Search Documents

By D. W. Scott

Thermodynamics is a powerful tool for investigating rotational isomerism in substituted ethanes and related molecules. Accurate calorimetric data can be interpreted to give information, not only about the energy difference between conformations, but also about the shape of the potential barrier hindering rotation from one conformation to another. However, a deterrent to this use of thermodynamics is the labor required to calculate the contributions to the thermodynamic functions for assumed potential functions. Tables of thermo-dynamic contributions for appropriate potential functions can eliminate that labor and greatly facilitate the thermodynamic study of rotational isomerism. In this research, tables of contributions to the thermodynamic functions were compiled for two potential functions typical of some commonly encountered examples of rotational isomerism. TYPES OF POTENTIAL FUNCTIONS Potential function 1, illustrated in figure 1, A, has two equal minima higher than the third. It has the general shape of the barrier to internal rotation in n-butane, for example. The trans conformation of n-butane has the lowest energy, and the two skew or gauche conformations have equal but higher energy. Potential function2, illustrated in figure 1, B, has two equal minima lower than the third. It has the general shape of the barrier in 2-methylbutane, for example. The two C1 conformations of 2-methylbutane have equal energy much lower than the assumed Cs conformation, which has not been observed spectroscopically.

Jan 1, 1962

By Oliver Bowles

This report covers the character, properties, origin, occurrence, and uses of the traprocks and describes briefly the methods and equipment employed in quarrying and preparing them for market. Production of traprock occupies an important place in industry. In 1960 the output in the form of crushed stone reached nearly 58 million tons valued at $87 million. Traprocks are also shaped into blocks of dimension stone for monuments, building construction and decoration, and specialized products such as surface plates.

Jan 1, 1963

By Harold L. Riley

This Bureau of Mines paper describes the methods and practices used at the Peck quarry of the Crab Orchard Stone Co., Inc., one of the leading producers of dimension stone in the Crossville, Tenn., area. The product is marketed under the registered trademark "Crab Orchard Stone". Another large producer of stone from the Crossville district sells its product under the registered trademark of "Tenn-Quartz". Both companies, and a number of other companies and individuals who quarry and process dimension stone from the same general geological formation, are members of the Quartzite Producers Association of Tennessee. The salable product is shipped throughout the country for use as architectural building stone. In 1959, 653,008 cubic feet of stone was produced in the Crossville area and was sold for $1,414,405. Terms and descriptions used in this report are those of the quarry and building trades. The offices, pitching sheds, wire saws, railroad siding, and storage areas of the Crab Orchard Stone Co., Inc., are on a side road 0.3 mile north from a point 2.2 miles east of Crossville, Tenn., on U.S. Highway 70. The quarry is on this same side road 2.0 miles south of Highway 70. Crossville is 62 miles west of Knoxville and 65 miles northeast of Chattanooga, Tenn.

Jan 1, 1962

By S. H. Ash

As part of the work done at the Washington coal mines during the year 1929 , a study was made of the safety practices in and about the mines . Inasmuch as electrical blasting has made considerable headway it is interesting to note the manner in which it is done and the reasons why it was discarded at some of the mines . Blasting is done at the mines in the State by means of capped fuse , electric blasting " caps , " and in some instances by electric delay detonators . Black blasting powder with fuse is used at most of the open- light mines . The use of squibs was discontinued several years ago because the coal operators , without exception , recognized the dangers incidental to their use . Permissible explosive and dynamite are also used at some of the open- light mines . With the exception of some rock work and the driving of level work in gangways and air courses the explosive is detonated by means of capped fuse .

Apr 1, 1930

By C. M. McCulloch

The methane content of virgin bituminous coalbed can now be measured accurately in the field with exploration core samples from vertical boreholes. The gas content of the coal per unit weight can be used either to design a mine ventilation system or to determine if degasification of the coalbed will be necessary before mining, and to determine the gas resources in the coalbed. The equipment necessary to conduct the test costs less than $50. The gas con-tent of the coal in place in the ground is determined by summing the gas lost from coring, gas measured during desorption, and the residual gas in the coal. Upon removal from the borehole, the core sample is placed in an airtight container and des orbed for several weeks until the desorption rate is below 0.05 cm3/g for 5 consecutive days. The gas lost from the core while it was being cored and the residual gas are estimated by a new graphical method. The amount of gas remaining depends upon whether the coal is friable or blocky. Friability appears to relate to the depth of the sample below the surface, fixed carbon percentage, Hardgrove grindability index, and proximity to tectonic disturbance. Friable coals emit nearly 96 pct of the total gas during desorption whereas a blocky coal emits only 60 pct of its total gas. Coalbeds that are ill defined as to their blocky or friable nature must be tested in the laboratory for unambiguous analysis.

