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By K. Wu, X. Yuan, R. Du, C. Chao

"Lump coals are currently employed to replace part of coke in the COREX melter-gasifier for ironmaking. In order to optimize the process, the pyrolysis kinetics of Datong coal used in the COREX process was studied. A sectioning method is proposed to overcome certain shortcomings of traditional methods for studying the pyrolysis of coal. Based on the sectioning method and the characteristics of the coal pyrolysis process, the temperature range was divided into three intervals. In the first, the adsorbed gas and water of crystallization were removed; in the second, the coal was transformed into semi-coke; and finally, the semi-coke was further coked. Three models of reaction were then established to study the different stages of the pyrolysis process: an interfacial chemical reaction model, a random pore model, and internal diffusion with shrinking volume. The results showed that the experimental data fitted the models well, with all correlation coefficients (r2) exceeding 0.97. Finally, the mechanisms of reaction and kinetic parameters for each temperature range were derived, which laid a necessary foundation for optimizing the usage of non-coking coal in the COREX process. IntroductionIn view of environmental concerns and the shortage of good-quality coking coal, the COREX process was designed as a new ironmaking technology, attracting wide attention (Fang et al., 2005). In this process, lump coal and a small quantity of coke are directly charged into the melter-gasifier, where a high-quality reducing gas is generated for the reduction of the iron ore (Kumar et al., 2009). In contrast to the conventional blast furnace (BF) process, non-coking lump coal is used as the reducing agent and as the energy source, and the iron charge consists of lump ore and/or pellets, which results in the elimination of the coke oven and sintering plant as well as a decrease in investment (Kumar et al., 2009; Liu et al., 2012).Although the COREX process has made great progress, in current production practice the energy consumption greatly exceeds that of the BF, and it requires a certain amount of coke to maintain permeability of the semi-coke bed (Wang et al., 2008). In addition, the process consumes a lot of good-quality lump ore and lump coal. The pyrolysis of coal is the first step in most coal conversion processes, such as carbonization, gasification, and combustion (Aboyade et al., 2013). The reaction behaviour of lump coals in the COREX melter-gasifier is crucial, as it determines energy utilization and gas composition, as well as the metallurgical properties and particle size of the semi-coke produced (Prachethan et al., 2011; Zhang et al., 2014). In order to optimize the process and improve its competitiveness, the pyrolysis kinetics of Datong coal used in Baosteel’s COREX C-3000 facility was studied."

Jan 1, 2016

By H. El-Faramawy, A. Ahmed, M. Eissa, M. El-Fawakhry, T. Mattar, S. N. Ghali, E. M. Kotb

As a result of the depletion of high-grade manganese reserves, it has become necessary to consider the exploitation of low-grade manganese ores. The main problem of low-grade manganese ore is the low Mn/Fe ratio, which makes it unfit for the production of manganese ferroalloys. In this work, a selective reduction technique was used for smelting low-manganese ore in the presence of coke and fluxing material in an electric submerged arc furnace to obtain a rich manganese slag and low-manganese pig iron. The product slag was blended with medium-manganese ore and smelted in an electric submerged arc furnace, in the presence of coke and the fluxing agent, to produce silicomanganese alloy. The influence of reducing agent ratio, charge basicity, and charge Mn/Si ratio on the smelting process was investigated. The optimum conditions were found to be a coke ratio of, 1.35, Mn/Si ratio of 2.0, and charge basicity of 2.5. The silicomanganese alloy produced under these conditions satisfies the specifications for Si16Mn63 and Si17Mn65. The experimental results were applied on a pilot scale, producing a silicomanganese alloy with a chemical composition close to that of the standard specifications.

