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By A. M. S. Hussein, B. E. Rogers

Progressively more stringent emission limits and advances in regulations and enforcement have made air compliance more difficult for metallurgical facilities. This has historically required improved collection and treatment of stack sources. Fugitive emission reductions are now increasingly required to achieve compliance. Typically small in magnitude, fugitive emissions have a disproportionate impact on ground level concentrations, can be visible to the public and can influence workplace health and safety. Moreover, these emissions are complex, as they are spread over multiple sources, distance and time and are affected by various activities and conditions. As such it is difficult to find, define and monitor these emissions and their impacts. This difficulty translates to the design of emission reduction measures and operational requirements. This paper presents an overview or ‘heuristic’ of fugitive emissions management for compliance in existing operations. This includes aspects such as the impact of regulations on project scope, approaches to developing a comprehensive emission inventory, considerations for solution development and the plant’s role in sustaining compliance once achieved. Case studies are presented to demonstrate how portions of this approach have been applied.

Jan 1, 2015

By A. McGrath, M. Trovant, M. Haque

Minimizing energy consumption is a priority for many industrial facilities. Metallurgical and gasification processes produce dirty syngas (CO and H2), which offers the potential for energy recovery. However, syngas handling can pose an explosion risk and even minor leaks can result in poor workplace hygiene. Furthermore, many jurisdictions around the world now discourage wet syngas handling due to limited water availability and secondary pollution. Hatch has developed a 100% positive pressure gas handling system that targets these safety hazards without using fresh water. The implementation of a system for calcium carbide smelters at Qinghai Salt Lake Industry Co. (QSLIC) in China is profiled as a case study.

Jan 1, 2015

By W. M. Armstrong

THE GROWTH of the major iron and steel industries on this continent and in many European countries was based on the use of as-mined, high-grade, lump iron ores and on the availability of metallurgical coking coals. The modern coke-fired blast furnace was developed for such materials and is one of the most efficient of ail pyrometallurgical processes. Most of the impure pig iron produced by blast furnaces was converted to refined steel by the Bessemer process in the years prior to 1900 but, when large quantities of low-cost steel scrap be-came available, the more flexible open hearth process was adopted by most large steel producers on this continent. Although this pro-cess has many desirable metallurgical features, the thermal efficiency is low, the capital cost is very high, and the method of charging scrap steel is inefficient by modern standards of material handling. In recent years several conditions have arisen which have stimulated the development of many new pro-cesses and the re-examination of the existing smelting and steelmaking techniques.

Jan 1, 1958

By C. D. Anderson, C. G. Anderson, P. R. Taylor

"Rare Earths have become critical for our energy and materials driven society. While primary production must ramp up to fill growing demands, the recycle of these strategic elements must also be initiated. This paper will outline the potentials of and metallurgical technologies employed for Rare Earths recycle from various secondary sources.INTRODUCTIONWhen investigating the recovery of rare earths from secondary sources it is necessary to understand the nature of the sources to be processed. As of 2009, the USGS reports the distribution of rare earths by end use, in decreasing order, was: chemical catalysts 22%, metallurgical applications and alloys 21%, petroleum refining catalysts 14%, automotive catalytic converters 13%, glass polishing and ceramics 9%, rare earth phosphors for computer monitors, lighting, televisions 8%, permanent magnets 7%, electronics 3%, and others 3% (USGS, 2011). Additionally, it is reported that the amount of recycling was quite small and consisted primarily of rare earth magnet scrap, although with the sharp increase in the price of rare earths, and the potential shortage in supply, focus in this area is continually growing. Thus, the opportunities, whether realistic or not, are extremely vast in the recycling of rare earth containing materials. The following subsections will present methods proposed for the recycling of rare earths based on the feed material type.RECYCLING OF RARE EARTH MAGNETSCurrently, investigations are ongoing in the area of recycling production scrap and end-of-life materials in the rare earth magnet industry. The following techniques illustrate potential methods for the recovery of rare earths from secondary RE magnet sources.Recycling of Rare Earth Magnet Sludge by Selective ChlorinationDuring the production of neodymium magnets, a by-product of production is the so called “magnetic sludge”. This by-product contains high amounts of neodymium, thus a process for the recovery of Nd has been proposed. In this process the Nd present is selectively chlorinated/distilled by the addition FeCl2 via the following reactions."

