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Technical Challenges in the Flotation of Molybdenite from Porphyry Copper Ores

Sep 13, 2010

By D C. Grant, D J. Goudie, E Baird

The Scanning Electron Microscope – Mineral Liberation Analyzer (SEM-MLA) laboratory, as part of the Core Research Equipment and Instrument Training (CREAIT) network of laboratories at Memorial University, NL, Canada, has recently published efforts towards increasing the throughput of automated mineralogy systems by producing single-step trans-vertical moulds, rather than traditional 30 mm polished epoxy moulds. Due to the small particle size of iron ore grains in the -200 mesh size fraction (<75 µm), not all of the surface area on a mould is needed for measurement in achieving good statistical representation. In a new study, trimming of the excess area of a mould results in a smaller sample and increases the quantity of unique samples that can fit in a newly designed trans-vertical adapter for a FEITM MLA 650 field emission gun (FEG) scanning electron microscope. The complete analysis, using a newly designed sample block holder capable of holding 98 samples, required 57 hours of running time where each sample had an average of 33?400 particles measured and identified. The analysis was calibrated to allow for off-line discrimination of hematite/magnetite. The calculated Fe-assay values derived from MLA results were compared to those from bulk sample chemical assay. This shows the Fe assay having a correlation coefficient of >0.99 when the particle count is greater than 20?000. This study represents the most expedient method yet reported to prepare well-polished samples and analyse them in a timely manner that can allow for quicker results in process mineralogy.CITATION:Grant, D C, Goudie, D J and Baird, E, 2017. Analysis of individual - mesh iron ore samples in a single Scanning electron microscope automated mineralogy session, in Proceedings Iron Ore 2017, pp 535–540 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

The AusIMM is concerned about the longer tem sustainability of the minerals sector in Australasia. Our contention is that the sustainability of the sector is at risk if we do not:   ò encourage more exploration in Australasia by removing impediments and         increasing incentives; ò fund our university and research centres appropriately to increase both our   prospectivity, and our processing efficiencies; and ò manage our human resources better.   This paper will focus on how we can better manage our human resources to assist in ensuring sustainability of the sector in Australasia .   From a production point of view:   Economic output = f (Land, Labour, Capital, Environment) where Land refers to all of the natural resources used in production. As well as land itself it includes water, forest, fisheries, oil, gas and mineral deposits. Labour refers to the skills and capabilities used by humans in the production process. Capital describes all of the manufactured aids used in the process of production1. The challenge for management is to ensure maximum efficiency and effectiveness of labour in the production process whilst maintaining sustainable development.   The 1992 Rio Summit defined sustainable development as maintaining and enhancing:   ò natural capital û defined as all natural resources, both environmental and   those of traditional economic value; ò manufactured capital û made by human kind, including produced goods,     infrastructure and built environment; ò human capital û defined as the health, well being, intellectual capabilities and   spiritual welfare of individuals; and ò social capital û defined as social relations and consultations within and   between societies, their norms and functionality2.   The minerals sector in Australasia has successfully focused on the technical aspects of each of these components of sustainable development with primary attention applied to natural capital and efficient utilisation of manufactured capital. The technical aspects of human capital and social have also been addressed through an emphasis on occupational health and safety and interaction with local communities however I suggest that, to date, insufficient emphasis has been placed on labour (human capital) to maximise economic output1.   It has become increasingly common practice to identify land as natural capital, labour as human capital and capital as physical capital. That is labour has been treated as a commodity rather than an opportunity to create a comparative advantage and this will be the greatest challenge for mine management to show leadership over the next decade of the 21st Century.   This paper will outline characteristics of the sector which are relevant to the management and utilisation of labour, outline the outcomes of recent AusIMM surveys, review the reasons for the current and future anticipated skills shortages, some innovative responses to the challenges and finally, suggestions on how mine management can show leadership.

Jan 1, 2006

By T Wootton

The Barrytown ilmenite pilot plant was commissioned in two stages using Westport Titanium Project heavy mineral concentrate. The wet concentrator was commissioned on the 17 December 1989 and produced magnetic concentrate from this date.   The Drymill was commissioned on the 27 January 1990 and produced product grade ilmenite successfully from the onset.   The commissioning period was exceptionally short by normal standards and few problems were encountered. This paper concludes with general observations of operations of the pilot plant.

