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By G. W. Grove

The Joseph A. Holmes Safety Association acid the Holmes Association have fostered many chapters that have served as a medium in increasing safety in the mining industry. Details relating to the formation, operation, and achievements of the J. J. Forbes District. Council of the Holmes Safety Association, which operates in the Uniontown-Brownsville bituminous coal district of western Pennsylvania will be of interest to all who are striving to increase safety in mines, quarries, and in the oil fields. The Joseph A. Holmes Safety Association The Joseph A. Holmes, Safety Association' was organized in 1916 by 24 of the leading technical societies and mining organizations to perpetuate 'the memory of Dr. Joseph Austin Holmes, first Director of the United States Bureau of Mines.

Jan 1, 1929

By T. A. Sullivan

High-purity vanadium metal was prepared by electrorefining commercial vanadium in a molten sodium bromide, potassium bromide, and vanadium dibromide electrolyte. Variables investigated were operating temperature, current densities, electrolyte composition, and condition of the anode. The purity of the refined metal was in the range of 99.95 percent vana-dium. Iron and oxygen in the 50- to 250-ppm range were the only major impurities. Metal with hardness numbers of 50 to 60 in the Rockwell F scale was prepared from feed material with a Rockwell B hardness of 90. The arc-melted metal was highly ductile and could be cold-worked into sheet or foil.

Jan 1, 1965

By Harry Freund, Kenneth H. Hammill, Francis C. Bissonnette

"Gallic acid is a sensitive, stable, colorimetric reagent for the determination of tantalum in the range of 2 to 40 µ g.Ta/ml. The method consists of the fusion of tantalum oxide with potassium pyrosulfate and solution of the cooled melt in saturated ammonium oxalate, followed by development of a yellow complex with an ethanolic solution of gallic acid. The tantalum-gallic acid complex absorbs over a broad region in the blue and near ultraviolet. Adverse effects due to interfering ions and solution conditions, such as oxalate concentration and pH, can be minimized by a suitable choice of wave length.by a suitable choice of wave length.A new and sensitive colorimetric method is provided that has been used successfully at the Northwest Electrodevelopment Laboratory of the Federal Bureau of Mines for determining minor amounts of tantalum.INTRODUCTIONThe development of corrosion-resistant alloys at the Northwest Electrodevelopment Laboratory prompted a review of the analytical chemistry of columbium (niobium) and tantahnn. Not only are these elements difficult to determine in small amounts, but tantalum especially lacks both sensitive and characteristic color reactions. Various phenolic compounds have been suggested as colorimetric reagents for tantalum, Quentin and Wagner (10, p. 24B) 1/ recommend the use of tannin. The use of pyrogallol was suggested originally by Krivoshlykov (6, pp. 59-60), whose method recently has been subject to a number of modifications (3, pp. 249-254; 5, pp. 1340-1344; 1, pp. 1803-18oi; 4, pp. 345-350). The yellow coloration produced by pyrocatechol in an oxalate solution containing tantalum may also be used to estimate tantalum ( 11, pp, ll-1-4-148) . The use of hydrogen peroxide has been recommended also (7, pp. 164-165; 9, pp. 926-931).Aside from a lack of specificity and sensitivity, the major failing of phenolic reagents is their susceptibility to air oxidation. The oxidation products are highly colored and absorb in the same spectral region as the tantalum complex. Holding reductants are not completely satisfactory in minimizing this effect. Increasing the acidity, while retarding the oxidation, has an adverse effect on the tantalum sensitivity."

