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By R. M. Hernandez

The Bureau of Land Management (BLM) constructed four passive biochemical reactor systems (BCRs) to treat mining influenced water (MIW) in the Bunker Hill Superfund area near Coeur D?Alene, Idaho between 2002 and 2003. Initially, the BCRs operated very effectively. However, in the past couple of years, the zinc removal effectiveness of the four BLM BCRs has declined [1]. The central objective of this study was to characterize the microbial communities and substrate present within the BLM BCRs and to use these factors to propose strategies to promote sustained sulfate reduction levels. Microbial communities were characterized by quantifying total bacteria and sulfate reducing species. Substrate was characterized by quantifying the percent organic, acid soluble organic, acid insoluble organic, and bioavailable material within the BCR. The results suggest the depletion of bioavailable organic substrates is the primary cause of the decline in zinc removal and not the microbial community structure. The ability to assess the amount of bioavailable organic substrate and microbial community is important to the understanding of the sulfate reducing capacity of the BLM BCRs and developing strategies to facilitate performance enhancement of the current BLM BCRs. The characterization of organic substrate and microbial community structure are also important to improving design of future passive treatment systems for mining influenced waters.

Jan 1, 2010

By Patrick Browne

Drilling programs and the study of active geothermal systems have shown that the reservoir rocks in many fields contain minor quantities of base and precious metals. Commonly, base-metal sulfides occur in the subsurface but, where present, Au, Ag, Hg, As, T1 and Sb rich precipitates deposit near, or at, the surface. Although in some fields (Geysers, Larderello, Tongonan) some of the ore minerals (and others) are relict, there is evidence that they are now depositing in a few systems. Recent work on active hydrothermal systems in New Zealand shows that: (1) Sphalerite, galena, chalcopyrite (forming veins and disseminated discrete crystals) plus rare pentlandite, cobaltite and arsenopyrite, occur at Broadlands, NZ. Rare quantities of base-metal sulfides also occur in cores and cuttings from the geothermal fields of Waiotapu, Kawerau, Tauhara, and Ngawha. Further, Kakimoto (1983) has identified cassiterite, native silver, and trace gold in cores from Tauhara, in the south-eastern part of the Wairakei field. Bore temperatures at the depths from which these minerals were recovered are mostly between 220° and 300°C, but at Broadlands are locally as low as 120°C. The host rocks are Quaternary talc-alkali, silicic lavas and pyroclastic rocks, andesites, dacite and deep Mesozoic greywackes and argillites; however, there is no obvious relationship between mineralization and stratigraphy, permeability or well output. (2) The deposition of amorphous precious metal precipitates (Au, Ag, Hg, As, Sb, T1) from hot springs and well discharges has taken place at Broadlands, Waiotapu and Rotokawa; it also occurs at Kawerau. (3) Water discharging from Frying Pan Lake, Waimangu, is presently depositing siliceous sinter containing up to 4.1% tungsten. A characteristic of mineral-depositing fluids in the New Zealand geothermal fields is their very low salinity (total dissolved salts of 3000 ppm or less but with high CO2); they are of near- neutral alkali chloride composition, although water discharging from Frying Pan Lake has a pH of 4.5, and very low metal contents. Very effective concentration processes (10 times for gold at Broadlands) must occur: in the subsurface these include boiling and rapid cooling but near, and at, the surface, mixing of waters of different pH seems to dominate. In particular, descending acid condensate, derived from separated steam and oxidation of H2S mixes with its parent alkali chloride water, resulting in precipitation of amorphous ore metals. Base-metal sulfides also occur in veins and as disseminated grains in geothermal fields at Tongonan, Leyte and Southern Negros, Philippines. These fields have a porphyry-type setting with host rocks of Miocene andesitic lavas and pyroclastics intruded by diorites so that the fields have undergone complicated thermal histories before cooling to their present base temperatures of about 325°C. Precious metals have precipitated from waters from some wells (Leach, pers. comm.) but they do not, as yet, form ore-grade deposits.