Jan 2, 2022

By D. Stone, M. Le Roux, Q. P. Campbell, M. Fofana

Float-and-sink analysis is widely used in the coal industry to obtain washability data, yielding important information about beneficiation potential and performance. This method is associated with health and environmental problems, and research into alternative densimetric methods is important. The RhoVol is a new technology developed by De Beers Group Technology South Africa (DebTech) for the image-based generation of densimetric data from ores. The analysis is done on a per-particle basis, within a size range of +3 mm –8 mm. In this paper we compare the established methods used for the float-and-sink analysis of coal with a new method using RhoVol. The aim of the study was to determine the validity of the information obtained from the RhoVol analyser by performing comparative densimetric analysis on three different coal samples. The results showed that the RhoVol method was more rapid, safe, and precise, but tended to consistently underestimate the density of the coal sample, probably due to varying coal porosity.

Oct 3, 2023

By V. I. Ryaboy, V. P. Kretov, I. V. Ryaboy

Attachment of collectors containing thioamide groups to sulfide minerals is interpreted as interaction between NH-acids and sulfides acting as solid bases with the formation of a donor–acceptor reagent–mineral bond. As the acid function of the reagents increases, their sorption optimum is observed to shift to a less alkaline region. The developed concept has enabled us to propose a method for calculating optimal pH values for the sorption of reagents on mineral surfaces depending on the acidity of the reagents and the pH value of the medium. Our estimates correlate well with the experimental data. We studied the spectra of the reagents containing thioamide groups and the spectra of copper salts and their surface compounds on an oxidised copper film, chalcopyrite, and pyrite using the infrared (IR) spectroscopy. Some effective applications are described of reagents containing thioamide groups in the flotation of copper, copper-molybdenum, and gold ores, both separately and in combination with other collectors. It is shown that the flotation performance is maximised by adding two- and three-component collector combinations, including collectors containing thioamide groups. In this case, the increase in the recovery of copper, molybdenum, and gold is up to 2-5% compared to conventional process conditions. A new, high-performing reagent containing a thioamide group is proposed. A commercial pilot batch of the reagent was produced and sent for flotation tests in gold ore applications. Keywords: Thioamide reagents, dialkyldithiophosphate, collectors, flotation, arsenopyrite, chalcopyrite

Jan 1, 2020

By S. Mohanta, B. C. Melkap

"SynopsisDry beneficiation of coal by air dense medium fluidized bed is an emerging trend. It is widely believed that the particle size of the medium has a significant effect on the separation efficiency. This investigation demonstrates that medium particle size has a major effect on separation efficiency. Experimental results show that different size fractions of the same feed respond differently to the same size fraction of medium solids. Furthermore, a particular size fraction of feed coal responds differently with different size fractions of medium solids. The Ep values and overall metallurgical performance parameters, obtained from experimental results, clearly indicate the superior performance of an air dense medium fluidized bed separator when using –150+106 µm magnetite powder as the fluidizing medium. These observations reinforce the importance of sizing the medium particle size for the air dense medium fluidized bed.IntroductionIn an air dense medium fluidized bed (ADMFB), a fluidizing bed of a particular density is created by suspending solid particles in an upward air flow. A feed containing coal particles of different densities is introduced into this fluidizing bed. The particles with relative density less than the bed density float on the top of the bed, while particles denser than the bed density sink through it. Since there is a general correlation between ash content and density of coal particles, it is possible to remove ash-forming impurities from a raw coal to the required level by regulating the density of the fluidizing bed. Recently, the ADMFB process has received significant attention world-wide for its specific advantages of low operating cost and less restrictive for small capacities (Luo and Chen, 2001; Houwelingen and de Jong, 2004; Dwari and Hanumantha Rao, 2007; Sahu et al., 2009; Mohanta et al., 2012). This process is not recognized as a well-established industrial practice because of the availability of efficient wet processing technology. However, with the revival of interest in dry beneficiation of coal in general, and ADMFB in particular, there is a concerted effort to improve the efficiency of the ADMFB process, and successive improvements have made the process a competitive and viable option for beneficiating coal."

