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By Ying Wang, Min Chen, Cuihuan Huang, Haohua Deng, Nan Wang, Ming Chen

Adding limestone directly into converter is considered to be favorable to energy conservation and emission reduction by transferring the decomposition reaction of limestone from the shaft or rotary kiln to the converter. In this paper, the kinetics of limestone decomposing in early converter slag was studied at 1300–1400 °C, and the effects of slag temperature and stirring speed introduced to the slag bath were examined. The kinetic results based on shrinking core model analysis showed that the limestone decomposition was a mixed rate control of chemical reaction and heat conduction through the lime layer, which could be promoted at higher slag temperature by supplying more heat to the converter bath. In addition, the chemical reaction rate constant and effective thermal conductivity were determined.

Mar 1, 2018

By Muammer Kaya

This paper reviews the existing and state of art knowledge for electronic waste (e-waste) recycling. Electrical/electronic equipments (EEEs) which are unwanted, broken or discarded by their original users are known as e-waste. The main purpose of this study is to provide a review of e-waste problem, give e-waste management strategies and introduce various physical e-waste recycling processes with special attention towards extraction of both metallic values and nonmetallic substances. The hazards arise from the presence of heavy metals (e.g. Hg, Cd, Pb etc.), brominated flame retardants (BFRs) and other potentially harmful substances in e-waste. Due to the presence of these substances, e-waste is generally considered as hazardous waste and may pose significant human and environmental health risks if improperly managed. This review paper describes the potential hazards and economic opportunities of e-waste. First of all, an overview of e-waste/printed circuit board (PCB) components and substances are given. Current status and future perspectives of e-waste and waste PCB recycling techniques are described. E-waste characterization, dismantling, liberation, classification and separation processes, are also covered. Manual selective dismantling after desoldering and metal-nonmetal liberation at −150 μm with two step crushing are seen to be the best techniques. After size reduction, mainly physical separation processes employing gravity, electrostatic, magnetic separators etc., which are commonly used in mineral processing, have been critically reviewed here for separation of metals and nonmetals. The recovery of pure metals from e-waste after physical separation can be performed by pyrometallurgical, hydrometallurgical or biohydro metallurgical routes, which are not covered here. Suitable PCB recycling flowsheets for industrial applications are also given. E-waste recycling will be a very important sector in the near future from economic and environmental perspectives for both developing and developed countries. Recycling technology aims to take today’s waste and turn it into conflict-free, sustainable polymetallic secondary resources (i.e. Urban Mining) for tomorrow. Recycling technology must ensure that e-waste is processed in an environmentally friendly manner, with high metal/nonmetal recovery efficiency a lowered carbon footprint. Taking into consideration our depleting natural resources, this Urban Mining approach offers quite a few benefits; it provides a substantial secondary resource, while also ensuring that the environment is kept free from harmful toxins in e-waste. This results in increased energy efficiency and lowers demand for mining of new raw materials.

Mar 1, 2017

By H. Ikeda

The new Onahama N0.3 tankhouse was put into operation early in 1973. This new tankhouse, which has a capacity of 90,000 metric ton cathode per year, is distinct in many important respects from conventional tankhouses. The major objectives in design were to simplify the construction and ope- ration for reduction of the costs for labor, interest and depreciation and also to reduce the copper inventory in the tankhouse by the use of conti- nuously-cast anodes. As a result, the investment cost was decreased by approximately 30% and the inventory cost by approximately 600, while the production per unit area of the tankhouse was increased by 80 - 100% as compared with the existing conventional-type tankhouses at Onahama. By abolition of cell inspection and maximum mechanization of materials handling the labor cost was decreased by as much as 80%. On the other hand, the new system has some disadvantages, such as increase in anode scrap ratio and increased cost of anode casting. The No.3 tankhouse system is, however, still at its starting point, while conventional methods have been continuously improved over the past years of operation. It is expected that the innovational ideas behind this system will serve as bases for a more efficient electrolytic refining system in future.

