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By W. H. Oppelt

A lignite from west-central North Dakota (Mercer County) was dried by the Bureau of Mines by the Fleissner process at saturated steam pressures to 1,500 pounds per square inch absolute (p.s.i.a.). Normally, the process is operated at pressures of 200 to 370 p.s.i.a. At the highest pressure the temperature of the saturated stearn is 596° F. The purpose of the investigation was to evaluate the influence of very high stearn pressure and temperature on moisture removal, steam consumption, and physical and chemical characteristics of the dried lignite. Two drying cycles were used: A normal cycle, corresponding to previously established standard time requirements, and an accelerated cycle, wherein time requirements were determined by boiler capacity and handling speed. Blank tests to determine stearn requirements for heating the empty autoclave were performed for each cycle and each test condition. Moisture removal, final moisture content, net steam consumption, and size stability of the dried lignite were determined.

Jan 1, 1959

By John R. Reeves

The data presented in this paper form the chief part of a general survey of the oil-shale resources of Indiana. Other papers* have already been published which contain data an various aspects of this resource. In combination, these papers present data with reference to the following points; (1) distribution of the New Albany shale; (2) amount of shale available; (3) homogeneity and thickness of the formation; (4) amount and quality of the oil obtained from the shale; (5) nitrogen content of the shale; (6) extractibility of the shale and its amenity to breaking; (7) some economic factors bearing upon the utilization of the shale; and (3) other miscellaneous factors and data. In the future, technical work on other phases of the general problem is expected to be done with the object of making a complete survey of this resource which is of much potential importance to the state and nation.

Jan 1, 1923

By Jr. East

The Bureau of Mines conducted an investigation of the Nightingale tungsten deposit about 38 miles north of Fernley, Nev., from September 1939 to March 1940, to determine possible resources of tungsten ore. The property was owned by the Gold, Silver & Tungsten, Inc., which maintained its offices in Boulder, Colo. Ore was discovered in 1917, and some ore was mined in 1918 and treated in a mill at Toulon, a station on the Southern Pacific Railroad, 40 miles east. Same shipments were made since 1918, but no production figures are available. The ore is mined from nearly vertical tactite bodies at the limestone-granite contact. The Bureau of Mines excavated 944 linear feet of trenches, drifted 52 linear feet, sunk a shaft 20 feet in depth, sampled the underground workings by cutting 743 linear feet of channels, sampled the surface trenches by cutting 415 linear feet of channels, and drilled 9 diamond-drill holes, totaling 3,000 feet. The ensuing sections note the location and physical features of the district and specify the property and ownership. The history of the mine is briefed, and the geology and mine workings are described. The work done by the Bureau of Mines is summarized and supplemented in detail by assay maps, logs of diamond-drill holes in appendix A, and a table of sample analyses in appendix B.

Jan 1, 1950

By Robert M. Cox

The objective of this study was to determine if significant relationships exist between coal mine roof stability and the time roof is left unsupported. Additional factors such as geology, opening geometry, and mining methods were also studied: to determine their relative influence on mine roof stability. The results of the study indicate that geologic factors such as shear zones (either joints or faults) and changes in roof rock lithology were the principal factors governing mine roof stability. The time lapse factor appeared to be of critical importance when poor mine roof conditions are encountered. The study pointed up the need for improved and permissible rock mechanics instrumentation for use in coal mine investigations.

