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By Yin Guangzhi, Song Zhenlong, Li Minghui, Li Wenpu, Deng Bozhi

"Darcy's law is widely used to describe the oil and gas flow characteristics in the multi-pore media reservoir. However, the low-velocity non-Darcy flow of oil and gas occurs in the multi-pore media reservoir under low permeability conditions. Meanwhile, the high-velocity non-Darcy flow of oil and gas occurs in the multi-pore media near the wellbore. The gas flow velocities in coal in different deformation stage under different gas pressure gradient were tested and the relationships between gas flow velocity and gas pressure gradient were discussed, which can help us to investigate the transformation conditions of gas linear flow and gas nonlinear flow in coal. The results showed that the gas flow in the coal under low effective stress environment can be described by Darcy's law. The low-velocity non-Darcy flow of gas gradually occurred and the start-up pressure gradient increased in the coal as the effective stress increased. The low-velocity non-Darcy flow of gas also occurred in the coal at the yield deformation stage, however, the start-up pressure gradient decreased as the effective stress increased in this stage. In post-peak stage, the highvelocity non-Darcy flow of gas occurred in the coal under low effective stress environment. The gas flow in the coal gradually returned to be Darcy flow as the effective stress increased. The mechanism of the phenomenon is discussed based on the experimental results. The research results can be used to guide well test analysis and prediction of oil-gas production. INTRODUCTIONThe oil and gas flow in original multi-pore media reservoir are usually regarded as steady and linear processes and can be described by Darcy’s law. However, the low-velocity non-Darcy flow of oil and gas occurs in the multi-pore media reservoir under low permeability conditions. Meanwhile, the highvelocity non-Darcy flow of oil and gas occurs in the multi-pore media near the wellbore or workface. The gas flow in the multi-pore media even may be unsteady under some conditions such as gas emission and outburst.The phenomenon of underground water low-velocity flow in clays was deviated from Darcy’s law was found in the end of the nineteenth century (King, 1898). The deviation from Darcy’s law was later reported and investigated more (Swartzendruber, 1962; Miller and Low, 1963). These researches revealed that the start-up pressure gradient exists under low permeability conditions. Klinkenberg (1941) proposed that the permeability constant as determined with gases is dependent upon the property of the gas, and is a linear function of the reciprocal mean pressure. This effect can be explained by taking into account the phenomena of slip, which are related closely to the mean free paths of the gas molecules."

Jan 1, 2015

By Yulin Zhou, WenFeng Li, Wen Chen

"In this article, with the help of the X-ray photoelectron Spectroscopy (XPS), a modern test method, all the characteristics of the chlorite,and adsorption collector A6 on the surface of chlorite have been studied. There exist abundant carboxylic C-O and C=O structures in the Carbon XPS atlas with strong adhesive ability after the reaction between new collector A6 and chlorite, which indicates that the ring structure and ether-base functional groups can strengthen the reaction between collector A6 molecule and chlorite surface. The results of XPS analysis indicate that the photoelectron spectroscopy peaks of Mg2p and Al2p moved towards low energy after collector A6 absorbed on chlorite surface, which indicates that chemical bonding through electron cloud transfer happened between collector A6 and Mg, Al ions of chlorite surface. The chemical reaction promoted the adsorption of A6 on chlorite surface and eventually improved the ability of A6 to float and collect chlorite.INTRODUCTIONThere are a large amount of iron-bearing silicate minerals such as chlorite in different types of gangue minerals in iron ore from different areas besides quartz (Yingyong et al, 2012; Qiang et al, 2009). There always exist Mg2+, Al3+ Fe3+ and other metallic ions due the isomorphic replacement among the irons of this kind of minerals. The dissolution often occurs on the surface of minerals with abundant metallic ions during grinding process, and some ions are exposed on the surface, such as Mg2+, Fe3+, Al3+, Si4+, which can increase the surface electrical behaviour of iron-bearing silicate minerals (Wanzhong & Chuanyao, 2002; Yuping et al., 2007), making it easy for the surface to react preferentially with the depressants such as causticizing starch which making it impossible for the surface to reach with conventional anionic fatty acid collector (Mowla et al, 2008). Thus, the beneficiation efficiency is dramatically decreased and the improvement of concentrate grade becomes very difficult. The conventional aliphatic acid collector has some defects such as poor selectivity, poor low temperature resistance, sensitive to water hardness, etc. Thus, the addition of synergist (Liu, & Yu, 2015) or other compound reagents (Zhou et al, 2015) can promote the adsorption of reagents to mineral surface, and improve the collecting capacity and selectivity of aliphatic acid collector to minerals. The addition of polar group to nonpolar group in aliphatic acid can improve the water solubility, dispensability and hard water resistance (Tian et al, 2013). The nitrogen atoms in amid ate aliphatic acid collector can adsorb on mineral surface by itself and supply coordinate electron which can form chelating keys to improve the collecting capacity of collector. There exist coordinate electron in oxygen atoms of ether acid collector, which, along with the oxygen on carboxyl compose chelate with metal (Luo et al, 2015). There are also exist some opinions that the ether acid can arrange into similar crown ether structure which can absorb on mineral surface. A new alicyclic unsaturated ether acid compounds collector A6 is adopted in this paper, the structural formula is listed in Figure 1. The A6 has a strong collecting ability to chlorite with strong water solubility and low temperature resistance."

