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By S. Ng, Peter Stapleton, Paul Mankowski, J. Spence, R. Siy

"Syncrude has developed a low energy extraction process for the recovery of bitumen from oil sand. This new process operates at a temperature of 25 °C, resulting in substantially lower energy costs and lower capital costs, especially for the thermal energy generation equipment. The process will be used in Syncrude’s Aurora Mine, which is scheduled for startup in mid 2000. The flowsheet for Low Energy Extraction includes hydraulic transport of oil sand slurry, and bitumen separation using collector and frother chemicals and air as process aids. A number of flow sheet innovations and optimizations have been included, resulting in the next generation of extraction technology. Experimental pilot plant results, engineering progress to date and areas of ongoing work will be discussed. SUMMARYThe Low Energy Extraction Process has been successfully developed for commercial implementation at Aurora. The 1996 100 tonne hour Field Pilot demonstrated that the bitumen recovery target could be met with an 11.1% grade oil sand. However, pilot plant bitumen recoveries for a lower grade oil sand were not acceptable. The subsequent flowsheet optimization study led to a new flowsheet for Low Energy Extraction, which includes a primary separation vessel, a flotation circuit for PSV middlings, and the use of middlings displacement in the PSV cone bottom with flotation underflow. A test program conducted in 1997 showed that the new flowsheet could significantly improve the bitumen recoveries for lower grade oil sands. Engineering work on process scale-up led to selection of a 30 meter diameter PSV, with a tangential feedwell. The successful development and commercialization of Low Energy Extraction for the Aurora Mine Project is a major enabling step in the Syncrude 21 program. The low energy requirements of this process allow Syncrude to develop the Aurora leases more cost effectively. The use of this process results in major capital cost savings, predominantly in the thermal energy infrastructure and also provides long term operating cost advantages for Syncrude."

Jan 1, 1999

By J. A. Finch

The metallurgical performance of a flotation cell is strongly influenced by the features of the bubble population, characterized by the gas dispersion properties, a collective term including bubble size, superficial gas velocity and gas holdup. It is required that gas be well distributed throughout the cell. Gas distribution is estimated here by simultaneous measurement of gas velocity (Jg) at different distances from the center (radial Jg mapping). This communication describes a technique to perform radial Jg mapping together with fundamentals for the interpretation of the data.

Jan 1, 2009

By O. C. Rojas, J. Sanhueza, J. C. Vargas

Empresa Nacional de Minería (ENAMI) is dedicated to the promotion of small and mid scale Chilean mining industry. Paipote, ENAMI Copper Smelter, processes a variety of mineral products as the result of this promotion. The mineral products characterize a wide variation of copper, iron, sulfur and precious metals content as well as the significant dispersion in the content of impurities, such as arsenic, antimony and bismuth. The Smelter Modernization Program, initiated in1997, introduced a series of technological and operational changes. The development of operational planning and control strategies was necessary to optimize the blending of a wide variety of concentrates and the control of metallurgical processes in order to ensure the stable operation, fulfillment of environmental regulations and the quality of produced copper anodes. A permanent optimization process carried out in the last decade led to the permanent increase of the smelting capacity and the production of anodes and sulfuric acid. Additionally, introduced improvements affected the smelter efficiency and metallurgical recovery, demonstrating the possibilities of the optimization of a small smelting facility reflected in good metallurgical and economic results. This paper presents the smelter evolution, introduced technological and process control changes as well as incorporated new reactors and equipment as a continuous process of optimization.

Jan 1, 2007

By E. C. Goodhue, R. D. Coleman, I. E. Puddington, A. F. Sirianni

Iron ore samples containing apatite are fractionated to acceptable products by spherical agglomeration methods. The phosphorus is upgraded by a factor of 10 at an elevated pH. High-grade iron products are obtained in good yields from the tailings in a second step of the operation. The grade of the phosphorus separated appears to reach a maximum at about pH = 10; recovery of iron decreases below about pH = 4. Both the recovery and grade of iron are found to be reduced sharply above about pH = 8.

