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By Hazal Melis Aytac, Lana Alagha, Fardis Nakhaei

Gallium (Ga) and Germanium (Ge) are essential strategic elements that are extensively used as semiconductors in many technological fields. Owing to their essential uses and supply disruption, Ga and Ge are deemed critical by the U.S. They are typically found as substitutions or inclusions in zinc minerals. However, their distributions within zinc minerals are not well understood. To address this, trace element and mineralogy analyses of representative samples obtained from an old high-zinc-grade tailing were performed using various qualitative and quantitative techniques. These techniques included Inductively Coupled Plasma Mass Spectrometry (ICP-MS), Tescan Integrated Mineralogical Analysis (TIMA) with Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD). Moreover, bench-scale froth flotation tests were conducted to enrich zinc minerals, the major hosts of Ga and Ge, using PAX as a collector, Na2S as a sulfidizer, Pb(NO3)2 as an activator, and MIBC as a frother. Comprehensive characterization analyses of the flotation products showed significant enrichment of Zn, Ga and Ge in the flotation concentrates.

Feb 1, 2025

By D. McElhinney, J. Winfield, G. Buchan, B. Slaker, A. Iannacchione, T. Minoski, G. Rashed, M. Van Dyke, M. Murphy

"The National Institute for Occupational Safety and Health (NIOSH) has previously established pillar design guidelines for the underground stone mining industry. These guidelines were created from an empirical database of pillar observations and were largely drawn from shallow, flat-lying mining operations. Current trends forecast a great amount of underground stone mines developing under deeper cover, higher seam dips, and more frequent multiple-seam mining configurations than in the past. The complex loading conditions and limited experience in these environments presents a substantial increased risk of ground failure. To investigate these loading conditions, NIOSH has installed a pillar and roof monitoring system at an underground limestone mine in central Pennsylvania. The mine is operating in a seam with dips ranging from 13 to 18 degrees and overburdens ranging from 275 m (900 ft) to 425 m (1,400 ft). Instrumentation installed in an undeveloped pillar and in surrounding strata is currently measuring pillar and roof behavior in response to stress redistribution during excavation. Laser scans are being used to measure ground displacement and changes in conditions associated with local mining conditions and significant geological features. Initial stress measurements show a gradual increase in stress in response to mining, and stress changes that correspond with blasts. The seismic system is operational, with calibration events signaling on each of the 18 sensors. INTRODUCTION Improving mine-wide ground control stability can help reduce the potential for catastrophic failure of underground structures. The National Institute for Occupational Safety and Health (NIOSH) has conducted prior research in stone pillar design and has established fundamental pillar design guidelines for the underground stone mining industry, which resulted in the development of the S-Pillar program (Esterhuizen et al., 2011; Esterhuizen and Murphy, 2015). The data that constitute the S-Pillar program were derived from past mining experience that was almost exclusively drawn from shallow, flat-lying, single-level mining operations1. Stakeholder interactions with NIOSH researchers have indicated that increased numbers of underground stone operations are expected to mine under significantly deeper cover, with greater seam dips, and under multi-level operating conditions (Slaker and Murphy, 2016). The complex loading conditions and limited experience in these challenging environments present a substantial increased risk of ground failure. Inadequate pillar design in these new and challenging environments could result in catastrophic wide-area pillar collapses and an increased safety burden to miners working in the U.S. limestone mining industry. To develop design guidelines and prevent inadequate pillar designs for these challenging environments, NIOSH is currently conducting detailed pillar response investigations at case-study mine sites operating in challenging environments."

Jan 1, 2018

By S. M. S. Azghdi, K. Barani

The effect of microwave treatment on the surface roughness and wettability of chalcopyrite (CuFeS2 ) and on the chemical composition of its surface was studied. The microwave source was a conventional multimodal oven with frequency of 2.45 GHz and maximum power of 900 W. Pure chalcopyrite specimens and purified chalcopyrite concentrate were used in this study. Analysis using atomic force microscopy showed a decrease in the surface roughness of the chalcopyrite after microwave radiation. This decrease may be due to oxidation of the surface and formation of iron oxide. Moreover, the surface wettability of the chalcopyrite mineral increased with increasing duration of microwave radiation, which was in good agreement with the micro-flotation mass recovery results. The increased wettability of the surface may be attributed to the decreased surface roughness by microwave radiation. Analysis using scanning electron microscope/energy-dispersive X-ray spectroscopy indicate that after microwave radiation, the contents of sulfur and iron increased whereas that of copper decreased on the surface of the chalcopyrite, significantly changing the average atomic number of the chalcopyrite surface.