Jan 1, 1976

By D. C. Lynch

While a sizable amount of data exist as to the activity and distribution of minor elements between matte and metal, there has been no unifying theory presented delineating the form of dissolution of these elements in molten sulfides. In order to alleviate that deficiency the literature concerning the behavior of As, Sb, Bi and Pb in mattes is reviewed. Models present in the literature, regarding the thermochemical behavior of minor elements, are tested, and new models are presented and evaluated using thermodynamic theory. The results of those analyses are used to predict optimum conditions for the volatilization of minor elements. The dearth of data on the behavior of minor elements in nickel mattes requires that this review focus on copper- iron mattes. An effort is made, however, to utilize basic knowledge regarding nickel sulfides and the interaction of nickel with the minor elements to predict the behavior of those elements in nickel-copper and nickel-iron mattes.

Jan 1, 1993

By Gennady I. Gulyayev

A mathematical model of plastic deformation occurring in cold plug drawing of mother tubes with initial cross-sectional wall thickness variations (CSWTV) has been developed. The main provision of the model is that eccentricity em is of such value that projection of all forces acting upon the plug in the deformation zone along the axis perpendicular to the drawing axis equals to zero. Calculations have proven that with other conditions being equal increase in the die cone angle and the deformation cycle number reduces CSWTV. Theoretical findings were confirmed by practical results. Keywords: cold, drawing, plug, die cone, plastic deformation.

Jan 1, 2003

By A. Arenas-Flores, Pandiyan Thangarasu, J. P. Hernández-Lara, F. R. Barrientos-Hernández, J. A. Romero-Serrano, A. Hernández-Ramírez, M. Pérez-Labra

BaTiO3 doped with Gd3+, was synthesized from BaCO3, TiO2, and Gd2O3 as powders using the solid state reaction method (Ba1-xGdxTi1-x/4O3). The milling of the precursors was performed in an agate mortar with acetone as control means and compositions x = 0.001, 0.005, 0.05, 0.15, 0.25, 0.35 Gd3+ (wt%). Firstly, the powder mixture was decarbonated at 900 °C for 8 h, after it was sintered at 1400 °C for 5 h. Tetragonality of synthesized BaTiO3 doped with Gd3+ was analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Raman spectroscopy (RS). Subsequently, the powders sintered were uniaxially compacted cold until to obtain pellets of about 10 mm in diameter; which again were sintered at 1400 °C for 4 h. XRD patterns and Raman spectra results revealed that the crystal phase of the obtained particles was predominately tetragonal BaTiO3.

Mar 1, 2017

By C. Hennesmann, D. Maijer, S. L. Cockcroft, P. Yo

"Die cast aluminum wheels are one of the most difficult automotive castings to produce because of stringent cast surface and internal quality requirements. As part of a collaborative research agreement between researchers at the University of British Columbia and Canadian Auto Parts Toyota Incorporated, work has been underway to predict heat transport and porosity formation in die cast A356 wheels. The basic heat transfer equations have been solved using the commercial finite element package ABAQUS to which specialized routines have been added to predict porosity. Preliminary work on predicting porosity formation focused on using the Niyama parameter as a measure of the probability of porosity. The latest version of the model incorporates a new fundamentally based porosity criterion, which takes into account the effect of hydrogen concentration. The development of this model together with its application to a series of cylindrical test castings as well as a production cast wheel are presented.I. IntroductionDie cast aluminum wheels are one of the most difficult automotive castings to produce because of stringent cast surface and internal quality requirements. Microporosity, in particular, is a common defect that can adversely affect wheel quality. The mechanism of microporosity formation in aluminum alloys is complex owing to its dependence on the interaction of a number of phenomena occurring during solidification including the decrease in hydrogen solubility, the decrease in volume, the development of the solidification structure, and the increase in difficulty in interdendritic feeding [1]. As a result, the amount, size, and distribution of microporosity is affected by a large number of casting parameters including thermal variables, melt composition, grain structure, modification, and inclusion content, making optimization by trial-and-error methodologies difficult.The use of criteria functions, based on thermal conditions during casting, offers a relatively simple approach to predicting microporosity. In practical terms, they are useful because they provide a straightforward method of assessing the impact of varying casting parameters on porosity through various thermal parametersl21 such as thermal gradient, cooling rate, solidification time, and solidus velocity. Drawbacks of criteria functions include insensitivity to varying hydrogen concentration and the limitation to qualitative predictions. Consequently, in aluminum alloys, attempts have been made to develop models incorporating the effects of hydrogen gas and microstructure evolution. However, these types of models represent a significant increase in complexity and sacrifice the simplicity and ease of application of the thermally based criteria functions."

