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By W. McCombe, G. Remple, L. Zunti, M. Bernardin, L. Nightingale-Mercer

"The McClean Lake Mill is located approximately 700 kilometres north of Saskatoon, Saskatchewan, Canada and is operated by AREVA Resources Canada Inc. (AREVA). The mill was designed to process high grade uranium ores, and has been undergoing a multiyear expansion to increase its production capacity to 24 Mlbs U3O8 per annum, while also undergoing upgrades to allow it to safely transition to processing high grade ores from the Cigar Lake Mine. During the metallurgical test work on the Cigar Lake ores, it was identified that some ore zones in the Cigar Lake deposit have a propensity to generate hydrogen gas during acid leaching. Hydrogen is a volatile and explosive gas, which poses obvious safety concerns in the leaching circuit. Uranium processing is further complicated by the fact that an oxidant in the form of oxygen gas or hydrogen peroxide is required to regenerate iron in the leach, which further increases the risk from hydrogen gas. During 2013 Hatch and AREVA designed and engineered a number of novel upgrades for the leaching circuit to mitigate the risk of hydrogen gas evolution in the process. Best in class technology was utilized in addition to control and operating strategy changes to ensure the leaching circuit can be safely operated with ores that can evolve hydrogen gas. This paper reviews the design concepts and modifications implemented on this unique and challenging project.INTRODUCTION The McClean Lake mill was originally designed to process high grade uranium ores, however until 2014 the average ore grade processed was 1%. The facility has been undergoing a multiyear upgrade and expansion to increase its production capacity from 12 to 24 Mlbs U3O8 per annum, while also undergoing upgrades to allow it to safely transition to new high grade ores, averaging 18% U, from the Cigar Lake Mine. During the last round of metallurgical test work on the Cigar Lake ores, it was identified that some ore zones in the Cigar Lake deposit had a higher propensity to generate hydrogen gas during acid leaching than previous test work had indicated. Hydrogen gas is a volatile and explosive gas, which poses obvious safety concerns in the leaching circuit."

Jan 1, 2017

By Yves Prévost, Guy St-Amant, Guillaume Dion

In 2010, the foreseen increase of copper grade in feed concentrate at the Horne Smelter was a significant challenge to maintain a steady copper flow throughout the process. The Horne Smelter process includes a Noranda Reactor, a Noranda Converter, pyro refining vessels and anode furnaces. Of the many challenges involved, improving the single casting wheel performance was one of the key topics. Its reliability had to be improved to meet the new production objectives, as anode copper production was to increase from 170 000 to 225 000 tonnes/year. A multidisciplinary team was dedicated to improve the casting wheel availability. The improvement project allowed pinpointing failure modes and reviewing operational and maintenance practices. The common understanding developed by the team allowed improving small components with a high gain-to-effort ratio. The project allowed reaching operational targets without any significant investment. INTRODUCTION In operation since 1927, the Horne Smelter, located in Rouyn-Noranda, in Quebec, has undergone several technological changes since its original construction. Built to smelt the Horne mine concentrates, the smelter also accepted some local custom feeds from the first years of operation. When the Horne mines stopped production in 1976, the plant became a 100% custom smelter. With the development of the Noranda Reactor (1973) and Noranda Converter (1997), the Horne smelter increased its productivity and improved its environmental performance. Continuous improvement of the Horne process allowed maintaining a high level of flexibility in the operation of the smelter, while improving its overall capacity.

Jan 1, 2019

By Thomas Clark

This report presents a review of the distribution and exploration potential of platinum-group elements (PGE) in Québec; it is based on published and unpublished analytical data. This qualitative evaluation of the PGE potential, whether in PGE-dominant deposits or in Ni-Cu-dominant deposits with co-product PGE, is based on interelement ratios such as Ni/Pd, Cu/Ir, Cu/Pt, and Cu/Pd. Good PGE targets, i.e., deposits associated with magmas fertile in PGE, are identified. Less favorable PGE targets, i.e., deposits associated with PGE-depleted magmas, are also mentioned. The importance of exploring for deposits similar to those at lac des Îles and East Bull Lake (Ontario) is emphasized.