Jan 1, 1984

By Naomi H. Harley, Daryl E. Bohning, Isabel M. Fisenne

INTRODUCTION Underground mines in many parts of the world have elevated levels of short-lived 222Rn daughters. Lung cancer implicating exposure to short-lived daughters is documented in the U.S., Czechoslovakia, Canada, Sweden, the U.K., France and Newfoundland. An elevated lung cancer mortality (in excess of that expected) has been observed when cumulative exposure to alpha emitting short-lived 222Rn daughters (218Po, 214pb 214Bi 214Po) is greater than about 60 working level months (WLM) [1]/ (Hewett, D. 1979). This is equal to an absorbed alpha dose of about 30 rads to shallow basal cells in bronchial epithelium. Long-lived alpha emitters are also present in underground mines, and especially uranium mines because of airborne particulates containing uranium. The 238U parent of this primordial series supports other long-lived emitters 234U 230Th, 226Ra, Pb(210Po) which are in some degree of radioactive equilibrium with the parent 238U. Airborne particulates can be present due to drilling on the face of the ore body as well as in all parts of the mine through resuspension from the mine floor. Particles from 1 µm to about 5 µm penetrate the nose with reasonable efficiency and deposit primarily in the tracheobronchial tree. They are removed by ciliary motion (the bronchial escalator) but deliver an alpha dose to basal cells in bronchial epithelium during clearance in the same manner as short-lived 222Rn daughters. It is the purpose of this work to indicate the alpha dose to basal cells in bronchial epithelium delivered by the long-lived emitters 234, 238U. The dose calculations reported here based upon a few measured values of these isotopes in air in uranium mines in New Mexico and Colorado. MEASURED 234, 238U IN URANIUM MINE ATMOSPHERES In 1979, the U.S. Bureau of Mines undertook a study to evaluate personal monitors to be worn by miners to measure short-lived 222Rn daughters. One of these devices sampled air at 100 cm3/min through a 13 mm glass fiber filter, with a small pump worn on the belt. Alpha particles emitted by 222Rn daughters on the filter were measured continuously by a thermoluminescent dosimeter (TLD) chip. Each monitor was worn by a miner for a 170 hour working month and approximately one cubic meter of air was sampled during this period. Six different mines were selected for the test in New Mexico and Colorado. The mines used either wet or dry drilling methods. Miners in each location were equipped with the personal monitors. Subsequent to their use in evaluating the shortlived daughters, Dr. Robert Droullard of the Bureau generously gave us these filter samples along with a few blank glass fiber filters from the same box of filters used in the study so that long-lived emitters present in these mine atmospheres could be determined radiochemically. Four of the samples have been run for 234, 238U. The radiochemical procedure for uranium is adapted from USDOE, Environmental Measurements Laboratory Manual (Harley, J.H., 1976). Briefly, the samples were placed in platinum crucibles, spiked with 232U tracer and pretreated with nitric and hydrofluoric acid. The residue was fused with potassium fluoride to transpose to pyrosulfate. The fused cake was dissolved in 7 [N] hydrochloric acid and the solution passed through an anion exchange column to isolate uranium. Iron was removed using mercury cathode electrolysis. Uranium was electrodeposited onto platinum dies and counted using solid-state alpha spectrometry. The samples from each type of mine (wet and dry) were analyzed. The samples in the "wet" mine in New Mexico were selected on the basis of the original TLD measurement because they were near the maximum occupational standard for radon daughters. These samples should also represent upper limits to longlived activity encountered, since they were obtained at drilling operations on the face of the ore body. Samples collected in the "dry" mine in Colorado were pot associated with a particular location in the mine and should be representative of a month long overall exposure in many locations and operations. The values are shown in Table 1. The two uranium isotopes are in equilibrium and their alpha activity

Jan 1, 1981

By Orlando Oliveros

The Los Bronces Mine and Concentrator, one of the three operating units of Compania Minera Disputada de Las Condes S.A. (an Exxon Minerals Co. affiliate), is located in the high Andes of East-Central Chile approximately 70 kilometers northeast of Santiago at an elevation of 3,650 meters above sea level. (Figure 1). Santiago, the capital city of Chile, is located at an elevation of about 500 meters above sea level and enjoys a very mild climate, similar to some areas of California. At the mine site, however, extremely heavy winter conditions prevail occasionally, with very heavy snow and the resulting snow avalanches endangering installations and people. At the same time, ideal skiing conditions are found at the nearby ski resort of Portillo and Farellones. Mount Aconcagua, the highest mountain in the western hemisphere is only about 55 kilometers further to the northeast of the Los Bronces mine.

Jan 1, 1983

By F. Milton Lewis

Several alternatives are available for treating lover grade gold ores averaging 0.04 to 0.10 ounce per ton. These include heap, vat and agitation leaching and may involve conventional zinc precipitation or carbon adsorption-electrowinning systems. Each of these processes have their inherent economic and operating advantages and disadvantages and the selection of the optimum method for a given gold ore is solely based on economic evaluation of the applicable processes. In this paper an effort is made to provide engineering feasibility estimates for the above processes under varying operational conditions such as ore grade and price of gold.