Jan 1, 1968

By John H. Fowler

Nova Scotia has been mining and exporting industrial minerals for over two hundred years. As an industrial mineral producer, this province continues to rank as the number one gypsum mining and exporting region in North America. Mining of many other commodities is ongoing, supplying many local and export markets. In all, excluding aggregate producers, there are nineteen industrial mineral producers operating at thirty sites producing nine commodities including anhydrite, barite, clay and shale, dolomite, gypsum, limestone, salt, silica sand and stone (Fig. I). Numerous aggregate producing operations supply all the province's aggregate requirements and export some of these materials to other regions of Atlantic Canada and as far away as Bermuda (Fig. 2) . Production value of industrial mineral commodities in Nova Scotia for 1982 was $105 million , representing 39% of the total value for all mineral production for the year. Because of the general improvement in the economy, indications are that the 1983 value of production will be higher.

Jan 1, 1984

By T. Lux, H. -J. Krassnig, I. Filzwieser, E. Hecker, R. Degel, A. Filzwieser

Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions for the primary copper production lines as well as for non-ferrous metals starting with the primary smelting of concentrate and ending with the electrolysis. PolyMet Solutions provides the process know-how whereas SMS group supplies the plants and equipment and Mettop the key components. SMS group and Mettop also cooperate in the field of tankhouse technology. Together with Montanwerke Brixlegg AG, Mettop has developed together with a parallel flow technology (METTOP-BRX Technology), allowing a current efficiency of above 98 % at a current density of 420 A/m², which is a milestone in copper electrolysis. For the secondary copper production route, SMS group and PolyMet Solutions developed an innovative refining furnace (PolyRefine) for the smelting and refining of copper scrap. The refined copper is directly charged to the Contirod line to produce copper rods and wires. The innovative cooling solutions of SMS and PolyMet Solutions come into play where furnaces have to stand the highest loads and stresses, for instance in areas of very high temperatures or temperature fluctuations, aggressive exhaust gases and slags, or at critical spots such as taphole areas. Custom-tailored cooling systems for furnace vessels make sure varying loads are compensated in a targeted and effective manner. The solutions include air cooling, spray cooling, cooling technologies with integrated copper elements such as CFM (Composite Furnace Modular) cooling systems, plate and finger coolers. The major innovation in the field of furnace cooling is the ILTEC (Ionic Liquid Cooling) Technology which paves the way for increased plant safety. This revolutionary, patented cooling technology is jointly marketed by Mettop and SMS group. It permits water-free cooling to be implemented and thus makes operation safe wherever it is applied. INTRODUCTION Non-ferrous metals or NF metals are changing the world. There is no modern industrial sector that can do without these valuable metals. Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. The importance of the non-ferrous metals market is reflected by two figures. In 2018, the production of non-ferrous metals was worth more than 237 billion Euros. This contrasts with 255 billion Euros of the value of iron and ferro- alloy production in the same year (International Organizing Comittee for the World Mining Congresses, 2018). Hence, the NF metal industry is almost as important as the iron and steel industry. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions and to enhance customer value. The prices of nearly all metals have come under pressure during the past few years. Therefore, competitive technologies are regarded a crucial factor to achieve success in this critical market situation respectively to stabilize the market position.

