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By M. B. Kime, E. K. Kanowa

"Heap leaching of low-grade copper-cobalt oxidized ore and solvent extraction of copper, cobalt, manganese, and zinc were investigated. Heap-leaching parameters were optimized using agitated and tray batch leaching tests, capped by tests on a pilot semicontinuous heap-leach plant. The optimum pregnant leach solution yielded 2,350 mg/L Cu, 3,800 mg/L Co, 3,600 mg/L Fe, 130 mg/L Mn, 25 mg/L Zn, and 0.58 g/L solids in suspension, with pH and acidity of 1.27 and 3.66 g/L, respectively. Copper, cobalt, and impurities (Mn and Zn) were extracted using (v/v) 30% CP-150, 20% IONQUEST® 290, and 20% D2EHPA, respectively; overall recoveries of copper, cobalt, and impurities were 98, 99, and 70%, respectively.RÉSUMÉ La lixiviation en tas des minerais oxydés de cuivre et de cobalt et l’extraction par solvant du cuivre, du cobalt, du manganèse et du zinc ont été étudiés. Les paramètres de lixiviation en tas ont été optimisés à l’aide d’essais de lixiviation en discontinu sur un plateau, complétés par des essais relatifs à une usine pilote de lixiviation en tas en semi-continu. La liqueur-mère optimale a produit 2 350 mg/L de Cu, 3 800 mg/L de Co, 3 600 mg/L de Fe, 130 mg/L de Mn, 25 mg/L de Zn et 0,58 g/L de solides en suspension, avec un pH et une acidité respectifs de 1,27 et 3,66 g/L. Le cuivre, le cobalt et les impuretés (Mn et Zn) ont été extraits avec un pourcentage volumique (v/v) de 30 % de CP-150, de 20 % d’IONQUEST ® 290 et de 20 % de D2EHPA, respectivement. Les récupérations totales de cuivre, de cobalt et d’impuretés étaient de 98 %, 99 % et 70 % respectivement.INTRODUCTIONBoss Mining S.P.R.L. is a privately owned hydrometallurgical plant located in southeastern Democratic Republic of Congo. It treats oxidized ores of copper and cobalt that are recovered by sulphuric acid heap leaching (Trujillo, Cisternas, Gálvez, & Mellado, 2014; Kime, Kanowa, Mulaba- Bafubiandi, & Diyambi, 2016) and solvent extraction processes (Crane, Urbani, Dudley, Horner, & Virnig, 2009; Fisher, 2011; Kime et al., 2016). The ore to the plant is primarily sourced from the Luita and Mukondo mines. Geological prospecting work by Gecamines and Boss Mining showed that the Mukondo mine contains a very large cobalt reserve not yet exploited, but with grades as low as 0.2%.Currently, Boss Mining is focusing on the production of copper, but is investigating methods to efficiently produce both copper and cobalt. A challenge in the production of cobalt from this ore is its presence in the third oxidation state. This requires the addition of reducing agents, which increases the overall operating cost (Kime & Makgoale, 2016). Cobalt solvent extraction is also very sensitive to impurities such as nickel, zinc, manganese, and aluminum, which are often co-extracted (Swartz, Donegan, & Amos, 2009). This sensitivity to impurities requires the optimization of operational parameters to lower impurity levels as much as possible in the electrolyte."