By J. Hong, K. Han, C. Park, C. Yoon, H. Yoon, N. Kim

The contents of three platinum group metals (PGM-platinum, palladium and rhodium), from the spent automotive catalyst, and two NIST SRM (National Institute of Standard and Technology Standard Reference Material, Used Auto Catalysts) were determined by the X-ray fluorescence (XRF) spectrometry. The XRF technique has been proven to be a fast, effective and accurate method in determining not only PGM but also other solid materials of less soluble for wet digestion analysis. The detection limit of the XRF analysis is better than that of the inductively coupled plasma mass spectrometry which usually requires significant dilution to avoid high dissolved solid concentration. However, the XRF technique suffers from a strong matrix dependent problem. The objective of this study was to examine the applicability of the XRF analysis where the sample matrix was not exactly the same as the standard materials with particular reference to PGM analysis. This study enabled to compare the effect of various matrices including alumina, iron, copper and nickel on determination of the contents of PGM.

Jan 1, 2004

By Joe Hachey, Jerry Dorn, Jeff Schutt, Derek Penrice

"Sound Transit’s East Link Project, a $3.7 billion (2015 $), 14-mile light rail extension, will connect downtown Seattle with the rapidly developing east side cities of Bellevue and Redmond. Among the most technically challenging aspects of the Project is the 2,435 foot long Downtown Bellevue Tunnel (DBT), which will be constructed through the central core of Bellevue underneath 110th Avenue NE using a combination of Sequential Excavation Methods (SEM) and cut and cover tunneling. The 1,980 foot long central SEM component of the DBT will be mined at shallow depth through challenging and complex geology, comprised of glacially overconsolidated soils, containing both regional and perched groundwater conditions and in close proximity to existing high rise buildings. The paper shares lessons learned from the planning decisions and risk based approach to the investigation, design and procurement processes which shaped the DBT configuration and enabled a successful transition to the project’s construction stage. INTRODUCTION The East Link Project is a voter-approved $3.7 billion (2015 $), 14-mile extension of the existing Sound Transit (ST) light rail transit (LRT) system from downtown Seattle, across Lake Washington via I-90, to the cities of Bellevue and Redmond on the east side of Lake Washington. With targeted completion in 2023, East Link will provide riders with an efficient and reliable connection between the largest population and employment centers on the east side and downtown Seattle. The project alignment is indicated in Figure 1 below.ST completed the Preliminary Engineering (PE) phase of the East Link project in late 2011. Subsequently the final design contract for the easternmost seven miles of the project was awarded to the H-J-H Team, a joint venture comprised of HNTB, Jacobs Engineering and Hatch Mott MacDonald in February 2012. H-J-H’s final design scope includes approximately 7 miles of double-track LRT between the east end of the I-90 East Channel Bridge and the Overlake Transit Center Station. While the project scope is extensive and diverse, the focus of this paper is the DBT. The DBT is located immediately north of the East Main Station, and travels approximately one half mile through downtown Bellevue under 110th Avenue NE between Main Street and NE 6th Street; terminating at the Downtown Bellevue Transit Center (BTC) Station. The location and extent of the DBT is indicated in Figure 2."

Jan 1, 2016

By Alexandr A. Abramov, Svetlana M. Angelova, Oleg P. Maljuk

In this paper the effect of the ratio of grinding and grindable size classes (ore lumps, particles and grains) and the guantity of intermediate size classes in the feed of the primary wet autogenous grinding "Cascade" mill is studied and the features of the influence of these factors on the mill capacity are shown. On the basis of the experimental data from Lebedinsky mineral processing plant, where magnetite guartzites are processed, a coefficient of the "total ratio of size classes" in the feed of 9x3 m "Cascade" mill was estimated. It helps to get an evaluation of the effect of ore size classes ratio in mill media on the mill capacity and to work out some ways for its optimization in closed or semiclosed technological circuites of primary autogenous grinding. The operation of the specific energy effects for some intermediate size classes, removed from the mill as circulating load, is proposed to improve its efficiency before regrinding in "Cascade" mill and decrease negative influence of such classes accumulation in the mill media.

Jan 1, 1995

The U.S. National Institute for Occupational Safety and Health (NIOSH) conducted a study to determine the effectiveness of a filtered air delivery system to reduce respirable dust exposure of roof bolter operators in underground coal mines. When performing roof bolting operations, roof bolter operators may experience exposure to high levels of respirable dust during a working shift, especially when working downwind of the continuous mining machine. While drilling and installing roof bolts, this filtered air system supplies a clean curtain of air over the roof bolter operator by means of a plenum mounted beneath the canopy. This experimentally designed air curtain, adapted for roof bolting machines used in this study, is based upon previous design prototypes, computational fluid dynamics (CFD) simulations and trial-and-error testing. Both the prototype and final designs were tested in the full-scale mining galleries at the Office of Mine Safety and Health Research (OMSHR) in Pittsburgh, PA before being taken underground for field testing. Test results of the system in both laboratory and field studies show reductions in operator exposure to respirable dust when the operator is positioned directly under the protected zone of the canopy.

