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By J. Yao

Synthetic indium-bearing zinc ferrite (IBZF) was mechanically activated by a tumbling mill. Subsequently, the behavior and kinetics of leaching zinc and indium from the initial IBZF and activated IBZF in sulfuric acid solution were investigated. The results demonstrate that the tumbling ball milling enhances the leaching reactivity of IBZF and increases the zinc and indium extractions. The reaction temperature and H2SO4 concentration have an important effect on leaching zinc and indium from the initial IBZF and activated IBZF. The kinetic model -ln(1-x) = kt was used to describe the kinetics of leaching zinc and indium from the initial IBZF and activated IBZF and to calculate the kinetic parameters. The tumbling ball milling causes a decrease in activation energy and reaction order, which indicates that the dissolution of IBZF after mechanical activation by a tumbling mill becomes less sensitive to temperature and H2SO4 concentration. For the zinc leaching, the activation energy decreases from 73.9 to 70.3 kJ/mol and the reaction order decreases from 0.72 to 0.70. For indium leaching, the activation energy decreases from 78.1 to 73.5 kJ/mol and the reaction order decreases from 0.82 to 0.69. It is found that the dissolution rates of the initial IBZF and activated IBZF are controlled by surface chemical reactions.

By E. A. Laurila

During last years many different types of X-ray fluorescence analysers have appeared in the market most of these instruments being designed for laboratory use. The instruments applied ins continuous processes are usually modifications of these laboratory types. The application of these instruments to the analysis of heavier elements seems to be quite satisfactory. By lighter elements difficulties are caused by the strong absorption of the characteristic fluorescence radiation, which sometimes makes the use of vacuum or helium chambers necessary. In the following an instrument of another type will be described. It has been developed exclusively for the analysis of titanium in ilmenite concentrate, where the content of Ti02 varies between 43 - 46%. Preliminary measurements have shown that in this interval absolute change of 1% in the Ti02 concentration causes a relative change of about 2% in the intensity. Because: the accuracy of 0.5 % Ti02 is sufficient, 1% relative accuracy should be, attained in intensity measurement. The problem is not very easy to solve due to the fact that Ti K radiation is rather soft and the requirement's for accuracy are rather high. Being applied to the analysis during a continuous process may statistically fluctuating variables in connection of sampling and disturbances of many kind set special requirements for the instrument design.

Jan 1, 1960

By A. Kaina

The San Luis deposit is one of the few documented gold deposits on a detachment surface. This paper presents mineralogic and geochemical data that was gathered to characterize the mineralization, classify the ore deposit, and provide details of the ore forming process. Included are data on the paragenesis; alteration-mineral assemblages major and trace element geochemistry, and fluid inclusions. The San Luis deposit occurs on the western slope of the Sangre de Cristo Mountains adjacent to the San Luis Basin about 5 miles northeast of the town of San Luis in Costillo County, south-central Colorado. Mineralization was discovered in the district in the early 17th century. Production began in 1890 on lead-silver ores from which the district took the name the old name of "El Plomo". From 1897 through 1934 gold was intermittently produced. Battle Mountain Gold Company took an option on the property in 1987 and proved on ore body comprising an eastern block that has 1,277,300 t ore at a grade of 1.68 g/t and a western block of 9,744,000 t with a grade of 1.34 g/t. Production began in 1990. A companion paper by Benson (1994) describes the San Luis district and the ore body, hence the reader is referred to this or Robert and David (1990) for details of the geology from which the following is summarized.

Jan 1, 1994

By Paul Basinski

The Northern Reese River Valley is in west-central Lander County approximately 31 miles north of Austin, Nevada in the north-central Basin and Range Province (Figure 1). Authigenic zeolites, which were previously undescribed in the literature, are voluminous in this small sedimentary basin. Uranium mineralization is also abundant in this study area. Until now, what we believe to be cause and effect have not been put together. X-ray diffraction, differential thermal analysis, and scanning electron microscopy reveal clinoptilolite, erionite, analcime, and minor chabazite to be present (Figures 2, 3). Assays show uranium to be present in thicknesses up to 0.7 meters at amounts up to 0.10% eU308. The sediments in the Northern Reese River Valley belong to the Mio-Pliocene Humboldt Formation equivalents. This formation consists largely of tuffacious lacustrine and fluviatile sedimentary rocks. Mudstone is the dominant lithology and intercalated thin zeolite strata (usually less than 0.6 meter thick) are present. Zeolites in the Northern Reese River Valley were diagenetically derived from rhyolitic glass deposited in a shallow, saline-alkaline lake under arid to semi-arid conditions. Clinoptilolite from the study area was K-Ar dated at approximately 4.7 + 0.5 million years which corresponds to Middle Pliocene age (Krueger and Basinski, in press). This age is further substantiated by Middle Pliocene mammalian fauna collected in the vicinity by Deffeyes (1).