Jan 1, 2019

By Horatio Sam-Aggrey, Margot Hurlbert

Small Modular Reactors (SMRs) have been touted as having the potential to spearhead a nuclear renaissance. Proponents of this view cite the relative advantages of SMRs over larger nuclear plants as reason for their optimism. Some of these merits include potential economies of mass production deriving from modular factory production, enhanced safety features, the ability to locate reactors in remote areas, and reduced requirements for technical workforces to install and maintain SMRs. Despite the optimism surrounding SMRs, nuclear power is still a contentious issue for many Canadians. The growth of nuclear power remains adversely affected by concerns over issues such as: the health and safety consequences of nuclear power generation, environmental impacts, proliferation of nuclear materials, terrorism, and radioactive waste disposal (Organisation for Economic Co-operation and Development (OECD) and Nuclear Energy Agency (NEA), 2010). Personal values, past nuclear accidents, and lack of trust in the industry are other factors influencing attitudes toward nuclear energy (IAEA, 2005). In Canada, three main areas where SMRs could be used have been identified. These include: a. Traditional, on-grid power generation, especially in provinces looking for zero-emissions replacements for CO2-emitting coal plants. B. Remote off grid communities that currently rely on diesel or fuel oil power generation. There are 279 off-grid communities in Canada, many of them being Aboriginal communities (NRCan, ND). Notably, all communities in each of Canada’s three territories qualify as remote. C. Resource extraction sites, such as mining and oil and gas extraction sites. Many of Canada’s principal producing mines and active mineral exploration projects are located within close proximity of Aboriginal communities. Any proposed implementation of small nuclear plants would, require the support of the local population, which is largely Indigenous in the northern regions. The possible deployment of SMRs raises important issue relating to consultation and accommodation of Aboriginal concerns regarding potential SMR deployment. This is especially pertinent given Canada’s pending implementation of the provisions of UNDRIP. One of the provisions of UNDRIP that has attracted a lot of attention is the one on Free Prior and Informed Consent (FPIC). Drawing on previously published information, this paper discusses some of the challenges posed by FPIC for the deployment of SMRs. The next section outlines the provisions of FPIC and its implementation in the Canadian context. Section 3, details some of the challenges posed by FPIC to the deployment of SMRs, while Section 4 provides some concluding comments.

Jan 1, 2020

By K. Lambrych

Hydrometallurgical equipment used to extract and refine copper and other metals is exposed to extremely corrosive chemical environments. These systems must be fabricated from materials that are durable against corrosion, meet exacting mechanical requirements, and perform economically over the life of the mineral processing plant. In several recent large hydromet projects, fiber reinforced plastic (FRP) has been shown to provide equal if not superior durability relative to alternative materials of construction. This paper will compare corrosion performance and cost of plant equipment fabricated with corrosion resistant alloys, rubber lined steel, and FRP made with Epoxy Vinyl Ester thermoset resins. Case histories for FRP piping, storage tanks, extraction vessels, and electrowinning cells combined with laboratory-based corrosion studies will be reviewed to demonstrate how FRP materials are selected for hydrometallurgical equipment. Specific examples from projects such as El Boleo, Long Harbour and others will be used to demonstrate how the versatility of FRP allows for remote fabrication of durable corrosion-resistant large-scale equipment for hydrometallurgical refinement of copper and other metals. INTRODUCTION Fiber reinforced plastic (FRP) began to emerge as a material of construction for corrosion service in many industrial processes in the late 1950s because of its ease of use and overall performance. Corrosion resistant (CR) FRP, as an alternative construction material to alloys, rubber and tile linings, grew steadily in following decades. The aggressive operating conditions associated with hydrometallurgical processes typically require materials of construction that can withstand acids and acid chlorides at temperatures up to 90°C, sometimes higher. Common metallic materials of construction, such as carbon steel, are not compatible with these conditions. High nickel alloys are capable of meeting performance requirements, but often at a high cost. In many cases FRP mining equipment based on epoxy vinyl ester resin (EVER) offers durability, long service life and lower maintenance costs. Through demonstrated performance and decades of case histories, more and more design engineers are confidently specifying FRP as the material of construction for new mineral processing equipment.