Jan 1, 2015

By R. Minnitt, C. Morgan, D. Fourie

The problems associated with outliers and their adverse effects on resource estimation in deep level South African gold mines are presented, and solutions suggested in available literature are reviewed. Traditional Witwatersrand type outlier capping uses the 99th percentile grade as the upper limit, a somewhat blunt approach. The occurrence of high and low grade areas in mining operations and the estimation of resources using geostatistical techniques require that the assumption of stationarity be upheld. Honouring the stationarity of data requires that mining areas be subdivided into appropriately sized and spaced domains. In order to overcome high-grade conditionally biased block estimates, the overly strong influence of extreme grades is mitigated by using naturally occurring grade sub-domains, by identifying outliers within the grade sub-domains, allocating relevant capping limits, and weighting them in a post-estimation process to. Rather than applying a capping value across a domain it applies a maximum cap based on the extreme value and its range of influence; the method also ensures that relevant capping occurs even in lower grade sub-domains. The proposed method for capping outliers recognises that metal contained in high grade chip samples should not be over-capped, and based on the grade of surrounding samples. The post-processing method of capping outliers does not interfere with the kriging equations. The method is simple, elegant, and can be easily applied. An advantage is that the output from the kriging process is not overwritten, allowing for comparison between original kriging results and post-processing results.

Sep 1, 2021

By A. K. Raji, M. O. Ojumu

Robotic subsea dredging crawlers are dynamically and remotely controlled vehicles that are used for deep sea mining and recovery operations. These exploration machines are released from a mother ship and move around on the ocean floor using tracks. Current ocean crawlers such as the MK3 ROST are hydraulically powered. In this paper we develop a scaled-down model for simulating and performing static loading analysis of an electrically powered robotic subsea dredging crawler (EPRSDC). The modeling, simulation, and analysis were carried out using modelling software from Solidworks. The structural frame was assembled using the Tetrix max robotics kit. The kit’s structural components were produced from 1050 aircraft-grade aluminum. The results were used in optimizing and for considering other materials, and the to identify specific areas to be reinforced in future crawler designs.

Oct 3, 2023

By R. Pipeleers

Recent experience has shown that all underground workplaces in the Campine Coalfield in Belgium will require controlled cooling within three years. Considering the socio-economic and legal importance of the climatic problems underground, IREA has undertaken studies in forecasting the climate of future workplaces, planning the necessary cooling equipment and optimizing efficiency in the existing cooling equipment. These studies are being carried out using the climate forecasting program of Bergbau-Forschung. So far, the German model has been obliged to utilize manually measured data from a few workplaces in the Campine. As the model does not fit very well with these measurements, it has been thought necessary to' develop a system of continuous data acquisition and transmission. This system is being tested in the Beringen mine of the N.V. Kempense Steenkollenmijnen. In the first part of this paper the digital tranmission system is described; in the second the sensors used to collect the necessary climatic data are presented, and in the third some results are given.

Jan 1, 1987

By R. van Heerden, T. R. Stacey

In the challenging environments of deep-level, narrow tabular orebody gold mines in South Africa, rock mass classification offers a potential method for predicting hazardous areas and optimising rock support systems. This study evaluates the applicability of various rock mass classification systems, with a focus on the Modified or Mining Rock Mass Rating system tailored for high-stress, deep-level mining conditions. Extensive data collection was conducted at Kusasalethu Mine, involving underground mapping and analysis of the 2020/2021 fall of ground database. The Mining Rock Mass Rating system was adapted to the unique geological and operational conditions, providing a simplified, user-friendly approach for rock engineering and geology personnel. Results indicate that this adapted Mining Rock Mass Rating system effectively quantifies rock mass conditions and influences proactive mining adjustments. The study’s findings highlight the system's capability to enhance understanding of rock mass behaviour and substantially mitigate the occurrence of rockfalls and ground collapses. Further application and refinement of the system are recommended to continuously improve mining safety and efficiency.

Oct 24, 2025

By R. P. King

"A model of the flotation process can be used effectively for design and control. For design purposes it can be used to predict the performance of a large plant from laboratory and pilot plant data. It can be used for control purposes to assess the utility of any proposed operating modification to an existing plant, and it can also be used to determine optimal control settings for best operating performance.A model has been developed that will allow for variations in feed properties and for variations in fineness of grind. The model can be used to assess the effects of reagent addition rate, aeration rate and pulp level on plant performance and these are the control variables that are used individually or together in all operating flotation plants. The model provides for a distribution in the values for flotation rate constants, particle size and mineral fraction, and, because of its complexity, requires a large computer when it is to be applied to a typical plant configuration. The computational method that is used to apply this model to such configurations is described in this paper, and particular attention is paid to the problem of allowing for feedback of tailings from cleaners and recleaners."