Jan 1, 1975

By H. W. St. Clair

This study was undertaken to provide a more adequate knowledge of the chemistry of the sulfide volatilization process for recovery of tin from low-grade Bolivian ores. The investigation was partly supported by the Department of State under its program for scientific cooperation with South American republics. The results of this investigation demonstrate the conditions under which cassiterite (Sn02) may be converted to stannous sulfide by reaction with pyrite or sulfur vapor, Quantitative data are given on the rate of sulfidization and on the vapor pressure of stannous sulfide.

Jan 1, 1954

By K. C. Dean

During investigation of the occurrence of manganese deposits in the western United States, examining engineers of the Bureau of Mines collected samples from several properties in Montana. Extensive laboratory tests were made to determine the amenability of these ores to standard ore-dressing methods of concentration to produce marketable-grade products. The Tzarena claim, one of the properties sampled, is on the western end of the Rama or Black Chief vein in the city of Butte, Silver Bow County, Mont., on the southwestern periphery of the mining district. The Black Chief 'WAR system contains one of the largest and most extensive known rhodochrosite deposits in the world. Test work was conducted on two samples of Tzarena ore. Sample 1 is representative of a vain 5 feet wide on the 150-foot level of the Tzarena shaft. Sample 2 is representative of a vein 8 feet wide in the 100-foot level of the shaft. The Minnie Jane mine, 1/2 mile northwest of the Tzarena claim, contains ore similar in mineralogical composition to Tzarena ore but differing materially in manganese content and to some extent in physical characteristics. Ore-dressing investigations were made on three samples of Minnie Jane ore. Sample 1 represented stock-piled ore, sample 2 represented ore from Minnie Jane mine having a considerable sulfide content, and sample 3 represented low-grade ore.

Jan 1, 1951

By James H. Jolly

Although zinc in the environment is generally considered to be beneficial or benign, excessive amounts can cause deterioration of environmental quality and toxicity problems for some plants and animals. High amounts of zinc in the environment are often associated with anthropogenic activities, mainly those involving zinc production and consumption and those related to the use and disposal of zinc-containing products. To obtain some upper limit parameters on the historical quantities of zinc chat may have entered the U.S. environment from anthropogenic sources, the Bureau of Mines conducted a materials flow study of zinc from the earliest beginning of the domestic industry through 1990 and for the year 1989. For comparative purposes a generalized historical materials flow of zinc for the world was also prepared. The United States was the world's leading producer and consumer of zinc in the 1850-1990 period. In that period, U.S. mines and smelters produced 15% and 20%, respectively, of world output, and U.S. zinc consumption accounted for about one-fourth of the world total. Maximum zinc losses into the environment related to the above production, consumption, and disposal of end use products total about 63 million tons. Dissipative uses and landfill disposal have accounted for about 73% of the potential zinc losses to the environment, followed by mining and smelting 22%, and manufacturing, 5%. At the end of 1990, contained zinc in useful end-products in the United States was estimated to be about 23 million tons. In 1989 slightly more than 1 million metric tons of zinc in new zinc-containing products were added to the domestic pool of zinc in use but in the same year, an estimated 0.9 million tons was dissipated and discarded, indicating only small net gains to the zinc pool of use annually.

Jan 1, 1992

By Joseph A. DeCarlo

For the first time the Bureau of Mines is combining, in one report, comprehensive tabulations on both beehive and slot-type ovens. This publication presents statistical data on the number and capacity of all such coke ovens in the United States on December 31, 1957. Combining data on both types of ovens should prove helpful to those interested in keeping abreast of the latest changes in carbonizing capacity, particularly since the coke has similar properties and uses. Annual reports furnished to the Bureau of Mines by coke-oven operators shared that 78 oven-coke plants were operating in 22 States on December 31, 1957. This was a decline of one plant from December 31, 1956, as the Republic Steel Corp. took the ovens at Canton, Ohio, out of production on December 17, 1957, for dismantling and rebuilding in 1958. Total oven-coke capacity was 80,299,400 tons in 1957.

