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By Donald O. Rausch, Robert H. Merrill, David W. Wisecarver, S. Jackson Hubbard

Results are reported for stress - relief borehole - deformation measurements made in three underground openings near open - pit mines in the Ruth mining district , Nevada . A total of 134 deformation measurements were made in 8 boreholes . These measurements determined the regional stresses in the horizons above , below, and at the elevation of nearby open - pit mine floors ; knowledge of these stress conditions is considered essential information relative to certain aspects in the designing of stable pit slopes . The determinations indicate that the stresses in the district are due to the gravitational load of the overburden in a confined stress field .

Jan 1, 1964

By T. H. Jeffers

The Bureau of Mines conducted laboratory tests to devise a procedure for extracting copper from low-grade discarded mill tailings. A solid extractant consisting of an organic solvent extraction reagent adsorbed on granular activated carbon was investigated and proved to be satisfactory for extracting copper directly from leach pulps. When this material was used in a cyclic leaching, stripping, and electrowinning pro-cess, 95 pct of the acid-soluble copper was recovered from oxidized mill tailings. The weathered tailings contained 0.24 pct Cu (total) and 0.20 pct acid-soluble Cu. The copper was recovered as cathodes containing, in parts per million, 1.6 Pb, 3.6 Fe, 0.5 Sb, 1.5 AI, 1.9 Mn, and <1 Mg.

Jan 1, 1985

By W. N. Marchant

The Bureau of Mines performed chemical research to elaborate details of sulfur chemistry pertaining to the citrate flue gas desulfurization process in which sulfur dioxide (SO2), absorbed (as bisulfite ion) in a buffered sodium citrate solution, is reduced by hydrogen sulfide (H2S) according to the overall reaction 2H2S + HSO3 + H+ ? 3S + 3H20. The rate-limiting step in the process was shown to be the reduction by H2S of thiosulfate (S2031-) that is formed as an intermediate. Pseudo first-order kinetic measurements were made at room temperature to retard the reaction sufficiently that adequate analysis was possible. These measurements showed the rates of the following net processes to be -d [S02]/dt (pH 4.5) = (0.409±0.050)min-1 [S02]; d [S2032-]/dt (pH 4.5) = (0.199±0.017)min-1 [S02]; -d [S2032-]/dt (pH 4.0) = (0.0437±0.0265)min-1 [S2032-]~1; -dH2S/dt (pH 3.9) = (21.6±3.0) mmoles/min-atm [H2S]g1.4, where [H2S]g is the partial pressure of H2S in the gas phase, in atmospheres, and the rate describes the consumption of H2S, in millimoles per minute; d[S]/dt (pH 4.0) = (38.0±3.4)min-1 [H2S]1, where [H2S] is the concentration of H2S in solution. Hydrogen ion consumption during the slow phase of regeneration was shown to occur at (2.1±0.5) times he rate of thiosulfate consumption, which is interpreted as evidence for the following as the rate-limiting reaction: 2H2S + S2032- + 2H+ ? 4S + 3H20 A scheme consisting of five sequential general reactions is proposed to account for sulfur formation.

Jan 1, 1981

By N. L. Wimmler

"INRODUCTIONSedimentary deposits of titaniferrous magnetite occur at various localities in the eastern foothills of the Teton Ranse in Deer Lodge County, Mont. The Choteau deposit was examined by a Bureau of Mines engineer in August 1942. An exploration project was recommended.Core drilling exploration was begun in June 1945; it was concluded in August 1945, Seventy-six holes were drilled. This report presents the data obtained by the Bureau of Mines exploration.ACKNOWLEDGMENTIn its program of exploration of mineral, deposits, the Bureau of Mines has as its primary objective, the more effective utilization of our mineral resources to the end that they make the greatest possible contri¬bution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, Chief, conducts preliminary examination, performs the actual exploratory work, and prepares the final, report. The. Metallurgical Branch, R. G. Knickerbocker, Chief, analyzes samples and performs beneficiation tests. Both of these branches are under the supervision of Dr. R. S. Dean, Assistant-Director. The field work was supervised by Earshel W. Newman, engineer in charge of the Helena Field Office. D. B. Hoiekvam was the project engineer; he provided most of the data used in the preparation of this report."