Jan 1, 2017

By Paul W. Shelley, Daniel J. Hodges

The mining industry is undergoing a period of rapid transformative change.  This is the result of the social and financial accountabilities that the industry is faced with because of the world’s desire to cap average temperature increase to 1.50C above pre-industrial levels (UNFCC, 2016).  To limit global warming to 1.50C, greenhouse gas emissions must peak before 2025 at the latest and decline 43% by 2030.  In hard rock mining, comminution is identified as the major energy consumer, being responsible for 40-60% of the electricity use.  It follows that comminution is the major greenhouse gas emission process of the mine.  All effort is being made to radically reduce the carbon emissions of comminution. Grinding media plays a large role in the energy consumption and carbon emission story.  In recent years industry practitioners have attempted to quantify the grinding media carbon footprint.  This paper makes a definitive contribution to that discussion.  The grinding media carbon footprint is quantified in Scope 1, 2 and 3 emission terms in the context of a grinding media supplier.  Major emission contributors, steel, natural gas and electricity are discussed in detail.  The steel industry transition is a key factor. The paper will explore the steel industry transition and its effect on grinding media manufacturing.  The carbon footprint of heritage steel process routes are analysed and compared with the process routes of the future.  Emerging steel making technologies are presented and discussed.  The future of the steel manufacturing and procurement route for grinding media is proposed. This narrative allows for a comparison between the heritage carbon footprint and the future carbon footprint of manufactured grinding media.  Of equal importance is the opportunity of reducing the grinding media carbon footprint in the field.  The paper explores possibilities of reducing the grinding media carbon footprint at the customer site.  Media in use options are presented that take account of the mineral characteristics, the mill dynamics, and the product metallurgy to optimise both carbon footprint and media performance. It is intended that this is a landmark paper in the discussion of the carbon footprint of grinding media.

May 4, 2025

By R. Minto, W. G. Davenport

The slag removed from the reverberatory furnaces of copper smelters contains significant copper values. A serious financial loss is involved, as further recovery operations are not normally carried out. This paper describes the factors affecting physical transport of matte into slag by gas bubbles, and the subsequent entrapment and flotation of matte drops. Three distinct patterns of transport behaviour have been identified from studies of a number of liquid/liquid systems, including liquid metal and liquid matte systems. A theoretical approach is proposed to explain these behaviour patterns, and to predict transport and entrapment behaviour in matte/slag systems. The concepts of "Film Coefficient" (ø) and "Flotation Coefficient" (?) are introduced. The effects of smelting process variables on the physical loss of copper matte in slag are also discussed.

Jan 1, 1972

By W. S. Fyfe

Gold is mobilized and precipitated in a wide variety of environments ranging from those of weathering and biological phenomena, to pluton emplacement to deep metamorph ism . But it appear that pervas ive leaching of large rock volumes fo llowed by the focussed di charge of typically low salin ity flu ids is frequently involved. There are great gaps in our knowledge, particula rly with re pect to gold in very high temperature fl uids generated at near Moho depths. But uch flu id may play an important part in Archaean pluton associated lode gold deposits whe re ultra high temperature fluids, rich in C02-CO-COS, may be associated with magma underplating and crustal assi mil ation processes (sag subduction) associated with very den e ult ramafic magma . Other environment with great potential include those of major thru t fau lt and strike slip fa ult s where large quant ities of fluids are mobilized .

Jan 1, 1986

By G. A. Vissac

IN THE preliminary design of a coal washery, the most important factor to evaluate is the ash content of the final product. The ash content permissible may be imposed by market demands, but, in the final analysis, sooner or later - as most consumers today are buying coal on a 'heat value' basis - the coal operator has a certain margin of latitude. and the ash content of the coal to be delivered can be determined on the basis of maximum returns and highest profits. A few years ago, the most desirable separation was selected on the basis of the plus-minus 0.10; that is, the most desirable gravity of the separation was selected at the point showing a minimum amount of near gravities in the raw coal. The reason for this was an expected wide error over these near gravities. Today with the recent development of cry accurate, automatically controlled cleaning apparatus, a much larger latitude is possible, and the most desirable gravity of separation can be selected, almost exclusively, on the basis of the economic factors involved. To illustrate these new methods of investigation we shall give two examples, based on actual coals from the western United States.