Jan 1, 2012

Small-scale flotation tests have been conducted to examine the effect of froth stability on the column flotation of finely pulverized coal. The results of this study demonstrate that the upgrading of coal in a column flotation cell can be significantly improved when froth stability is properly controlled through the manipulation of appropriate operating variables. Several important correlations have been established from the test data. These relationships should prove useful for the design and ore ration of column flotation cells for fine coal processing.

Jan 1, 1991

By E. Suoninen, K. Laajalehto, L. Kartio

Efficient separation of pyrite from other sulfides is of great importance for the metallurgical performance of flotation processes. In this work Fourier Transform Infrared Spectroscopy (FTIR) and X-ray Photoelectron Spectroscopy (XPS) were used to study the surface chemistry of pyrite in depression, activation and xanthate adsorption under conditions of controlled potential. Modifications of pyrite surfaces after treatment with depressants (lime, sulfur dioxide, sodium cyanide) and after activation with metal ions (Cu, Pb) were studied. The principal adsorption product identified on pyrite was dixanthogen whose formation started at about +0.15 V and +0.25 V (vs, SHE) in ethyl and amyl xanthate solutions, respectively. Copper xanthate was formed on copper(II) activated pyrite. Activation mechanism of pyrite by copper(II) salts is likely to be electrochemical where copper occurs as copper(I) on the surface of pyrite. Effective depression is achieved by sulfur dioxide and sodium cyanide. Depression at high pH is due to formation of iron(III) hydroxides. Calcium ions do not affect the electrochemistry but adsorb on pyrite and reduce the surface sites for dixanthogen adsorption.

Jan 1, 1995

By J. Derwin King, Harrison R. Cooper

Applications of nuclear magnetic resonance (NMR) offer possibilities for on-line sensing of the concentrations of several elements in flowing sample streams. In addition to hydrogen, these elements, generally of low-order atomic number, include aluminum, phosphorus, fluorine, sodium, boron, and lithium contained in minerals having commercial importance. Many such elements have been difficult or impossible to successfully measure on-line using the more familiar X-ray fluorescence and neutron activation analysis techniques. The availability of practical on-stream analysis methods is essential to applying advanced controls to processes incorporating these elements. On-stream NMR instrumentation has been demonstrated in the past for several process applications including, as an example, coal flow and analysis; and the technology has recently been extended to the measurement of phosphorous BPL in Florida beneficiation plants. The technique involves simultaneous sensing of proton (hydrogen) and 31P intensities to provide data for continuous calculation of BPL in the phosphate through calibration to volume fractions of water and solids. Initial operating results are described using the PhospholyzerTM on-stream phosphorous analyzer designed for plant application.

Jan 1, 1990

By W. F. Cannon

Many high-grade manganese deposits of the world occur in marine transgressive sedimentary sequences deposited on stable platforms. These include the Nikopol and related deposits in the Soviet Union and Groote Eylandt, Australia, among others. We suggest that the Atlantic and Gulf Coastal Plains and the vast area of Cretaceous rocks in the middle of North America are favorable provinces for sedimentary manganese deposits because regionally transgressive units are widespread. North America has 16% of the world's land area but only about 0.2% of known high-grade manganese reserves. This disparity is difficult to reconcile in view of the fact that large areas of North America are underlain by rocks that we consider at least broadly favorable to contain manganese ores, and we suggest, therefore, that important high-grade deposits remain to be found in North America.

Jan 1, 1982

By Chuck Hornaday, Brad Miller

Geosynthetic clay liners (GCLs) are manufactured barrier layers containing a high-quality sodium bentonite clay attached or adhered to geotextiles or a geomembrane. The GCL's low permeability and high strength make it an ideal replacement for low permeability soil or clay liners for mineral extraction and processing containment applications. This paper will discuss the advantages of utilizing a GCL versus compacted clay in containment applications. Some of the advantages include: the GCL's lower permeability (5 x 10-9 centimeters per second (cm/sec)) and corresponding better composite liner leakage protection, the GCL' s greater resistance to desiccation, differential subsidence and freeze­thaw, and lastly, the ease and speed of installing the GCL. This paper will also detail a number of important case studies related to the mineral extraction and processing industry. These case studies include using GCL in two large reclamation capping projects, as a secondary liner in two gold heap leach pads, as a composite liner in a dam for stormwater runoff control, and lastly, as a primary liner for a tailings runoff diversion channel.