Jan 1, 2019

By E. Brouillette

Difficult operating and mining conditions such as low visibility, difficult roadbeds, fast cycling, small openings, and sharp corners create high demand for LHD manoeuvrability and operator dexterity. Operator experience and patience is especially solicited to fill the bucket rapidly and efficiently and performance can be particularly affected by the skill level of individual operators. Teleoperation and automated loading are viewed as options to improve overall equipment and operation performance in certain mining conditions. Comparative statistical measurements of autoloading performance in different production environments at Noranda demonstrate an increase in bucket filling efficiency and a reduction in filling variance, allowing LHD operation to be more consistent and within manufacturer specifications. Consequential cost savings and productivity increases are demonstrated to be transferable to other mining situations.

May 1, 2003

By Charlie Jefferson

Main Goal: Resource Assessment 1. Incorporate existing data & results, old process. 2. NEW Quantitative Analysis (Chung and Chen) 3. Try mass balance of U and geochemical tracers 4. Use holistic process approach ?with key foci ?Targeted basin / belt assessments ?Is there as much in the Athabascaas they say? ?Athabasca reference for other basins (Thelon, etc) ?Compare sandstone & volcanic with USA, Kazakhstan etc: do their models apply here? ?Which IOCG systems are prospective for uranium? 5.Consider Groundwater, Environment; 6.Communicate

May 1, 2006

By J. P. Jylhä, A. Jokilaakso

The Outotec Flash Smelting process is widely used in primary copper production. A layer of slag on top of matte (copper–iron sulphide melt) creates a barrier through which matte droplets descend. Droplets of different sizes settle through the layer at different rates, which increases possibility of copper losses as smaller matte droplets may be removed with the slag. In this work CFD-DEM (computational fluid dynamics – discrete element method) coupling was used to simulate matte droplets settling through the slag during slag tapping. Discrete droplets and slag flow were simulated with DEM and CFD, respectively. This new approach enables tracking and solving movement and interactions of individual droplets. User-defined models were created to take coalescence and reaction kinetics into account. Coalescence created larger droplets, while the reactions decreased droplet size and increased its density. Drag caused funnelling effect, which pulled droplets towards the centre line of the descending cluster. This research is the only study known by the present authors in modelling liquid-liquid systems with the CFD-DEM coupling. Simulating coalescence and chemical reactions for discrete droplets enables more realistic simulations. However, CFD- DEM simulations are computationally resource intensive already without additional models, so a full scale industrial settler modelling still waits for further increase in computer performance. INTRODUCTION Flash smelting is a method used in copper and nickel production. In the flash smelting process, oxidation of sulphides in a concentrate is used to release energy needed to smelt the feed. In the process, copper matte is formed. Matte has copper content in the range of 55 – 70% (Sridhar, Toguri, & Simeonov, 1997), the rest is mainly sulphur and iron but has still many other impurities (Taskinen, Seppälä, Laulumaa, & Poijärvi, 2001). Oxidized iron forms iron-silicate slag while SO2 is collected for acid production (Davenport & Partelpoeg, 2015). The Outotec flash smelting furnace (FSF) can be divided in four major component: concentrate burner, reaction shaft, settler and uptake. Concentrate, flux and oxygen enriched air are injected into the reactor through the concentrate burner. The mixture then reacts in the reaction shaft forming matte and slag, which are collected in the settler, while off-gases flow out of the reactor through uptake for heat and dust recovery, and SO2 collection for H2SO4 production. The matte and slag form separate layers due to immiscibility and density difference. Raw material feed is continuous, but the matte and the slag are tapped periodically. A flash smelting furnace is depicted in Figure 1.