Jan 1, 1958

By Raymond G. Travis

This paper, which describes mining methods and practices at the Hurricane Creek bauxite mine of Reynolds Mining Corp. in central Arkansas, is one of a series being prepared by the Bureau of Mines on mining methods, practices, and costs in various mining districts of the United States. The Hurricane Creek mine is in sec. 12, T. 2 S., R. 14 W., and sees. 7 and 18, T. 2 S., R. 13 W., Saline County, Ark., about 4 miles east of Bauxite. (See fig. 1.) Bauxite has been mined underground at the Hurricane Creek property since 1942. The operation is notable for relatively high recovery of bauxite under the adverse conditions of unconsolidated water-bearing overburden and unstable clay floor. Controlled caving, timbered stope walls, and efficient drainage systems on the surface and underground have minimized the problems and raised ore recovery about 25 percent above that formerly obtained.

Jan 1, 1961

By A. B. Clayton

The Bumpus Cove area is in Unicoi County, Tenn., about 9 miles south of Jonesboro and 5 miles northwest of Erwin. Iron and lead ores were mined in the Bumpus Cove area before the American Revolution. The production of those metals continued intermittently until 1916. In 1850 this area was the most important producer of iron in the South. In 1911 several carloads of zinc ore was recovered from old dumps and shipped to Missouri smelters. In 1913 systematic mining of zinc ores was begun and continued until 1916. After that year, mining again became sporadic and continued so until discontinued in 1943.

Jan 1, 1949

By Wilbur I. Duvall, Thomas C. Atchison, Joseph M. Pugliese

Short cylindrical charges were detonated in drill holes in rock to determine the effect that decoupling ( defined as the ratio of the radius of the hole to the radius of the charge ) has on the strain - generating abilities of explosions in rock . The amplitude and period of the strain pulses produced in the rock were studied as a function of distance , size of charge , and decoupling . The main results of these studies were that , for a given distance and size of charge , the amplitude of the strain pulse decreases as decoupling increases and the period of the strain pulse decreases at first and then increases as decoupling increases . A simplified theory of decoupling is presented that satisfactorily explains the experimental results . The information presented makes it possible to predict the effect of decoupling on explosiongenerated strain pulses in rock and thus helps the explosives user evaluate the effect of decoupling on his blasting .

Jan 1, 1964

By William R. Roy

Seven coal-related waste samples (mining, cleaning, and gasification) were characterized chemically and mineralogically. Laboratory extracts of each sample, using a variety of different extraction methods, were used in both acute and chronic bioassays. A coal slurry sample (coarse fraction) and two coal cleaning refuse samples were chemically and mineralogically similar, and generated acidic water-waste systems, both in the laboratory and in the field. Acidic laboratory extracts and field samples of acid mine drainage in the area where the solid samples were collected, tended to be in equilibrium with some type of CaSO4 phase and with maghemite. The chemical composition of the extracts was sensitive to the method used to generate the extracts, but generally had the same prevalent chemical character as the field samples. The acidic wastes contain appreciable quantities of soluble Al, Mn, Ni, SO4, and Zn as indicated by both laboratory extraction and field data. Long-term extractions suggest that some constituents (Al, Fe, SO4) continued to be released by the acidic wastes after 22 weeks with no apparent associated change in pH. Two mine spoil samples, essentially shale, tended to generate water-waste systems that were neutral in pH and consequently released lower quantities tit potential pollutants than the acid wastes. The gasification residue was compositionally similar to coal-fired power plant slag and fly ash and generated moderately alkaline extracts with low concentration of soluble potentially toxic constituents. All of the solid wastes contained a variety of organic compounds, many of which are on the EPA Priority Pollutant List. However, these compounds were essentially insoluble in aqueous media. Each extract was tested for acute toxicity with tour species of freshwater aquatic organisms; green sunfish (Lepomis cyanellus), fathead minnow (Pimephales promelas), a crustacean (Daphnia magna), and a snail (Physa anatina). The extracts of the two mine spoil samples and of the gasification residue were not toxic to any of the organisms while the extracts from the acidic refuse and slurry samples were acutely toxic to all of the organisms. For all cases, pH was significantly correlated to mortality while Al, Fe, Mn, Ni, and Zn were significantly correlated to mortality in specific instances. Data from 96-hour LC-50 determinations showed that dilutions up to 1:1000 were necessary to eliminate mortality. The most toxic extracts were those with the lowest pH which necessitated the largest amounts of dilution to eliminate mortality. Chronic bioassays with the same test organisms were investigated with leachate samples from a relatively unweathered refuse sample and an older, more weathered refuse sample. The unweathered refuse sample generated a leachate that was acutely toxic while the leachate from the weathered refuse sample was not acutely toxic. No detrimental chronic effects were noted in organisms exposed to dilutions of the non-toxic leachate while low concentrations of the acutely toxic leachate produced lower hatchability for the Lepomis cyanellus and Pimephales promelas eggs, increased mortality with chronic exposure for Lepomis cyanellus, Daphnia, Physa, and reduced weight gain for Physa. Dilutions of a toxic, high-Fe leachate resulted in the precipitation of ferric hydroxide that was implicated as the major causative factor accounting for the physical and physiological toxic effects exhibited by all of the test organisms in these acutely sublethal concentrations. The toxicity of this leachate demonstrates the potential effects that these types of wastes can have on the aquatic ecosystem if they enter a receiving water in a natural setting.