Dec 1, 1946

By T. A. Sullivan

High-purity vanadium metal was prepared by electrorefining commercial vanadium in a molten sodium bromide, potassium bromide, and vanadium dibromide electrolyte. Variables investigated were operating temperature, current densities, electrolyte composition, and condition of the anode. The purity of the refined metal was in the range of 99.95 percent vana-dium. Iron and oxygen in the 50- to 250-ppm range were the only major impurities. Metal with hardness numbers of 50 to 60 in the Rockwell F scale was prepared from feed material with a Rockwell B hardness of 90. The arc-melted metal was highly ductile and could be cold-worked into sheet or foil.

Jan 1, 1965

By Eugene T. Sheridan

The United States has extensive reserves of peat. Peat and muck lands are estimated at approximately 79 million acres, with reserves of 13.8 billion net tons. Within the past decade domestic production of peat has increased 2-1/2 times, and apparent consumption has tripled. During the same period imports have increased greatly, and in 1955 they almost equaled domestic production. The substantial increase in the demand for peat in the United States was due chiefly to expanding markets in agriculture and horticulture, for the reason that in this country peat is used primarily as a source of organic matter to improve the physical condition of mineral soils and as a mulch for shrubbery. A valuable constituent of any soil is its organic matter, and its depletion will injure cultivated soils and subject them to greater erosion.

Jan 1, 1957

By Harold E. Marr

The computer program XRF4 was designed by the Bureau of Mines to provide for the calculation of several different interelement correction procedures in X-ray fluorescence analysis, including Lachance-Traill, Rasberry-Heinrich, and Claisse-Quintin procedures. The program was written in the BASIC language for timesharing application, and a conversational interaction with the computer is employed during operation. This report presents test problems using data for iron-nickel-chromium alloys and aluminum alloys and directions for use of the program.

Jan 1, 1976

By J. E. Chilton

Underground miners may be exposed to hazardous quantities of toxic gases, such as carbon monoxide (CO), generated from mine fires or explosions. Every underground miner is required to carry a filter self-rescuer (FSR), which when operated will remove CO from the miner&apos;s breathing air. In addition, every underground miner must have a self-contained self-rescuer (SCSR) near the worksite that will supply breathing oxygen. In many situations, miners do not know when to don either rescuer since they do not know if there is a fire in the mine, nor do they carry instrumentation necessary for the detection of the toxic, colorless, and odorless fire product CO. If each miner carried a personal CO alarm, which would respond to high concentrations of CO, the miner would then be alerted when to don either the FSR or SCSR and exit the mine. A prototype personal miner&apos;s CO alarm called PEMCOAL was developed by the U.S. Bureau of Mines. The PEMCOAL unit is small enough to be carried on a miner&apos;s belt, has a flash lamp visual alarm, requires no calibration for use, and uses a chemical sensor that changes color by reaction with trace quantities of CO. The chemical sensor was tested at concentrations of CO from 10 to 1,000 ppm, at temperatures from 5° to 40° C, and with several potential mine gas interferents. The PEMCOAL alarm times were sufficiently fast to warn miners before they are exposed to hazardous quantities of CO.

Jan 1, 1989

By R. E. Perry

To develop new or improved flotation methods for beneficiating low-grade red iron ores, the Bureau made many bench scale and continuous anionic flotation tests on ferruginous sandstones and calcareous iron ores from the north-eastern part of the Birmingham, Ala., iron district. The ores contained about 21 to 36 percent iron, a to 11 percent lime, and 22 to 64 percent silica. Production of iron concentrates containing 48 to 52 percent iron was technically feasible in batch tests, and the iron recoveries ranged from 85 to 92 percent. In continuous tests 49 to 51 percent iron products were obtained with 80 to 90 percent recovery.