Jan 1, 2014

By A. Çelik

Wheel loaders are widely used in many sectors due to their mobility, operational flexibility, and low costs. The literature is mainly focused on improving the hydraulic, mechanical, and electronic subsystems of these machines in terms of efficiency or developing strategies for controlling these systems. In this study, the effects of the loader operator and different working conditions on the loading performance were investigated. The study was carried out at the Can Lignite Enterprise (CLI), which is a major coal producer in Turkey. In the study, which lasted approximately four months, a total of 808 measurements were performed to investigate seven different scenarios. The effect of a single parameter on loading performance was investigated in the first six scenarios. The results showed that the biggest impact on loading performance was caused by the operator's experience with 63.4%. On the other hand, the worst and most ideal working conditions determined from the first six scenarios were tested in the seventh scenario. It was tested as a script. The test results showed that the loading performance was 285.5% more effective under the most ideal operating conditions compared to the worst operating conditions. In addition, in the study, the loading performances of five loaders with four different capacities were examined in terms of energy efficiency and it was determined that the Kawasaki 115 work machine, which has a higher model and lower engine operating hours, was more advantageous. In the study, various suggestions were developed in parallel with the research results. The most prominent and easiest to implement of these suggestions is related to the selection of the loader operator.

Nov 27, 2024

By Xiaoxu Sun, Jianchao Yao, Qiheng Zhu, Dubo Wang, Jiancheng He, Shijie Lu

Tower mill is considered to have a better regrinding and fine grinding effect compared with ball mill, and its application is much broader. The spiral agitator of the tower mill is driven by the motor. Media inside the mill is under the combined actions of the spiral mechanism, the cylinder, and media nearby, and these parameters are key factors affecting the grinding effect. However, it is not possible to obtain detailed information of kinematic law of media based only on traditional laboratory experiments, let alone the relationship between parameters of kinematic law of media and grinding effect. Experimentation is the only way to develop industrial equipment. However, this is time-consuming and costly, which hampers the further research of the tower mill’s grinding mechanism. The paper selects two structural parameters (gap between the edge of the spiral agitator and the cylinder wall, ratio between the diameter of cylinder and that of the spiral shaft.) and three operating parameters (diameter of media, filling ratio, the speed at the edge of the spiral agitator) as variables to do an orthogonal designed experiment of five factors, four levels, and thereby obtaining change law of grinding indicators of different parameters. Experimental equipment may be simplified to enable an applicable simulation strategy. Simulation based on a discrete element method is conducted to obtain the change law of the speed of media, collision frequency, normal force, and radial force. The relational curve between parameters of kinematic law of media and energy consumption of grinding is clarified, and key factors affecting grinding efficiency are determined. Those factors will be used for optimising the design and operating process. The research result of this paper obtained from laboratory experiments and computer simulation provides data support and theoretical bases, and has directive meaning and applicable value for tower mill’s optimisation and large-sized design. Keywords: Tower mill, discrete element method, kinematic law of media, energy consumption of grinding

Jan 1, 2020

By I. Ince, S. Kahraman

Preparation of suitable core specimens for physico-mechanical testing s not always possible, particularly for soft and clay-bearing rocks. Although several indirect test methods have been proposed to predict the properties of rocks, specimen preparation from soft rocks for some indirect tests is still difficult. For such cases, the needle penetration test has been developed. In this paper we present a study on the predictability of the physico-mechanical properties of pyroclastic rocks from the needle penetration index (NPI). The NPI, uniaxial compressive strength (UCS), Brazilian tensile strength (BTS), density, and porosity tests were performed in the laboratory on specimens from ten different locations in Turkey. Correlations were established between the NPI values and the physico-mechanical properties. Strong correlations were observed between NPI and both UCS and BTS. General correlations were found between NPI and both density and porosity.