Jan 1, 1979

By Paul Dean Proctor

The known northern ore zones of the New Lead Belt of Southeast Missouri extend to the drainage divide between the Meramec River draining north and east and that of the Black River draining southward. Intensive geochemical studies related to the environmental impact of the new mining area have been carried out in the vicinity of some of the newly developed mines, mills and smelter complexes (Bolter,1970; Gale, et al, 1973; Wixson, et al, 1969, 1977). Other investigations have related to fringe studies of the Northern New Lead Belt and the possible additions of heavy metals to the surface waters, stream sediments and selected aquatic life (Proctor, et al, 1975, 1976). Similar studies have been completed in the Joplin area in the Tri-State district, and in the fringe area near Springfield, Missouri (Proctor, et al, 1974). A surface geochemical study is currently underway on the lead-zinc-copper-cobalt-nickel province near Fredericktown, Missouri (Proctor and Sinha, 1977). This report summarizes some of the distribution patterns of heavy metals in the waters, stream sediments and selected aquatic life in the Upper Meramec River drainage basin just north and west of the known northern portions of the New Lead Belt of Southeast Missouri. The region studied includes the site of the proposed and somewhat controversial Meramec Dam and the reservoir site behind it. Some 3905 km2 (1508 mi2) are included within the drainage basin of the Upper Meramec River. Six distinct drainage areas are included within the drainage basin; 1) a combined, lightly industrialized and farm area around Rolla and Salem, Missouri representing the Dry Fork drainage; 2) a primitive, mostly forested area with some farms and cattle rancheseast and north of Salem, Missouri comprising the Upper Meramec River

Jan 1, 1977

By C. A. Rowland

With the rapidly rising cost for electrical energy and the long range pre¬dictions for continued rising costs and even possible energy shortages, operation of rod, ball, autogenous and partial autogenous grinding circuits to efficiently utilize the power delivered to the mills will be demanded. This calls for a method to evaluate grinding circuit performance that is accurate, reliable and readily usable as an operating tool by supervisory, technical and operating personnel. Neither the Rittinger and Kick theories of comminution,(1) which preceded the Bond Theory by more than 50 years, had a mathematical means that could be used to predict and evaluate the performance of crushers and grinding mills used to comminute ores and rocks. This severly limited the practical use of these two theories, which were contradictory to each other. They have been superseded by the Bond Third Theory of Commnution.(1)

Jan 1, 1976

By Robert E. Moore

Investigators have attempted to develop lime refractories on a scale for broad applications in the metal and ceramic industries for several decades. There was a flurry of activity in the early to mid-fifties but no commercial developments were forthcoming. The literature of that period yields little information on plant trials. A major factor suppressing past interest in lime has to have been the high success with the application of magnesic and dolomitic materials. These materials, usually tar-bonded or impregnated, have become the refractories success story of the past two decades, especially in BOF applications. It is safe to say that their development and application has essentially plateaued, and that work today is focussed on finding cheaper paths to produce MgO-based refractories. For example there are efforts underway to extract MgO from mineral magnesite and to combine natural dolomite with MgO1. Beginning in the late sixties, rather intensive research began on the development of CaO brick, especially in East and West Germany, in Poland, and other communist bloc satellites, 'and also in Italy and Spain. One speculates that the motivation was a regional shortage of good magnesia and dolomitic material. Of course, There has always existed the prospect of cost savings should it be possible to use raw limestone as the starting material. Quite a large literature has appeared treating of these developments which in the early seventies had already reached full plant scale trials and uses. Some of the directions followed in the research have led to novel methods of brick manufacture.