Sep 1, 1956

By R. Clark Lantz, Charles Stanley, David E. Hinton

Morphometric examination of lung alterations following exposure to toxic and pathogenic substances is invaluable in detecting subtle changes which might otherwise be overlooked. Results, from evaluation of initial structural alterations, support and guide subsequent nonmorphological techniques and, when coupled appropriately, can lead to a better understanding of the pathogenesis of a disease. Morphometry is a technique which can be used to determine, quantitatively, the site, extent, development, and progression of a disease state. Determination of the extent of tissue and cellular involvement in the response to inhalation of silica has been performed in order to gain a better understanding of the development of fibrosis following inhalation of this toxicant. In addition, since silica has been postulated as one of the important pathogenic minerals in coal mine dust' it is important to understand the lung tissue response to silica prior to evaluating the effects of inhaled coal mine dusts. Male Syrian golden hamsters were placed in Hazelton 1000 inhalation chambers and were exposed to either filtered air (controls, n = 24) or filtered air plus 30 mg!m3 silica (Min-U-Si110,95%ofparticles < 5 um,n =24)for16hours per day, five days per week, for two weeks. Animals were returned to the animal quarters prior to subsequent tissue processing at 1, 4, and 12 weeks following exposure. This schedule was designed to allow time for the development of fibrosis. Lungs were fixed by intratracheal perfusion of ½ strength Karnovsky's fixative at a pressure of 20 cm H20 and tissues were taken for embedment and analysis at the light level. Determination of site, extent, and development of alterations was performed using a multitiered approach. Changes in large structures (airways, blood vessels) was determined prior to evaluation of changes at the septal tissue level. Data will be presented outlining the progression of changes. Results indicate the usefulness of morphometric analysis of lungs following inhalation of toxic substances in quantitatively defining the structural alterations.

Mar 1, 1989

By James S. Browning

The Bureau of Mines conducted laboratory batch and small-scale continuous flotation tests of weathered mica pegmatite ores from Alabama and North Carolina to determine the technical feasibility of recovering commercial-grade mica concentrates. A new anionic-catonic method was developed for recovering mica in the presence of clay slimes. In continuous tests, concentrates containing 98.1 percent mica were obtained from the Alabama pegmatite ore; the North Carolina pegmatite ore concentrates contained 97.2 percent mica. The recoveries were 83.8 and 81.6 percent, respectively.

Jan 1, 1965

By D. B. Gawthrop

"One of the properties of an explosive, of interest to the user, is its ability to transfer detonation across an air gap to another explosive charge. This Property is of particular importance with permissible explosives used in coal mines, since they are relatively insensitive to detonation when compared to many of the commercial dynamites used in metal mining.An essential characteristic of an explosive is that it shall always be sufficiently sensitive to propagate detonation completely. An insensitive explosive constitutes a hazard because of (1) the danger of drilling into unexploded portions of charges of explosives which have partially misfired, and (2) the likelihood of a low order of detonation, or the burning, of all or part of the charge in a hole prepared for blasting. The latter condition not only usually produces large volumes of poisonous gases, but it is particularly hazardous in gassy or dusty coal mines where explosions may result.The Bureau of Mines and manufacturers of explosives determine the sensitivity of explosives to detonation over an air gap by means of a [(halved-cartridge gap test,"" for which the ends of the cartridges of explosive exposed to one another, are cut off. Since in blasting, the crimped ends remain on the cartridges used, this investigation has been made to ascertain the effect of the crimped paper ends on the distance detonation is propagated over an air gap as compared with the propagation distances obtained when the crimped-paper ends are removed."

Nov 1, 1932

By A. B. Hooker, P. G. Guest, E. J. Gleim

"From time to time the United States Bureau of Mines has received reports of gas explosions alleged to have been caused by correctly assembled flame safety lamps. In most of the mines where the explosions occurred the lamp was in use at a working face where the velocity of the ventilating current would be relatively low. The inference has been that the lamp was correctly assembled but that the gauze became sufficiently overheated to ignite the surrounding atmosphere.As part of its routine investigation of flame safety lamps the Bureau of Mines subjects each lamp to a test in still and moving atmospheres to determine its safety. Heretofore, as long as the lam, successfully passed this and other tests no determinations as to the margin between success and failure were made; hence, in attempting to answer inquiries concerning the reported explosions it was found desirable to be able to give actual gauze temperatures as a measure of the comparative safety of lamps under various conditions. The previous laboratory tests of flame lamps in still mixtures were made in a chamber or ""gallery"" of relatively small volume where the lamps might have been subject more or less to the smothering effect of the combustion products. It was therefore decided to make a special series of tests to obtain the gauze temperatures of both bonneted and unbonneted lamps in still and low velocity mixtures, using a larger gallery to offset any smothering effect.These tests are believed to represent the first attempt at measuring gauze temperatures by means of themocouples. The results will not only be of interest but will also be helpful to many in determining the status of flame safety lamps relative to gas ignitions in mines."