Jan 1, 2001

By Ilija Ilic

Recovery of tin from tinplate and production of good-quality detinned-plate for further processing in ironworks has been the subject of interest for many years. Tinplates are mostly used for production of tin containers for food industry and consumer goods. The research carried out so far included determination of the parameters of dissolution of tin from tinplates by alkaline solution of NaOH and electrochemical recovery of tin from the alkaline solutions. During leaching, NaNO3 and methanitrobenzoic acid (MNBA) as oxidants were studied. By leaching the waste tinplate which contains 0.31 % of tin with a solution of 1.12 mol/dm3 NaOH, 0.26 mol/dm3 Na2CO3 and 0.09 mol/dm3 MNBA at temperature of 70°C for 60 mm, a degree of tin leaching of 97 % was attained. MNBA facilitates oxidation of Sn2+ into Sn4+ suitable for obtaining compact, and not spongy, Sn cathode deposit, as it was the ease earlier. Recovery of tin by electrolysis from solutions obtained by leaching was studied to determine the effect of electrolyte composition on the quality of cathode deposit and the degree of electric current efficiency. Experimental results obtained at a laboratory level were checked on an enlarged laboratory set up where continuos leaching of tin from waste tinplate and its electrolytic recovery from the solution obtained were carried out. The experimental set-up -operated under semi-industrial conditions, and about 500 kg of waste tinplate was processed yielding about 1.160 kg of tin (99 % Sn).

Jan 1, 2000

By R. W. Charles

The Los Alamos National Laboratory, under the sponsorship of the U.S. Department of Energy; is involved with laboratory and field experiments to assist in development of the Hot Dry Rock concept of geothermal energy. The field program consists of experiments in which hot rock of low permeability is hydraulically fractured between two wellbores. Water is circulated from one well to the other through the fractured hot rock. Our field experiments are designed to test reservoir engineering parameters such as heat-extraction rates, water-loss rates, flow characteristics including impedance and buoyancy, seismic activity, and fluid chemistry. Laboratory experiments were designed to provide information on the mineral-water reactivity encountered during the field program. Two experimental circulation systems tested the rates of dissolution and alteration during dynamic flow. SOlubil ity of rock in agitated systems was studied. Moreover, pure minerals, samples of the granodiorite from the actual reservoir, and Tijeras Canyon granite have been reacted with distilled water and various solutions of NaCl, NaOH, and Na.CO.. The results of these experimental systems are compared to the observations made in field experiments done within the hot dry rock reservoir at a depth of approxi-mately 3 km where the initial rock temperature was 150 to 200°C.

Jan 1, 1981

By Jorge Alberto Soares Tenório, Flávia Paulucci Cianga Silvas, Denise Crocce Romano Espinosa, Ivo André Homrich Schneider, Erika Gusmão, Daniella Cardoso Buzzi, José Roberto de Oliveira

"This study evaluated the Salvinia sp action on metals biosorption in a synthetic sample of acid mine drainage (AMD) in order to determine the time and amount of metals uptake. Biosorptives tests were realized varying the contact time of 5, 20, 60 and 240 minutes. And keeping constant the follow parameters: pH (2.6), biomass concentration (1g.L-1), temperature (25°C) and agitation (175rpm). In order to quantify the metals concentration captured by biomass, the AMD samples will be analyzed by ICP. Biosorbent, Salvinia sp., will be characterized before and after the biosorptives tests through analysis of SEM and IR. The micrographs indicate the occurrence of micro-precipitation and changes in biomass physical structure. The infrared spectra indicate changes in functional groups present in the biomass before and after the biosorptives tests.IntroductionThe current emphasis on environmental sustainability leads the industry in general, to treat their waste. The human activities are increasing, highlighting the industrial and mining activities, and have promoted the contamination of soil, waterways and groundwater by metals (1). The waste must undergo treatment processes aimed at reducing pollution, and therefore, less aggression ecosystems.This means the importance of studies of economic and effective methods to eliminate these metals from wastewater generated. The bioindicators are good investments in this area. The aquatic weeds are plants that inhabit swamps up from truly aquatic environments. They have several morphological and physiological adaptations that enable them to colonize the various aquatic environments. They are used as bioindicators of water quality and have also been used in decontamination of aquatic environments, production of biomass for livestock feed, fertilizers, soil and fish tanks (2)."