Jan 1, 2019

By M. J. Nicol, T. Moyo

Ammoniacal solutions are an effective lixiviant for the oxidative dissolution of some mineral sulphides. A detailed study of the anodic dissolution of chalcopyrite in ammonium sulphate-ammonium hydroxide solutions has been carried out using cyclic voltammetry, chrono-amperometry and rest potential measurements. The role of the copper(II)/copper(I) redox couple in the oxidation process has been evaluated. Rest potentials have been found not to be affected by oxygen but to increase with an increase in initial copper(II) concentration. Pseudo-steady-state anodic current densities measured in the absence of copper(II) ions at the rest potentials obtained in the presence of copper(II) ions increase with increasing concentration of copper(II) ions, confirming the positive effect of copper(II) ions on the rate of dissolution of the mineral. Cyclic voltametric and chrono-amperometric data show that in the absence of initial copper(II) ions, the rate of dissolution in the presence of dissolved oxygen is significantly lower. These results confirm that the effective oxidant for the mineral under the conditions of the study is copper(II) and not dissolved oxygen. Coulometric measurements have been used to establish the stoichiometry of the anodic reaction at different potentials.

Jan 1, 2014

By S. G. Shabestari

In the metal casting industry an improvement of component quality mainly depends on better control over the production parameters. Thus, thermal analysis cooling curve of the alloy is used for process control in aluminum casting industry. Cooling rates of the alloy during solidification process affect microstructure, grain size, eutectic silicon morphology, and dendrite arm spacing (DAS). In this research, effect of cooling rate on the microstructure and solidification parameters of 319 aluminum alloy that is a widely used alloy in automotive industry, has been investigated by means of thermal analysis. Seven different cooling rates have been obtained by using CO2-bonded silica sand molds with two different wall thicknesses, hot-work tool steel molds (H13) with and without coating, thin-wall steel molds with different coatings. In each case, cooling curve and first derivative cooling curve have been plotted by use of very accurate thermal analysis equipment. Effect of different cooling rates on solidification parameters e.g. Nucleation temperature (TN,a), nucleation undercooling (ATN,a), recalescence temperature (TR,a), solidification range (AT,s), and total solidification time (t 0 have been studied in the liquidus region. Microstructural evaluation has been carried out and DAS were measured in all solidification conditions. A numerical equation was proposed to predict cooling rates via measuring DAS in 319 aluminum alloy. Nucleation process and the effect of cooling rate have been interpreted by using thermal analysis cooling curves and microstructural study.

Jan 1, 2004

By Pier-Olivier Devin, Daniel Hodouin, Maryam Sadeghi, COREM, Claude Bazin, François Lavoie

"Spiral concentrators are used for processing coal and heavy minerals such as it is the case for the concentration of iron oxide from light silica gangue. The concentration process for iron ore usually consists of a rougher bank of spirals followed by two stages of spiral cleaning. The process control applied to the concentration circuit aims at maintaining a target iron content of the final concentrate and is mainly conducted by adjusting the wash water addition and the position of the splitter gates at the discharge of the spiral. This paper describes the use of a simulator to study control strategies for a gravity concentration circuit using spirals.INTRODUCTION The Canadian iron ore mines are located in the Northern part of Quebec and in Labrador (Neal, 2000). These iron ores consist mainly of hematite with some ore bodies rich in magnetite and ilmenite. The processing of the coarse hematite iron ore consists of the extraction from an open pit mine, followed by the conventional crushing and autogeneous grinding of the ore to obtain a particle size smaller than 1.2 mm. The ground ore assaying 40% hematite (Fe2O3) with quartz (SiO2) as the main gangue is processed by spirals to produce an iron oxide concentrate assaying 90 to 95% hematite.Spirals separate the particles according to their specific gravity and size (Burt, 1984; Bazin et al., 2014). These environment friendly devices have been used for decades and are still used for the preparation of coal and for the concentration of heavy minerals such as iron oxide (Staff, 1977; Wills, 1992). However very little information is available concerning the control of gravity concentration circuits. This paper analyzes the control practice of a gravity concentration circuit using a simulator. The paper consists of 3 sections. The first section describes the operation of spirals and spiral concentration circuits. The second section briefly describes the simulator and shows some simulation results for a gravity concentration circuit. The third section shows the application of the simulator for the study of control strategies for a spiral concentration circuit."