Jan 1, 1974

By R. M. Santmyers

Umber and sienna, like ocher, are naturally occurring mineral pig- ments composed largely of clay permeated with hydrated iron (ferric oxide), but they differ from ocher in that they also contain hydrated manganese oxide. The presence of manganese accounts for their browner color. In addition to silica and alumina (clay) and the coloring oxides of iron and manganese, these pigments often contain lime, barium, and other metallic salts as impurities. Sienna most nearly approaches ocher in chemical composition, and the chief distinction is its physical character. It grades into ocher with de- creasing iron content and into umber with increasing manganese content. Sienna is translucent rather than opaque and is more of a stain than a pigment; as the iron oxide content is rather high (often 60 to 80 per cent), the color is strong and rich and varies from pure brown to reddish brown. This pigment raw sienna, terra di Siena, and Italian earth. is known under several names: Burnt sienna is a pigment of an orange-brown tint made by cautionsly calcining raw sienna. It is divided into two grades; American, and Italian burnt sienna. American burnt sienna is a reddish-brown pigment containing from 25 to 60 per cent iron oxide (Fe2O3). One grade, found in Pennsylvania, analyses as high as 80 per cent and is mown as double strength sienna. Italian burnt sienna is a pigment generally containing more iron than the American product, averaging 60 to 75 per cent iron oxide.3 American pig- ments of the same iron content differ materially in shade, having a Havana- brown color, whereas the Italian is more of a maroon. Italian siennas when tinted with 20 per cent of white, show a bluish tint, whereas American siennas yield a brownish or yellowish hue. Raw umber, also known as Turkey umber, Levant umber, and terra ombra, is a greenish to yellowish brown siliceous and ferruginous earth, containing a considerable proportion of one or other of the higher oxides of manganese, Mng04 and MnO2." It is similar in many respects to raw sienna except that it is much coarser and contains more manganese oxide. All umbers contain over 5 per cent of manganese dioxide. Like sienna, umber is a permanent pigment, not being injured by light or by impure atmospheres. Burnt umber (velvet brown, chestnut brown, etc.), results from the calcination of raw umber. The color is much richer and warmer than that of the raw umber. The colors are equally permanent and can be used in conjunc- tion with all other durable pigments.

Sep 1, 1931

By F. E. Diebold

The methodology for describing the geochemistry of elements in a coal seam have been developed. This has been applied to the Rosebud Coal Seam, which is an economically important member of the subbituminous coals of the Fort Union Formation in Eastern Montana. The method development has involved a detailed study of two popular techniques for determining the metal geochemistry of coal, namely, whole coal analyses and coal physical fractionation. The mathematically contrived element associations (whole coal analyses technique) and the element concentration trends in the float and sink fractions (physical fractionation technique) are considered to lead to only qualitative conclusions concerning the chemical associations of the elements in coals. Additionally, the processes taking place with the coal during low temperature ashing in an oxygen plasma are experimentally investigated and shown to be of sufficeint extent that the use of such low temperature ash for deciphering element geochemistry is questionable. The method developed in this study is a chemical fractionation that involves the sequential leaching of coal with water, 0.5 N HC1, 3 N HC1, 2 N HNO3, and 48% HF. These leach solutions are shown to selectively dissolve the predominate inorganic phases, sulfates, Ca and Mg carbonates, Fe sulfides and K alumino-silicates and quartz, respectively. These phases were identified with the use of XRD, SEM, EM and leaches (water and 0.3 N HC1) of whole coal and low temperature ash. The incorporation of the anion-exchange step in the leaching scheme was investigated and was observed to warrant further study of such intensity to be, at the time, unuseable. The use of this sequential leaching technique on several coal samples from the same seam generates element concentration trends that can be quantitatively interpreted with respect to the chemical associations of the minor and trace metals in the coal seam. The properties of the various seams of economic importance in the Fort Union Formation in Eastern Montana are compiled and presented. The subsequent conclusion is that there is not a large variation in the properties of these coal seams and that the variations within the Rosebud are within one order of magnitude. The chemical fractionation technique, investigated in this study, was applied to composite tipple samples of the Rosebud seam. Each composite sample represented 76,800 tons of coal. A minimum of 32% of the Ca and Mg are present as separate water soluble sulfates. An excess of the sulfate ion in the water extracts shows the predominating influence of the ion exchange capacity of the organic compounds in the coal. Based upon the CO content of the coal and the HC1 leachate data, 25 to 30% of the alkaline earth elements exist as separate carbonates and the remainder are associated with the organic compounds. The small fraction of the illite that dissolves in the HC1 and HNO3 leachates accounts for the K and Al. Slight dissolution of the pyrite in the HCl solvent occurs, the small amounts of Li and As do not relate to any known phase and Mn is present as a separate carbonate phase. Fe and a significant amount of the As exist in the pyrite that is dissolved in the HNO. Se is equally partitioned between the pyrite and the organic compound~. Most of the trace elements are found in the HF solutions. Li, V, and Cr were interpreted to be associated with the clay minerals (kaolinite and illite). Ni and Pb appear to be present as separate phases and 50% of the Hg is HF soluble but is not chemically related to any known inorganic phase.