Jan 1, 1984

By R. L. Brown

This report, the seventeenth in an annual series, summarizes Bureau of Mines research and technologic work on coal and related investigations for July 1, 1951, to July 1, 1952. It 1s based largely on publications issued during the fiscal year, although 10 some instances data are presented that have not been published previously. Footnote references are given to the publications so that further details on the work may be obtained. Bureau of Mines research on the mining, preparation, and utilization of coal is directed toward developing and encouraging safer and more efficient mining practices and preparing and utilizing coals to the best advantage.

Jan 1, 1953

By T. A. Sullivan

The use of sulfur combined with either sand or waste copper tailings was investigated by the Bureau of Mines as a substitute for a good graded aggregate in asphalt paving materials. The research was part of a utilization program to develop meaningful uses for a projected oversupply of sulfur. Many sections of the country lack good aggregate for paving but do have available sources of sands and sulfur. The development of paving mixtures of desert sands or tailings with sulfur and asphalt was accomplished in the laboratory and tested by laying small paving test sections. Three types of material were studied for use with the sulfur and asphalt. They were (1) a concrete sand similar in gradation to river or beach sands, (2) desert blow sand, and (3) waste copper tailings. Desert blow sand and waste copper tailings are much finer than concrete sand. Mix designs were established for the three types of materials, sulfur, and asphalt used in the paving materials. The best mix designs were as follows, in weight-percent: 80.5 concrete sand, 13.5 sulfur, and 6 asphalt; and 77 either blow sand or tailings, 17 sulfur, and 6 asphalt. Small-scale testing showed that these mixtures were suitable paving materials but would require specialized equipment for transporting and laying. The chemical modification of sulfur to obtain properties that would allow placement of these materials with normal asphalt paving equipment was studied. Results indicate that reacting sulfur with dicyclopentadiene before adding it to the paving mixture was effective in modifying the sand-sulfur-asphalt paving so it could be placed and rolled with conventional equipment.

Jan 1, 1975

By P. M. Sullivan

This report describes a new application of electroamalgam metallurgy in recovering all the zinc as refined metal from galvanizers' sal skimmings. Pure zinc was recovered by electrolysis of skimmings leach liquors in amalgam cells. The following information was gained as a result of literature studies and subsequent laboratory investigations. 1. Reports in the literature indicate that pure zinc can be recovered from chloride solutions with the aid of amalgam cells. From Europe it was reported that amalgam cells could be used to recover pure zinc and chlorine from leach liquor obtained from pyrite cinders following a chloridizing roast.