Jan 1, 2016

By Yu Chen, Charlie C. Li

The application of rock bolts for the stabilisation of underground openings needs a good understanding of the response of the bolts during rock excavation. The pull-and-shear performance of two types of rock bolts—that is, the fully encapsulated rebar and the D-Bolt—has been studied both experimentally and numerically. The rock bolts were tested under a pull-and-shear load at five displacing angles (i.e., 0°, 20°, 40°, 60°, and 90°), and at the same time, the strains on the bolts were monitored during testing. The two types of rock bolts have similar loading capacities, while the loading angle has obvious influence on the deformation capacity of the D-Bolt. The ultimate total displacement of the D-Bolt decreases from 140 mm under pure pull loading to 70 mm under shearing. The displacement capacity of the rebar is not significantly influenced by the loading angle but remains at a quite low level from 29 to 53 mm. The D-Bolt yielded in a longer section the rebar bolt under pure shear. A trilinear material model was used to simulate the strain hardening behaviour of the bolt steels in the numerical code FLAC3D. The numerical results show that the axial load in the bolt decreases exponentially with the distance from the loading position for the rebar bolts, but it remains constant in the bolt sections between the anchor positions for the D-Bolts. When the bolt is subjected to a lateral load, shear stresses are created on the D-Bolt surface within a short distance from the loading position.

Jan 1, 2015

By F. P. Hassani, A. Hara, M. Momayez

To be competitive on the international market, the Canadian mining industry must reduce its costs, increase its productivity and maintain a high standard of safety. There is a great need today for improved methods that would allow the detection of geological structures in advance of mining to reduce dilution and the monitoring of underground structures to increase safety. This will facilitate planning for optimum exploitation of the mine and to increase production at lower costs. This paper discusses two examples of more efficient mine planning using new technologies such as Ground Probing Radar (GPR). In Kidd Creek mine, GPR technology was used at the 2500and 2600 levels to (1) monitor the stability of the sill pillar; (2) locate the presence of disseminated sulphide pockets in the sill pillar for extracting the mineral content; (3) monitor the stope backs and wall structures to evaluate the effect of on-time filling sequences; and (4)assess rockfill quality in terms of the presence of voids and fractures within the rockfilled areas. In the New Brunswick coal mine in Minto, GPR was used along with core log data to map and construct a 3D block of a section of the bench showing the relative position of different layers overlying the coal seam.