Jan 1, 1997

By V. Duddempudi, B. Goertz, J. Brune, G. Bogin, F. S. Barreto

"INTRODUCTION In designing a new pneumatic Dust Sampling Device (DSD) for coal mines, it was essential to analyze the air and particle flow inside the device in detail using Computational Fluid Dynamics (CFD) modeling. Several CFD models were developed to simulate the air and dust flow and sample collecting process of the DSD. These CFD models were developed to assist in the design of the DSD instrument prototypes for laboratory testing. Nozzle and injection parameters such as geometry, air velocity and pressure, were varied across a wide range to obtain the optimal settings to accurately simulate the fluid dynamics of the multi-phase flow within the DSD. Accordingly, these parameters were used as a guide for the design of the DSD and to verify the dust scouring dynamics, which is designed to represent the dust entrainment during an actual methane or coal dust explosion. BACKGROUND The 2010 explosion at the Upper Big Branch mine has demonstrated the destructive violence of a coal dust explosion. A major contributing factor for this disaster was that the mine operators did not have a reliable, direct-reading method to collect mine dust and determine inert content and combustibility. This led to the development of a new prototype handheld, pneumatic mine dust sampling device (DSD), which blows a puff of air and entrains the mine dust by mimicking the entrainment process during a mine explosion. A computational Fluid Dynamics (CFD) model is used to analyze the air and dust flow inside the DSD. The objective of the CFD modeling effort is to find the optimum design of the DSD prototype, nozzle orientation, air pressure and pulse length by analyzing and varying these parameters so that the scouring action collects a valid, representative and repeatable mine dust sample. CFD MODEL DESIGN Figure 1 shows a wireframe image of the DSD which is utilized in the setup of the CFD model. The DSD has a triangular cross section and is 10 cm wide. Two nozzles with cross-sectional dimension of 2.8 cm by 0.25 cm act as inlets at the narrow end of the triangular cross section. The CFD model includes a reference plane 6 cm away from the nozzle to measure the quantity of dust collected. The geometry shown in Figure 1 was created for the model and it matches with the design of the actual device shown in the figure 2. Symmetry, along the plane X-Y through the center of the device, is used to reduce the number of computational cells in the CFD model. Figure 2 shows the prototype device used for experimental testing. CFD MODEL SETUP Figure 3 shows a hexahedral mesh with a cell size of 0.8 mm and the total number of cells is around 650,000. The ANSYS Fluent® pressure based solver with a transient case was used with a total duration of 40 ms. The 40 ms simulation time is based on experimental measurements to capture the injection of air and initial scouring of dust."

Jan 1, 2016

By Edward Holloway

The basis for the selection of the ultimate pit for an open pit mining operation is generally opaque. Some form of value-based analysis will generally guide the final decision; however, the value will often gradually plateau whilst the ultimate pit size continues to increase. There is no established framework to guide specialists in the selection of the ultimate pit, with such decisions regularly made on a somewhat arbitrary basis. The key component that is missing from the analyses typically used to select the size of the ultimate pit is risk. Once risk is quantified within the analysis framework, the decision-making range is significantly reduced, and the process for selecting the ultimate pit becomes more consistent, replicable, and defensible. This paper provides an approach to including risk in the process used to select the ultimate pit.

Feb 21, 2024

By Kenneth J. Miller

A novel two-stage froth flotation process to remove pyritic sulfur from fine- size coal is described. The process consists of a first-stage, standard coal flotation step in which high-ash refuse and some of the pyrite are removed as tailings. The first-stage clean coal froth concentrate is then repulped in fresh water, and a coal depressant, a pyrite collector, and a frother are added to float the remaining pyritic material. Laboratory and pilot plant flotation results with coals from the Lower Freeport and Pittsburgh beds are given. The pilot plant test results show that up to 80 percent pyritic sulfur reduction was achieved with the Lower Freeport bed coal and up to 50 percent with the Pittsburgh bed coal. Laboratory and pilot plant results were in excellent agreement, indicating that the process is a viable means of removing much of the sulfur from some coals.