May 1, 2001

By Graham Sim

Agenda ?The Water Challenge ?Examples from Three Case Studies ?Mine Drainage, 99% recovery ?Mine Drainage, 80% recovery ?Road Dust Control ?Technology Development ? Conclusion Global water challenges Assuring sustainable quantity Improving water quality Reducing energy consumption

May 1, 2011

By H. Tan

The effect of carbonaceous matter on gold extraction was investigated in cyanide systems with pure gold as well as pre-robbing sulfide gold ores. Auger studies demonstrated that the carbonaceous matter preferentially smeared on iron sulfide rather than aluminosilicate surfaces during wet or dry grinding. During mechanically mixed leaching, coating of sulfides and silicates and stripping of carbonaceous matter occurred simultaneously. TEM and XPS studies indicated preferential coating in the form of elemental (graphitic) carbon at the edges and the defect sites of particles. Interestingly, carbonaceous matter extracted from the gold ore was predominantly graphite and not preg-robbing in a solution with a high KCN concentration. However, the carbonaceous coating had a significantly detrimental effect on gold dissolution when gold was pre-ground with the gold ore. Artificial coating on gold surfaces with the natural carbonaceous matter from the ore was also found to substantially retard gold dissolution. With the addition of the natural carbonaceous matter from the gold ore, gold extraction from two non preg-robbing sulfide gold ores was inhibited owing to carbonaceous coating. The presence of carbonaceous matter significantly reduced the current density for gold oxidation and increased the current density for pyrite oxidation. This could explain the fact that carbonaceous coating hindered gold dissolution while enhanced sulfide preg-robbing.

Jan 1, 2005

By Patrick J. Williams

Defining Features of IOCGs ? Sulphur-poor Cu-Au(-Fe) deposits ? Contain low-Ti iron oxides ? Hydrothermal origin (breccia, vein, replacement) ? Local structural controls (no ?causitive? intrusions) Common Features (Economically-Significant Terranes) ? Regional space-time association with plutons ? Association with widely metasomatized crust ? Na ? Na-Ca ? K ? Variable enrichment in F, Co, Ba, LREE, U ? Little hydrothermal quartz (cf. porphyry deposits)

May 1, 2006

By Jr. Fackler

The ionization potentials of gaseous Group 11elements are similar, with Au(0) being 1.5 eV greater than the next highest member of the group, Cu(0). The ionization potentials are all very much greater than the alkali metals, making these ?coinage? elements rather unreactive to chemical oxidation. Ionization from the first oxidation state shows a different pattern, with Ag(I) being the most difficult of the Group 11 ions to lose an electron. Gold(I) is noble and only normally oxidized in the presence of strongly coordinating ligands such as thiols or cyanide. Gold(I) compounds are 2-, 3- and 4- coordinate, with 3-coordinate species generally showing visible photoluminescence under UV excitation. Dinuclear Au(I) compounds with strongly coordinating S or C ligands can be oxidized to form isolable metal-metal bonded Au(II) compounds which are often readily isolable. Many have been structurally characterized. T he ease with which electrons are lost from closed shell dinuclear sp ecies (with anti-bonding M-M interactions) increases when metalmetal bonded compounds are formed. T his observation was made by our group with oxidative-addition studies of dinuclear gold(I) ylide complexes. It was superbly demonstrated recently by Cotton?s group who reported the isolation and characterization of a dinuclear closed shell transition metal species which is more readily oxidized than cesium. Trinuclear Au(I) pyrazolates, TR(pz), carb eniates, TR(carb), and benzylimidazolates, TR(bz), are well known and undergo electron loss through oxidative addition forming Au(I,III) mixed valence species and ultimately trinuclear Au(III) species. Au(II) species are absent from isolation in these oxidations. These carbeniates and benzylimidazolates also are excellent bases for metals ions such as Tl(I) and Ag(I). The acidic, neutral trinuclear compound [Hg(C6F4)3]3 also interacts with these bases. We have also shown that the neutral organic pi acids C6F6 and TCNQ form stacked pi-acid pi-base products with the trinuclear Au(I) compounds. In this paper, the structure of the octafluoronaphthalene acid-base product will be described. It displays a feature not observed previously in that the product is photoluminescent with a bright yellow emission. The 3.5 ms lifetime is very long and reminiscent of the long lifetimes observed by Balch for the stacked methyl,methoxy Au(carb). The electrochemical oxidation of tetragold(I) clusters, [Au4(form)4] have been studied in 0.1 M Bu4NPF6/CH2Cl2 at Pt working electrode at different scan rates. Three waves are obtained at 0.75, 0.95, and 1.09 V vs Ag/AgCl at scan rate 500 mV/s. The potential of the three reversible waves is independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two waves. These tetranuclear species app ear to be effec tive catalyst precursors for the oxidation in air of CO. Introduction. The electronic structural relationships of the coinage elements and the alkali metals are similar in the sense that each have a [closed shell]ns1 configuration, yet their ionization energies (Table) and chemistries are clearly vastly different. The Group 11coinage elements have an underlying nd10 level immediately below the ns1 level. Unlike the alkali elements, ionization leaves the filled d electron shell the next accessible for further ionization. The coinage elements are all relatively ?noble?, much less reactive to environm ental conditions than the alkali metals. With the coinage elements, oxidation becomes very much dependent upon the types of ligand s availab le to bo nd to the ionized state.