Jan 1, 1956

By Thomas A. Phillips

The Bureau of dines present, an economic evaluation of its process for the ferric chloride leaching of chalcopyrite concentrate. In this process, chalcopyrite concentrate is leached with ferric chloride solution to extract copper, which is precipitated from the solution by electrolysis while leaving sulfur in the residue. Spent liquor from electrolysis is treated with oxygen to regenerate the ferric chloride leach solution and the sulfur-laden residue is processed to recover the sulfur. A cost estimate was prepared for a plant capable of processing 600 tons of chalcopyrite concentrate per day, 330 days per year. The fixed capital cost, on an early 1.975 basis is $27,831,600 and the estimated operating cost is 9.9 cents, per pound of copper product. In comparison, the estimated operating cost of a smelter equipped with a citrate process plant to recover sulfur is about 13.6 cents per pound of copper product. No charge for chalcopyrite concentrate or credit for recovered byproducts has been included in either operating cost. The ferric chloride leach process, therefore, appears to be economically attractive.

Jan 1, 1976

By John D. Sullivan

The recovery of copper by leaching from relatively low grade ores containing both oxidized and sulphide minerals is rapidly gaining in commercial importance. There is an economic limit below which certain ores can not be treated by concentration methods, and material with values below this limit must be discarded, possibly to be treated later, or the copper must be extracted by wet processes. Heap leaching has been carried out by the Phelps Dodge Corporation, Copper Queen Branch, for several years, and to-day its plant is a large producing unit. The Ohio Copper Coy at Bingham, Utah; has been leaching in place since 1919. Many other leaching operations are also being; carried out in various parts of the United States and in foreign countries. The plant at Rio Tinto, Spain, may be considered the father of heap leaching.

Jan 1, 1931

By E. V. Cilento, K. A. DiGregorio, R. C. Lantz

"An electro-optical method was used to quantify superoxide (SO) release from single rat pulmonary alveolar macrophages (PAM) exposed in vitro to respirable quartz and kaolin dusts and in vivo to quartz. Release was determined by measuring the reduction of nitroblue tdrazolium (NBT) to a diformazan precipitate at 550 nm from video-recorded images of individual cells. In vitro exposure to 0.025 or 0.05 mg/ml kaolin for 40 minutes resulted in no significant differences in either the total diformazan produced (max) or the maximum rate of diformazan production (R)./n vitro exposure to 0.025 mg/ml c1uartz decreased max 38 percent while no significant change was found using 0.05 mg/ml. However, R was decreased 31 percent and 24 percent for the low and high dose, respectively. In contrast, PAM obtained from animals exposed in vivo to quartz dust for two or four weeks in inhalation chambers exhibited increased production of diformazan. However, only PAM analyzed three days post-exposure showed significant increases, while PAM from animals sacrificed ten or 31 days post-exposure were not significantly different from control. The combined in vitro and in vivo quartz results might suggest that there is an initital acute response to exposure that decreases the ability of PAM to produce SO, followed by recruitment of production of PAM with increased SO producing capability. It appears that removal of animals from the source of exposure permits PAM to return to control levels of SO production by31 days. Whether this would be true for chronic exposure remains to be elucidated.IntroductionPulmonary alveolar macrophages (PAM) protect the lungs by phagocytizing foreign debris and bacteria.(1) This process involves ingestion as well as destruction of foreign matter. Phagocytosis usually is accompanied by a respiratory burst which increases cellular oxygen consumption leading to the release of highly reactive oxygen metabolites.(2) These agents have been implicated in the killing of bacteria by phagocytes, but they have also been shown to be toxic and,have been linked to cancer, emphysema, arthritis, diabetes, and other diseases.(3) Toxic effects may be a result of 1) an abnormally low production of metabolites, resulting in damage to lung tissue by the respired bacteria and/or dusts; or 2) an abnormally high production resulting in direct damage to lung tissue by metabolites themselves."

Mar 1, 1989

By A. E. Nagel, J. E. Carpetta, M. G. Zabetakis, T. D. Moore

The method of moving averages was found useful in assessing the nature of methane emission in coal mines. Emission rates were influenced markedly by the presence of abandoned oil and gas wells in the vicinity of the mine. Such wells appeared to increase the flow rate of methane into the mine by a factor of 2 to 30 in an active mine in the Pittsburgh coal seam.

Jan 1, 1972