Jan 1, 1996

By R. B. Paine, B. M. Wright

"Syncrude has entered a new era involving the use of pipeline slurries to convey oil sand to the extraction plant. Hydrotransport operations and base plant operations encounter vast performance differences when processing different types of oil sand. This paper describes the hydrotransport process, its history at Syncrude, methods of describing the source ore characteristic and plant performance. The use of this information within Syncrude and how it will be managed on an ongoing basis will also be described. IntroductionThe Syncrude Canada Ltd. site is located 43 km north of Fort McMurray, Alberta, on the Athabasca oil sand deposit. The Syncrude operation consists of mining, extraction, upgrading, utilities and other support facilities. The mined ore is sent to the extraction plant where water and solids are removed from the bitumen. The bitumen is then sent to the upgrading plants to be further processed into Syncrude Sweet Blend (a light sweet crude oil). Syncrude produced 73.5 Mbbls of Syncrude Sweet Blend in 1996 and produced 75.7 Mbbls in 1997. Prior to 1993, Syncrude moved ore from the pit to the extraction plant via four dragline / bucketwheel/ conveyor systems. These systems, supplemented by auxiliary ore crushers, satisfied the feed requirements of the extraction plant. Ore was conveyed to the control tower area and placed in the dump pocket via four radial stackers. Various blending scenarios occurred at this point, using feed from the four mining quadrants and from auxiliary feed crushers. Upon entering the extraction plant from the base mine, the oil sand passed through a series of tumblers where it was mixed with hot water and caustic. It then proceeded to one of four primary separation vessels where bitumen froth was floated off and the middlings and coarse fractions were recombined and sent to the tail oil recovery vessels, or TORs, for further processing."

Jan 1, 1999

By A. K. Debnath

The water resource is key to survival of the mankind and this resource is now becoming critical in many parts of globe including India. As per an assessment of Central Ground Water Board (CGWB) of India, a huge shortfall of about 58 billion m3 of water is anticipated by the year 2050. In order to counter this shortfall, there is thrust from Government of India to adopt water conservation measures. National Environment Policy, 2006 of Government of India also stresses upon the need to take up water conservation measures for water security of the country. The coal mines in India provide an excellent opportunity to take up water conservations measures therein. The mine water is not acidic unlike western countries and it conforms to the prescribed regulatory standards. This nature?s gift is utilized in Coal India Limited by allowing mine voids to get filled with mine water. The net recharge potential of the opencast mining area is found to be about 5% in comparison to 2% in non-mining area offering good prospects for ground water recharge. The seasonal rainwater is also diverted into mine voids left at the end of mining operations which act as huge reservoirs/ pit lakes for storage of the water. They also serve as surface water bodies for recharging of water table in the surrounding areas. The area and space left from where coal has been extracted completely in underground mines and will not be entered by any man or machinery after the extraction, called goaf, are also potential source of water conservation. These additional water resources created are being utilized for meeting the industrial, domestic, irrigation and other requirements of the projects and local communities eliminating the need to tap other fresh water resources including ground water. Presently, 75% of the water demand of the coal mining project is being met from the water stored in the mine pits. In future, CIL is likely to create about 3.3 billion m3 of water resource, on an average, in its opencast mines alone. In the mine closure plan of opencast mines, the last cut is proposed to be developed into water body for recharge of ground water and creating additional water resources. A clean potential source of potable water is thus developed after mine closure. This will ensure water security of the country.

Aug 1, 2013

By A. McLean, Q. R. Yang, Y. D. Yang, G. F. Zhang, P. Wu

A considerable amount of waste slag from the pyrite roasting process is discharged every year. Recovery of iron from the waste slag is of great interest for comprehensive use of mineral resource, reduction of environment impact and improvement of economical benefit to related companies. The objectives of the present work are focused on: (1) Compare various procedures for recovery of iron from the waste slag and select a best procedure for industrial trial which is roasting of the waste slag under reducing condition followed by magnetic separation; (2) Investigate the optimum conditions for maximum recovery of iron from the waste slag. The experimental result shows that under the treatment condition found in this work about 36 to 40% of the iron oxide was recovered from the waste slag, where the iron content in the concentrate is 57%. The total recovery ratio of iron, up to 70%, from the waste slag was achieved. After the treatment, sulphur content in the waste slag was reduced significantly and gangue materials, such as SiO2, Al2O3 and TiO2, were reduced effectively.