Oct 1, 2003

By Rick Coleman, Chelvan (Chevy) Veloo

"P.T. Freeport Indonesia's lrian Jaya Operation has been producing copper concentrate continuously since 1972. Numerous ore discoveries and five mill expansion programs have seen the initial milling rate of 7,200 MTPD escalate to the present rate of 125,000 MTPD, producing 2.5 million pounds of copper and 3,500 troy ounces of gold per day. The latest expansion, commissioned in February 1995, incorporates a 34 foot Semi- Autogenous Grinding (SAG) Mill, two 20'x30' Ball Mills, conventional roughing, cleaner column flotation, and attendant upgrades to the existing concentrate pumping and dewatering facilities. This paper will describe the SAG Plant flowsheet, and focus on the key training issues which contributed to a successful plant start-up.IntroductionP.T. Freeport Indonesia's operations in the Ertsberg mining district are located in the Jayawijaya Mountains of Irian Jaya, the easternmost province of the Republic of Indonesia. P.T. Freeport Indonesia (PTFI), the operator, is owned by Freeport MacMoRan Copper and Gold (81.3%), the Government of Indonesia (9.4%), and private Indonesian investors (9.4%). Geographical location, and sailing distances are provided on the attached location map.The operation stretches over 7 4 miles ( 114 km) from the dewatering and concentrate shipping facility at the Port of Amamapare on the Arafura Sea to the Grasberg open pit located at 3400m. The regional geology is covered in detail by Van Nort et al (1991 ), with current proven and probable reserves estimated at 1.13 billion metric tonnes grading 1.30% Copper, 1.42 ppm Gold, and 4.06 ppm Silver. The Grasberg open pit mining operation provides 92% of the mill feed, and is described in detail by Hickson (1991). The remainder of the mill feed is derived from several underground block caving operations. Current production rates provide a mine life in excess of 25 years. However, very favorable geology in the area leads to expectations that additional reserves will extend the life of the operation considerably."

Jan 1, 1996

By V. M. Robb, F. Walraven, L. J. Robb

"The old Albert Silver Mine is a polymetallic deposit comprising concentrations of CuPb- Zn-Ag-U-F within a set of sub-parallel quartz-hematite veins which occur within the fine-grained apical phase of the 2050 Ma old A-type Bushveld granites. Mineralization occurs as an early pyritechalcopyrite- arsenopyrite-galena-sphalerite-(argentiferous) tetrahedrite paragenesis followed by a later, more oxidized assemblage comprising chlorite-hematite-fluorite-pitchblende. Accumulation of metals appears to have taken place at the interface between a coarse-grained porphyritic granite and an overlying fine-grained phase: veins occur in the latter and represent leakage of magmatic fluids from the differentiated, water-saturated, subjacent granite.Mineralization processes in the Bushveld granites are believed to be related to long-lived circulation of dominantly magmatic fluids stimulated by the high heat productive capacity of the host rocks. Endo- and exogranitic tin-tungsten and base metal mineralization formed during an evolving hydrothermal system that lasted for several hundred million years, forming innumerable small- to mediumscale polymetallic deposits. At the Albert Silver Mine, unroofmg of the cover sequences at circa 1600 Ma to 1700 Ma resulted in the incursion of lower-temperature, high-f02 meteoric fluids which remobilized the earlier sulfides and introduced the paragenetically late U-F mineralization."

