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By R. A. Strehlow

This is the final report for U.S. Bureau of Mines contract HO-122122, which was in effect from June 30, 1972 through January 4, 1976. The work resulted in the design and construction of a large laboratory scale coal dust burner and the use of this burner to study gaseous and coal dust flammability. A new technique for determining gas phase flammability was developed and the effect of solid and gaseous suppressants on the propagation of coal dust flames was studied. In addition, a technique for measuring the C/H ratio in the flame was developed and the C/H ratio that was measured in a coal dust flame on this burner showed that the burning process was preceeded by pyroysis of the coal dust. Both experimental and theoretical studies showed that radiative trans-port is very important to the propagation of a coal dust flame.

Jan 1, 1977

By John P. Hager

A special inlet system has been developed for a TOF mass spectrometer that allows the equilibrated high-temperature vapors from an atmospheric-pressure flow reactor to be leaked into the ion source of the mass spectrometer without undergoing any compositional changes. Using this flow reactor - mass spectrometer system and a modified transpiration system (one that allows for the carrier stream to be equilibrated with two different condensed samples) a series of fundamental vapor transport studies were undertaken. The results of these studies are summarized as follows: 1. The vapor species in equilibrium with condensed copper (I) chloride were determined to be Cu3C13, Cu4C14, and Cu5C15. The gas mixture is fifty percent tetramer near the melting point (703°K), with the percentage of tetramer decreasing with increasing temperature. The following thermodynamic results were obtained.

Jan 1, 1977

This chapter summarizes data on crude mineral production for the United States, its island possessions, and the Common-wealth of Puerto Rico. Included also are tables that show the principal mineral commodities exported from and imported into the United States, and that compare world and U.S. mineral production. Except for the mineral fuel commodities, the detailed data from which these tables were derived are contained in the individual commodity chapters of volume I and in the State chapters of volume II of this edition of the Minerals Yearbook. In October 1977, responsibility for the collection of data on mineral fuels-coal, petroleum, natural gas, and natural gas liquids-was transferred to the newly created Department of Energy. Although chapters covering these commodities will no longer appear in Volume I of the Minerals Yearbook, quantity and value data have been included in most of these summary tables to maintain statistical consistency in State and national value of overall crude mineral output. This shift in responsibility has also resulted in changes to the composition of the "Nonmetals" and "Mineral Fuels" groups in table 1 and table 2. The commodities-asphalt and related bitumens (natural), carbon dioxide (natural), helium, and peat-have been removed from the "Mineral Fuels" group, and are now included under the "Nonmetals" group. There has been no change in the components of the "Metals" group.

Jan 1, 1980

By John H. Soule

Appreciable quantities of sine and lead orus have been produced from the West. Pinos Altos district of Grant County, N. sex. This area was visited many times by engineers of the Bureau of ines. D. H. Johnson and 4. R. Storms visited the district in haren 1943 in connection with an acrenu road to toe wines. M. H. Storma again visited the area in July 1943 in connection with a hetals Feserve Corporation loan on the Routen-Thomas

Apr 1, 1948

By G. W. Jones

As a part of its general safety program the Bureau of Mines has investigated various means useful for the elimination or mitigation of the explosion hazards in connection with combustible gases incident to the mining industry. Information has been obtained relative to the explosibility of numerous simple and complex gaseous combustible atmospheres. Although experiments along this line have pertained largely to combustible gases in the mining and allied industry, considerable information has been obtained relative to the explosive hazards of combustible gases and vapors used as anesthetics.

Jan 1, 1939

By G. W. Jones

As a part of its general safety program the Bureau of Mines has investigated various means useful for the elimination or mitigation of the explosion hazards in connection with combustible gases incident to the mining industry. Information has been obtained relative to the explosibility of numerous simple and complex gaseous combustible atmospheres. Although experiments along this line have pertained largely to combustible gases in the mining and allied industry, considerable information has been obtained relative to the explosive hazards of combustible gases and vapors used as anesthetics.