Jan 1, 1957

By J. R. Levin, E. J. Schelter

"We present some of our recent efforts in the development of predictive, directed oxidation chemistry of cerium(III) complexes under non-aqueous conditions. The electrochemistry of cerium(III)- alkali metal heterobimetallic aryloxide complexes is reported and compared with cerium aryloxide complexes that are kinetically stabilized by hydrogen bonding cations that span between the complexed aryloxide ligands. Comparative electrochemical measurements reveal differences between the heterobimetallic complexes and the hydrogen-bonded complexes.INTRODUCTIONThe rare earth elements comprise the lanthanides, La–Lu, and the element yttrium (Aspinall, 2001). Rare earth ores such as monazite, LnPO4, and bastnäsite, LnFCO3, typically bear mixtures of light rare earths: La–Sm while monazite, LnPO4, contains mixtures of heavy rare earths (Eu–Lu) (Cotton, 2006). Pure rare earth elements typically are isolated using a liquid-liquid separations process.(Bautista, 1995) The hydrometallurgy of these elements is a difficult problem because the separation factors between neighboring rare earths, which are predicated on the small differences in the sizes of the trivalent ions, are quite small (Cox, 1992). The element cerium, with its 4f1 electronic configuration in the trivalent state, is unique among the rare earth elements due to a relatively accessible 4f0 electronic configuration. The accessibility of the 4f0 configuration underlies the chemistry of cerium(IV), the only rare earth ion with molecular chemistry in the tetravalent oxidation state (Cotton, 2006). Cerium is trivially separated from mixtures of light rare earths by making use of its unique oxidation chemistry. In an effort to extend separations chemistry by oxidation reactions to other rare earth elements such as terbium and praseodymium, the solution electrochemistry of well-defined cerium complexes is of interest."

Jan 1, 2012

By Robert Y. Lamarche

On exploite le chrysotile dans le sud du Quebec depuis plus de cent ans. Au cours des dernieres decennies, cette variete d'amiante est devenue une des principales substances minerales produites au Quebec. Bien que la production de fibres d'amiante ait diminue de J 365 779 ten /979 a que!que 700 000 ten 1983, le Quebec n'en demeure pas mains une des principa/es sources d'approvisionnement mondial de ce mineral, la valeur des exportations quebecoises ayant ete de l'ordre de 315 millions de dollars en 1983. Dans la presente contribution, nous passons en revue que!ques-unes des notions mineralogiques sur l'amiante, depuis l'etymologie du mot et les proprietes physico-chimiques du mineral, jusqu'd ses principales utilisations commercia/es et industrielles. Un des deux objectifs principaux de noire article est de definir brievement le contexte geologique regional, la lithologie et /'age des roches ultramafiques serpentinisees et de decrire les principales caracteristiques des gftes de chrysotile qu'elles renferment et qui furent exploites a date dans /es Appa/aches du sud quebecois. Nous concluons en dressant un tableau synoptique de la metallogenie et en soulignant le role preponderant qu 'ont joue /es mouvements tectoniques majeurs, a la jonction des plaques et au sein des feuillets et copeaux de la croute oceanique (lithosphere et manteau superieur), sur la genese des gftes de chrysotile dans les roches ultramafiques serpentinisees, et tout particu!ierement dans celles associees aux series ophiolitiques du Paleozaique inf erieur.

Jan 1, 1984

By G. Mousavian, R. Bagheri, N. Dalili

Polypropylene (PP) and its composites have an increasing use in automobile and domestic industries. Since the published results on strain rate effect on yield behavior do not match, and there is a high attention paid for effect of nanometeric fillers on deformation behavior of composites, in this research the strain rate effect on yield behavior of PP and the effect of nanometeric fillers on deformation behavior of PP have been studied. Microscopic observations and tensile tests in different strain rates on neat PP samples and on samples filled with 5, 10 and 15 %wt have been used. A dramatic change in behavior for the modulus and post-yield slope curves when the strain rate is between 0.0433-0.05 s-1 has been observed. Microscopic observations on PP indicate a change in deformation mechanism from shear yield to crazing at the same strain rate that the change in behavior of curves occurs. It has been observed that in PP nanocomposites with higher amount of calcium carbonate, fracture in early stages of deformation occurs in lower strain rates. In other words for a fixed stain rate there is a critical filler percentage such that if the filler percentage is higher then early-stage fracture will occur. Similarly for a fixed filler percentage there is a critical strain rate and in higher strain rates early fracture will occur. The critical stain rate will decrease as the filler percentage increases and vice versa.

Jan 1, 2006

By P. Reyes

The start up and operational optimization of the No. 3 Oxygen Plant at the Caletones Copper Smelter of the Codelco - Chile El Teniente Division is summarized. In addition, the economic impact of such optimization on the production cost of oxygen and others aspects associated to the operational robustness as well is detailed.