Jan 1, 2016

By A. Darragh

"Past Growth The Canadian coal industry has grown rapidly during the past two decades. Coal production increased over four-fold between 1965 and 1982; consumption almost doubled, imports remained relatively flat, exports soared and total demand increased nearly two and a half times. Coal production grew during this period at an average rate of 8.60/o, compounded annually; this remarkable performance is shown in Table 1 and Figure 1. The relationship between production and consumption is shown in Figure 1, where in 1981 the total Canadian production of coal for the first time exceeded total Canadian consumption. ln Figure 2, the relationship between imports from the United States and Canadian coal exports is shown; in_ 1981 again for the first time, exports offshore exceeded imports into Canada. The rapid growth in Canadian coal use between 1965 and 1982 followed a major decline after World War II, as the country moved rapidly to an oil based economy. Changes in consumption patterns between 1945 and 1982 are shown ~n Table 2. Railway consumption of coal was reduced to zero m the early 1960s. The industrial and domestic consumers market share fell from about 660/o in 1960 to 6.70/o in 1975; this share, however, appears to have stabilized in recent years and actual volumes can be expected to increase in the future. The steel industry's share of the coal market fell over the same period, but the volume in recent years has remained fairly constant at about seven megatonnes per year.Perhaps the most significant change in consumption is in the share of coal consumed in the generation of electricity; this has increased from 80/o in 1960 to over three quarters of the total Canadian coal consumed in 1982. This increase in thermal coal consumption has been supplied by indigenous coal, and was accompanied by a decreasing share for coal imported from the U.S.A. into central Canada. It is expected, because of the nuclear power commitment in Ontario, that this share will continue to decrease, although the total volume of coal imported may increase slowly over time. This will likely also have a dampening effect on future coal sales to Ontario from western Canada."

Jan 1, 1985

By D. Janney

Kennecott's Utah Smelter commenced operations in June 1995 utilizing Outokumpu Flash Smelting (FSF) and Kennecott-Outokumpu Flash Converting (FCF) technology. After some initial teething and equipment problems the smelter achieved its design capacity in mid-1997 and now processes over 1.0 million tonnes of copper concentrate per year with exceptional environmental performance. The smelting furnace has operated for 11 years and the converting furnace for 5 years without major shutdowns. The first major smelter shutdown commenced in September 2006 after extensive planning. The FSF was completely re-bricked and the latest above and below bath containment systems installed. The FCF was inspected and re-bricked with some improvements made to the above bath containment system. The FCF life is now anticipated to be the same as the FSF. Numerous improvements and modifications were made to the rest of smelter facility including extensive upgrades to the dry electrostatic precipitators. Production ramp-up was smooth with the smelter now frequently operating at acid plant capacity.

Jan 1, 2007

By Gordon A. Irons, H. Y. Hwang

An impinging gas jet on a water surface was studied to understand momentum transfer in oxygen steelmaking. Depth, width and oscillation frequency of the jet cavity were measured and the splashes interpreted with Kelvin-Helmholtz instability and combined Rayleigh-Taylor and Kelvin-Helmholtz instability theory. A model to calculate separate gas and liquid velocities, applying the exact momentum boundary condition, is proposed.