Jan 1, 1994

By V. I. Ryaboy, V. P. Kretov, I. V. Ryaboy, E. D. Shepeta

This paper studies the features of known and newly synthesized dialkyldithiophosphates and reagents with thioamide groups when separating copper-containing and arsenic-containing minerals in the flotation of skarn-scheelite-sulphide ore at the Primorskaya concentration plant. The optimization of dialkyldithiophosphate collectors was based on the study of their surface activity at the liquid-gas interface and estimated hydrophobic abilities. The flotation experiments show that the selectivity of action of the reagent increases with an increase of its surface activity and a reduction of hydrophobic ability when separating chalcopyrite and arsenopyrite. IMA-225-5 was proposed as a more efficient dialkyldithiophosphate collector, which increases the recovery of copper by 2.8% compared to the industrially used collector IMA-I413. Selection of the optimal structure for reagents with thioamide groups (derivatives of thionocarbamate and thiourea) was carried out according to their acidity and the presence of hydrophilic particles in their structure. Calculations were performed depending on the pH of the solution of chalcopyrite to determine the optimum reagent sorption and to further optimize the structures of these reagents. The tests with reagents with thioamide groups show an increase in copper recovery by 3-4% together with a significant increase of arsenic content compared to IMA-225-5. As a stronger collector with thioamide groups, it was recommended to use sample 234, which belongs to the thiourea derivatives. IMA-225-5 was recommended for industrial tests at the Primorskaya concentration plant. Thus, this study has shown that using dialkyldithiophosphate is more appropriate if it is necessary to increase the selectivity of separation of copper-containing and arsenic-containing minerals, and using reagents with thioamide groups, or their combinations with dialkyldithiophosphates, is more appropriate if it is necessary to increase the recovery of copper or the quality of copper concentrate with less selectivity of the process.

Jan 1, 2016

By R. A. Sproule

Abitibi Greenstone Belt ? ~2.745 to 2.680 Ga (U-Pb zircon ages) ? Several lithologically-distinct and structurally repeated(?) assemblages ? Represents: ? Allochthonous terranes? ? Single autochthonous terrane? ? Combination of the above Volcanology of Komatiites in the Abitibi greenstone belt ? Tisdale and Kidd-Munro assemblages have channelized flows ? Pacaud and Stoughton-Roquemaure assemblages DO NOT have channelized flows ? Only Tisdale and Kidd-Munro assemblages are mineralized

May 1, 2003

?Podolsky Water treatment plant discharges to Norman North bog which drains into Whistle / Post Creek watershed and into Wanapitei Lake ?Whistle Mine closed and reclaimed but continues to treat and discharge water to Whistle Creek

May 1, 2009

By Reik M. Winkel

Radar Technologies are successful implemented in the military industry since decades and recently found their way in the mining industry as level gauge radars for bin applications. The latest generation of microwave radar sensors are capable to provide geometrical data of the surrounding area of mining machines, too. Radar sensors are an improvement to laser scanners as they are more robust and able to penetrate dust and mist. Radar sensors will be the key source for operator assistance systems. indurad and RWTH Aachen University conducted a large series of tests at open pit mines and underground coal mines to determine the potential of the new two dimensional Dual Range Radar iDRR. Several applications were determined as highly feasible and are now completed respectively in the implementation stage. The authors are giving an insight in the experimental results, the implementation and an outlook of future applications for this technology.

