presented for selecting, designing, and sizing one or several passive mine drainage treatment systems that can be used in remediation of AML. The three principal types of passive mine drainage technologies for the treatment of coal mine drainage are an aerobic system, a compost wetland, and an anoxic limestone drain. The multistep approach presented here provides a simplified method to characterize the type and magnitude of the water quality problem and then to select either a single treatment system or a combination of treatment systems to address the specific site situation. How It Works Step 1. Discharge Characterization. Characterization of the discharge consists of measuring the discharge flow rate and collecting water samples at the point of discharge for chemical analysis. Both the flow rate and chemistry of a discharge can vary seasonally and in response to storm events. It is important to account for this variability by determining flow rates and water chemistry under various conditions. Water should be analyzed for pH, dissolved iron (Fe), alkalinity, and hot acidity (using the H2O2 method).

Jan 1, 1994

By D. Harrington

"The recent discovery and exploitation of petroleum territory have resulted in the enactment of new petroleum laws in most of the South American Republics. The activities in the discovery of these new fields were engendered by the knowledge of the fact that present producing fields must within well defined periods be exhausted. Oil operators were willing to take the initial steps in exploitation in the absence of legislation that applied strictly to petroleum operations. The enactment of modern legislation in many of these Republics encouraging and protecting exploitations may cause tremendous oil activities in these countries, and the results may be comparable with the magnitude of the undertakings and the prestige of the companies now entering this territory.These, oil fields are admirably located for convenient distribution of petroleum by water to all the Nations using oil as fuel for shipping and industrial concerns. The oil markets of the western coast of South America will derive immense benefits from the Panama Canal. This navigation route brings these markets into direct ocean shipment with the Atlantic coasts of the Western and Eastern Hemispheres.One deterrent to oil production in the Republics of South America is the want of inland. transportation facilities, but the recent laws of these Republics without exception provide for acquiring rights of way for pipe lines and other modes of transportation; and doubtless the great interests and. syndicates already operating in these regions will, as production increases, provide ample pipe line transportation sufficient to convey to the coast the oil produced. It way be assumed, from the legal guarantees afforded, and from operating equipment and machinery that are now being concentrated that refineries will be erected at shipping points for the purpose of making these petroleum products accessible to the world."

Jun 1, 1921

By Glenn C. Reed

"Preliminary examination of the Glass Buttes mercury deposits, Lake County, Oregon, was made in August 1945 at the request of W. S. Lazier, present lessee of the deposit.Most of the prospect openings in the area were inspected. The more significant workings were sampled and napped in detail. This report presents the data obtained from the investigation to date.In its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. noon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. P. S. Dean, assistant director.Special acknowledgment is due to S. H. Lorain, chief, Albany Division, Mining Branch and to S. R. Zimmerley, chief, Salt Lake City, Utah, Metallurgical Division, for analyses of the ores.The presence of quicksilver in the Glass Buttes district has been known since about 1930. The area immediately north of Middle Butte has been superficially prospected by numerous test pits, trenches, shafts, and short adits, which revealed a number of opalized zones. Many of these opalized zones contain weak to strong concentrations of cinnabar. The area has not boon explored thoroughly; no mercury has been produced from any of its deposits.A block of 48 full-size claims has been located to cover a large part of the area in sections 34 and 3, Tps. 23 and 24 S.,R. 23 E.,W.M. These claims, held by, location are owned by H. S. Miller, lumberman of Bend, Ore. W. S. Lazier, 10N. W. 20th Avenue, Portland, Ore., currently controls the property under,a nominal leasing agreement. J. W. McDaniel, 44 Lake Place, Bend, Ore., has done much of the underground and surface exploration on the property.The Glass Buttes district is an area of low relief in the Deschutes River drainage system near the northeast corner of Lake County, Ore. (See fig. 1.) The arid climate is marked by extremes of winter and summer temperature. Water for cane use is not available in the immediate area. Well water, however, can be obtained in limited supply on ranch property 5 miles to the south."

Aug 1, 1946

By M. H. Stanczyk

Bench-scale laboratory tests were made by the Bureau of Mines of a segregation-flotation concentrate, assaying 20.43 percent copper, to investigate the influence of various ratios and concentrations of ammonia and carbon dioxide on copper extraction. Leaching the concentrate with a solution containing 900 pounds of ammonia and 360 pounds of carbon dioxide per ton of feed, followed by washing the leach residue with 1.75 tons of a 10-percent solution of ammonium carbonate and about 1 ton of water (as steam) per ton of solids, resulted in a copper recovery of 96.3 percent. Resegregation and flotation tests of the washed residues revealed that 85 percent of the copper in the residue could be recovered. Steam distillation tests of a typical ammoniacal leach liquor, assaying 39 grams copper, 105 grams ammonia, and 77 grams carbon dioxide per liter, recovered over 99 percent of the copper as a mixed oxide-carbonate precipitate. The ammonia losses in leaching, filtering, washing, and distillation were 0.12 pound per pound of copper recovered in the precipitate. Calcination and subsequent hydrogen reduction of the precipitate yielded a metallic copper powder assaying 98 percent Cu, 0.87 percent Si02, 0.10 percent MgO, 0.54 percent CaO, and 0.41 percent R203.

Jan 1, 1961

By Helen W. Lang

The Bureau of Mines has developed a very rapid gas chromatographic method for routine determination of oxygen, nitrogen, methane, and carbon dioxide in mine atmosphere samples. Analysis is accomplished in 3 min; readout appears on a single strip chart. The gas sample is split between two columns contained in separate chromatographs. A 5 A molecular sieve column separates oxygen, nitrogen, and methane; a porous polymer column separates carbon dioxide from an air peak. Direct selective analysis of methane from this unresolved air peak is accomplished using a hydrogen flame ionization detector (FID). Carbon dioxide is catalytically converted to methane and detected by FID.