Feb 1, 1929

[In selecting deposits of exploration projects, tabular deposits or large mineralized masses are favored because they may be explored systematically and because they afford the best opportunity for blocking out reserves in advance of mining, whereas irregular, small pipes and scattered]

Jan 1, 1941

[In selecting deposits for exploration projects, tabular deposits or large mineralized masses are favored because they may be explored systematically and because they afford the best opportunity for blocking out reserves in advance of mining whereas irregular, small pipes and scattered]

Jan 1, 1941

By W. A. Dunkley

During the past year and a half the Western United Corporation of Aurora , Illinois , has been distributing carburetted water ges from its Lockport , Ill . , plant , to an extensive territory , under an initial pressure ranging up to 90 lb.. per sq. in . The most distant distributing point on the system is at Harvard , Ill . , about 35 miles from the plant.. The territory supplied is approximately 85 miles long and 35 miles wide , the total mileage of rains being 1223 , or approximately 24 per cent of all the gas trains in Illinois outside the city of Chicago .

Feb 1, 1923

By B. I. Ferber

Sodium chloride aerosol was employed to determine respirator filter penetration in a manner suitable for use in Bureau of Mines approval and certification procedures. The aerosol was produced by an ultrasonic generator and treated to yield the proper conditions of relative humidity, particle size, and concentration. Respirator filters were exposed to the aerosol; filter penetration (down to 0.02 percent) was determined with a flame photometer. Results are comparable with those obtained in another laboratory using different equipment.

Jan 1, 1970

The panic bars (and associated linkages and electrical circuitry) that are defined in this document are a machine operator-actuated control for the emergency deenergization of the tram motors on self-propelled, electric and diesel face equipment; including haulage equipment such as shuttle cars. There are nine basic types of panic bars (and several variations) that are recommended in this document, but all of the panic bars arc characteristically of the &apos;fire door" type that is frequently encountered on outside exit doors of many public, and some commercial buildings. It is also the intent of the following panic bar designs that, when emergency brakes arc added to the face equipment machinery for which they arty required, that they be designed and hooked up so that actuation of the panic bar will result in automatic application of the emergency brakes (immediately following the deenergization of the tram motors). The following panic bar design requirements are a restatement of the proposed requirements defined in the Federal Register, requirements cited in "Guidelines for the Design and Installation of Devices for Deenergization of Self-Propelled Electric Face Equipment/Automatic Emergency Brakes" by C. E. Lester and J. D. Greenhalgh of MESA, and Bendix recommendations that were formulated as a result of discussions with personnel at the various machine manufacturers and underground coal mines that we surveyed, discussions with G. I. Judy (our consultant), etc:

Jan 1, 1974

By M. M. Tilman

The objectives of this research were to determine the practicability of using cobalt as a means of controlling the amount of ferrite in the micro-structures of semiaustenitic stainless steels, and to determine the effects of reduced ferrite content on mechanical properties of these steels. Cobalt additions of up to 3 weight-percent were made to type 17-7 PH2 (AISI 631) stainless steel. Ferrite contents were determined for alloys in the aged condition, and for alloys quenched from the hot working temperature. Ferrite can be completely eliminated from the microstructure of 17-7 PH stainless steel by additions of cobalt, but complete elimination of the ferrite phase results in lower tensile strength, yield strength, and hardness. Tensile properties, hardness, and impact strength were determined for aged material. A subzero temperature treatment before heattreating was necessary to obtain maximum strength in the alloys containing cobalt. Addition of 2 weight-percent cobalt enhances mechanical properties of 17-7 PH stainless steel.

Jan 1, 1968

By Wilbur I. Duvall

A linear array of shot and gage holes 30 feet deep in a granite outcrop was used to compare the size and shape of radial strain pulses produced in the rock when short cylindrical charges of cast composition B were detonated axially or at one end. The axially detonated charges produced radial strain pulses that had shorter rise times and larger peak strain than the strain pulses produced by end detonated charges.

Jan 1, 1965

By Joseph A. DeCarlo

The annual survey of the oven-coke industry by the Bureau of Mines, United States Department of the Interior, described in this report shows that 79 plants were operating in 22 States December 31, 1956. On that date 15,923 serviceable ovens existed, with a maximum total annual coke capacity of 79,965,100 net tons, and 631 new ovens were under construction. Their annual coke capacity was 3,307,300 net tons. The number of serviceable ovens in existence relates only to those capable of producing coke and does not include (1) any ovens that were blanked off or retired permanently in batteries that were operating December 31, 1956, and (2) ovens that had been demolished and were being rebuilt on that date. For this reason, the number of ovens at furnace plants reported by the Bureau of Mines at the end of each calendar year differs from the number reported for the same group by the American Iron & Steel Institute, as the institute includes ovens being rebuilt.