Jan 1, 1974

By Paul H. Johnson

A new system for leaching many types of ores has recently been developed on a commercial basis by J and J Research and Development, Inc. of Hanover, New Mexico. This revolutionary new leaching system consists principally of three new leaching reactors; viz, (1) a large, air-agitates, column-like reactor for leaching crushed ores that is constructed in an underground environment and has the inherent ability to do a very efficient job of leaching, (2) a vat-like, air-agitated vessel for leaching an rinsing finely ground ores and , (3) an air-agitated copper precipitation column that is built underground and utilizes an inexpensive dense or heavy scrap iron as a copper precipitant. Each of these new reactors have been used in a large leaching plant near Hanover, New Mexico.

Jan 1, 1973

By H. W. Breathitt

World demand for phosphate rock has increased significantly in the past fifteen years. Prior to the early 1960's, most of the world production was obtained from Florida, North Africa, and Kola. As the 1960's arrived, new mines in North Florida and Eastern North Carolina, as well as expanded production in the Western United States, .increased domestic production. Many new mines overseas have also become significant. This includes countries such as Senegal, Togo, Israel, Spanish Sahara, and Jordan. Limited production, often as by-products, has been noted in South Africa, Brazil, and other countries. In recent years, and even recent months, we have learned of many new areas being considered as potential sources of phosphate rock. This includes Australia, Saudi Arabia, Mexico, Colombia, and Brazil. Many other developing countries have discoveries and are considering their new deposits, often with difficult beneficiation problems, as potential sources of phosphate. These factors all relate to expanded world, population and the demand for more fertilizer products to produce food. In this paper, four areas of the world with different types of phosphate deposits are briefly reviewed to contrast the ore beneficiation problems to Florida procedures--long considered the "standard" of the industry, at least for most of the United States' domestic production. Agrico has three large operating mines in Florida with total production capacity exceeding seven million tons per year. Here, pebble phosphate (+14 mesh material) is produced without the use of flotation, whereas all of the material finer than 14 mesh is subjected to flotation beneficiation to upgrade into high grade concentrates.

Jan 1, 1977

By F. F. Peng

A unique collector dispersion techniques was developed and used to improve the flotation rate and recovery of coarser and ultrafine coal-rich particles in the froth flotation processes. In this novel collector dispersion method, the collector such as hydrocarbon-oil is gasified and transported by gas phase (air stream) into the pulp. In addition to the excellent mode of collector dispersion, the collector-encapsulated air bubbles are generated in the pulp. This approach alters the surface properties of air bubbles and provides the fast rate of flotation compared to that of direct liquid collector addition froth flotation. Using gasified kerosene as the collector, the effect of altering surface properties of bubbles on the recovery of larger and finer coal-rich particles of -1.7 mm (-12 mesh) and -600 µ m (-30 mesh) raw coal samples were studied. The Redstone seam coal obtained from Northern Central region of West Virginia was used in this work. The effect of particle size on oil-coated bubble flotation rate and recovery were also evaluated. The conventional froth flotation test with a liquid form of kerosene addition was also conducted for comparison purpose.

Jan 1, 1991

By D. Boreck

The Bureau of Mines is conducting research on the feasibility of incorporating in situ stope leaching into active underground metal mines. Stope leaching, a modified in situ leaching technique, proposes to recover metals by leaching fragmented ore in existing underground openings and collecting and processing the metal-bearing solution to recover the valuable metals. If leaching solutions escape from the stope, either through geologic discontinuities or highly permeable zones in the rock, valuable metals dissolved in the solution may be lost. Escaping solutions may also contaminate ground waters. Consequently, in fractured rock, the characteristics of the fractures in the vicinity of the leaching stope must be understood before introducing actual leach solutions into the stope. Effectively characterizing a rock mass requires the integration of several disciplines including structural geology, borehole geophysics, hydrology, geochemistry, and mining engineering. This paper will focus on the general geologic and geophysical techniques that can be used to characterize the rock mass at an underground simulated stope leaching site. The results of several geophysical logging methods, tested at the site, are compared to the geologic core descriptions. Then, the? effectiveness of the different geophysical techniques in delineating fracture zones will be assessed. Knowledge gained through the geologic and geophysical analyses can be used to supplement results from hydrologic testing. This information can also be utilized in designing blast patterns and developing strategies for controlling or blocking movement of escaping leach solutions.

Jan 1, 1991

By G. Davis

Mineral properties and mineral firms often trade at a market value that is significantly greater than the value indicated by discounted cash flow (DCF) techniques. A possible explanation is that DCF analysis does not consider the value derived from managerial flexibility. Presumably, then, at least some of the difference between DCF value and market value is due to managerial flexibility. This paper surveys the recent attempts to empirically quantify the value of managerial flexibility using option pricing theory. The results indicate that managerial flexibility, at least as measured by the option pricing methodology, falls well short of explaining the gap between DCF value and market value.

Jan 1, 1995