Jan 1, 2011

By Y. Jin, H. You, H. Pang, B. Lin

Successful application of steam assisted gravity drainage (SAGD) on the recovery of land facies ultra-heavy oil in Xinjiang oilfield depends largely on shortening the preheating period with the aid of the micro-fracturing technology, which is conducted through controlled water injection to a pair of horizontal wells to create homogenously distributed microcracks in the zone between the two wells. The numerical simulation of this mechanical process is yet to be investigated. Up to date, there has been research work on rock mechanics during the SAGD production period of marine deposited ultra-heavy oilsands, but the counterpart research on land facies ultra-heavy oilsands of Xinjiang oilfield is left undone. In this regard, this study is attempted to perform numerical simulation of the fracturing process on land facies unconsolidated oilsands. With this objective, the study first investigates geological and physical identification of the field collected cores, then carries out mechanical analysis on laboratory triaixal test results, based on which numerical simulation of the fractured zone is performed. The simulation is applied through a finite element platform adopting extended Drucker-Prager constitutive model, with the parameters determined by experimental work. It is verified that hydraulic fracturing of unconsolidated oilsands generates a microcrack feature in terms of a dilative zone instead of linear apertures. The extent to which the fractured zone propagates is visually demonstrated based on the magnitude distribution of equivalent plastic strain or volumetric dilation. Evaluation of the connection of injection and production wells can possibly be determined by the expansion of the saturated region around each well. Finally, the implications on the efficiency of hydraulic fracturing in stimulation of the pay zone are investigated.

Jan 1, 2015

By Louis Frost

The coal-mining industry of Nova Scotia, particularly of the island of Cape Breton, today faced as no other industry with economic problems calling for progressive engineering with production on an economic basis, must soon enter upon a phase of reorganization wherein all factors conducive to the cost of producing coal relative to the prolongation of the life of the collieries with the ultimate winning of the maximum submarine area must be closely reviewed. Bearing this in mind and applying the process of elimination to coal-mining costs generally, we are left with only three channels through which we may approach the problem of cost reduction in producing coal: (a) intensive mechanization (b) reduction in the cost of labour (c) reduction in the cost of materials. Assuming that mechanization has reached an economic stage and that labour costs have reached an economic limit, we must turn our attention to the general material costs, which may be classified as 'live' and 'dead' costs. The former take in all things which can be accredited with a fractional depreciation and written off the balance sheet over a period of years. On the other hand, the ?dead'costs-of which the cost of supporting the underground workings form part must be completely written off: for these, no return may be expected, other than the economic return in the reduction of the cost per ton of coal produced.

Jan 1, 1928

By W. E. Newton

THE following notes are offered primarily to show that industrial minerals or their products have a much more important place in the metallurgical industry than is perhaps generally realized, and with the hope also that some statement by the metallurgical consumer of the relative merits of various materials for particular requirements or services will l;>e of value to the industrial mineral producer. These notes are not in any way presented as complete. Also, some of the statements made may be debatable. The grouping adopted is as follows: (1) Refractories; (2) Fluxes; (3) Construction materials; and ( 4) Miscellaneous applications. Fuels are not dealt with in the present paper. REFRACTORIES GENERAL: Refractories are materials which will withstand high temperatures with-out melting or becoming markedly soft or pasty. While their primary function is to withstand heat, they are usually called upon to resist one or more of the following destructive influences: abrasion, pressure, corrosion by slags or fluxes, and rapid changes in temperature. Refractory materials may be conveniently divided into three classes: (1) Acid refractories-consisting of silica, or containing silica as their chief constituent. They combine more or less readily with metallic oxides, forming silicates, and are hence termed 'acid'. The most important of these are quartz, quartzite, siliceous sand, tripoli, Dinas rock, and ganister. Most fire-clays, although generally considered neutral sub-stances, contain relatively small amounts of free silica and are, to that extent, acid. (2) Neutral refractories-the term is merely relative in most cases, since, at high temperature, many of the refractories that are classed as neutral will react chemically with a strong base, functioning as a weak acid; or, conversely, with a strong acid, functioning as a weak base. Chrome and graphite are the most nearly neutral of all the commonly used refractory materials.