Jan 1, 1985

By Miles L. Silberman

Three major suites of igneous rocks were erupted in the Great Basin in middle and late Cenozoic time. The first, most likely, resulted from sub- duction of a Pacific plate (Farallon plate) beneath the North American plate, resulting in eruption of andesitic rocks in the northern Great Basin between 42 and 43 m.y. ago. Between 34 and 17 m.y. ago, igneous activity migrated to the southwest, largely as eruption of volumincus rhyolite-quartz latite ash-flow sheets, ending about 17 a.y. ago with the onset of crustal extension and north-south-trending Basin and Range (rift) faulting. The second volcanic suite erupted between 17 and 8 m.y. ago in the northern Great Basin; is mostly basaltic or bimodal basalt-rhyolite. The third volcanic suite consists of andesitic and rhyolitic lavas and some basalt erupted between about 22 to 6 m.y. ago in the western Great Basin along the northwest-trending Walker Lane fault zone. Hydrothermal ore deposits are associated with all suites of igneous rocks, but the largest production has come from mines associated with andesitic rocks of the third (western Great Basin) suite. The oldest (34 to 42 m.y.) andesitic rocks (first suite) of the northern Great Basin have produced some large deposits; slightly younger silicic rocks of this suite are mostly barren. Many small ore deposits are associated with the 17- to 8-m.y.-old basalts (second suite) of northern Nevada.

Jan 1, 1976

By K. Fair

Using an agitated column 203 mm (8") diameter by 1829 mm (72") tall with independent agitation units for the gas dispersion zone and the collection zones, respectively, permitted the independent evaluation of the attachment and the detachment mechanisms for the chalcopyrite/ silica system. Three particle size fractions were used in this study, i.e. coarse (+75 µ m), intermediate (-75 µ m + 10 µ m) and fines (-10 µ m). The optimum selection of the two agitation zones for the three particle size fractions were determined as a function of grade, recovery, residence time and air superficial gas velocity.

Jan 1, 1990

By W. Miola

The MSHA prescribed method for the determination of quartz in airborne respirable dust samples from underground coal mines is the P-7 method, a combination of low temperature radio-frequency ashing (LTA) and infrared analysis (lR). There is no prescribed procedure for quartz analysis in bulk samples of coal and host rock. Dispersive Infrared (IR), Fourier-transform Infrared (FTIR), and X-Ray Diffraction (XRD) methods are most commonly used for quartz analysis in powders. Several aspects of the experimental procedures such as the analysis sample preparation from bulk samples, ashing techniques, scanning procedures, peak measurement location, calibration techniques, sample amounts, size consist, and data interpretation affect differently the results from each of the methods. Significant differences in analysis results from X-ray diffraction (XRD) and infrared spectroscopy (IR) on the same samples are reported. All these studies point to the need for reliable quartz analysis methods. In a recent research, a procedure for preparing bulk coal and host rock samples for quantitative quartz analysis was developed. Further the results from X-ray diffractometry and infrared spectroscopy for quartz content on identical samples were compared. Calibrations with pure and mixed standards were used to assess the influence of particle size distribution, matrix, and calibration on analysis results. In this paper, several issues with the measurement of quartz in the samples of coal, host rock, and airborne respirable dust from mines are outlined and quantified.

Jan 1, 1994

By Thomas M. Larimer

Prior to April, 1961, the coal charge to Clairtonts coke oven batteries was 3" x 0" mine waslied coal having approximately 6.0% to 7.0% moisture. Even at this size and moisture content, the arching, rat-holing and hang-up was excessive and the effective live storage of coal was only 60% to 70% of the rated capacity of the coal bunkers, depending upon the moisture of the coal. In addition, many production delays were encountered in the time and methods required to fill the larry cars. The need for an improved metallurgical coke led to the introduction of pulverized coal to a portion of the plant in 196 1. When the full potential of the pulverizing equipment was realized, we were able to serve seven batteries in our second unit of batteries with pulverized coal through two coal bunkers. The discharge hoppers of these bunkers were equipped with air vibrators to assist the flow of pulverized coal into the larry cars. The vibrators were helpful in this respect but required considerable maintenance and caused damage to the bin plates.