Jan 1, 1962

By J. V. Scalera

Because of U.S. dependency on imported critical metals, the Bureau of Mines has conducted research to evaluate the possible substitution of nitrided low-alloy steels for higher chromium-containing alloys. The corrosion data for nitrided steels are limited primarily to the Soviet literature. The objective of this study was to determine the corrosion properties of six commercially nitrided low-alloy steels in a 5-wt % NaCl solution at pH 4. Weight-loss tests indicated that, in deaerated test solutions, most of the nitrided steels were less corrosion resist-ant than nontreated steels. However, electrochemical tests indicated that under more oxidizing conditions, nitrided materials are converted to a passive state with a significantly reduced corrosion rate. Elec-trochemical tests performed in an aerated environment confirmed the passivity of the samples in an oxidizing environment.

Jan 1, 1984

By T. A. Henrie, E. K. Kleespies

Carbon reduction of rutile and ilmenite in nitrogen and ammonia atmospheres was studied as a method of preparing titanium nitride . Ammonia was a better nitriding agent than nitrogen . The contact between the solid reactants , carbon and rutile , was a prime factor in nitrogen atmospheres and was of lesser import in dissociated ammonia . The reduction process for conversion of rutile to the nitride required carbon . The nitriding of ilmenite- carbon mixtures produced titanium nitride and elemental iron .

Jan 1, 1964

By E. J. Matson

The Table Mountain copper deposit is in an isolated portion of north-eastern Churchill County, Nev. Although copper-bearing outcrops have been known to exist in the area since 1909, no copper ore has been mined. Development of the property has been hampered by poor roads and rugged topography. Until 1941, the last 4 or 5 miles to the property had to be traveled either by foot or pack animal. As a part of the Bureau of Mines program of investigation and development of domestic mineral deposits, a project was started at the Table Mountain deposit. The Bureau began its field work on July 29, 1947, and completed it on October 18, 1948. Thirteen holes aggregating 2,711 linear feet, were drilled; samples were analyzed - 509 from cores and 143 from sludges. This report contains a brief history of the district and a description of the geology, deposits, and drilling done by the Bureau.

Jan 1, 1949

By B. K. Shibler

A highly flexible laboratory-scale fluidized-bed reactor was designed, constructed, and successfully operated continuously at temperatures up to 1,300° C during an investigation of thermal methods for decomposing gypsum. This report discusses briefly the many problems encountered in developing the 10-inch-diameter reactor and describes its design and construction in sufficient detail to enable other research organizations to build a comparable unit. The reactor consists of a 10-inch-inside-diameter vertical tube which can be varied from 6 to 10 feet high; it is formed from 2-and 3-foot sections of silicon carbide pipe. The tube is surrounded by a 3-inch heating space formed by an outer 4.5-inch-thick circular wall of insulating firebrick. A cone-shaped fluidizing chamber is bolted to the bottom of the reactor. Fluidizing gas enters through the bottom of the cone, and ore is introduced by means of a screw feeder connected to an inlet located just above the gas port. A silicon carbide overflow tube of 1.25-inch inside diameter extends upward into the reactor. The depth of the bed is controlled by substituting different lengths of overflow tube. Twin dust-recovery systems, each composed of a cyclone and Fiberglas filter, are attached to two gas outlets at the top of the reactor tube. The reactor is designed for research on both exothermic and highly endothermic reactions. It can be fired externally by means of four natural gas burners that jet tangentially into the annular space at the base of the reactor. Alternatively, it can be fired internally, using a mixture of air or oxygen and natural gas as the fluidizing medium. A separate instrument panel contains flowmeters, manometers, an automatic program controller, and a multiple-point recorder for printing a record of the temperatures measured by thermocouples located at critical points in the reactor.

Jan 1, 1963

By F. M. Boler

The U.S. Bureau of Mines has configured a flexible data acquisition and analysis workstation, which incorporates control and analysis software written in-house for use in mining research experiments conducted in the laboratory and in operating underground mines. This data acquisition system combines computer-automated-measurement-and-control (CAMAC) modular instrumentation with a Unix-based graphics workstation. The data acquisition front-end hardware can be interfaced to almost any computer. CAMAC instrumentation modules adhere to mechanical, electrical, and digital interface standards and can be custom designed or purchased off the shelf. Communications along the CAMAC bus are regulated by the crate-controller module, which contains the only hardware link to the computer interface. Software support for the data acquisition and analysis workstation consists of a series of functions and programs written in the "C" programming language designed to provide flexible and fast data acquisition, processing, and analysis. The user can interactively control the digitizers and other CAMAC modules by sending standard CAMAC read, write, and command function codes from a menu-driven program. Automated data collection is achieved through software that responds to hardware interrupts triggered by acoustic emission or microseismic events. Graphics display routines are used to plot part or all of the data and provide the ability to process and store signal information selectively.