Jan 1, 1972

By Richard L. Sayrs

The Idol zinc prospect, formerly known as the Comstock, was examined by Harold B. Ewoldt, a Bureau of Mines' engineer, accompanied by Deane F. Kent of the United States Geological Survey on July 22, 1943. Previous to that time, the Geological Survey had contoured and studied the area. As a part of the war minerals program, further investigation of the area was recommended. The Dalton property, a mile and a half northeast of the Idol property, was examined during the progress of the work at the Idol, and it was decided to include this property also in the project. From February 7, 1944, to May 16, 1944, six holes totaling 2,739 feet were diamond-drilled on the Idol property and eight holes totaling 1,850 feet were diamond-drilled, and three pits channel sampled on the Dalton property. The drilling showed sphalerite to be sparsely distributed through a 100 foot thickness of the Kingsport member of the Knox dolomite.

Jan 1, 1949

By R. R. Sayers

Carbon monoxide poisoning is one of the most widely distributed and most frequent causes of industrial accidents . Carbon monoxide gas is a product of incomplete combustion , and since it is without color , odor , or taste , its presence is frequently unsuspected in many places where it exists . It is an ever present danger about blast and coke furnaces , smelters , and foundries . It may be found in buildings having a leaky furnace or chimney , and in buildings where a gas stove is used without a proper flue connection , such as is often found in tenements , tailor shops , and boarding houses . Hospitals receive annually a great number of victims of poisoning , either by accident or in an attempt at suicide , from artificial illuminating gas . People may be affected by leaks wherever water gas is formed or used . The exhaust gases from gasoline motors under average running conditions usually contain 5 to 7 per cent carbon monoxide , and sometimes as much as 13 per cent ; deaths from running an automobile engine in a closed garage are not infrequent . A similar danger may arise in operating gasoline engines in launches without sufficient ventilation . The gas is formed also in stoker rooms , in gun turrets on battleships , in petroleum refineries , and by the Lablanc soda process in cement and brick plants . In underground mines carbon monoxide may appear as the result of shot firing , mine explosions , or mine fires , and in tunnels where automobiles , coal or oil - burning locomotives are operated . In spite of the common occurrence of carbon monoxide poisoning there appears to be no uniformly recognized treatment for a person overcome by carbon monoxide . In the rescue work of the United States Bureau of Mines , however , a method has been developed which has been supported by laboratory investigation , and has proved successful in practical experience , over a period of years . As outlined in this article , the method is useful in the hands of first -aid men as well as physicians .

Dec 1, 1921

By G. S. McCaa

Rock-dusting is an. effective means of preventing coal-dust from propagating an explosion in a coal mine, but it will not prevent gas from igniting-explosively and with much attendant damage locally. Ventilation must therefore be effective at all times, regardless of the employment of other explosion-prevention methods, if gas explosions are to be avoided. This paper describes a gas explosion which occurred in as bituminous mine that was well rock-dusted at the point of ignition and which exemplifies the value of rock-dusting, the necessity of maintaining effective ventilation, and the need of permissible rock-dusting machines receiving power from a permissible locomotive. Description of Explosion The mine in which this explosion occurred is developed on a panel system in a practically level seam; the panel entries are driven in pairs, and the air current intakes on the right entry and returns on the left entry. Near the mouth of the intake a door is placed to control the ventilation; board stoppings are placed in crosscuts, except the second from the face, in which a brattice cloth curtain is hung, the last crosscut is left open and line brattices conduct the air current from the last crosscut to the faces. In No. 7 entry the last cross-cut was 152 feet from the face, the line brattice being within 38 feet of this face, and the second crosscut was 250 feet outby the face of the back entry or return. Seven days prior to the explosion the intake and return entries were rock-dusted to within 38 feet of the face, and as the entry had advanced during the week, the rock-dusting was to be extended.

Jan 1, 1929

By A. L. Engel

Included in the program of the Rare and Precious Metals Station, Metallurgical Division, Bureau of Mines at Reno, Nev., are investigations of treatment methods for ores representative of various mining districts throughout the country. The samples received for this work may come from areas only recently explored or from newly discovered ore deposits in older mining districts. The present investigation deals with a case of the latter type, the. ample having come from a section that has a past record of considerable precious. metals production. The application of current treatment methods to this type of ore seems to offer excellent possibilities of satisfactory economic results. Definite identification of the silver mineral in this ore asthe chloride cerargyrite, AgCl, adds considerable interest to, the investigation, as in many cases where silver occurs in comparatively small amounts in an ore it is not possible to identify the particular mineral carrying the silver or else it is contained in or combined with other more common minerals. Cerargyrite is the "horn silver" of the bananza period and is mentioned in many accounts of pioneer mining of high-grade ores The occurrence of this mineral in finely disseminated form it a low-grade ore is believed to be unusual. The sample investigated was obtained from the' Bullfrog District neat Beatty, southwest Nye County, Nevada. The ore contained 16.7 ounces of silver per ton of ore, 0.007 ounce gold, and 0.32 percent copper in a silicious gangue, with accessory minerals, including iron oxides and scorodite; the hydrous iron arsenate.

Jan 1, 1949

By R. Barany

The heat of formation at 298.15 ° K of muscovite was determined by solution calorimetry . The value obtained for the heat of formation from the elements was -1,421.2 ± 1.3 kcal / mole , and the value for the heat of formation from the oxides was -55.9 ± 1.3 kcal /mole .

Jan 1, 1964