Jan 1, 1974

By Peter J. Szabo

In 1980, a caravan of representatives of Japanese trading companies debarked on the shores of the United States bearing gifts of watches, electronic games, and radios. In early 1983, we find in a parking lot of a major U.S. coal company, a haggard general manager of marketing returning to the Orient with a box under his arm of trinkets of his own; cross pens with company logos, alarm clocks, etc. The tables have turned, but our fellow sitting in a jet plane over the Pacific Ocean had only to heed the warning of the famous 19th Century poet well familiar with the ways of the Far East. Kipling said; "And the End of the Fight is a tombstone white and with the name of the late deceased, And the epitaph drear, a fool lies here who tried to hustle the East."

Jan 1, 1984

By Arthur E. Lewis

A contained nuclear explosion is proposed to produce a chimney of broken ore well below the water table. After the chimney is filled with water and reaches hydrostatic equilibrium, oxygen, under pressure, is introduced near the bottom of the mass of broken rock. The increase in solubility of oxygen at high hydrostatic pressure is sufficient to initiate the oxidation of the primary sulfides: chalcopyrite and pyrite. The oxidation and dissolution of these sulfides produces enough heat to increase the temperature of the ore and water in the chimney as much as 1000 to 150°C. The rate of dissolution of chalcopyrite becomes so rapid under these conditions that the rate of recovery is no longer limited by the rate of chalcopyrite dissolution, but by the degree of exposure and other factors. Means of solution control and distribution of oxygen in the chimney have been examined in some detail. A calculational model utilizing experimentally determined solubility rates is utilized to estimate the temperature rise in the chimney and the rate of copper recovery as a function of initial temperature, sulfide content of ore, size of sulfide particles, and fraction of sulfide exposed to solution.

Jan 1, 1972

By P. Crouse, J. Obermeyer

"INTRODUCTION Site location and history The Holden Mine is a former underground copper mine that was developed and operated by the Howe Sound Mining Company (Howe Sound) from 1938 to 1957. The mine is located in north-central Washington State, U.S., near Lake Chelan in the area shown as Holden Village in Figure 1. Although Rio Tinto never owned or operated the mine, they are managing and funding a several hundred million dollar clean-up to prevent future water and soil contamination and to reclaim the former mine site under the United States Environmental Protection Agency (USEPA) Superfund process. The former mine included an onsite mill and a nearby housing complex for the miners. Howe Sound developed the mine as a series of near-horizontal drifts and tunnels, interspersed with stopes and shafts that connect different mine levels underground. The tunnels that were excavated to develop the mine total nearly 100 km in length.During development of the underground workings, Howe Sound removed more than 230,000 cubic meters (m3) of waste rock from the tunnels and deposited this material in two waste rock piles. Ore was processed from the mine in the onsite mill to produce a copper concentrate that was shipped off site for smelting. Roughly 10 million tonnes of tailings were produced as a by-product of the milling operation, most of which were deposited in three large impoundments (Tailings Piles 1, 2 and 3) directly south of and adjacent to Railroad Creek. Howe Sound closed the mine in 1957. In 1961, the property was transferred to Holden Village, Inc. (Holden Village), a not-for-profit corporation that maintains a year-round community and operates an interdenominational religious retreat in the former miners’ town. With the exception of the patented private land, the remainder of the Site is on National Forest lands and is administered by the U.S. Forest Service. The mine is remote. It is only accessible by boat or float plane from Chelan, Washington, up Lake Chelan to Lucerne, nearly 40 km. Vehicle access from Lucerne to the mine is provided through a 17.5-km-long winding gravel road that climbs 640 meters in elevation. The general site features are shown in Figure 2. Physical setting The Holden Mine is located on the eastern slopes of the Cascade Mountain Range at an elevation between 975 and 1,050 m above mean sea level. Holden Mine was developed adjacent to Railroad Creek, which lies in a glacial U-shaped valley carved into the igneous and metamorphic bedrock with steep-sided slopes (Figure 2)."

Jan 1, 2017

By R. V. Ramani

In this paper, the application of the concepts of reliability engineering to the evaluation of longwall system performance is illustrated with data from an operating longwall face. A number of cases are analyzed to highlight the impacts of longwall equipment, geological conditions and outby haulage on systems reliability and availability.