Jan 1, 1990

By T. L. Marchewka

As part of its program to conserve the Nation&apos;s natural resources by developing improved performance materials, the Bureau of Mines, U.S. Department of the Interior, in cooperation with the U.S. Department of Energy, has conducted an investigation of materials of construction able to withstand the high temperature and hostile environments encountered in coal gasification units. Refractory pipe liners are required when extremely hot gases or abrasive solids are transported between processing units in the gasification plants. One promising technique for producing refractory pipe (or refractory pipe liners) is centrifugal casting. For this study, the effect of processing variables such as workability, additives, reinforcement and spinning time, and centrifugal force were evaluated using four commercial refractory concretes. In addition, data on characteristics such as strength, density, abrasion, and spalling resistance of 5-inch-diam refractory pipe were developed. Techniques for forming large-diameter (19-inch) refractory pipe also were evaluated. The test results indicated that all four refractory concretes could be made into strong, homogeneous pipe, but that optimum casting parameters had to be determined for each specific composition. The investigation revealed that the major controlling factor in the production of the centrifugally cast pipe was the workability of the refractory concrete.

Jan 1, 1979

By Irving Hartmann, Edward Thomas

"INTRODUCTION Adoption of rubber-tire shuttle cars underground in conjunction with mobile coal-loading machines has introduced new problems in the control of dust on mine roadways. Where this type of loading and transportation is used, development and extraction are generally rapid, with the result that much coal is spilled from the shuttle cars during normal operation, Coal in the roadways from this source and from sloughing of the ribs is ground to fine dust by the wheels of the 'shuttle cars and by the treads of the loading and mining machines. The coal dust usually is somewhat contaminated by pulverized rock, and the mixture could not be loaded with the run-of-mine coal without undue contamination of the product even if it were cleaned up promptly.The presence of large quantities of fine, loose dust, which is constantly stirred up and kept in suspension in air by the traffic, constitutes a grave explosion hazard, reduces visibility along the roadways, and is physiologically harmful to the workmen who breathe the air. From the operating standpoint the loose material is undesirable along the roadways because it provides poor traction for the trucks and thereby increases wear and power consumption. The dust-explosion hazard could be eliminated or reduced by frequent application of sufficient rock dust on the roadbed; but this would not remedy the other difficulties, and in fact it might intensify them. Where practicable, the most direct and effective safety measure is to clean up and remove promptly all dust that forms and settles on the roadways. Unfortunately, in many cases this procedure is not feasible. A third Suggested remedy is to prevent dispersal of the dust into the air and to promote its consolidation on the floor by wetting the dust particles.During the past few years several mines have used calcium chloride on shuttle-car roadways to allay the dust thereon. When exposed to the' humid atmosphere of the mine this salt absorbs Moisture from the air and deliquesces, and in this way wets the dust on the floor of the roadway. In a survey conducted in coal mines in southern West Virginia and in eastern Kentucky where calcium chloride has been in use, somewhat conflicting re- ports were received regarding the merits of the application, and several operators have abandoned the practice either because of actual or assumed disadvantages. The purpose of the study described in this report was to collect and correlate evidence and, on the basis of experimental data obtained in the field and in laboratory tests, to present a clearer picture of the factors involved in the allaying of dust by use of salts."