Jan 1, 2012

By E. J. Wasp, T. L. Thompson, T. C. Aude

The paper will deal with some of the more important technical aspects of slurry pipelines as they apply to the mineral field. In addition, the use of these technical concepts in arriving at realistic economic figures will be discussed.

Jan 1, 1970

By E. Godfrey

The average man one meets on the street thinks of an explosive as a medium of death and destruction, something unstable which should be given a wide berth, because he knows little or nothing about its use or its stability. Briefly, explosives are compounds that develop very large quantities of heat and gas in an extremely short time and in a small space, thereby exerting enormous pressure upon surrounding bodies, and by the rapid expansion of this highly heated gas are able to perform a considerable amount of useful work. The amount of heat generated and the volume of gas produced by the decomposition of an explosive determines the amount of mechanical work it can do, and the time occupied by its change from solid or liquid condition to gaseous condition determines its shattering effect. Explosives manufactured by reputable people are not extremely dangerous, on the other hand they are quite safe if handled in a proper manner. Furthermore, before an explosive can be placed on the Canadian market a sample must be submitted to the Explosives Division of the Mines Department, who may condemn or permit its manufacture, according to their findings regarding its safety in handling and its stability during storage.

Jan 1, 1926

By M. A. Hararah, T. Neesse, M. G. Farghaly, G. Proellss, P. Kaniut, W. Rubarth

ABSTRACT: This paper presents two new options for hydrocyclone control. Volume split control using a control valve in the overflow is applied for the stabilization of separation results at changing feed conditions. Controlled water injection to the conical part of the cyclone leads to the reduction of fine particles in the underflow. Hydrocyclone monitoring in both cases is performed by optical sensors that indicate the spray angle of the underflow. Applications in mineral processing for desliming, classification in closed-circuit grinding, and dewatering are demonstrated.

Jan 1, 2011

By P. Mišcevic, B. Kavur, I. Vrkljan, N. Štambuk Cvitanovic

It is known from earlier and recent research that mechanical properties of intact rock like uniaxial compressive strength (UCS), Young's modulus (E) and Poisson's ratio (?) are influenced by shape deviations of test specimens as deviations from the ideal cylinder. That impact can be significant at certain level of inaccuracy of specimen preparing, and it should be objectively evaluated and controlled in testing. The effects of intact specimens side straightness, ends flatness, ends parallelism and perpendicularity to the specimen axis, on UCS, E, and ?, measured in several actual ways during laboratory compression tests, were determined by previous research on 90 homogeneous specimens of limestone. In this paper, we subject these new experimental results to Response Surface Methodology (RSM) to model the mentioned dependence, to identify significant connections of variables and to evaluate the conclusions obtained directly from experimental phase. This study indicates how the responses of the model (outputs) – parameters UCS/E/??of limestone rock depend on factors (inputs) – parameters of specimen shape deviations like flatness R, parallelism P and perpendicularity O, assuming modern test machines with spherically seated upper platen. Starting from general RSM model with three factors (R, P, and O), we investigated the multiple linear regression models of specific mechanical property (UCS, E, and ?). Using the NCSS program ("NCSS 2004 and PASS 2005") in several steps, final models with very high coefficients of determination were developed for properties with the most evident effects of specimen shape deviations: nine models for strength UCS and UCS50 (equivalent UCS for specimen with 50 mm diameter), and three models for ?L (Poisson's ratio calculated from axial deformations measured on the entire specimen length). These statistical models with their response surfaces further strengthen and confirm the results and conclusions from the experimental phase. The critical values of R, P, and O are established using an additional statistical analysis to determine the lower and upper engineering limits. These findings set the basis for the new eligibility criteria for specimens of limestone (and similar rock with UCS about 100-150 MPa) in further testing of strength and deformability.