Jan 1, 1988

"Mining of ore bodies that are located at great depths enforces long distances to move the excavated rock masses to the surface. The excavated rock mass contains not only ore that can be economically extracted from the face but also waste, which is usually discarded several steps further downstream in the process. As a result, a large amount of rock is transported to the surface, influencing the costs at which the ore is produced. Reducing the amount of waste rock being transported to the surface by introducing a near-to-face sorting plant would improve the in many cases strained transport system in the deep mine. In this study, one of Boliden’s cut-and-fill mines was analysed with respect to the challenges related to rock transportation and increasing mining depth. The study aims to evaluate the potential use of a new near-to-face sorting system in the operating underground mine. Discrete event simulation was used to study and analyse the rock transportation system with and without the near-to-face sorting plant. The paper shows how the underground rock transportation system and the production were influenced when the near-to-face sorting equipment was added into the current system. INTRODUCTION The locations of waste rejection in the mining processes and the cost of removing waste from the system compared with the cost and energy necessary for further comminution are important parts in the material handling system (Bowman and Bearman, 2014). In an underground mine, longer material transportation distances generate the need for further investment in the mobile fleet and ancillary equipment in order to reduce the waste from the material handling as early as possible. One of the ways of reducing the waste (coarse particle size) in material handling is by use of pre-concentration. The benefits of pre-concentration are well known (Schena et al. 1990; Feasby, 1995; Peters et al. 1999; Klein et al. 2002), as well as the factors governing the feasibility of underground pre-concentration (Peters et al., 1999) and the mining integration issues (Klein et al. 2003). In the Onaping Depth orebody in Sudbury, Ontario the study of implementing the pre-concentration resulted in increased capital costs of 6% and a reduction in the operating costs of between 20-40% (Bamber et al, 2004). In this paper, the effects on the production and the transportation system of implementing underground pre-concentration by means of a near-to-face ore sorting plant in the Kristineberg mine are modeled and analyzed using the AutoMod tool. This tool is based on discrete event simulation (DES) (Banks, 2004), allowing high flexibility in customization and enabling the user to view the production of the system before ore sorting plant integration. The sorting plant selected in the simulation is built from modules. The material is fed by conveyor and goes through the comminution, classification, sorting and service processes after which the waste is redirected to backfill headings via trucks. The system mechanically ejects the particles from the feed stream on the basis of the information obtained from both the XRT sensor’s signal and 3D laser scanner based on both density and rate of refraction of light within a particular mineral. The sorting plant could pre-concentrate the metal ore up to 300 mm size. The plant requires little auxiliary infrastructure, is easily modularized for underground installation and can be easily relocated to different areas."

Jan 1, 2016

By L. Yuan, J. H. Rowland, R. A. Thomas, D. Bahrami

Blasting is the main method of production in many non-coal underground mining operations and produces multiple toxic gases as a result. The Mine Safety and Health Administration (MSHA) requires mine operators to measure the level of toxic gases in mines as frequently as necessary to ensure they are below regulatory safety limits. The current practice uses portable gas monitors to check the concentrations of toxic gases after a fixed post-blast time. This paper studies the application of a gas monitoring system in the return entry of a limestone mine to determine a safe re-entry time. The National Institute for Occupational Safety and Health (NIOSH) conducted such a monitoring program in a limestone mine from September 2016 through May 2018. NIOSH/PMRD (Pittsburgh Mining Research Division) is endeavoring to develop workplace solutions to improve detection of and reduce the risk of hazardous conditions. This study showed that the use of gas monitoring in the return air can be a useful tool at the mine operator’s disposal to detect and reduce the risk of hazardous conditions and also to reliably estimate the re-entry time. INTRODUCTION Underground miners are at risk of overexposure to toxic gases from various sources. Production blasting operations using explosives in underground mines are a source of multiple toxic gases that could be harmful and even fatal to humans if prolonged exposure occurs beyond the safe limits. According to Code of Federal Regulations, Title 30, Part 57.5002 [1], metal and nonmetal mine operators must conduct gas, mist, and fume measurements as frequently as necessary to determine the adequacy of control measures to protect miners from overexposure to harmful gases. MSHA will inspect mine operators’ activities to verify the evidence of such measurements [2,3]. Continuous gas monitoring in the return air is an effective way to make sure that toxic gas concentrations at the working areas are kept below the regulatory limits before the return of miners. Toxic gases can enter the mine atmosphere from different operations, such as welding, combustion, and blasting. The main gases produced from blasting are carbon monoxide (CO), carbon dioxide (CO2), nitric oxide (NO), and nitrogen dioxide (NO2). Other gases are produced in small amounts and, therefore, were not considered for this study. Related regulatory and recommended exposure limits of CO, NO, and NO2 gases are summarized in Table 1 [4].