Jan 1, 1936

This paper discusses three case studies conducted at Highland Valley Copper mine (HVC) that illustrate operational improvements and insights which resulted from using the McGill University gas dispersion sensors. In the first study, the superficial gas velocity (Jg) sensor was used to implement a gas profiling control strategy for the rougher, scavenger and first cleaner cells in the Cu/Mo separation circuit. The data showed a 40% reduction of down-the-bank Cu recovery at constant Mo recovery which resulted from operating the cells at the target profiles. In the second study, the bubble size analyzer was used to better understand two mechanisms of bubble formation in the two flotation columns that make up the final Mo cleaning stage: the conventional rubber-sleeve sparger and the Microcel(TM) system. The data showed a considerable reduction of bubble size in the Microcel column which resulted in a significant increase in concentrate quality (1-2% Mo absolute) and a dramatic (4-5 fold) increase in concentrate production rate compared to the typical operation. The estimated economic benefit resulting from the improved column flotation operation was an overall 4% increase in Mo circuit recovery. In the third study, real-time measurements obtained from the gas holdup and bulk density sensors were used to infer the pulp density (% solids) in a rougher cell of the bulk flotation circuit. Validation tests demonstrated that this approach provides reliable pulp density measurements. Although promising, more work is required before implementing this approach at HVC.

Jan 1, 2009

By H. S. Wilson

"The property owned by the Lamaque Mining Company comprises a group of forty-four claims and fractions occupying an area of about 2,458 acres, in west-central Bourlamaque township, Abitibi county, Quebec. It is on ,the outskirts of the towns of Bourlamaque and Val d'Or, about 70 miles east of Noranda, near the eastern end of the belt of greenstones of Keewatin and Timiskaming age that extends eastward through Kirkland Lake into northwestern Quebec, terminating in Haig and Jurie townships 40 miles to the east.The claims on which the orebodies occur were first staked in 1923; No. 3 vein was discovered the following year. The original discovery was made by R. Clark in 1923. This was a small quartz vein containing a pocket of coarse gold on the north side of a hill near the northwestern corner of block 3. It is said that all the gold was removed in one shot in blasting into the vein; elsewhere it was barren. A picket line was then run west along the strike of the vein, which occupied a narrow shear zone, and about 2,000 feet west, in prospecting on either side of the picket line, a large boulder of quartz and tourmaline containing visible gold was found. This led to more intensive prospecting by trenching in the vicinity with the result that the No. 3, or 'float' vein, about 250 feet north of the boulder, was found. Due to low ground this vein was exposed in only one trench. The only other important vein found on the surface was the No. 1, or H, vein, which was exposed in several places by stripping and trenching, but it did not carry appreciable amounts of gold."

Jan 1, 1954

By J. L. Llanca

The New Level Mine project (NLMP), the planned underground expansion of the El Teniente mine in Rancagua, Chile, is expected to reach a daily extraction rate of 137 to 180 ktpd upon achieving full capacity. Production is planned to start in the year 2017 and the current plan is to meet that target through two development phases, from the year 2012 to 2014 and from the year 2015 to 2017. To achieve the 2012 to 2014 underground development schedule, the ventilation requirements have been estimated in the range of 189 m3/s (400 kcfm), and cannot be made available without significant modifications to the current system of El Teniente. As a result, a certain number of alternatives were explored to find a solution to this shortfall, for example, adding raises to generate parallel airways and installing fans to reinforce the current ventilation system. From the alternatives studied, the installation of a second main fan (system) in parallel to an existing one was identified as the best solution, and selected for implementation, however the location was not ideal and there were concerns as to the operation of both fans once the second fan was installed. This paper presents the study used to estimate the operational points of both the current and the new fan, and to justify the parallel installation of the additional main fan. An additional computational fluid dynamics study was undertaken to validate the operational point, given the particular geometry of the fan?s location and placement, to guarantee a stable operation of the fans. Finally, the protocols arising out of this work for starting the fans, and operating them in parallel to avoid generating a stall condition and damaging the investment are discussed.