Jan 1, 2007

By Gerald Sanders

Presentation Topics ? We?re Going to the Moon Again? ? What is Lunar Mining ? In-Situ Resource Utilization? ? What Are The Challenges to Lunar Mining? ? What is NASA Currently Doing?

May 1, 2009

By G. N. A. Senhorinho, J. A. Scott, C. A. Laamanen

"Closed mine sites are widely regarded as a negative asset due to their legacy of environmental impacts. These sites are often characterized by waterbodies with elevated metal concentrations and low pH that are traditionally considered to have little or no value. These sites are potential sources of beneficial biocompounds produced by microalgae in response to environmental stresses. A bio¬prospecting program found that certain microalgae from waterbodies near historical mine sites exhibited higher antibacterial activity than any microalgae previously reported in the literature. There is potential for the mining industry to be involved in examining features such as tailings ponds at mine sites for high-value compounds, including ones that might help mitigate rapidly growing microbial resistance to current antibiotics. ¦ KEYWORDS Antibacterial, Closed mining sites, Metabolites, Microalgae, Stressed environments RÉSUMÉ Les sites miniers clôturés sont généralement considérés comme des actifs négatifs en raison de leurs répercussions sur l’environnement. On trouve souvent sur ces sites des étendues d’eau affichant de fortes concentrations en métaux et un pH faible, généralement considérées comme ayant peu, voire pas de valeur. Ces sites sont des sources potentielles de biocomposants bénéfiques produits par des microalgues en réponse aux perturbations environnementales. Un programme de bioprospection a permis de déterminer que certaines microalgues trouvées dans ces étendues d’eau à proximité de sites miniers historiques présentaient une activité antibactérienne supérieure à celle mentionnée dans toute la docu¬mentation existante. L’industrie minière pourrait bien participer à l’examen de particularités telles que la recherche de composants à haute valeur dans des bassins de décantation des résidus sur des sites miniers, notamment des composants qui pourraient aider à atténuer l’augmentation rapide de la résistance micro¬bienne aux antibiotiques actuels. ¦ MOTS CLÉS antibactérien, environnements perturbés, métabolites, microalgues, sites miniers clôturésINTRODUCTION The mining industry is one of the largest economic drivers in the world. Within Canada, for example, it contributed 2.8% (C$57.6 billion) of the 2016 gross domestic product (Marshall, 2016). Canada also has the highest non-ferrous exploration budget worldwide (Marshall, 2016); therefore, it is likely that mining operations, mine waste disposal, and the number of closed sites will continue to grow in Canada. The environmental impact of mining operations stems from the volume of tailings produced, which can be up to 97–99% of the total volume of ore processed at a mine (Adiansyah, Rosano, Vink, & Keir, 2015). In 2010, mining was the world’s largest industrial producer of waste at a total of 65 billion tonnes: 51 billion tonnes of waste rock (mine overburden) and 14 billion tonnes of tail¬ings (Jones & Boger, 2012)."

Jan 1, 2019

By R. Blosser

Phelps Dodge introduced a process improvement model known as Quest for Zero in 2001. In 2004, the focus of Quest for Zero shifted from corporate-led initiatives to projects led by site personnel. The Hydrometallurgical Division at Morenci focused on two (2) significant process improvements: reducing electrolyte bleed and organic losses. In September 2004, Morenci kicked off a bleed reduction project to reduce electrolyte bleed by 45%. By the end 2005, electrolyte bleed was reduced by 55% through understanding and reduction of variance. Significant process changes made during this time period include changes in acid-addition strategy, reduction of uncontrolled bleed, and optimization of bleed placement. In April 2005, the organic reduction project began with the goal of reducing losses by 15%. Operational improvements during this project included improved organic recovery systems, mixer speed optimization, and picket fence installation. By the end 2005, this project reduced organic losses by 35% and current losses are 48% lower than at the start of the project. These projects and smaller Questfor Zero projects have resulted in sustainable annualized savings of $13 million in Morenci hydrometallurgical operations. Through the use of Six Sigma tools, process variances can be controlled and reduced.