Oct 1, 2009

By Belinda Campbell

Tools for Consistency 1. GIS Web Site 2. National Project Management System 3. Site Grouping Approach (721 PIDs) 4. Mine Reclamation Standing Offer Agreements ?Contracting tool 5. Remedial Objectives Guidance Document Background ?CBDC (now ECBC) is a Federal Crown Corporation and falls under federal jurisdiction. ?When it stopped mining coal, CBDC turned its attention to cleaning up and closing out its industrial sites. ?Public Works and Government Services Canada is common service provider to the GoC. ?Expertise in environmental, engineering, IT, project management, communications, GIS, real property management.

May 1, 2011

By H. J. McQueen

Friction stir welding (FSW) generates complex microstructures in the nugget and thermomechamically affected zones (TMAZ) that have led to diverse explanations. However, consideration as an extension of microstructure development in piercing/extrusion can lead to a better understanding of flow patterns and microstructures during FSW. Furthermore, the intense strains in the nugget/TMAZ can be interpreted by comparison with ultra-high strains in torsion that exhibit dynamic recovery as extending into regions with high angle boundaries strongly serrated with spacing near the subgrain size defined by the high temperature. The subgrain diameter and extrusion pressure have been shown to be dependent on the Zener-Hollomon parameter Z (=t exp(Q/RT), Q activation energy, R gas constant) combining temperature T and strain rate E in the same mariner as for torsion and compression. Moreover, such tests exhibited steady state stress os above a certain strain Es (rising as Z increases) in which T, , subgrain diameter and dislocation spacing remain constant. Due to the subgrain boundaries (SGB, low angle <5°, i.e.,LAB), continually rearranging by migration, decomposition and reformation, the subgrains remain equiaxed in elongating grains, whose boundaries (GB) become serrated as they migrate to absorb SGB. As confirmed by straining in torsion at constant T and Z. , more subgrains bordering the greater GB area have several high-angle facets (HAB) ; these small cellular regions with a mixture of HAB and LAB facets are designated HAB-subgrains. As serrations in neighboring grain boundaries impinge, the grains pinch off becoming shorter; this occurs at higher strains as subgrain size decreases with rising Z. The pinching-off makes the neighbors thicker so the grains never become thinner than about two subgrain diameters. In conjunction with such geometric dynamic recrystallization (gDRX), GB&apos;s undergo a net migration into grains with denser substructure, enlarging those with larger subgrains. Consequently a better name has been proposed: grain dimensioning dynamic recovery (gDRV).

Jan 1, 2007

By E. Dernedde

A few studies have suggested that the rate of adsorption of hydrogen fluoride on smelter grade alumina is determined by kinetic factors. However, no performance equation for dry scrubbers has appeared in the literature so far. Experimental data from a pilot dry scrubber with co-current flow were compared with results of kinetic models of adsorption, film diffusion and pore diffusion. The pore diffusion model was deemed the most appropriate. It was transformed into a performance equation for steady-state operations of dry scrubbers by the inclusion of the alumina recirculation. Operating results of industrial dry scrubbers with co-current flow were successfully evaluated by means of the performance equation. The average fluoride content of the alumina was also estimated by using the pore diffusion model.

Jan 1, 2011

The New Zealand opportunity NZ?s only significant phosphate deposit 1 million tonnes imported annually - mostly from Morocco US $180/t + $75/t freight

May 1, 2013

By Alvis L. Lisenbee, Colin J. Paterson, Mustafa M. Hariri

"Abstract-The schist-, sediment-, and intrusion-hosted Tertiary Au-Ag hydrothermal deposits of the northern Black Hills, South Dakota are localized and controlled by various types of fractures. This study is an attempt to distinguish between and discuss the possible causes of these fractures in three mines: Richmond Hill, Annie Creek - Foley Ridge (ACFR), and Gilt Edge.Five models based on the structural and tectonic settings of the northern Black Hills are proposed for the fracture origin. In Richmond Hill mine, mineralized fractures within the schist-hosted deposits are in the form of veinlets and stockworks. Larger veins filling open spaces along schistosity planes are also present. Fractures in Richmond Hill mine are related to breccia pipe emplacement and influenced by the Precambrian foliation.Fractures in sediment-hosted (ACFR) and intrusion-hosted (Gilt Edge) deposits are mode I systematic joints. These fractures, and similar ones examined in seven locations outside the mines, are related mostly to the formation of the Lead-Deadwood dome. Fracture trends vary from one area to another depending on their location with respect to the dome. Other factors, such as the Black Hills uplift, pluton emplacement, and Precambrian foliation, may also affect the fracture trends. The proximity of the mines to domes formed by multiple intrusions, the associated fracture patterns and density, and existence of breccias, may be used in exploration for similar deposits in the northern Black Hills or other areas of similar geologic settings."