Jan 1, 2012

By C. J. Parradies

During injection into a die, semi-solid metal alloys exhibit a shear-rate, history-dependent flow response. Simulating the injection of a thixotropic material requires that empirically determined boundary conditions and viscosity are specified as a function of both temperature and shear rate history. Experiments were performed using an industrial die casting machine that was instrumented with sensors to measure the pressure and temperature during the injection of a semi-solid aluminum alloy through a tube. This benchmark experiment was used to develop a simulation of the die casting process that could then be applied to more complex die geometries. The results of the experiments were analyzed using the exact, steady state solution for a power law fluid and simulations accounting for slipping at the boundary between the semi-solid metal and the die. Results indicated that the no-slip condition cannot be used to simulate the velocity boundary condition, because the measured pressure is much lower than that predicted by the models. An estimated apparent slip coefficient was introduced to account for the reduced pressure. During some of the experiments, a sudden drop in the measured pressured, prior to decreasing the ram velocity, coincided with observations of segregation in the form of concentric rings visible on the polished surface of cross-sections cut from material remaining in the tube.

Jan 1, 1997

By James M. Fragomeni

"The mechanical behavior of an Al-Li alloy was studied and related to the extrusion processing parameters, the plastic metal flow during defonnation, the anisotropy, and the microstructure. The extrusion temperatures, strain rates, extrusion ratios, billet temperatures, and extrusion geometries were varied during processing and correlated with the microstructure and properties. The extrusion processing variables were related to the mechariicar behavior, anisotropy, and microstructure through the ZenerHollomon parameter i.e., the temperature compensated strain rate. Based on optical and electron microscopy studies it was found that regardless of the extrusion conditions, the various microstructures for the most part were unrecrystallized for both the as-extruded and the solution heat-treated conditions. Smaller grain sizes were correlated to larger Zener-Hollomon parameters. The extrusion temperature and ratio did not significantly affect the strength or ductility as did the section geometry, which had a large affect on these mechanical properties. The anisotropy of the properties varied substantially when comparing the extruded longitudinal versus transverse grain orientations.IntroductionThe extrusion process also has a substantial influence on: the microsfructure and mechanical properties of a material that is Athens, Ohio, 45701 fonned The plastic defonnation that occurs during the extrusion process alters the grain size, crystallographic texture, anisotropy, subgrain size, dislocation density and various other microstructural features. Often the material being extruded is not homogeneous, therefore variations in the microstructure and properties occur across the cross-section of the final extruded product. The mechanical properties and microstructure can also vary with length since it is hard to maintain a constant temperature throughout the extrusion process. The extrusion temperature often varies from the heat generated during the extrusion process. The demonstration material that was extruded for this .study was an aluminum alloy containing 2.6wt, % lithium and 0.09wt.% zirconium. This alloy was strengthened by heat treatment causing nucleation, growth, and coarsening of coherent metastable o' (Al3Li) precipitates in the microstructure. The ? precipitates which are a consequence 9f artificially aging the AlLi alloy, are spherical, ordered, and coherent with the aluminum matrix and impede the dislocation glide inotion during plastic defonnation. Theo particles grow homogeneously in the matrix, and have the Cu3Au (L 12)"" superlattice crystal structure. Aluminum-lithium alloys are used primarily for aerospace structural applications since they have attractive properties such as a lower density and higher elastic modulus than conventional 2XXX and 7XXX alloys."