Jan 1, 2004

By M. Li, T. H. Dubaniewicz, H. N. Dougherty

"INTRODUCTION Underground mines have the risk of accumulation of gases if not ventilated properly or during and after emergency situations when ventilation controls become damaged or stop working. Common gases that are monitored in underground coal are carbon monoxide (CO), oxygen (O2), and methane (CH4). Methane is a gas found in coal and released through mining; its explosive range is between 5% and 15%. Methane is commonly monitored on all mining equipment and with handheld gas sensors carried by most underground coal miners. Fiber optics (FO) is a popular technology applied in underground mining, particularly for its electric isolation. Many miners are familiar with FO cables hung throughout the mine, which are primarily used in the communication of voice and data (Taylor et al. 2010). Advancements in laser and fiber optics have made this technology well suited for gas sensing the harsh environment of mining applications. The work of the U.S. Bureau of Mines on the use of fiber optic monitoring of gases in mines started in 1992. Dubaniewicz et al. (1992, 1993, 1995, 1999, 2003) developed prototype gas sensors, including methane gas sensors, for research purposes. Previous research (Dubaniewicz & Chilton 1992) identified potential fiber optic gas detection cross-sensitivities associated with the index of refraction of various gases. Index of refraction effects was noted for carbon dioxide (CO2), which is produced in significant quantities by mine fires or explosions. NIOSH released a broad agency announcement (BAA) for the development and demonstration of mine safety and health technology (CDC NIOSH 2017). The objective of this announcement was to validate a sensor, specifically fiber optic, for the mine environment and test it in an actual working mine. The RSL FO sensor “OptoSniff” provided from this work is capable of hundreds of sensing points over distances of up to 20 km, has a measurement range of 0.05% to 100%, senses in an oxygen- deficient environment, and has no gas cross-sensitivity (RSL, 2014). The RSL system is totally electrically passive outside the central control unit (CCU), which can be housed in an MSHA-approved explosion-proof (XP) enclosure or in a control room outside of the permissive area. The sensor was tested in dusty and signal loss situations, showing it is tolerant of dust, has functioned at signal losses up to 90%, and was successfully tested in a mine environment for a five-month period (Walsh et al. 2014). This paper describes how the RSL FO sensor is used for testing using smoke and its contaminants for applicability in emergency situations. The testing investigates individual contaminants such as CO2, temperature, and smoke. Each test was performed separately and methane concentration, laser power, and response time data were collected."

Jan 1, 2019

By Michael Cullen

The Quinsam Coal Mine is in the process of extracting a panel beneath the mine access road. To prevent damage to the road, and adjacent powerline, it was necessary to establish a ?protection zone? within which the extent of mining would be limited. The protection zone is analogous to the setback limit. For economic reasons it was desirable to make the protective zone as small as possible, and with the greatest extraction ratio possible. The size of the protective zone was established by determining the angle of critical deformation using the numerical model FLAC, coupled with field data on subsidence from the Mine. The angle of critical deformation (defined as the angle, measured from the vertical, at which intolerable damage is sustained by a structure) was determined to be between 0 and 5 degrees. The allowable extraction ratio in the protection zone was established using the ARMPS method of pillar design coupled with field data on pillar stability from the Mine. Excavations spans to prevent caving were determined by historical experience and field data on span stability from the Mine, coupled with numerical modeling. The minimum pillar size was determined to be 7.5m. The maximum pillar height was established at 2.5m. The maximum allowable excavation span was determined to be 8.5m. With these criteria, extraction ratios between 54 and 73% (measured in plan view) were determined to be appropriate for the protection zone.

May 1, 2001

By Z. Tang

A collaborative project was performed between NRC Institute for Fuel Cell Innovation and MagPower Systems Inc, to develop a cost effective fabrication process to manufacture the anode for magnesium-air fuel cell with improved performance. A novel fabrication process was developed, which resulted in a porous microstructure with increased surface area, instead of the traditional solid structure. This porous anode greatly increased power density in the magnesium-air power source. This fabrication process is very simple and cost effective. Especially, this process makes it convenient to incorporate different alloying additions, as well as hydrogen inhibitor and electrolyte management additive into the anode. The anode composition was designed so that micro galvanic cells were formed as current is drawn out of the fuel cell, and resulting increased dissolution rate of Mg. It is feasible to incorporate hydrogen inhibitor and electrolyte management additive into the porous anode, and the anode with some kinds of inhibitors exhibited improved electrochemical performance. This paper describes the microstructure and electrochemical performance of anodes with designated porous structure and alloying additions. Furthermore, quantitative kinetics analysis of the obtained I-V curves and electrochemical impedance spectroscopy were carried out to clarify the mechanism.

Jan 1, 2005