Sep 1, 1945

By Irving Hartmann

At the 9th International Conference of Directors of Safety in Mines Research a paper6/ was presented describing the initial phases of research by the Safety in Mines Research Establishment at Buxton, England, on the remote control of timber fires with high-expansion foam plugs in a rock tunnel. The work received extensive publicity, and great interest was aroused by the implied possibility that the method might be used successfully to control coal-mine fires, which for various reasons cannot be approached and attacked by standard fire fighting measures and frequently require sealing extensive, valuable coal properties and lead to loss of production and coal reserves and occasionally loss of lives. To investigate the practicability of the foam-plug technique under American min¬ing conditions, with room-and-pillar-type extraction and multiple entries, the Bureau of Mines in 1957 began an investigation at its Experimental Coal Mine, Bruceton, Pa, In preparation for this work it was necessary to rehabilitate and reinforce an elliptical tunnel in the mine where studies had been made, many years ago, leading to development of a ventilation system used in the Holland Tunnels between New York and New Jersey, and in many other vehicular tunnels.

Jan 1, 1958

By Henry J. Kellner, Michael J. Brnich

This U.S. Bureau of Mines report addresses issues involved in using a limited number of training apparatus to give hands-on self-contained self-rescuer (SCSR) training to a succession of miners, and provides guidance regarding methods for minimizing the spread of infectious diseases. Procedures used for preventing the spread of infectious organisms in dentistry, cardiopulmonary resuscitation (CPR) training, and scuba training are examined. The sanitizing methods of three organizations that require individuals to insert the mouthpiece as part of the SCSR donning sequence are discussed. It was found that each of these organizations was able to render their mouthpiece assemblies microbe free simply and inexpensively.

Jan 1, 1989

By P. E. Churchward

Rhenium sources and recovery methods were investigated by the Bureau of Mines to delineate potential resources of the metal. The only significant rhenium resource appears to be about 28,000 lb of rhenium contained in the domestic annual output of approximately 20,000 tons of byproduct molybdenite concentrates from porphyry copper operations. An estimated 70 to 80 pct of this rhenium is potentially recoverable by processing the rhenium-bearing fumes and dusts obtained during conventional roasting of molybdenite concentrate. At 70 pct recovery this would amount to 19,600 lb of rhenium. A more conservative estimate by the Committee on Refractory Metals of the National Research Council (1513 is that 12,000 lb of rhenium metal could be produced annually from current production of molybdenite from porphyry copper operations in the United States. A procedure was developed in the laboratory for recovering rhenium in the form of electrolytic flake by electrowinning the metal from a solvent extraction strip solution. The procedure included (1) water leaching of molybdenite roaster flue dust, (2) selective extraction of rhenium from the leach liquor by contacting it with a kerosine solution of a quaternary amine, (3) stripping of rhenium from the loaded organic solution by a perchloric acid solution, and (4) electrodeposition of rhenium from the loaded strip liquor. Raw material for the studies was flue dust containing 0.48 pct Re, 35 pct Mo, and 23 pct S in sulfide and sulfate form, and small amounts of numerous metallic impurities. Water leaching dissolved 85 pct of the Re and yielded a solution that was 13 in sulfuric acid and contained, 1 g/l Re and 16 g/l Mo. The solvent extraction strip solution that was electrolyzed for rhenium deposition was 1 molar in perchloric acid and 1 molar in ammonium sulfate and contained 13 g/l Re and 0.01 g/l Mo.

Jan 1, 1963

By C. B. Daellenbach

A prototype particulate size analyzer system was developed that would rapidly determine size distributions of homogeneous and two-mineral materials in the 74-micrometer (200-mesh) to 7-micrometer size range. The system sizes particles in a series of hydrocyclone elutriation steps and senses the weight of the five sized fractions by nuclear attenuation techniques. Size distribution of materials was determined from experimentally developed mathematical relationships that existed between particulate weight and the measured transmittance of gamma rays from an Americium-241 source. In the developmental phases, size distributions of three minerals (quartz, magnetite, and hematite) and a laboratory prepared two-mineral mixture of quartz and magnetite were accurately determined by the prototype system. In later stages of the investigation, semiconcentrates, an intermediate magnetic product from a taconite plant, were evaluated. Using 25-gram feed samples of this industrial material, the analyzer system was found to predict weight percentages for individual size fractions with an accuracy of ±0.85 percent or better at a 95-percent confidence level.

Jan 1, 1974