Jan 1, 1958

By R. J. Gajan

As part of its research program on secondary metal refining, the Federal Bureau of Mines has developed a fast method for determining aluminum, iron, copper, cadmium, and lead in zinc-base alloys. The new method is intended for use by trained technicians in laboratories with inexpensive equipment. It can be used either in the analytical laboratories of the many small plants that are characteristic of the secondary metals industry or in laboratories engaged in basic research to improve refining processes. A complete analysis for the foregoing elements can be made in less than 3 hours from a single sample in solution. The method is especially helpful when a small amount of sample is available. Aluminum and iron are determined spectrophotometrically and the other elements polarographically. The new method is now being used for control analysis in metallurgical research, and the results compare favorably with previously used spectrographic methods. Luke and Braun4/ described a photometric method for the determination of aluminum in zinc diecasting alloys in which the aluminum was complexed with Aluminon reagent (ammonium salt of aurintricarboxylic acid), forming a red lake. An adaptation of this method was used for determining aluminum. Beers law is obeyed between 0.01 and 0.06 milligram of aluminum.

Jan 1, 1961

By Howard F. Carl

"INTRODUCTION Talc is a hydrous magnesium silicate mineral found throughout the world in deposits of economic importance. This mineral occurs in different physical forms and varying degrees of purity, both of which affect its ultimate commercial usage. Talc is used in finely ground condition by the ceramic, paint, paper, rubber, cosmetic, and other industries. Most domestic talc production is of this type. Talc also occurs, although much less frequently, in massive, fine-grained, fairly homogeneous bodies; the impure varieties are the familiar soapstones, and the purer form is frequently called ""steatite."" Because of certain properties, the purest grades of this massive variety have a monetary value about 20 times that of the ground talc.One desirable property of this massive talc is its amenability to accurate cutttng, machining, and working in many ways, similar to a hard wood or soft metal, and then firing without warping or appreciable shrinkage into a hard, refractory ceramic body. Consequently, shapes that cannot be formed conveniently by molding and pressing can be produced readily with ordinary machine tools. When talc is fired to about 1,100° C., it is converted to a ceramic body with certain very desirable physical properties. This fired material has a hardness and toughness frequently superior to steel. It is a refractory and an exceptionally good electrical insulator. When formed from a high-grade talc essentially free from iron, it has unusually low dielectric losees, even at very high frequencies."

Feb 1, 1945

By Andrew B. Cecala

As deeper seams are continually mined, methane liberation will continue to increase and must be monitored effectively. To effectively monitor and develop appropriate control technology, methane-liberation patterns must be known. The Bureau of Mines recently completed a study to identify specific patterns of face methane liberation during long- wall mining. Both of the longwall faces surveyed had high methane liberation rates. At one longwall face, most of the methane was liberated during cutting of coal by the shearer mining machine. At the second face, a significant portion of methane was emitted from the face and floor. An effective methane-monitoring system would be different for each longwall panel because of the differences in how the gas is released along the face.

Jan 1, 1985

By A. L. Engel

[This report describes preliminary tests of samples from six deposits of oxidized copper ores .in Nevada. The tests for the most part were confined to laboratory-scale acid leaching to extract the copper.&apos;The exceptions consisted of flotation tests to demons&apos; ate the possibilities of treating the ore by that method. The samples tested were representative of oxidized copper ores from six counties in all parts of Nevada. The results obtained by the preliminary tests described were indicative of the extractions of copper to be expected, In the five leaching experiments, the approximate consumption of acid was also indicated.]

Jan 1, 1953

By I. L. Nichols

Volatilization of cesium from pollucite ore was investigated as an initial step in the production of purified cesium metal or cesium salts. High recovery of cesium and rubidium as chloride sublimates was accomplished by 2-hour roasts in a tube furnace using charges containing 1 part ore, 2 parts limestone, and 0.23 part calcium chloride. Recoveries of cesium in the sublimate product were 89.1, 92.9, and 95.2 pct, respectively, using 1,100° C and vacuum, 1,250° C with an air sweep, and 1,250° C without an air sweep. Most of the lithium, sodium, and potassium sublimed with the cesium and rubidium, but virtually none of the calcium, aluminum, and silicon in the charges was volatilized.

Jan 1, 1966