Jan 1, 1995

By Alvis L. Lisenbee, Colin J. Paterson, Mustafa M. Hariri

"The schist-, sediment-, and intrusion-hosted Tertiary Au-Ag hydrothermal deposits of the northern Black Hills, South Dakota are localized and controlled by various types of fractures. This study is an attempt to distinguish between and discuss the possible causes of these fractures in three mines: Richmond Hill, Annie Creek – Foley Ridge (ACFR), and Gilt Edge.Five models based on the structural and tectonic settings of the northern Black Hills are proposed for the fracture origin. In Richmond Hill mine, mineralized fractures within the schist-hosted deposits are in the form of veinlets and stockworks. Larger veins filling open spaces along schistosity planes are also present. Fractures in Richmond Hill mine are related to breccia pipe emplacement and influenced by the Precambrian foliation.Fractures in sediment-hosted (ACFR) and intrusion-hosted (Gilt Edge) deposits are mode I systematic joints. These fractures, and similar ones examined in seven locations outside the mines, are related mostly to the formation of the Lead-Deadwood dome. Fracture trends vary from one area to another depending on their location with respect to the dome. Other factors, such as the Black Hills uplift, pluton emplacement, and Precambrian foliation, may also affect the fracture trends. The proximity of the mines to domes formed by multiple intrusions, the associated fracture patterns and density, and existence of breccias, may be used in exploration for similar deposits in the northern BlackHills or other areas of similar geologic settings."

Jan 1, 1995

By T. S. Grewal, S. C. Gupta, H. Natarajan, T. W. McQuade, N. Nejibulloev-Mamedov

Cigar Lake is one of the world’s largest high-grade uranium mines. The ore mined at Cigar Lake is milled at Orano Canada Inc’s (Orano) McClean Lake mill. The average Cigar Lake ore uranium grade since the start of mining activities in 2014 is 17.8% U (range 8– 28%). To achieve budgeted production of 18 M lbs U3O8/yr the required average feed tonnage to the mill is about 45 kt/yr. Arsenic, occurring as arsenides and sulpharsenides, is one of the major elements of concern associated with Cigar Lake ore. The leaching process is a sulphuric acid leach under oxidizing conditions at near atmospheric pressure. The presence of arsenic in the ore consumes oxidant in leaching as well as ferric sulphate in tailings preparation for arsenic sequestration. The average arsenic grade since the start of mining at Cigar Lake is 0.57% As. Further, the ore is hosted in a matrix of sandstone and clay, which results in poor settling in CCD. The average uranium grade for the balance of Cigar Lake Phase 1 ore is expected to drop to 12.5% U and the average arsenic grade is expected to increase to 1.6 % As, with an annual average peak of 2.5%. Therefore the tonnage throughput required to sustainably meet the production target will increase to 55 kt per year. Orano partnered with Hatch Ltd. (Hatch) to perform a gap analysis study to identify key circuits and equipment in the mill that would require debottlenecking. A METSIM mass balance model of the McClean Lake mill was generated and validated with actual mill operating data. Various feed scenarios were then studied, and the outcome was a traffic light table, which highlighted feed scenarios that exceeded installed capacity of major equipment and circuits. The results provided the basis for the PDC for the pre-feasibility study. This paper will outline the results of the gap analysis, the mass balance model, the feed scenarios and the study undertaken to prepare the McClean Lake mill for the change in ore quality from Cigar Lake.

Jan 1, 2020