Aug 1, 2013

The extractive industry has the potential to impact the health and well-being of workers, families and surrounding communities. In the current environment of social performance, project planning considers that activities should be conducted in the best environmentally, socially and economically acceptable way across the development cycle (i.e. from exploration ? post-closure). In this context, health impacts of mining can be mapped and extend over the Life of the Community and can encompass worker injury and disease, exposure to communicable and non-communicable diseases, and health outcomes specific to family and community health and well-being outside the fence. To contribute to an emerging field focused on Health and the Extractive Industry, this paper reviews and compares health activities extracted from social and environmental reports published by selected major mining, oil and gas companies with operations in Australia and Canada. The objective of this review is to map corporate approaches to public health management across our previously developed Life-of-Mine within Life-of-Community (LOMLOC) framework in order to identify and compare trends and behaviour in corporate health investments across the project cycle, as well as identify the level of prevention targeted by this investment activity (i.e. primary, secondary and tertiary prevention of detrimental health impact). With the extractive industry facing ongoing rapid growth worldwide, this paper provides preliminary comparative information about corporate health spending by some companies in Australia and Canada. This information serves as a resource for minerals industry managers, civil society and regulators regarding current health management approaches in this sector.

Aug 1, 2013

By T. C. Crosby

"Grinding has a marked effect on concentrator recovery and operating cost, and improved operation through automatic control can enhance plant performance. The correct application of automatic control can only be accomplished after the basic process variables and their effect on mill operation have been defined. This paper develops a control system for a closed circuit grinding system. Typical control systems, such as those for feed, water flow, level and circulating load, are discussed. A method of determining controllability, using the calculated reaction curve technique, is outlined. Various successful automatic grinding control applications are discussed and future possibilities are outlined. Although this paper primarily deals with closed wet grinding• circuits, the principles involved can be readily applied to other processes."

Jan 1, 1967

By W. D. Mulholland

"I ASSUME that any effort on my part to deal with the question of the importance of the mining industry is going to be largely an exercise in preaching to the converted, but there are one or two aspects that I'd like to particularly mention.The first is that, in terms of almost all factors, the mining industry is a very important industry in Canada. It is important in terms of employment in relation to the gross national product of Canada and it is particularly important in the international trade of Canada. So far from being insignificant domestically, it is also an extremely important factor in the international picture. That's an important point to bear in mind, because as we talk about all the other matters we never can lose sight of the fact that mining management always has to be conscious of its international competitive position. It is something that one forgets at one's peril, and to a somewhat greater extent than is true of many other industries, those managements have to compete in an international context for their markets, to some extent for their people for specialized skills and of course for finance. In the evolution of domestic policies it is a very, very perilous step to take to impair that competitive ability of the domestic mining industry."

Jan 1, 1972

By W. Keith Buck

This paper defines the discipline of mineral economics. By example, it describes the application of the tools of economic analysis to mineral problems - to problems in the areas of: mineral resource analysis and forecasting, mineral industry activity from exploration to distribution and marketing, mineral commodity analysis, and mineral policy analysis and policy formulation - all in a regional, national or international context.