Jan 1, 2019

The last decade has seen the use of powerful computerized Mine-Wide Monitoring (MWM) systems for detecting hazardous conditions in underground coal mines. Recently, the U.S. Bureau of Mines and Jim Walter Resources, Inc. (JWR) expanded the scope of MWM system to include ground control. Single-point extensometers were installed in each of 30 intersections along a tailgate entry. These instruments monitored the rate of roof sag, a sensitive indicator of roof instability. Data were collected by the mine's own computerized MWM system. The paper describes the successful integration of ground control instruments into MWM, the data reduction procedures, and the identification of several hazardous areas.

Jan 1, 1994

By Pawan Bharadwaj, Wim Mulder, Thomas Tscharner, Guy Drijkoningen, Rob Jenneskens

"The Earth’s properties, composition and structure ahead of a tunnel boring machine (TBM) should be mapped for hazard assessment during excavation. We study the use of seismic-exploration techniques for this purpose. We focus on a seismic system for soft soils, where shear waves are better and easier to interpret than compressional waves, as has been shown over the last decade. The system is intended to be deployed on the machine’s cutter head, with a few seismic sources and sufficiently many seismic sensors to tackle spatial variability and noise characteristics. An important property of the newly developed system is its ability to process data with very little human interaction. Images need to be available in near real time, without human interactions slowing down the imaging process. This can be achieved by employing Full Waveform Inversion, which minimizes the difference between modeled and observed data. Because this method may suffer from local minima in the cost function if the data lack low-frequency information, we employ a dedicated seismic source that can generate sufficiently low frequencies for the relevant length scales. With data acquired in a number of field settings that mimic realistic TBM configurations, we show that the designed seismic system can successfully look ahead of the TBM and offers a valuable capability to support decision-making during tunnel excavation. INTRODUCTION While excavating a tunnel with a Tunnel Boring Machine (TBM), the geology and the ground conditions along the planned tunnel trajectory need to be investigated in order to safely and efficiently carry out the underground operations. This entails detecting the occurrence of boulders, foundations, pipes and faults, necessary to prevent hazards and time-consuming delays in the tunnel boring operations. In order to facilitate ground prediction ahead of a TBM, techniques as used in seismic exploration can be deployed. Two components common to seismic-exploration techniques are data acquisition and processing, the latter including inversion. We will discuss each of these for the application to tunnel excavation with TBM, in particular for soft soils."

Jan 1, 2016

By S. Chander

The effect of sample storage in argon and in air on kinetics of oxidation of pyrite from a coal source was studied using accelerated weathering test in laboratory columns. Prior to the weathering tests the samples were crushed, ground, and stored for various time periods in argon and air. The results showed a dramatic difference in the rate of oxidation of the aged samples. The differences were interpreted based on the hypothesis that the aging of pyrite led to the formation of surface coatings which changed with time. The significance of these results in pyrite/reagent interactions in flotation and in evaluating the acid mine drainage potential of pyritic waste materials is discussed.

Jan 1, 1993

By Paul C. Lingo

Two recent antitrust cases, coming from widely separated areas, different industries and involving wholly different facts were decided by the Supreme Court on June 7, 1965. The decisions in these two cases may well prove to be the most important and far-reaching decisions in the field of labor law that have been handed down in the last 24 years. These cases, although quite dissimilar factually, had one common element. In both, the gravamen of the antitrust violation was bottomed on the terms of labor agreements negotiated by a multiemployer group. These cases are usually referred to as Pennington1 and Jewel Teat. Since a number.-of references will be made to the antitrust laws, it may be well to state briefly the applicable portions. Section I of the Sherman Antitrust Act makes "every contract, combination in the form of trust or otherwise, or conspiracy, in restraint of trade or commerce among the several states, or with foreign nations, is declared to be illegal...". Section 2 imposes criminal sanctions against "Every person who shall monopolize, or attempt to monopolize, or combine or conspire with any other person or persons, to monopolize any part of the trade or commerce among the several states...". Under Section 4 of the Clayton Act a person who sustains damages as a result of a violation of the antitrust laws is entitled to recover treble damages plus costs.