Jan 1, 2007

By R. Wang

"Under high stress conditions, rock bursts, borehole breakouts, and spalling events are common phenomena that occur around underground openings. In general, together these three phenomena represent brittle failures of an intact rock mass; however, individually they reflect different failure modes under high stresses. After analyzing and comparing the stress-to-strength criteria for rock bursts, borehole breakouts, and spalling events, proposed by previous researchers, it is found that these brittle failure phenomena share common stress-to-strength prerequisite. The stress-to-strength preconditions for brittle failures can be defined by the ratio of the maximum tangential stress around an underground opening to the uniaxial compressive strength (UCS) (s?max/sci) or by the ratio of the maximum far-field principal stress to the UCS (s1/sci). Both these indicators can be used to reflect the same stress preconditions. For s?max/sci, a ratio of 0.4±0.1 represents the critical stress requirement for brittle fracture. However, for s1/sci, a ratio of 0.15±0.05 should be considered as the critical stress requirement. Numerous engineering case studies and analysis of rock mechanics based on the Hoek-Brown criterion also verify these two stress-to-strength preconditions. Here, these two indicators are presented with an error range because complex rock mass quality ratings, lithology, and geotechnical conditions have profound impacts on the stress-to-strength preconditions for brittle failures. INTRODUCTIONHigh stresses are one of the most important factors that must be considered when undertaking underground rock mass projects (Kaiser et al., 1998). Wang et al. (2009) reviewed current progress in the evaluation of high stresses and their corresponding criteria. However, after clarifying the definition of high stress, civil engineers need to understand the deformation and failure behaviors of rock mass around an opening under high stresses. Under high stress conditions, the deformation of rock masses around an opening can be categorized into two groups, i.e., severe brittle failures (or rock bursts) and compressional plastic deformation of the surrounding rock mass, as indicated in Figure 1."

Jan 1, 2015

By J. P. Grau, J. Z. Lu

"Thickeners/clarifiers are widely used in coal preparation plants, potash processing and other mineral processing facilities. Thickeners play a very important role in slurry treatment systems to accomplish solid/liquid separation. The demand for larger plants and the increased thickener handling capacities sometime require thickener diameters as large as 200m. The development and use of high capacity thickeners makes it possible to increase the handling capacity of these thickeners by several to more than 10 times compared to conventional thickeners. Hence, for a given slurry rate, selection of a high capacity thickener will significantly reduce the footprint of the thickener. Much higher handling rate, higher concentration of underflow, clearer overflow and lower capital cost are obvious advantages of high capacity thickeners; however, some process requirements and the concerns of operational cost, especially the flocculant cost of a high capacity thickener operation, keep some engineers selecting conventional thickeners and staying away from the high capacity thickeners. Forty years after the first high capacity thickener was developed, there are still arguments in the selection of conventional thickeners or high capacity thickeners in mineral processing. The arguments will continue unless there is a clear picture of capital cost vs. operational cost for each of the thickener types. The purpose of this paper is to analyze these costs and to provide guidelines for selection of thickeners. INTRODUCTIONThickeners/clarifiers are widely used in various slurry treatment systems. For mining and mineral processing, thickeners are an integral part of the solid/liquid separation system. The feed to the thickeners are processing slurries. The fundamental mechanism for the solids/liquid separation is for the solid particles in the slurry to gravity settle inside the thickener tank. The clear water overflows from the top of the thickener tank and is typically reused in the processing circuit, and the concentrated underflow is discharged to different downstream process systems depending on the application of the thickeners. The general requirements for a thickener operation include high density of underflow and clear overflow. Since thickener operation consists of continuous feeding, overflow and discharge of underflow, the solid particles will gravity settle against an upward flow with its velocity dependent on the feed rate and the underflow discharge rate. Higher feed rates to a given thickener produce higher upward velocities. Underflow discharge is typically relatively small compared to the amount of overflow. The upward flow tends to take particles up to the overflow. Only those particles having a settling velocity greater than the upward flow velocity will possibly settle out. Hence, thickener feed rate has to be controlled so that the required overflow water clarity can be achieved."