Jan 1, 1990

By V Lawson

Vale’s Sudbury Clarabelle Mill processes Cu/Ni ores from a number of mines in the Sudbury basin in Ontario, Canada. Bulk sulphide flotation produces a copper-nickel concentrate with pyrrhotite as the major diluent. After successful commissioning of the Voisey’s Bay Cu/Ni Mill (VBN) in Labrador, a miniplant campaign on Clarabelle ore with the VBN flow sheet produced a significant recovery improvement over current performance. In 2001, the Mill Redesign Project moved grinding energy into rock/sulphide and pentlandite/pyrrhotite separation and in 2006 Cu/Ni separation was re-introduced to Clarabelle Mill to produce a saleable Cu concentrate. The projects were a great success. What remained was to simplify the Clarabelle flow sheet by introducing the missing components found in the VBN flow sheet. This project known as CORe has evolved through many stages including the mining boom and surviving the 2008 economic downturn and it is scheduled for completion in mid 2013. This paper outlines some of the challenges faced in this major brownfields project – organizational, technical, financial and operational.

Aug 8, 2011

Tonnage and grade are the principal reported components of mineral resource estimates but tonnage is a derivative of two more fundamental estimates; volume and bulk density. Typically, most of the effort in a resource estimation study is directed towards grade and volume, yet poor application of bulk density data to resource models can result in significant biases. The impact on tonnage estimates is easily recognised but poor density estimates may also introduce subtle biases into the grade estimates. Methods for measuring bulk density have been discussed previously. This paper focuses on the manipulation of bulk density data and the extension of bulk density from essentially point measurements to block estimates within resource models. Bulk density is a continuous, geologically controlled, spatial variable and should be treated as such. Issues such as combining data from multiple sources, sample support and the interdependence of bulk density and grade estimates must be resolved. The statistical and geostatistical techniques used for grade estimation are, under the right circumstances, equally applicable to bulk density. The importance of bulk density needs to be recognised. With robust raw data and correct estimation procedures, better estimates of bulk density can be obtained and both local and global tonnage and grade estimates can be improved.

Jan 1, 2000

By Kuzmitch O, Morozov A

The main direction in the mechanisation in the mines of the Donbas and the USSR is long-face technology with complexes on the base of hydraulic supports. On the base of the 30 year old experience of exploitation of the coal clearing systems the serious data about the behaviour of the contained rock, display of underground pressure 'on longwalls and preparatory workings have been accumulated. Exploitation works in mines of the USSR are carried out at different depths: from 1000m to 1200m. There are 26 mines in Donbas, which exceed the depth of 1000m. It is the mines of Donbas, where is a rich experience of the exploitation of coal seams in various conditions. Besides, there are wide variations on the factors of the extraction thickness, depth of seam, angle of dip, occurrence of gas dynamics and others. In many scientific establishments, and in Donetsk Polytechnical Institute also, there are scientific research/results, which can be of interest for the coal mining countries.The volume of coal mining from longwall system-mechanised walls in Donbas became stable at the end of the 70s at level of 70 percent. All the efforts to increase this level have not given any notable results, not saying about the technical-economical data, which gradually deteriorate. It shows that positive progress in using the technology for the long walls is over and it is necessary to find new ways of mechanisation of coal winning.

Jan 1, 1991

Core samples, which were collected by the author from the Busang prospect, East Kalimantan, reflect a progressive evolution of a large magmatic-related hydrothermal system that is comparable to that encountered in many similar systems elsewhere in the Pacific region. The initial, localized deposition of sheeted porphyry quartz-molybdenite veins took place at high temperatures and fluid salinities, and at relatively deep levels. This was followed by an extensive phase of phyllic (sericite-quartz-pyrite ¦ tourmaline-apatite) wallrock replacement and vein formation. Propylitic (epidote-chlorite-carbonate-quartz) alteration was formed marginal to the phyllic assemblages. These porphyry-related events were centred in the Southeast Zone, and are probably associated with the emplacement of a felsic intrusion at depth. This event contributed only trace gold to the system. The early stages of hydrothermal activity were followed by an episode of quartz (¦ adularia) û carbonate û base metal sulfide veining, which was accompanied by argillic (illitic-kaolin clay) wallrock alteration. This event was sulfide-rich in the Central Zone and carbonate-dominated in the Southeast Zone. Gold mineralisation was observed in Central Zone drillcore to be associated with both sulfide, as well as carbonate, deposition. A final stage of epithermal-style quartz ¦ stibnite û realgar veins are, in the Central Zone, locally gold-bearing. The latter two events are interpreted to be associated with the late-stage exsolution of metal-bearing brines from the felsic intrusion that formed the earlier porphyry quartz-molybdenite veins and widespread phyllic-propylitic alteration.