Jan 1, 1972

By M. L. Trépanier

"Engineering and technical services are supplied by the Engineering Department, located at Thetford Mines, Quebec, approximately 60 miles southwest of Quebec City. The department serves the three operating mines in the Thetford area, the Asbestos Hill mine at Putuniq, Nouveau Quebec, and the Nordenham plant at Nordenham, West Germany. The Engineering Department is responsible for supplying the following services. 1. Administration and coordination of capital projects. 2. Engineering, design and drafting services for in-plant changes or improvements. 3. Preparation of geological plans for mine planning and ore reserves determinations. 4. Short-, medium- and long-term mining plans. 5. Rock mechanics studies and monitoring. 6. Grade control monitoring. 7. Environmental control engineering and construction. Details of the organization and services rendered will be the basis of the paper."

Jan 1, 1976

By A. Hayatdavoudi, K. G. Sawant, F. Boukadi

"In this work, we found that contact between shale and water results in development of micro fractures. Based on results of experiments on Pierre shale, we conclude that appearance of micro fractures begin with saturation of capillaries, ionic and diffusive transport of water into the shale clays and once capillaries are saturated, the cause of micro fracture propagation is the conversion of ionic activity/exchange to excess pressure that did not exist before fracking. Based on these findings, the spread of micro fractures appear to be a time-dependent phenomenon which has not been addressed in the existing macro/micro fracture models.INTRODUCTIONShale has often been involved as a hazard in drilling operations. This hazard can be defined as “destabilization” of shale. When contacted with water-based drilling fluids, some shales readily swell and sometimes, cause the wellbore to cave-in, slough, wash-out, close, and pack-off, impeding the drilling by sticking the drill-pipe. However, once drilling reaches the desired depth or length, the casing is set, cemented, and perforated, and then actually we wish to initiate fractures and destabilize the shale formation, using hydraulic fracturing.Clays constitute a major portion of minerals in shale. These clays contain a large amount of free energy which is the main factor for “slick” water adsorption/absorption. In fact, the reason for using “surfactants” in hydraulic fracturing fluids is to make the penetration of the fluid into the capillaries much easier, thus water meets with less resistance to enter the small capillaries. Also, the result of high capillary suction pressure is due to small Angstrom size capillaries, smaller pores and presence of ions and hydrateable metal atoms. The free energy is thus, related to all the above mentioned and other affects. Capillary pressure, osmotic pressure and other pressures are responsible for creating the micro-fractures in shale, thus, increasing the network of micro-fractures which leads to more gas production. The objective of this study is to evaluate the pressures of the individual ions which are released by the diffusing “slick” water into shale. These pressures would be added to the above mentioned capillary pressure, osmotic pressure, bacterially-induced pressures, chemically-induced reaction pressure, pressure due to exchangeable ion-transport, pressure due to release of free energy of solvation and eventually to the pore pressure as suggested by Terzaghi’s equation."

Jan 1, 2015

By F. W. Guernsey

Of all the elements, sulphur occupies a place by itself. It is mined in situ, in such quantities and of such purity that, as regards the tonnage produced, it is the first of any element on the list. Iron and coal the great tonnage producers, are combinations of elements, while sulphur is mined and marketed almost chemically pure. It is sold, in large quantities, commercially, calling for a purity of 99.5 per cent while for medicinal purposes, the Pharmacopoeia requires only 99 per cent. purity. It is a very common commodity, and like many common things is of extreme importance, in the progress of our civilization. The substance has been known from the earliest times, the word sulphur being derived from the Sanskrit Culvari", hence the Latin Sulphur. Commercially it is also called brimstone, this word being a derivative of the Anglo-Saxon Bryne Stane or burning stone. From our younger days, we have been more or less familiar with the mineral. On the spiritual side being threatened, if we did not behave ourselves, with an ultimate consumption in a lake of fire and brimstone, (which in moments of reflexion was not pleasant to contemplate) while our bodily ills were taken care of by inward applications as a spring medicine. In both instances, the effect required, was generally attained. Sulphur occurs in nature, both free and in the combined state, it being estimated that it forms, over one tenth of one per cent of the first ten miles of the earths surface. (I do not know who did the estimating and it is not guaranteed).

Jan 1, 1923