Jan 1, 2012

By Peter A. Adcock, Rob Fraser

Interest in monitoring nucleation overpotential in electrometallurgical processes dates back some 40 years or more. Conversely, remarkable progress has been made in recent years on describing in detail the processes involved in the formation of thin films by electrodeposition. The newer body of work underscores a need for greater clarity in speaking about the role of nucleation and in the acquisition and interpretation of nucleation overpotential measurements – the aim of this paper. In electrometallurgy, it is generally desirable to form deposits that remain smooth, compact, and relatively fine-grained while the deposit grows to a thickness on the order of 5-10 mm, about 100 times thicker than technological thin films. Hence, we distinguish two kinds of nucleation that can result in formation of new grains:- (1) initial nucleation (onto the substrate surface) of islands that coalesce into growing deposit, and (2) ongoing nucleation of new grains on the deposit surface long after the substrate has been covered and ceases to have a direct influence. Nucleation overpotential of the first type should be measured on an electrode surface truly representative of a real industrial substrate. The second type requires judicious choice of electrode material – an “ideal foreign substrate”. In general neither the industrial substrate nor native metal to be deposited is suitable for measurement of the second type of nucleation overpotential, because of interference by other processes. For the future, clear terminology is needed to distinguish these two types of nucleation potential. The second is the one for which the type of plot dubbed by Moats and Derrick as an “Adcock plot” and by us as a “Kerby-Adcock plot” was first conceived and correlated with relatively thick zinc electrodeposits. The data of Moats and Derrick showing trends for copper electrodeposition on stainless steel and on copper electrodes are interpreted within this framework.

Jan 1, 2016

By R. T. Saxon

Prior to November 1975 there were several failures of front -wheel spindles on large haulage truck s in B.C., attributed to fatigue cracks. Since that time, a non-destructive test program has succeeded in detecting the cracks before catastrophic failure, However, the author regards the failures as just one example of a. general unreliability in large high-strength steel castings and urges the industry to look to forgings for sensitive components of heavy equipment.

Jan 1, 1977

By C. Rocha R.

Petioles is a mining group with integrated operations in the smelting and refining of non-ferrous metals, and is also a chemicals producer. Peñoles is the world's foremost producer of refined silver, metallic bismuth and sodium sulphate and is the leading Latin American producer of refined gold, lead and zinc. The Met-Mex Petioles Zinc Plant commenced operations in 1973 with an annual production capacity of 105,000 t/y. Year after year the production has been increased, and at present, the production capacity is 240,000 t/y. In this paper, the leaching process, particularly the operation of the jarosite circuit and its effective removal of impurities such as arsenic, antimony, indium, selenium and tellurium, is reviewed.

Jan 1, 2006

By A. Abdollahi

Modification of the silicon in Al-Si alloys can be performed by adding a very small amount of some elements like Na, Sr and Ca to alter the form of silicon from an acicular shape to a fine fibrous one. This modification results in a considerable improvement in mechanical properties especially elongation, Metallographic observations in A356 alloy indicated the degree of the modification with Na, Sr and Ca, They showed that the effect of Ca as a modifier is not as strong as is Na or Sr while Na is the most effective modifier, Although modifiers improve mechanical properties, they also increase porosity in castings, The reduced pressure test (RPT) and Tatur test showed that the increasing porosity with Na is the most and with Sr is the least.

Jan 1, 2004

By E. Ghali, J. F. Dorion

This paper presents the results of on-going investigations on the influence of corrosion on the performance of support systems in selected underground gold mines. Rock support is exposed to various conditions that can be aggressive. Samples of corroded support were analysed using SEM and photomicrography to determine the main corrosion forms. Tests are on-going in controlled corrosion chambers to qualify and quantify the impact of rock and minerals particles on steel corrosion. As more data become available these relationships can lead to useful information on the choice of support systems and reliable estimates of their longevity.

Jan 1, 2011

By David Penswick

Despite anecdotal evidence to the contrary, the mining industry is not in decline. Rather, the world?s largest mining companies are among the most consistently profitable companies in any industry. In many cases, profitable mining companies have been built around a few large scale, long life mines. These criteria for success ? size and long life ? have led to the current preference for deposits that can be exploited using open pit methods. However, developments in the science of block caving have resulted in this mining method achieving costs and productivities that are competitive with the largest open pits, while achieving widespread applicability. One implication of the low costs and widespread applicability of block caving is that some current open pits are possibly too deep.

May 1, 2003