Jan 1, 2002

Optical sensors have emerged during the telecom boom in the late 1900s, due to the availability to low-cost telecom-grade optical components. It's only after the telecom industry's fall in 2004 that optical sensors became sufficiently developed to be a viable technology for real-world applications. Geotechnical applications have long relied on electrical sensors such as thermocouples, strain, and the venerable vibrating wire to measure physical phenomena. Although these are well suited for a large variety of applications, electrical sensors cannot be used for all applications: these are vulnerable to noise, hazardous voltages and corrosion, limiting the environments in which they can be used. In addition, electrical wires can also become an issue when sensors require external excitation or are distant from the measurement system. Finally, changes in physical properties of electrical sensors and systems over time makes regular calibration a necessity - not easy to do when these are permanently mounted on structures. Optical sensing systems are non-conducting and use light to perform various measurements. There are several optical sensor technologies available, each with different strengths and weaknesses. In addition, there are different methods of interrogating optical sensors, each of which also present different strengths and weaknesses. To make matters worse, configuring the interrogation and scaling to physical units can also be challenging to the unprepared engineer. This paper will present a holistic view of optical sensing, presenting the different optical sensor technologies and interrogation techniques. Sample optical sensing systems will be revealed and top considerations for optical sensing will be presented.

Nov 25, 2010

Teleseismic travel time residuals measured on 600-1000 km seismic arrays across the Rio Grande and East African rifts provide evidence for upper mantle low velocity zones beneath each rift of velocity contrast 6%-8%. Refraction studies show thinning of the crust below the rift axes. Regional uplift which extends hundreds of km either side of the axes, is isostatically compensated by negative density contrast at depth. Since the refraction argues against compensation by thickened crust, compensation in the upper mantle low velocity zones is suggested. Temperature effects alone can not explain the reduced velocities. Generation of a few percent of partial melt is the most probable source of the reduction. A passive extensional mechanism is investigated for the Rio Grande rift in which hot asthenosphere intrudes the lithosphere raising its temperature and generating moderate melting. It requires less than 1% extension to explain the melting but a prodigious 26% to raise the temperature from a pre-rifting continental geotherm to the solidus. Geological estimates find that extension is less than 10% over the uplift zone. Such a mechanism is possible only if the prerifting lower lithosphere geotherm lies closer to the solidus than that of stable continent. This is supported by the observed high heat flow in the Rio Grande rift uplift region which, given the long time constant for thermal diffusion, reflects elevated temperatures at depth well in advance of the onset of rifting.

Jan 1, 1987

This paper covers only the energy uses of natural resources and does not deal with non- energy uses, which in 1975 were of the order of 10 per cent of the total consumption of energy resources. The United Nations `J' Series of Statistics ex- presses each of the various forms of energy in terms of its coal equivalent in metric tonnes and this basis is followed in this paper. One tonne of black coal (referred to as tce) has been taken as the equivalent of the following. 29 X 109 joules or 27.5 X 106 Btu 0.68 tonnes or 4.8 barrels of crude oil 750 cubic metres or 26.5 X 103 cubic feet of natural gas 1 ò5 to 3.3 tonnes of peat or lignite (world average 2.54; Victorian brown coal 3 0) 8055 kWh (at 3.6 X 106 joules or 3412 Btu per kWh at 100% efficiency) 2660 kWh at 33% efficiency of generation 50 grams of uranium present in natural uranium reactors (see note later under nuclear energy) 0.8 grams natural uranium in breeder reactors Nuclear and hydro electricity are expressed as the coal equivalent required to produce, at 33 per cent efficiency, the same amount of electricity. In other words, electricity produced by these sources is converted to its coal equivalent at the rate of 2660 kWh = 1 tonne coal.