Jan 1, 2015

By M D. Winning

The historical development of the elemental sulphur recovery industry in Western Canada is reviewed for the period 1952 to 1965. A brief technical description of a typical modified Claus sulphur recovery unit is presented. Some predictions are made concerning the future of the elemental sulphur recovery industry in Western Canada. THERE are evidences of sulphur or its compounds having been used for religious and medicinal purposes as far back as we have a recorded knowledge of history. As typical examples, sulphur was burned as a sort of inverse incense to drive away evil spirits at religious festivals, sulphur ointments were used by the early Egyptians to cure eye ailments, and hot sulphur-spring water was used as a cure for a variety of ailments. Thermopyle was called "Hot Gates" be-cause of its fame as a spa as well as a mountain pass. The Romans discovered the sulphur deposits in Sicily and mixed sulphur with bitumen for incendiaries; and, of course, anyone familiar with the travels of Marco Polo knows about the Chinese development of gunpowder, which contains sulphur. In some aspects things haven't changed much today. We still use sulphur-bearing ointments, and we still use the hot sulphur springs such as the one at Banff in Western

Jan 1, 1965

By S. W. Marcuson, P. J. Mackey

The 1973 Oil Embargo and succeeding disruptions in supply had a profound effect on energy costs and consumption patterns in the developed world. This was especially true in the USA where post World War II growth, fueled by low-cost imported oil, left the country dependent on uninterrupted oil shipments from the volatile Middle East. In this atmosphere, Professor H.H. Kellogg of Columbia University, convinced of the necessity of good environmental stewardship by the writings of the era’s leading environmentalists, developed a methodology for evaluating energy and process efficiency of metallurgical processes and wrote a series of papers describing and applying the techniques. One of these, "Energy Use in Sulfide Smelting of Copper" is recognized as a seminal work which both described the state of energy usage in copper smelting in the mid-1970’s and portended future developments. The background to these papers is examined and the current and past Cu-Ni matte smelting practices in Canada are examined in the context of the results. Data from early 20th century publications describing reverberatory and blast furnace operation is employed to show that energy consumption for much of the century was several multiples higher than that calculated for best reverberatory operation in the 1970’s.

Jan 1, 2015

By K. J. Daun, C. J. Shi

UsiborThrough the second step heating at 900 °C, the spectral emissivity shows a gradually decreasing trend with increasing soak time, caused by the surface phase transformation from Al® 1500P coupons are austenitized in a Gleeble 3500 thermomechanical simulator using a two-step heating procedure in an argon atmosphere. Variations in spectral emissivity are measured in-situ using a near infrared spectrometer and ex-situ with a Fourier transform infrared reflectometer. Microstructural evolution and surface roughness are investigated using optical microscopy, FE-scanning electron microscopy, and a surface profilometer. A series of phase transformations of Al-Fe-Si intermetallic phases at the coating/steel substrate interface cause the surface phase and surface roughness to change, which in turn influences the spectral emissivity. At the beginning of the first heating step, the coupons have very low spectral emissivity, due to the molten Al-Si coating. Spectral emissivity increases significantly with increasing soak time from 5 to 12 minutes, associated with the surface phase transformation of the coating into Al7Fe2Si intermetallic phase and an increase in surface roughness. 5Fe2 into AlFe intermetallic phase with a decrease in surface roughness.

Jan 1, 2015

By T. Johnson, K. Lambrych, D. Kelley

Materials for construction of equipment used in hydrometallurgical plants are selected based on a combination of their ability to perform as required in aggressive process environments as well as their cost. As a material of construction, fiber reinforced plastic (FRP) has been shown to provide equal if not improved durability relative to alternative materials such as corrosion resistant alloys at a considerably lower cost. This is particularly true in the case of equipment used in acid leaching processes for copper, cobalt, nickel and rare earth elements. The selection and extensive use of FRP over alloys in new hydromet plant construction in North and South America illustrates this advantage of FRP effectively. This paper will compare corrosion performance and cost of plant equipment fabricated with stainless steel alloys and FRP made with Epoxy Vinyl Ester thermoset resins. Real world case histories for FRP piping, storage tanks, extraction vessels, and electrowinning cells combined with laboratory based corrosion studies will be reviewed to demonstrate how FRP materials are selected for hydrometallurgical equipment.