Jan 1, 1983

By C. L. Severy

The Reeder No. 1 well was drilled by the Bureau of Mines in cooperation with the Geological Survey as agents for the Defense Plant Corporation. The well is south of Crescent Junction near Thompson, Grand County, Utah. It was started May 5, 1942, and completed August 3, 1942, for the purpose of con-firming the presence of magnesium salts in a deeply buried bed. Drilling was done under contract by the Mack Drilling Co. This report contains an outline of the physical features of the well, a brief history of drilling, and a description of the deposits and occurrences of oil and gas encountered in the drill hole. The work performed by the Bureau of Mines is described in considerable detail, with particular emphasis on drilling procedure and sampling. The report is concluded with a brief description of core-sample preparation for analyses. Appendix A comprises a log of the drill hole, and appendix B is a tabulation of analyses of cores.

Jan 1, 1949

By J. Bootle

Marrow vein deposits will continue to be an important source of valuable minerals. Productivity per manshift is not keeping pace with operating costs. Increased mechanization of stoping operations must be obtained to create greater productivity at a reduced cost per ton. This application of mechanization may be to either present methods or to newly developed concepts. The total mine unit operations will be effected by increased productivity. Two approaches to increasing the mechanization of narrow vein stoping were studied with the intention of increasing stope productivity and decreasing stoping costs. A method of bringing efficient rubber-tired equipment into narrow cut and fill stopes was designed. It proposes to provide stope access by way of a ramp constructed on the stope fill. Impact breaking equipment was studied and specific applications proposed.

Jan 1, 1977

By GLADYS G. HEFFNER, William H. Waggaman, Edwin A. Gee

Thallium is one of the rare and relatively neglected elements that has recently assumed conspicuous importance. This element is widely distributed in nature but occurs in such minute quantities in most rocks and minerals that its recovery at present is only commercially feasible as a byproduct of other industries. World War II, with its unprecedented demand for products having special or unusual properties, led to a study of a number of the rarer elements that previously had been given comparatively little attention for one or more of the following reasons: 1. 2. Limited knowledge of properties. Small quantitios present in available raw materials. 3. High cost of concentration and recovery. Some of those rare elements, either alone or in the form of compounds, have already proved of such value for certain military and industrial purposes that their extraction from ores and waste products, oven at high cost, is fully justified. On the othor hand, further investigation of their character- istics, discovery of more adequato sources, and improvement in methods of con- centration and recovery would greatly broaden their field of usefulness and establish new and expanded industries. The current market for some of these elements exceeds the available supply. One of the functions of the Bureau of Mines is to study the properties of such elements in greater detail, locate the most promising raw materials from which they can be derived, and work out methods of extraction that will render the recovery of such elements more economical. The purpose of a serios of information circulars on the raror elements is to present in condensed form the facts and data so far available. This information may serve as a basis in planning more complete investigations loading to a full utilization of such elements.

Mar 1, 1950

By F. M. Goodwin, John Campbell, W. P. Yant, G. W. Jones

"INTRODUCTION The cooperative investigation dealing with the general hazards of combustible gases and vapors in manholes owned by the Edison Electric Illuminating Co. and the New England Telephone and Telegraph Co. in Boston, Mass. and surrounding territory, was continued during 1934.The method and procedure of conducting the survey for 1934 were the same as those followed heretofore.ACKNOWLEDGMENTSThe cooperative investigation was arranged through the interest and effort of F. D. Comerford, president of the Edison Electric Illuminating Co. of Boston; E. M. Farnesworth, Jr., vice president and general manager of the Boston Consolidated Gas Co.; and A. C. Fieldner, chief engineer, Experiment Stations Division, U.S. Bureau of Mines. Thomas H. Haines, superintendent, Distribution Department, of the Edison Electric Illuminating Co., cooperated in furnishing both men and information for the work.The New England Telephone and Telegraph Co., through Chief Engineer G. K. Manson, R. F. Esterbrook, H. G. Crush, and A. J. McCarron, cooperated by assigning a telephone company employee for the test truck. The company has borne its proportionate share of the expense and has taken an active interest in the work during the year. The test crew was operated under the direct supervision of John Campbell, superintendent of the Special Service Department of the Edison Electric Illuminating Co., and 7. M. Goodwin, vice president of the Boston Consolidated Gas Co."