Jan 1, 1965

By P. R. Thomas

This paper addresses the relative long-term cost and resource position of new and existing ferrochromium production in selected Market Economy Countries (MEC'S). The market impact of new ferrochromium production in nations such as India and the Philippines and the continuing change in international trading patterns are also evaluated. This paper draws upon the data and analyses of a recent Bureau of Mines, Department of Interior, Minerals Availability Program appraisal that evaluated the cost and availability of chromite and ferrochromium production from the demonstrated resources of 80 producing or potential mining operations in 10 market economy countries.

Jan 1, 1984

By Ernest E. Thurlow

The Geology Division of Northern Pacific Railway Company has adapted to its exploration efforts field procedures for geochemical sampling and semi-quantitative analysis which have been developed through research by the U. S. Geological Survey. The sampling is done in conjunction with reconnaissance geologic mapping on aerial photographs or during field checking of maps which have been prepared largely by photogeologic interpretation.. Stream sediment or soil samples are taken and readily soluble combined heavy metals are extracted with ammonium citrate followed by colorimetric titration with dithizone at the sample site. The effectiveness of this approach has been demonstrated both in positive and negative results, thereby assisting in the elimination of large areas of land from further immediate attention and in providing targets for followup exploration. An occasional sample is submitted for spectrographic analysis as a check on the possible presence of other elements of economic significance. Field laboratory procedures are also being implemented for determining molybdenum, mercury, and other metals which may be valuable in themselves or useful as pathfinder elements in outlining mineralized areas. A lead-zinc occurrence in Oregon and a copper deposit in Montana were readily detected and outlined by stream sediment and soil sampling and a heavy metal anomaly that lacks obvious interpretation has been found in northwestern Montana. Detailed mapping and additional sampling are followed by other exploration techniques if warranted.

Jan 1, 1964

By D. E. Walsh

Over a period of seven years (1989-1996) the Mineral Industry Research Laboratory (MIRL) University of Alaska Fairbanks, has investigated the effects of temperature, residence time, and particle size on the degree of low-rank coal (LRC) upgrading for a non-evaporative, hydrothermal drying process, also known as hot water drying (HWD). Three Alaskan LRCs were used in this study: Usibelli coal (Seam No.4) from the Nenana Coal Field, Little Tonzona coal from near McGrath, and Beluga coal from the Beluga-Yentna field on the west side of Cook Inlet. Replicated, factorial tests were conducted. Experimental results indicate that most of the low-rank coal upgrading via HWD occurs rapidly within the first 10-20 minutes of residence time. Thereafter, the upgrading process slows down and over 100 minutes of additional residence time are required to produce similar percentage increases in coal properties to those achieved in the first 10-20 minutes. The properties of the hot water dried products were very sensitive to process temperature. Calorific value, carbon and oxygen contents, equilibrium moisture levels and Hardgrove grindabilities all appear to change linearly with temperature within the 275" C to 325" C range.

Jan 1, 1997

By T. A. Lloyd

The use of tank cells over the years has provided a means for low cost, space efficient, extra capacity in existing flotation circuits. In some cases, new plants have selected tank cells as the machine of choice. Typical tank cells use high efficiency impellers for mixing, which results in low power draw. Unfortunately, these mixers have poor aerating characteristics that compromise metallurgical performance. This has all changed with Outokumpu's new flotation concepts. Outokumpu has recently developed the HG or High Grade flotation cell that can provide higher recovery with better selectivity while maintaining the simple operation of conventional cells.

Jan 1, 1993

By P. Moyo, S. Dixon, R. Norcross

The separation and recovery of copper from cyanide solution has been investigated since the early 1900s. The precipitation of copper using sulfide ion was patented in 1911 by Williamson, published by Leaver & Woolf of the USBM in 1931 and Cyanamid in 1960s. The current practice of sulfide precipitation is used in various processes such as “SART" for cyanide regeneration and copper recovery. The precipitation of copper sulfide requires the pH of the clear solution to be in the range of 4-6. The precipitated copper sulfide can be sold to smelters. Alternatively, copper cyanide can be precipitated from clear solutions in the pH range of 2-3. However, selling copper cyanide is challenging because of its cyanide content. Past work has focused on the use of boiling sulfuric acid to convert copper cyanide to copper sulfate as published by Seracini in 1991. This paper describes a simple process to convert copper cyanide to copper oxide using sodium hydroxide at ambient temperatures. The cuprite can be sold to smelters or used as a feed to an electrowinning circuit to produce copper cathodes. The process provides an effective method to recover copper from cyanide solutions with a lower capital requirement.

Mar 2, 2022