Jan 1, 2015

By John C. Lyons

"The Wabana iron ore deposits occur as flat-dipping beds of oolitic hematite and chamosite, of Lower Ordovician age, which outcrop for 3 miles along the northwest coast of Bell Island, Conception Bay, Newfound-land, about 16 miles from St. John's.The deposits occur in three zones, Upper, Middle, and Lower beds, separated respectively by 30 feet and 215 feet of shale and sandstone. They are primary sediments laid down in a shallow tidal basin by the precipitating action of a marine environment on iron-rich fresh waters flowing into the basin.The ore-bearing zones, while of wide areal extent, are not uniform beds of hematite that can be mined wholesale. The action of waves and currents during sedimentation; the delta pattern, velocity, and transporting power of streams flowing into the basin; the contours and oscillations of the sea bottom on which the sediments were laid have all been fundamental in the emplacement of richer and thicker mineable sections, and of lean zones so intercalated with shale as to be unmineable.The preservation of the deposits is due to their location in the Conception Bay syncline and to a considerable upthrust of the country east of the bay in post-Ordovician time.The hematite deposits were first recognized as such in 1892, and soon after were acquired by the Nova Scotia Steel and Coal Co. They are now being mined by Dominion Wabana Iron Ore, Limfred, a wholly owned subsidiary of the Dominion Steel and Coal Corporation, Limited. Production started in 1895, and up to the end of 1955 totaled 58,588,516 long tons of hematite ore, having an average dry analysis of about 51 5 per cent iron, 11 8 per cent silica, 0·9 per cent phosphorus, and l ·5 per cent moisture. About 40 per cent of the total tonnage mined has come from surface stripping and on-shore mines. These areas have now been almost completely depleted, and operations are confined to submarine mines extending for two miles off shore under the waters of Conception Bay. Three sub-marine slopes are currently in operation, Nos. 3 and 4 working in the Lower Bed and No. 6 in the Middle Bed. A general picture of the workings is shown in isometric projection in Figure 1. Submarine mining has been entirely by the room-and-pillar method, with an extraction of 60 per cent. The deepest workings, at a vertical depth of 1,850 feet below sea-level, have a rock cover of about 1,500 feet. No mining is done in areas where the rock cover is less than 200 feet. To date mining has explored six square miles of a potential area that may exceed 50 square miles."

Jan 1, 1949

By M. Aushouri, S. H. Mansouri, N. Aminizadeh

A thermo-chemical model of the Peirce-Smith copper converter in blowing the copper stage has been developed to predict the molten temperature. The key assumption of the model was that white metal and gas phases in the converter were in thermal and chemical equilibrium. In this model, the chemical reaction of white metal and oxygen was accomplished completely. So long as sulfur existed in the bath, the generation of Cu2O was frozen. The reaction rate was considered to be constant and controlled by the reacted sulfur. The converter temperature was calculated by heat balances over time. The model was validated by a detailed comparison with measured industrial data. A good agreement was obtained. The converter temperature depended on process parameters such as oxygen efficiency, molten emissivity and oxygen enrichment.

Jan 1, 2007

By J. Gogal

Cameco's Cigar Lake Operation (CLO) started commercial uranium ore production in 2015. Initial mining was focused in areas of the ore body with relatively low concentrations of elements of concern (EOCs). As mining progressed into areas of the ore body that were richer in EOCs, some statistically significant behavior of certain analytes was noted in the water treatment circuits. It was ultimately found that the CLO ore body natively hosts numerous alkyl arsine compounds in addition to inorganic arsenide minerals. The alkyl arsines were found to be recalcitrant to typical adsorption on ferrihydrite, with the degree of recalcitrance associated with the degree of alkylation. A number of changes to the process circuits and water balance were performed and planned in order to inhibit the transport of alkyl arsines from the ore stream into the process water stream, and to optimize the overall site water usage. In some instances, the interactions of equipment in conjoined circuits of the process had controlling effects on the behavior of the overall circuit. Work continues to iterate upon the capital design features in order to further tighten the water balance, and to optimize water usage and operating costs.