Jan 1, 1978

By B Lumsden

During periods of high metal prices and strong metal demand tailings retreatment can be economic. Most tailings retreatment operations are technically challenging, low margin operations, because the easily recovered mineral has already been removed, therefore, process improvements can potentially yield large economic benefits. The Hellyer tailings dam was owned by Intec Ltd and contained 10.9 million tonnes grading 2.8 per cent zinc, 3.0 per cent lead, 88 g/t of silver, 0.16 per cent copper and 2.6 g/t gold. In November 2006 the Polymetals Group, as operator, restarted the Hellyer plant to retreat these tailings. Within a few months the operation had stabilised and Polymetals was meeting budgeted targets of throughput, metal recovery and concentrate quality. Polymetals and Intec then investigated methods that would improve the metallurgical result for this difficult to treat tailings. Since the tailings are fine-grained with 80 per cent <45 ¦m, magnetic aggregation of the paramagnetic sphalerite was evaluated. Magnetic aggregation of an oxidised tailings feed has not been tested before, nor had the technology been available when Hellyer ore was originally processed. Extensive statistical test work showed magnetic aggregation of the sphalerite fines in the zinc cleaner circuit increased total zinc recovery. The increase in the mean zinc recovery with magnetic conditioning was 3.63 per cent, at a statistical level of confidence of 97.8 per cent, and at the same mean zinc concentrate grade.

Jan 1, 2009

Kinetic Dependence of Refractory Gold Sulfide Biooxidation Using Different Microorganism Association In this investigation, refractory sulfide concentrate from a deposit located in northern Russia was treated using biohydrometallurgical technology. The objective of this work was to compare the accelerated refractory sulfide concentrate biooxidation abilities of the pure and mixed mesophilic and moderately termophilic acidophiles cultures. Pure culture of Acidithiobacillus ferrooxidans and two associations of the: Acidithiobacillus ferrooxidans + Acidithiobacillus thiooxidans and Acidithiobacillus ferrooxidans + Acidithiobacillus thiooxidans + Leptospirillum + Sulfobacillus were used in this investigation. Results of sulfide concentrate bioleaching were analysed using the enzyme catalysis theory. Different effective kinetics parameters were calculated for Michaelis-Menten equation, such as Michaelis' constant and maximum rate of the enzymatic reaction. It was shown that the increase of microorganisms' species decreased Michaelis' constant. Lower Michaelis' constant characterises increasing bacteria ferment affinity to substrate (treated concentrate). As a result, the rates of sulfide minerals biooxidation have increased. This investigation has demonstrated that cultures of the different microorganism species, including moderately termophilic, allow to enhance different parameters of the biohydrometallurgical technology for the refractory gold sulfide concentrate treatment. We can see that bacterial leaching stage duration decreased and sulfide minerals oxidation increased. When the bioresidues were subjected to the hydrometallurgical stage, which includes aeration and sorption cyanidation, the operation factors were also enhanced. The decrease of aeration duration and the growth of the precious metal extraction by sorption cyanidation was achieved. Cyanide consumption was also reduced. The results of this investigation were used in design of an industrial plant.

Sep 13, 2010

By J P. Jona, S R. Poulson, C H. Gammons

Spatial and temporal trends in water chemistry in the acidic (pH ~2.6) Berkeley Pit lake, Butte, Montana, can be explained by a newly developed iron-cycling model. Key elements of this model include: subaqueous oxidation of pyrite and other metal sulfide minerals by dissolved ferric iron, producing Fe2+ as a by-product; re-oxidation of Fe2+ to Fe3+ in the epilimnion, assisted by A ferrooxidans; precipitation of secondary ferric minerals (schwertmannite, jarosite) in the epilimnion; and replenishment of the Fe3+ concentration of the hypolimnion by seasonal lake turnover and gravitational settling and re-dissolution of ferric precipitates. Pyrite oxidation rates were approximated by using published rate laws and information on the Fe3+ concentrations (~5 mmol) of the Berkeley Pit as a function of depth. The results indicate that subaqueous pyrite oxidation may be releasing as little as 6 + 106 or as much as 600 + 106 moles of H+ each year to the lake; the large range reflects uncertainty in calculation of the specific surface area of pyrite in the flooded pit. This helps to explain the observation that the pH and metal concentrations of the Berkeley Pit have not improved with time since mine flooding began in 1983. Vertical cycling of ferric iron in the pit lake permits pyrite oxidation to continue in deep water, even in the absence of dissolved oxygen. This hypothesis is supported by preliminary stable-isotope data.