May 1, 1936

By C. R. Bopp, N. A. C. Smith

"For a period of several years, beginning with 1915, there has been a continuous change in the quality of motor gasoline. The average volatility has decreased, this to the fact that higher boiling fractions of the crude oil have been included in the gasoline. This change in quality was made necessary by the tremendous increase in the demand for motor fuel, caused by the development of the motor car, and during the war was an absolute necessity to avoid gasoline shortages. The Bureau of Mines has kept in close touch with this situation by making surveys from time to time of the gasolines sold throughout the country, as this information is of value to manufacturers and users of motor cars and also indicates when any changes are required in the Government specifications. The Bureau has just completed a gasoline survey and is in a position to make public the fact that there has been very little change in the quality of motor gasoline in recent months.During the period from January 17 to February 3, 1920, 81 samples of actor gasoline were collected by representatives of the Bureau of Mines in seven districts of the United States. The cities selected for this survey were New York, N. Y., including Brooklyn; Washington, D. C.; Pittsburgh, Pa.; Chicago, Ill.; New Orleans, La.; Salt Lake City, Utah; and San Francisco, Cal., including Berkeley. In every case the samples collected were taken in such a manner as to represent material actually being sold as motor fuel, and to include samples from each refinery marketing in the district."

Jan 1, 1920

By E. K. Stanek

This volume describes software developed for programmable calculators that is useful in the analysis and design of mine electrical power systems. The programs are equally useful for any industrial or commercial power system. All programs are written for both the HP-97 and the TI-59 programmable calculators. Listings of both versions of the twelve programs that were developed appear in the report. The programs that were developed can be broken into two groups. The first group encompasses design-oriented programs. The second group encompasses analysis programs. For each program the following items are provided: a description of the program's capabilities, the solution technique used, instructions on how to use the program, a worked out example with data and results and, finally, listings of the programs for the HP-97 and TI-59 programmable calculators. Typical problems that can be attacked with these programs include ground bed design, selection of contactor size, fuse size, relay settings, instantaneous overcurrent trip settings for trailing cables, allowable cyclic cable loading, short circuit analyses, prediction of transient voltages and others.

Jan 1, 1979

By W. E. Anable

The Bureau of Mines studied the purification of commercially available vanadium in the 100-kw electron-beam furnace. Purification studies were conducted on a 100-gram button scale by melting and holding the liquid vanadium at temperatures ranging from 2,060° to 2,080° C at pressure of 5(10)-5 torr for periods ranging from 5 to 20 minutes. The effect of doping vanadium with carbon and metallic additions was determined. This study demonstrated that hydrogen was readily removed to 3 ppm or less, oxygen and carbon were reduced to less than 100 ppm each, and the metallic impurities were reduced Co the range of 10 to 500 ppm. The nitrogen content was not reduced in any of the buttons; rather, the nitrogen concentration generally increased as samples were held for successively longer periods. Oxygen was removed much faster and more completely when vanadium was doped with small carbon additions or one of several dopes prior to melting.

Jan 1, 1967

By Alan J. Fejes

As part of its mine subsidence research program, the Bureau of Mines and the American Electric Power Co. cooperated on a study, conducted at the Price River Coal Co. No. 3 Mine, directed toward developing the capability to estimate the surface subsidence resulting from longwall mining in a geologic, topographic, and mining environment common to coalfields in the Western United States. Subsidence was monitored at the No. 3 Mine over two adjacent longwall panels. The subsidence study area was reduced when the two planned panels were reduced in length because of equipment failure and a mine fire. Subsidence was measured for 21 months. Subsidence continued for 6 months after mining had been completed. A maximum of 2.2 ft of subsidence occurred over the two longwall panels mined at an overburden depth ranging from 300 to 1,500 ft.

Jan 1, 1986

By J. H. Field

Results of studies by the Federal Bureau of Mines on a pilot-plant scale for removing hydrogen sulfide and carbonyl sulfide from gas mixtures by the hot carbonate system are given in this publication. Gases containing up to 10 pet. hydrogen sulfide and 48 grains carbonyl sulfide per 100 cu.ft. were treated. In most tests carbon dioxide also was present and was removed simultaneously with the sulfur compounds. Because the rate of absorption of hydrogen sulfide is much more rapid than that of carbon dioxide over a wide temperature range, selective removal of hydrogen sulfide occurred in the bottom section of the absorber near the point of gas entry. Hydrogen sulfide was removed to pipeline specifications with carbonate solutions by using split-stream flows in the absorber and regenerator.