Jan 1, 1968

By H. Fayed

Two-phase (water and air) flow in a self-aspirated WEMCO flotation machine has been investigated using computational fluid dynamics (CFD). The geometric model is a replica of a 300 m3 cell. A 72-degree sector containing two blades of the ten-blade rotor has been modeled and periodic boundary conditions are applied in the circumferential direction. Simulation of a sector of the machine allows acceptable resolution of the mean flow field using 4x106 grid points. The flow is modeled by Euler-Euler approach, and transport equations are solved using a commercial software ANSYS-CFX5 [1]. Unsteady simulations have been performed. In a self-aspirated machine, airflow rate is not known a prior; it is an output from the CFD simulation. Uniform mean bubble diameter of 0.7 mm has been specified as an input for the simulation. Air flow rate and power consumption have been monitored with time, and results indicate a stable operation. Air volume fraction contours and velocity field in different regions of the machine are presented and discussed.

Feb 27, 2013

By Koichi Nishimura

Japan's coal reserves are estimated at 8,583 million tons (according to the materials on X World Energy Conference,. 1976). Japan is a long island country in the shape of an elongated cashew nut whose top is pointing to the north and its lower tip is pointing to the west. And her major coal fields are located in the two extreme far parts of Hokkaido in the north and Kyushu in the south. On the other hand, Japan's major industrial center are located in the central part of the country far from either coal-producing areas. This fact places coal a great geographical disadvantage in comparison with petroleum whose refining bases are concentrated on the coastal regions virtually next to major industrial centers.

Jan 1, 1982

By Aleksandar N. Nikoloski, Rorie Gilligan

Brannerite, UTi2O6, is the most common of the refractory uranium minerals and requires leaching under intense conditions to effectively extract the uranium contained within. Brannerite is often found together with apatite in metasomatic uranium deposits. Apatite and other phosphate gangue minerals can inhibit uranium leaching by generating phosphate ions which interfere with the reactions between acidic ferric sulphate and uranium minerals. As part of a detailed fundamental study on the leaching reaction mechanisms for brannerite, tests under a range of selected leach conditions were carried out with the addition of 10 g/L fluorapatite with the goal of identifying conditions where the negative effects of phosphate are reduced. Leaching was carried out for 5 hours with 0.05 mol/L Fe3+ as Fe2(SO4)3 with 0.25–1.00 mol/L H2SO4 and at temperatures between 25 and 96 °C. A single test was performed with 0.05 mol/L Fe3+ as FeCl3 and 1.00 mol/L HCl. In the sulphate system, the effect of phosphate was weakest at the highest acid concentration (1.00 mol/L H2SO4). In the chloride system, phosphate did not suppress uranium extraction, suggesting that HCl leaching could be a viable alternative for the leaching of high-phosphate refractory uranium ores.

Mar 17, 2021

By O. D. Staman

The risk assessment project examines the likelihood of inorganic contaminants from copper dump-leaching operations to contaminate domestic water supplies. The project examines contaminant transport by modeling contaminant movement from the base of a leach pile through the unsaturated zone and into the saturated zone. The modeling effort is unique in that it models infiltration, contaminant transport in the unsaturated and saturated zone combined with geochemical modeling of the unsaturated zone. The project incorporates probability theory to reflect the uncertainty of hydrogeologic parameters.

Jan 1, 1994

By F. J. Susko

The Bureau of Mines applied a flotation model to the hydrodynamics of the Bureau-developed rapid flotation system. Rapid flotation is a process which separates the bubble-particle attachment and froth-pulp separation stages of the flotation sequence into two discrete unit operations allowing the operations to be individually optimized. Both an air-injected hydrocyclone and an in-line mixer were used as the bubble-particle attachment unit and a shallow-depth froth separator was used to separate the ore-laden froth from the pulp. A 10-L/min batch system was tested on a coarse coal feed sample. The system was tested using two different bubble-particle attachment units at various aeration levels in order to test the flotation model. The results of the flotation model reflect general trends observed in the experimental data.