Jan 1, 2020

By C. Bernier

This paper deals with three major problems associated with mining operations during the winter. These are the maintenance of the cooling systems of diesel engines, the high incidence of hydraulic dump failures on packaging machines, and the build-up of frozen fines on wet-ore conveyor belts.

Jan 1, 1966

By T. Xue

429 As part of Inco's S02 abatement project for its Sudbury operations, a weak acid treatment plant (W ATP) was commissioned at the Copper Cliff smelter in August of 2004 to treat the weak acid streams generated by the flash furnaces, the MK reactor and the fluidized bed roaster (FBR) gas cleaning plants. The W ATP process was developed by Inco Technical Services Limited (ITSL) by means of laboratory and mini-pilot plant programs. In the W ATP process, the feed solution containing arsenic, sulphur dioxide, iron and other impurities is treated by oxidation and neutralization to form a stable precipitate for disposal in Inco's tailings impoundment area. During the commissioning of the WATP, a team of operations, maintenance, engineering, project and R&D personnel was formed, and the designed capacity was achieved in less than a month. Since then, the W A TP has been operating smoothly and the impurities, specifically arsenic, in the Copper Cliff smelting process have been effectively removed.

Jan 1, 2006

By C. A. Grandison

The economic evolution from an agrarian society to an industrial and service-oriented economy is apparent to most students of history. The long-term trend is almost taken for granted, it does not require explanation — it is accepted as the nature of man to improve his standard of living. However, there are fluctuations around this trend line which have provoked a great deal of thought. The ability to understand and control these fluctuations would yield many benefits, it would eliminate economic waste and public hardship, and would no doubt make a few fortunes. I f it is not possible to control or eliminate these fluctuations, then a reasonable forecast of the tinting, rate of change and magnitude of the fluctuations would be invaluable to industry and government.

Jan 1, 1976

By I. Spector

A SHORTAGE of cement in the Prairie Provinces, together with an aggressive policy on the part of the Saskatchewan Government in bringing new industries to the province, combined to create a favourable set of conditions for the establishment of Saskatchewan's first cement plant on the outskirts of Regina. Built by Saskatchewan Cement Corporation Limited, this single-kiln plant, tl1e latest addition to cement producers on the Prairies, began operations in the Fall of 1956. Location of the plant followed the trend of building cement manufacturing facilities in market areas rather than at raw material sources. In 1957, all assets of the Corporation were taken over by Inland Cement Company Limited and the plant and quarry now operate as Saskatchewan Cement Company, an Inland division. The Regina plant's production makes up approximately eleven per cent of the productive capacity of all plants in the Prairie Provinces. At present, two types of cement are manufactured -normal portland and sulphate resisting.

Jan 1, 1960

By Alex Matheson, Nick W. D. Massey, Peter T. Bobrowsky

Crowing pressures on aggregate resources include diminishing reserves, high transportation costs, sterilization and land use conflicts. In the absence of detailed resource knowledge for a particular region, aggregate resource potential maps provide the best "first approximation" regarding the surficial distribution of sand and gravel. The 1:50 000 scale Level Ill aggregate potential map integrates several important factors which influence the management of sand and gravel. Data used to generate this type of thematic map is readily available in most areas, fieldwork required is minimal, there is a logical quantitative evaluation of the data layers and integration is easily accomplished on a desktop PC-based platform. Also the aggregate potential map, with its focus on identifying areas of potential future aggregate exploitation as well as present inventory, provides a useful tool for the aggregate explorationist.

Jan 1, 2001