Jan 1, 1939

By Allan E. Martin

As part of a comprehensive investigation of tae mechanism of desulfurization of iron and steel by slags, the Blast Furnace Studies Section, Metallurgical Division, Bureau of :lines, in cooperation with the Institute of Technology., University of Minnesota, has made a study of the forms in which sulfur occurs in blast-furnace slag. This report presents data on the three sulfides most important in iron smelting, namely, ferrous sulfide, manganous sulfide, and calcium sulfide. The tendency of these sulfides to form colloids in the molten slag was determined by an examination of quenched samples with an ultramicroscope. Vogt5/ conducted experiments on sulfide silicate melts and examined synthetic blast-furnace slags in a partly crystallized condition. His conclusions were that FeS, CaS, and MnS, or isomorphous compounds, such as (FeXCay)S and (MnxCay)S, were precipitated from the melt, depending on the composition of the slag. In all specimens sulfides were visible and were spherical.

Jan 1, 1941

By Lisa A. McDonald

The environmental compliance process affects all aspects of hardrock-mining operations, from exploration through post-closure. The primary components of the environmental compliance process are requirements under the National Environmental Protection Act of 1969 (NEPA) and the permitting requirements associated with various other federal, state and local laws. This study considers the Greens Creek Mine and the development of two other projects (Alaska-Juneau & Kensington). These mines were used as the foundation for a case study of the impacts of the environmental compliance process on hardrock-mining activity in Southeast Alaska. The case study presents the institutional and legal requirements, followed by a discussion of the impact of this process on the production and timing of the three mines. The results of this preliminary study reveal some interesting findings, some expected and others unexpected, regarding the impact of the permitting process on the exploration, development and (proposed) operation of the three mining projects in the Juneau area. Determining the cost of compliance with these requirements is an important step in evaluating the appropriate course of action to protecting the environment while providing the necessary raw materials needed for society. This preliminary study highlights the initial starting point for such an analysis.

Jan 1, 1992

By Ronald F. Balazik

[This Bureau of Mines study is intended to identify and evaluate potential effects of impending large-scale U. S. rail line closings (abandonment) on domestic nonfuel mineral industries. This is the first nationwide study of rail abandonment impacts focused on nonfuel minerals. The analyses presented is based principally on a survey of 200 rail freight records and on statistical tests that correlated 2,000 points in the Bureau's Mines Industry Location System (MILS) with 700 prospective abandonments throughout the United States. The conclusions derived from the analysis can be useful in evaluating proposed national rail abandonment policy rind legislation regarding nonfuel miner it shipping. Among these conclusions are the following: (1) Certain mineral materials (especially fertilizers) are likely to account for a large percentage of the rail traffic affected by abandonment in the next few years, but the total tonnage- involved will be small; (2) abandonment will adversely affect some mineral shippers, particularly local smart haulers; and (3 abandonment could significance reduce the opportunity to develop new resources or reopen defunct mining facilities. Despite these problems, however, the data examined in this study do not indicate that current abandonment trends will cause widespread disruption 01 domestic nonfuel mineral shipping.]

Jan 1, 1980

The objective of this study was two-fold: 1. To perform a world literature search pertinent to the analysis, selection and design of hoisting systems and their components and to codify the search into a literature compendium. The search resulted in a technical data file of over 1500 hard copy items. The compendium index was also suitable for establishing a comprehensive computer-loaded data base on the subject. 2. To develop a comprehensive system of guidelines to cover salient aspects of analysis, selection and design of electrical, mechanical and structural components of a hoisting system with a view to establish parameters for maximum safety and efficiency of operation, installation and revision of the system. 3. Considerations in the mine shaft layout, design, sinking, outfitting, testing and commissioning are set forth against the background of requirements of applicable parts of Code of Federal Regulations, Title 30.

Jan 1, 1988

By H. A. Wright

This report assesses the economic, legal, institutional and technical factors that affect the current and future status of implementation of mine monitoring systems in the United States. It begins with a description of a poll of the Mining Production Research Committee and the Mine Monitoring and Communications Committee of Bituminous Coal Research that was conducted to establish industry monitoring needs and constraints. Existing systems in the United States and foreign countries are then reviewed and compared with the requirements set forth by the industry committees. At the same time, state and federal mining laws are reviewed, and equipment currently available from suppliers of mine monitoring systems and components is discussed. A framework for cost/benefit analysis is established and a series of case examples for various monitoring functions are presented. The total values of the market for mine monitoring systems in 1980 and 1990 are estimated on the basis of industry statistics and system cost estimates.