Sep 6, 2023

By L. Naude, J. Cloete, S. Engelbrecht

The results of an investigation evaluating whether an industrial plant, currently operating using sodium isobutyl xanthate (SIBX) as primary collector for sulphide minerals (mainly chalocopyrite), could adapt to operate using an alternate primary thiol collector without compromising plant and metallurgical performance. Initial laboratory scale flotation tests identified commercial dithiophosphate (DTP)-based and thionocarbamate (TC)-based collectors, that when blended, showed potential to replace the incumbent SIBX primary PGM collector. Industrial plant trail results show that there was no deterioration in recovery of 4E PGMs, even at a lower concentrate grade when operating the plant on the identified (DTP + TC)-based collector blend compared to SIBX. The effect on Cr2O3 content in the final concentrate was also found to be negligible. The (DTP + DTC)-based collector blend also showed promise in terms of plant adaptability in accommodating a new primary specialty collector blend. These observations highlighted the potential of replacing xanthate primary collectors with alternate thiol collector blends for PGM flotation. Keywords: PGM, xanthate replacement, specialty collector, sodium iso-butyl xanthate (SIBX), dithiophosphates (DTP), dithiocarbamates (DTC)

Jan 1, 2020

By G. Akdogan, S. M. Bradshaw, A. P. Van Wyk

In the mineral processing industry, Ni-Cu-Fe-S converter matte is leached to remove base metals from a concentrate containing platinum group metals (PGMs). We investigated the atmospheric leaching process to develop a better understanding of the leaching behaviour of the base metals (Cu, Fe, and Ni) and the PGMs, in particular Ru, Ir, and Rh with respect to key process variables, acid concentration, and Cu concentration under oxidative and non-oxidative conditions. With oxidative leaching, a higher initial acid concentration resulted in higher Cu, Ni, and Fe extractions, as well as faster leaching reaction rates. A higher initial acid concentration also resulted in faster precipitation of Cu, Ru, and Ir under oxidizing conditions. Under non-oxidative conditions, Ni and Fe extraction was much slower, and the effect of initial acid concentration on Cu precipitation was less pronounced. The initial Cu concentration had a slightly smaller effect on the leaching behaviour of Fe and Ni, as well as precipitation of Ru, Ir and Rh. Moreover, a higher initial Cu concentration suppressed both Ni and Fe leaching and had a slight inhibiting effect on the precipitation behaviour of Cu, Ru, and Ir.

Nov 1, 2021

By S. Polansky, J. Kolacz

The new sorting system has been developed to achieve efficient separation at low mineral content levels. The system employs high resolution X-ray sensors providing multi-energy analysis, thus giving maximal information about processed materials measurable by X-ray radiography. It makes it possible to analyse the internal structure of the particles and directly detect inclusion of minerals and metals like copper or gold. The paper describes sorting application examples for zinc, lead, copper and gold ore with low metal content below 0.1% of Cu. The sorting system still allows high efficiency analysis, quantification and removal of rock particles representing waste fraction with no metal or a negligible amount being uneconomic to process. This brings a huge advantage during pre-concentration, where almost no losses of valuable minerals in the waste fraction can be achieved. The presented sorting system has been developed by Comex and X-MINE EU Project Consortium. Keywords: X-ray sorting, ore sorting, XRF analysis, XRT analysis

Jan 1, 2020

By C. Bester, G. M. Rohde

A major challenge in the mining sector is the responsible management and efficient storage of mine residue. Over recent years numerous tailings dams have experienced unintended spills and failures, with severe consequences for the mining industry, the environment, local communities, and the regional economy. The fourth industrial revolution (4IR) is impacting society due to increased interconnectivity, processing speed, and automated technologies. This paper explores whether 4IR technologies have the potential to mitigate risks associated with tailings dams. Experts in the field of tailings dam operational management were surveyed to determine their view on the risks associated with tailings dams and the potential of 4IR technologies to mitigate these risks. The survey found that a majority of experts believe that certain 4IR technologies have the potential to reduce the risks associated with tailings dam failures.