Jan 1, 2003

A series of in situ pull tests has been conducted to determine the holding capacity of the standard SS46 Split Set Stabilisers. The experiments have been conducted in a wide range of geological conditions ranging from bedded rock to blocky ground. The results presented in this paper indicate that cement grouted split sets bolts are likely to provide up to three times the initial bond strength per metre of embedment length provided by the ungrouted bolts. The increased load transfer capacity of the grouted bolts provides an alternative for permanent excavation support using split set stabilisers.

Jan 1, 1997

Radio Detection and Ranging is an active form of remote sensing. The-imaging system sends out a source of electromagnetic energy to 'illuminate' the terrain and then records the energy returned. The wavelengths used by radar are in the microwave region and vary from a few millimetres to about a metre. Radar systems are independent of lighting conditions and weather. In addition, targets may be illuminated in the optimum direction to enhance features of interest. New Zealand was one of the principal investigators on the Shuttle Imaging Radar (SIR-B) experiment, part of the payload on Challenger Mission 41-G in October 1984. Data collected over New Zealand was restricted to two very poor quality optical images and one poor quality digital data take. The digital image covered the ranges between the Hawke Bay-Wairoa Basin and the Volcanic Plateau. Variations of texture in this image frequently were indicative of variations in lithology and induration. The image also clearly depicted major faults where these had had a significant effect on the topography.

Jan 1, 1986

The Dynamics and Thermodynamics of Absorbing Lithium of Ion Sieve Preparing Pollymetallic Nodules

Sep 13, 2010

Gold was first discovered in the Shotover by Thomas Arthur in 1862. He left his job as a shearer and soon there were up to 3000 miners working over the length of the river. Some parts were extremely rich and a few early miners recovered as much as 300 ounces in a day. From these early days of hand working the operations progressed through to hydraulic elevating once water races and pipes were installed after the Skippers road was completed about 1890. The riverbed was worked in paddocks with .the gravel being sluiced to a central suction which elevated the material over a sluice box. Use of this system continued intermittently through until 1977 when Joe Schieb retired û the last of the hydraulic miners. Many bucket ladder dredges worked on the lower Shotover near Big Beach where the Sew Hoy family recovered a lot of gold. Just after 1900, at least three worked further upstream, one on the beach where Shotover Jet now operates and one further up below the Moonlight. All the sections for this were transported in over the Moonlight Track and the boiler, steam engine and bucket ladder are still sitting at the edge of the river. up near Maori Point a dredge operated from Dredge Slip upstream. Records are poor on these dredges but they all suffered from the frequent floods and large boulders which damaged the bucket line. The last dredging attempt was about 1930 when a suction dredge was constructed on Maori Beach. This failed as seems to be normal for most suction dredging ventures. The river can drop to very low levels in the middle of a dry summer, and in winter when the water is tied up in the mountains as ice and snow. During 1863 when heavy rain melted snow in the high country, the river rose 35 feet overnight and drowned many miners camped on the banks. The ever present risk of flooding dominates the method of working and plant design.

Jan 1, 1987

By G W. Heyes, P J. Guy

Investigations were undertaken to assess the suitability of CSIROflotation methods for improving the efficiency of separation of heavyminerals in the monazite circuit at the Westralian Sands Limitedoperations at Capel, Western Australia. Flotation work was conducted on two plant samples. The first was a high-titanium product containing considerable amounts of zircon and silica as quartz and aluminosilicates, and the second was a low monazite/zircon material containing high levels of silica. A three-stage process including reverse flotation was developed totreat the first sample. In this process monazite, zircon, quartz, andaluminosilicates were selectively concentrated by flotation and screening to produce a titanium-rich product. In the first stage, an acid amine float, monazite, zircon, and some non-zircon silica were recovered and in the second stage, an alkaline amine float using a fluoride activator, more quartz and staurolite were floated. The titanium minerals were thus concentrated in the unfloated fraction. In the third stage, the titanium-rich flotation tail was screened at 250 ¦m to remove the remaining coarse aluminosilicates. In a single pass, the three-stage process yielded a TiO2 recovery of 64.0 per cent with the titanium-rich product assaying 70.3 per cent TiO2.

Jan 1, 2001

Media Type Effect on Grinding Efficiency

Sep 13, 2010