Jan 1, 2000

By Takashi Miyamoto, Hideo Nakae, Hideki Yamaura, Takeshi Yanagihara

"For the production of partially composed metal matrix composites, namely discontinuous MMCs, using a casting· process, the interpenetrated phase composites with SiC particles were fabricated by pressureless iDfiltration using molten Al-Si alloys. This process is based on a wetting phenomenon, therefore, we discussed the technique based on the reactive wetting. The SiC particles coated by diluted water glass were sintered in a mullite Tammann tube and simultaneously infiltrated with molten Al-Si alloys in air at 1173~1573K. As for the improvement of the wettability between the SiC and the liquid aluminum alloy, Fe3O 4 powder was mixed with the water glass due to the thermit reaction between Fe3O4 and molten aluminum alloy. In some experiments, pure aluminum powder was placed on the sintered SiC to increase the interfacial area and the chemical reaction between the sintered Sic. and the melt. By combining these conditions, we succeeded in the complete infiltration without pressure at 1173K.IntroductionAs is well known, the mechanical properties of metal matrix composites (abbreviated MMCs) are superior than that of ordinary metals. However, their use has not been widely accepted because the production cost is very high due to their poor machinability. Therefore, the production of partially composed, namely discontinuous MMCs, by as the Lanxide process [l,2] has been investigated for many years. The Lanxide process, it takes a long time, sometimes up to 10h, in a nitrogen atmosphere for the infiltration. Therefore, the cost will be higher for common use. On the other hand, a high 'pressure process has been adopted for the production of discontinuous MMCs by the Toyota Motor Corp.[3]."

Jan 1, 2000

By Xuemei Zheng, Aiyuan Ma, Guojiang Li, Tingfang Xie, Jinhui Peng, Libo Zhang

A new microwave roasting technology for the removal of Cl from zinc oxide dust is proposed in this paper. The effect of important parameters, such as roasting temperature, holding time and stirring speed, were investigated and the process conditions were optimized using response surface methodology (RSM). The experimental results show that zinc oxide dust dechlorination rate can reach more than 95.66% and meet the requirements of wet smelting electrolysis when controlling the stirring speed of 60 r/min,roasting temperature of 650 °C, holding time of 30 min. In addition, the effect of roasting temperature and holding time on removal ef ficiency of Cl was most signi ficant. As a result, the Cl content was decreased without the risk of pollution. This makes it as a good choice for a more ecological treatment of zinc secondary resources.

Mar 1, 2018

By Mingming Zhang, Marshall S. Coe, Marcelo W. Andrade

To supply iron units and flux burden in blast furnaces, sinter basicity is one of the vital parameters for sinter plants. The sinter basicity also plays an important role in sinter quality since it imparts the formation of different mineral phases in sinter. Pot-grate sintering tests were carried out with low and high basicity to investigate the effects of sinter basicity on sinter mineralogy, properties and productivity. It was found that with an increase in sinter basicity, both sinter productivity and reducibility (RI) increased. Tumbler index (TI) and low temperature degradation index (LTD) of high basicity sinter were comparable to low basicity sinter. Softening and melting tests showed that sinter with 3.5 C/S basicity had slightly higher softening temperature comparing to lower basicity sinter with C/S 2.6, acid and fluxed pellets. XRD analyses confirmed the formation of silico-ferrite of calcium and alumina (SFCA) and calcium ferrite (CF) in the tested sinter samples.

Jan 1, 2015

By Monica M. Jimenez Correa, Jorge A. Soares Tenorio, Denise Crocce Romano Espinosa, Paula Aliprandini

The surface zone of nickel laterite ore is generally considered as residue. However, because of the depletion of ore sources and the increase in demand, this previously discarded zone may now be processed economically for nickel and cobalt. After leaching and removal of the impurities, the solution contains cobalt, magnesium, manganese and nickel. Solvent extraction is a hydrometallurgical technique used in the separation of metals from aqueous solutions. Cyanex 272 and D2EHPA are extractants used to separate nickel from cobalt. The mixture of extractants can change the performance during the metals extraction. This work aims to evaluate the solvent extraction of nickel and cobalt when Cyanex 272 and D2EHPA are mixed. The results showed that the increased concentration of D2EHPA in the organic phase increased the extraction of nickel and magnesium. However, cobalt extraction was reduced and the manganese extraction was not altered.