Jan 1, 1982

By S. H. Ash

Unusual mining conditions prevail in the State of Washington because the majority of the coal seams lie on extra steep dips, and the roof and floor of the seams are of such a character as to require an excessive amount of timber- ing. The seams as a rule give off a considerable amount of methane, which makes good ventilation imperative. Due to physical conditions, supervision is costly and travel about the workings is difficult. Because of the facts stated, the accident rate has been above the average, and for some time considerable thought has been given the idea of making promotion of safety in and about the mines a responsibility to be shared equally by the employees and the management. With this idea in mind the legislature of the State of Washington, turing March, 1927, passed laws providing that safety committees be selected to function at the coal mines of the State and at the same time recognizing the fact that first-aid education is an integral part of any safety movement; legislation was passed making it mandatory to have all persons in and about the ines trained in first-aid administration. The provisions of the State mining law3 are as follows: "In every mine a general safety committee shall be selected, composed of the mine superintendent or manager of mines, one man selected by the employees or any association of employees in or around said mine, and a third member selected by these two. "The general safety committee shall elect one of the members to act as chairman and one to act as secretary. The duties of the chairman shall be to preside at all meetings of the general safety committee, enforce its rules and regulations and see that its business is conducted in a prompt and business-like manner. The secretary shall keep an accurate written record of the proceedings of all meetings, conduct its correspondence and post notices of regular and special meetings and other matters pertaining to safety. The duties of the general safety committee shall be to investigate all serious and fatal accidents; make bi-monthly.

Jun 1, 1930

By J. S. Miller

This report presents a complete coverage of results from Bureau of Mines preliminary research and the field application of explosive fracturing techniques to prepare oil shale for in situ recovery of shale oil. Small-scale surface tests were conducted to determine the feasibility of using a nitroglycerin-base explosive for creating rock fractures. Prior to underground testing, surface and near-surface tests with liquid explosives showed that explosions in sheetlike layers simulating underground fractures would propagate effectively. Successful surface experiments were conducted using layers of explosive placed between glass plates and explosive-saturated sand confined in small-diameter metal tubes. The tests in glass-plate reservoirs and metal tubes demonstrated that nitroglycerin would detonate and the explosion would propagate in cracks as thin as 1/32 inch and through distances up to 12 feet. In a shallow field test, nitroglycerin was detonated in a vertical crack in limestone and produced extensive fracturing. Explosive fracturing tests were performed in oil shale formations on seven sites near Rock Springs, Wyo. The procedures included (1) displacing and detonating nitroglycerin in natural or hydraulically induced fracture systems; (2) detonating nitroglycerin in wellbore shots; (3) displacing and detonating nitroglycerin in induced fractures followed by wellbore shots using pelletized TNT; and (4) detonating wellbore charges using pelletized TNT. The research on oil shale formations demonstrated that nitroglycerin displaced in a natural or hydraulically induced fracture would detonate, and the explosion would propagate through the explosive-filled fracture. Shooting a pattern of wells in oil shale at 100-foot depth with wellbore charges of pelletized TNT developed a satisfactory interwell fragmented zone. Tests performed on other sites at depths to 385 feet caused fragmentation of rock around the wellbore and provided interwell communication. Fourteen methods used to evaluate the extent and degree of fragmentation in the explosive fractured oil shale are discussed.

Jan 1, 1974

By G. W. Jones

Fires in anthracite refuse banks are troublesome and may become exceedingly costly to combat. Instances are known in which refuse-bank fires have grown to such magnitude that entire mining properties have been endangered. In one instance4/ a refuse-bank fire cost the mine management several hundred thousand dollars to extinguish. The exact number of fires formerly existing or now active in the anthracite region of Pennsylvania is not known. There are hundreds of anthracite refuse banks in this region, some very high and large in area, that have never caught firs, although a few are over 50 years old. This would indicate that spontaneous ignition of the material in these banks is improbable, a conclusion confirmed by recent laboratory research.

Jan 1, 1939

By G. W. Jones

Fires in anthracite refuse banks are troublesome and may become exceedingly costly to combat. Instances are known in which refuse-bank fires have grown to such magnitude that entire mining properties have been endangered. In one instance4/ a refuse-bank fire cost the mine management several hundred thousand dollars to extinguish. The exact number of fires formerly existing or now active in the anthracite region of Pennsylvania is not known, There are hundreds of anthracite refuse banks in this region, some very high and large in area, that have never caught fire, although a few are over 50 years old. This would indicate that spontaneous ignition of the material in these banks is improbable, a conclusion confirmed by recent laboratory research.