Jan 1, 1993

By C. Sampaio, C. Petter, M. Veras

"INTRODUCTION Use of sensor technology applied to the gravimetric beneficiation is intended for the selective preconcentration or separation of various minerals. Sensor Based Sorting (SBS) uses sensors to identify the particles and separate them by a mechanical process (flap) or pneumatic ejection valves (Wotruba et al. 2014). The principle of the SBS technology to separate mineral particles consists of three phases which cover feed,detection and separation. (killmann, 2009 Apud nienhaus et al. 2014). The applicability of the technique in an early stage of beneficiation enables free particles and poor grade to be a part of the process. The mass of tailings to be processed can be removed at the initial stage to save energy, water and equipment maintenance (Wotruba et al. 2014). Lindner (2010) suggested that the use of SBS technology would only will be possible if there exsists an electromagnetic interaction in all the wave spectra interacting with the solid ore. The interaction of electromagnetic waves depends directly on the characteristics of the material. The material receives a spectrum of electromagnetic waves by irradiation and this results in a reduced wavelength with differing types radiation such as fluorescence, reflection, remission, absorption, transmission and transmission. The frequency of the wave spectrum varies between 1000 and 1020Hz, illustrated by the data in Figure 1, which shows that each type of sensor emits a wavelength inversely proportional to the frequency ranging from 10-11pm to 104km, and the frequency that varies between EHz 103 and 1020kHz. The difference between the electromagnetic spectrum variations can only be visible to the human eye at wavelengths with intervals between 380nm and 780nm (Wotruba et al. 2014). One of the main advantages of operating with imaging sensors is the versatility of the images which can take on zero, one, two or three dimensions shown below as a point, a line, an area or a spatial image, as illustrated in Figure 2. According to Schubert (1988), to separate a mineral particle it is necessary to follow the characteristics of mineralogy, physics and chemistry with or without use of water. The use of new technologies can help reduce operating costs and improve utilization of mineral resources."

Jan 1, 2016

By Guillermo V. Borquez

The economics of open pit mine design are dictated by three basic elements: cut-off grade, stripping ratio and slope angle. Although these elements are functions of a number of independent parameters, they are interrelated through their influence on the overall economics. The optimum slope angle is the most uncertain element to determine, because rock mass properties are difficult to obtain. However, for preliminary estimation, the slope angle can be determined from the relationship between the probability of failure and the safety factor. The economics of the slope selected will depend on a profit versus risk judgment. In this paper, the author will present an actual case of application of this postulate.

Jan 1, 1977

By A. Leppala

Scope of the Courier 300 System The fact that reliable on-stream analysis is a prerequisite for effective flotation control is hardly disputed today. Nevertheless, up to now no system has been available that includes all the equipment necessary for successful analysis. However essential an on-stream analyser is in itself, reliable and accurate assaying can only be assured after techniques for sampling, handling the slurries and computing the X-ray data have been developed for the purpose. The Outokumpu Company's Courier 300 System is a complete package that can be installed and handed over with the key. It includes the equipment needed for sampling and handling the slurries. It has been developed from the start to meet industrial demands. Obviously an on-line system must comply with far stricter standards than one designed for a laboratory. Assays are computed by an Outokumpu 316 digital data processor, which is an integral part of the system and controls its entire performance. The computer software is programmed as a standard package, including a highly advanced new model for assay computation. Analysis output is available for a process computer, report typewriter:, and recorders. The package also includes calibration for slurry assays at our pilot installation before delivery. A complete Courier System can analyse up to 4Z slurries and six elements in each slurry. Thanks to its modular design, it can be dimensioned initially to the customer's requirements and is easy to expand later at low cost. Being a mining company itself, Outokumpu has been able to utilize its own long experience in non-ferrous metallurgy - an important factor contributing to the success of the Courier system. History of the project and present installations The first on-stream analyser was installed at Outokumpu'a Pyhasalmi Con¬centrator at the end of 1967, after several years' development. Since then,

Jan 1, 1971

By Ying Lu, Jeffrey C. Johnson, Chen-Luh Lin, Jan D. Miller, Sindhoora Puvvada

The amount of energy used to break rock is of interest in mine-to-mill operations to minimize energy consumption during blasting at the mine site and comminution at the processing plant. In this research, a direct energy measurement was made using high-velocity impact to cause breakage of long granite cores, and to study the energy dissipation along the entire bar length. The results show the formation of three zones of damage — fragmentation, fracture and elastic — that have been characterized in 3D using X-ray tomography. The fragmentation zone of the granite bars was studied in detail to describe the particle size distribution and the particle shape characteristics. The experimental energy dissipation in the fragmentation zone was found to be in close agreement with the expected energy calculated from the Bond work index (BWI) equation [1] when the anisotropic granite particles in the fragmentation zone are defined by length rather than by sieve size. The results increase our understanding of rock breakage and energy consumption and may find future applications in mine-to-mill operations.