Mar 1, 2018

By Omid Marzoughi

Chromium has a wide range of applications, including as an alloy addition in various steels and also as a corrosion resistance coating. Carbothermal reduction of chromite ore (FeCr2O4) in a submerged arc furnace is an important industrial process for extracting chromium, but the energy consumption is excessive. It is suggested that one area for future research is the low temperature carbothermic solid state reduction of chromite to produce an intermediate product, which can subsequently be upgraded to ferrochromium. In this regard, a thermodynamic model has been developed to investigate this process and the effects of temperature, carbon additions and ore composition on the recovery of chromium and the grade of the ferrochromium, have been studied. Further development of the model may allow it to be applied to the simulation of other processes for the recovery of chromium from chromite ores.

By V. I. Lakshmanan

Crown ethers are gaining importance in separation technology specifically for rare earth elements (REE, La to Lu plus Y) and precious metals (Au, Ag, Pt, Pd, Rh and Ir) due to their specific binding ability, metal complex stability and high extraction efficiency. The selectivity of crown ethers in extraction of these metals depends on different factors, including the cavity diameter and nature of a donor atom of the crown ether, size and charge of the metal ion, diluents and counter ion. Demand for strategic REE and precious metals are consistently increasing in the world while the separation of these metals is most challenging tasks. In this paper, the use of crown ethers in separation of REE and precious metals, reaction mechanisms and simplified process flowsheets will be elucidated. New reagents with high selectivity for the separation of these metals are further expected to produce high purity metals.

By R. D. Lrwin, W. M. Mullins, S. Venugopa, J. C. Malas

"Physical models for acoustic emission (AE) are introduced and expressions are derived to predict AE activity from such parameters as applied stress, strain and strain-rate. These models are then incorporated into a visco-plastic finite-element simulation program, and the acoustic emission event rate generated during metal forming operations are predicted. Simulation results are presented for upsetting operations on a typical C-Mn type steel for various friction and die geometry conditions. The AE model predictions compare well with the limited available experimental results reported in the literature and demonstrate that AE signatures can be reliably simulated. The signatures predicted for metal forging are fairly insensitive to processing parameter changes. This suggests that AE event rate monitoring may not be well suited to process monitoring for forging. However, the size of the features is conjectured to influence the frequency content of the AE signals. Thus, since current simulations include only the ability to predict the number of events for a set of processing conditions, future work is required to simulate the duration and magnitude of acoustic events. Fourier analysis techniques may then be applied to investigate correlation with microstructural features.IntroductionThe open loop control system method for deformation processing design, as described by Malas et al. [1 ], consists of several steps in series to achieve the final design. The first step uses microstructure development models to determine the optimum deformation path to achieve the desired final microstructure. The second step, the process model, calculates the processing parameters required to achieve this deformation path. Finally, the metal-working system uses the required processing parameters to produce the part. Figure 1 shows this in block diagram form"

Jan 1, 1997

By Shengfan Zhou, XUEWEN WANG, Fuhong Xie, Qi Ge, Bianfang Chen, Biao Liu, Mingyu Wang, Sheng Huang

To recover iron, titanium, vanadium and chromium from vanadium bearing titanomagnetite, a process of direct reduction has been proposed. After magnetic separation, a material containing titanium, vanadium and chromium was obtained. In this paper, a salt-roasting process was proposed to extract vanadium and chromium from the material containing titanium, vanadium and chromium. The effects of the several parameters that included roasting temperature, roasting time and the addition of sodium carbonate were investigated. Under the most suitable conditions including a roasting temperature of 900 °C, roasting time of 2 h and sodium carbonate addition of 33 wt%, the leaching of vanadium and chromium reached 91.2 and 68.4%, respectively. After leaching, the leach residue can be used as the raw material for extraction of titanium.

Mar 1, 2018