Jan 1, 1939

By Paul Meadows

This Bureau of Mines report presents operating practices and results of pressure maintenance and secondary recovery by water injection or by water injection supplemented by gas injection. Particular emphasis is placed on the results of water injection, which is the principal oil-recovery method employed in projects covered by this report. No attempt is made to study gas-injection projects or operations that are considered water-disposal projects. Also, this report does not include water-injection projects that have not been in operation long enough to evaluate results. Figure 1 is a map of north Louisiana showing the geographical locations of the projects included in this report. Most of the data used in this study were supplied by unit operators, operating companies, and the Louisiana Department of Conservation. Reservoir information and recovery data are generally those supplied by the operators, but include revisions where deemed necessary.

Jan 1, 1962

By J. R. Ross

A reconnaissance for sources of scandium and a metallurgical investigation of recovery methods for byproduct scandium from uranium mill solutions were conducted by the Bureau of Mines. The work on scandium was undertaken to obtain information on domestic resources and to explore and develop recovery procedures in consonance with the Bureau's long-range program for conservation and wise utilization of mineral resources. The element scandium is widely distributed in the earth's crust in trace amounts, but it seldom occurs as an important constituent in any mineral. An exception is thortveitite, (Sc,Y)2 Si207) a rare mineral that contains various amounts of scandium and yttrium and may contain up to 42 percent scandium oxide (SC203). Knowledge of the chemistry of scandium has expanded rapidly in recent years (1, 4, 9)4 but only fragmentary information is available about the metal because it is still largely a laboratory curiosity without established uses (2, 3). A recent study shows some of the physical proper-ties of the metal are (1) density of 3.05 grams per cubic centimeter) (2) melting point of 1,540° C, (3) hexagonal close-packed structure) (4) hardness of about 50 Brinell (500-kilogram load), and (5) an alloy behavior similar to yttrium and rare-earth metals (2). The price of $2,850 a pound for scandium oxide of 99.9 percent purity and $2,700 a pound for oxide of 99 percent purity reflects the scarcity and complex chemistry of the element.

Jan 1, 1962

By W. T. Abel

The rate of the steam-carbon reaction, which is of fundamental importance to coal gasification, was determined by passing steam over graphite specimens suspended in an electrically heated tube. The measurements were made at 1,900° to 2,400° F. and at steam-feed rates of 0.1 to 2.0 moles of steam per mole of carbon per minute. At the maximum steam-feed rate, the reaction rate of carbon ranged from 0.4 percent per minute at 1,900° F. to 7 percent per minute at 2,400° F. Up to about 2,200° F., the steam-feed rate had only a slight effect; above this temperature, it limited the reaction velocity when the final mole fraction of steam in the reaction products was much less than 1.

Jan 1, 1962

By Virgil A. Marple

The objective of this contract was to investigate time-integrated and real-time methods for determining the diesel exhaust particulate concentration in underground mines, in particular, coal mines. The microorifice uniform deposit impactor (MOUDI) is recommended for obtaining the time-integrated measurement of the size distribution. The mass concentration of diesel exhaust particles can be obtained from the particle size distribution of mine aerosols. On a mass basis, diesel exhaust particles are primarily in the submicrometer size range while coal dust particles are larger. Size distribution measurements made in the laboratory and in three underground coal mines exhibited two distinct modes with the diesel exhaust particles in the smaller particle mode and the coal particles in the larger particle mode. The point of separation between the two modes occurred in the 0.7 to 1.0 pm size range. The separation was found to be independent of mass fraction of the diesel exhaust particles, particle concentration and sampling site. Methods recommended for further consideration as real-time monitors of diesel exhaust aerosols in mines are photometers and filter pressure drop techniques. A preclassifier would be required in both cases to separate the larger dust particles from the sample. The Metrex Mineral/Diesel Photometer should also be investigated further once the electronics problems are eliminated.

Jan 1, 1986

By A. C. Fieldner

ONE of the important functions of the Bureau of Mines is the, analysis of coal from every coal-mining State and Alaska. These analyses are being published for use of Government officials and the public. In connection with analytical data showing composition and quality of coals of the States, consumers, Producers, and the general public will be interested in a brief description of the geologic structure of the coal basins, typical mining conditions in the several districts, and the principal economic data of the industry. These publications have therefore heel) designed to include such features to present concisely the principal facts regarding occurrence, reserves, duality, characteristics, production, and uses of coals of each producing State.

Jan 1, 1952