May 27, 2025

By L. Roux

This review was initially motivated by the author’s own experience in attempting to reconcile run-of mine production tons with the Coal Resource and Reserve estimation of mineable, in-situ tonnages. The primary scientific measurements and observations that are collected during exploration at the beginning of the value chain will have a profound effect on the future of the mining operation. Due diligence must be exercised during the planning of a new mine and during the life of an existing mine. The comments provided by the technical and economic assessment group of Venmyn Deloitte confirmed the need for this critical review. They found the reporting of Coal Resources in South Africa to be inconsistent. This was particularly problematic in the Waterberg Coalfield in Limpopo Province. In this coalfield there are two types of coal deposit present. The first is comprised of the thick intercalated, cyclic coal and shale/mudstone sequences of the Volksrust Formation. This overlies multiple coal seams within the Vryheid Formation, each of which is thick enough to be extracted as an individual raw coal unit. On the other hand, the interbedded coal and shale seams of the Volksrust Formation require beneficiation to separate the coal from the shale. The review examines practices and methods, investigates alternatives, provides checks and balances, and tests these against actual production reconciliations. In conclusion, the best estimates of the mineable, in-situ tonnage will be obtained from the air-dry raw material density. These estimates should be adjusted afterwards to allow for free moisture content. The adjustments are derived from reconciliation data. The greatest contributing factor to the over-estimation of Reserve tonnages is the moisture content of the raw material. This fluctuates significantly under varying conditions in situ, as well as upon exposure to the natural environment. The air-dried density of the raw material includes inherent (structurally bound) moisture within the matrix. It provides credible tonnage estimations of raw material available while also providing an indication of voids within the volume of material being assessed. The calculated solids percentage can be used to adjust the specific gravity, which is determined via the Archimedes principle. This will supply a representative estimate of the material to be mined.

Nov 1, 2021

By Wei Sun, Ruolin Wang, Wenjuan Sun, Junhao Fu, Haisheng Han, Zhao Wei

Pb–benzohydroxamic acid (BHA) (lead complexes of benzohydroxamic acid) exhibits high selectivity but low collecting efficiency in scheelite flotation. This paper reports the manner in which BHA and sodium dodecyl sulfate (SDS) were employed as ligands to coordinate with the lead ions to obtain a colloidal lead-group multiple ligand complex, i.e., the Pb–BHA–SDS, for improving the collecting efficiency of Pb–BHA. The flotation mechanism of Pb–BHA–SDS with respect to scheelite was investigated from the viewpoint of interface science based on the pure mineral flotation, Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and contact angle measurements. The results showed that the BHA and SDS coordinated with Pb2+ to form novel leadgroup multiple ligand complexes, which are different from the traditional understanding associated with the mixed collectors. Pb–BHA–SDS was a better collector with stronger collecting ability and excellent selectivity in regard to a scheelite flotation than Pb–BHA. The addition of SDS to Pb–BHA enhanced the latter’s adsorption ability on the scheelite surface and improved the hydrophobicity of the collector’s nonpolar groups, rendering Pb–BHA–SDS as a more efficient collector at a low dosage. Keywords: Scheelite; Pb-BHA complexes; sodium dodecyl sulfate; multiple ligands; Pb–BHA–SDS

Jan 1, 2020

By Tian Yingzhong, Guo XIN, Wei Peihe

The intention is to solve a series of problems in the flotation and desiliconisation of complex bauxite; aiming to achieve monomer dissociation of target minerals based on process mineralogy. According to the mineral surface, there are differences in physical and chemical properties and the molecular design theory of flotation agents. Designing the polar and non-polar groups of the bauxite flotation collector to make the reagent group easily combine with the mineral to form a cyclic chelate, will enhance the collection performance, and strengthen the drug selection performance. Developing a new type of positive flotation collector for bauxite with small dosage, strong selectivity and low foam volume. Keywords: Process mineralogy, monomer dissociation, molecular design, new positive flotation collector

Jan 1, 2020