Jan 1, 1960

By Henry E. Blake

The Bureau of Mines has been engaged in a continuing research effort to develop processes for increasing the recovery and utilization of fluorine from low-grade resources. This current research has shown that over 98 percent of the fluorine in phosphate rock is extracted when the ore is treated with excess phosphoric acid in the presence of water vapor at 150° to 180° C. More than 80 percent of the fluorine can be recovered as fluosilicic acid, which can then be converted to commercially useful hydrogen fluoride or fluorspar by previously developed Bureau processes. Extraction of P205 from the ore was about 98 percent in batch tests and 90 percent in semicyclic tests.

Jan 1, 1974

By Jr. Sillers

This is the sixth report of investigations in cooperation with the steel industry to establish the technological acceptability of electrolytic manganese in steelmaking processes. The bulk of the .electrolytic manganese used in these tests was produced by the Bureau Of Mines from domestic ores at its Boulder City, Nev., pilot plant by the process developed by the Bureau. Electrolytic manganese for the first series of tests made in 1940 was supplied by the Electro manganese Corp., Knoxville, Tenn. The first report dealt with the application of electrolytic manganese to the manufacture of stainless.steel;9 the second with tests in acid electric and acid open-hearth low and medium carbon-steel castings; the third with its use in rimmed and? killed low-carbon steels; the fourth with its application to the manufacture of stainless steel as well as the Timken 16-25-6 alloy for gas turbines; and the fifth with tests in acid and basic electric steel foundry practice and basic steel ingot production.

Jan 1, 1948

By Thomas R. Bur

This method of performing general transformations by use of Eulerian angles greatly reduces the time required for the determination of values for the elastic compliance constants (sij), elastic stiffness constants (cij ), Young's modulus, shear modulus, or Poisson's ratio for any orientation the cartesian coordinate system in an anisotropic material.

Jan 1, 1969

By E. G. Noble

The effects of HBr concentration and temperature on the solubility and hydration state of AlBr3,' CoBr2, PbBr2, MnBr2, KBr, and NaBr were investigated by the Bureau of Mines. Saturated aqueous solutions of the AI, Pb, K, and Na bromides were sparged with HBr gas at 20°, 40°, and 60° C, and saturated solutions of Co and Mn bromides were sparged at 20° C. Increased HBr concentration caused decreased salt solubility because of the common ion effect for all the investigated bromides except PbBr2. Aqueous solubilities at 20° C were, in percent, 51.7 for AlBr3, 53.2 for CoBr2, 1.1 for PbBr2, 59.6 for MnBr2' 39.5 for KBr, and 47.4 for NaBr. At 60° C, the solubilities were, in percent, 53.3 for AlBr3, 2.2 for PbBr2' 46.0 for KBr, and 53.8 for NaBr. Solubilities in solutions sparged to HBr saturation at 20° C were, in percent, 0.5 for AlBr3, 42.0 for CoBr2, 32.2 for PbBr2, 21.0 for MnBr2, 0.6 for KBr, and 0.3 for NaBr. At 60° C, the solubilities at HBr saturation were, in percent, 1.8 for AlBr3, 41.4 for PbBr2, 1.3 for KBr, and 0.4 for NaBr. CoBr2 precipitated out to a minimum solubility of 27.2 pct at 28.7-pct-HBr concentration. Further increases in HBr concentration increased CoBr2 solubility because of the formation of bromide complexes. PbBr2 in-creased in solubility as HBr concentration increased.

Jan 1, 1988

By Sidney Katell

This Bureau of Mines study estimates capital investment, operating costs, and selling prices for three underground bituminous mines producing coal with annual production ranging from 1.03 to 3.09 million tons. It is assumed that the mines have a 20-year life. Wages and union welfare payments are considered as of November 12, 1973, under the Bituminous Wage Agreement of 1971, and costs for material and equipment are based on 1973 indexes. Initial capital investment ranges from $12,938,200 for the 1.03-million-ton-per-year (MJ.Vl tpy) mine to $31,435,500 for the 3.09 MM tpy mine. Total capital investment ranges from $21,607,200 to $51,982,000 for the same mines. Corresponding selling prices for the coal range from $9.11 to $8.06 per ton, assuming a 12-percent discounted cash flow rate of return after Federal income taxes.

Jan 1, 1974