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By Michael S. Wieland

This report investigates whether it is tractable and thereupon reasonable to remove the booster influences when ranking the toxic fumes of non-cap-sensitive mining explosives. The hazard potential is represented by relative fume toxicity RFT, the resultant influence computed from a formulated rule with a restricted set (tally) of fume components and multiplying constants. The RFT result is compared to the rule criterion that represents the worst case tolerable toxicity stipulated by regulations or otherwise. The typical nonstoichiometric booster composition can render notable unwanted influence on the RFT ranking results. Historically, the remedy was to shoot the booster separately and reduce the trial concentrations by the relevant subtractions. Unreal negative concentration results were noted on rare occasions, revealing the faulty nature of the reduction procedure. With thermodynamic reaction chemistry codes TDRC, on the other hand, the booster ingredients can be retained in or removed from the reactant tabulation, yielding reduction factors taken as the concentration ratios for the two circumstances. The underlying presumption regarding reduction factors is that the ratios of component concentrations with and without the booster ingredients when resolved theoretically ought to equal those rendered experimentally, when tractable. Upon rearranging the presumed relationship, the unadjusted fume concentrations divided by theoretical reduction factors yield the wanted readjusted fume concentrations, thereby removing the booster influence without generating unreal negative concentrations. The work principle from thermodynamics restricted by the constraint of zero-net interaction loss is utilized in conjunction with the TDRC to resolve the wanted (Z-state) fume spectrum. This circumvents the recognized difficulty with traditional hydrodynamic detonation theory that is related to the nonideal reaction characteristics of typical mining explosives. The tacit characteristic of the Z-state resolved from the non-trajectory work principle is that it can not be remedied or tampered with, unlike the traditional trajectory techniques where the reaction products can be readjusted by changing formula representations, nullifying specific reactions or otherwise manipulating the thermodynamic trajectory process. Though the work principle theory is an unfinished formulation, the Z-state results prove worthy enough for rendering trends and comparisons and reaching otherwise useful conclusions. Further refinements should yield more reliable fume spectra and indicate explosive composition readjustments that would reduce toxic effects within underground mines and the wider world environment.

By William J. Campbell

One of the principal objectives of the Bureau of Mines program for developing super refractory materials is to obtain fundamental data on the physical properties of refractory oxides. This particular investigation obtained accurate thermal expansion coefficients for alpha alumina and evaluated, critically, those coefficients with other published values. High-temperature X-ray diffractometer measurements, by the Bureau, showed that alpha alumina expands anisotropically with expansion parallel to the c axis approximately 10 percent greater than parallel to the a axis. Thermal expansion characteristics of four different alumina samples were determined up to 1,200° C.; the results are presented in both tabular and graphical form. The combined random and systematic errors in the measurements are considered less than 3 percent above 500° C, and approximately 2 percent at 1,000° C. No differences in expansion were observed between the samples or between the heating or cooling cycles.

Jan 1, 1961

By Robert Lee Stahl

Comprehensive field tests were made in the Gas Hills, Wyo., to determine whether surface geophysical techniques could be used to detect and delineate faults in marginal uranium deposits. The tests were made on property owned by Federal American Partners, Gas Hills, Wyo., and included seismic refraction, self-potential, induced polarization, magnetometer, electrical resistivity, airborne infrared thermal scanning, and airborne photography. Of the several geophysical techniques tested in the field, horizontal resistivity profiling with electrode spacings in the range of 25 to 50 feet was most diagnostic of faults. The method is quick, cheap, accurate, and one that can be easily used by personnel employed by mining companies to detect and delineate faults.

Jan 1, 1973

By J. A. Taylor, H. F. Yancey

"INTRODUCTION Froth flotation as applied to coal is a process for separating desirable carbonaceous material from undesirable inorganic matter. In general, the feed must be finer than one eighth inch in size. The principal use of the process in the preparation of coal appears to be in the treatment of the fine sizes produced by breakage during mining and preparation.The Bureau of Vines in Information Circular 6714 has published general information on coal flotation, summarized investigative studies of the process, and described operating plants throughout the world with their tonnage, reagent consumption and operating costs.4ACKNOWLEDGMENTSThe present study of means for depressing pyrite and reducing ash ty froth flotation was conducted at the Northwest Experiment Station of the United States Bureau of Wines in cooperation with the College of vines. University of Washington, under the general direction of A. C. Fieldner, chief engineer, Experiment Stations Division, Bureau of Wines. Grateful acknowledgment is made for suggestions and criticisms received from W. H. Coghill, supervising engineer, U.S. Bureau of Mines Mississippi Valley Experiment Station, Rolla, Mo.; J. B. Morrow, and R. E. Zimmerman, of the Pittsburgh Coal Co.; and Dean Milnor Roberts and Prof. Joseph Daniels, of the College of Mines, University of Washington.FLOTATION AND DEPRESSIONA substance will tend to float if its surface attracts a gas film more strongly than it does a liquid film when both air and liquid are competing for this attraction. On the other hand, a substance will not float if its surface attracts a liquid film more strongly than it does a gas film. All theories of depression depend upon this fact. A wetted particle of floatable size most likely will be found in the tailings after the flotation process has been completed.The crux of flotation is the selective wetting of the undesirable material that tends to float. Two general methods 5, 6, 7 of depression are in use: One combines a chemical substance with the surface to form a wettable compound, and the other employs some colloidal or ionic substance which the surface selectively adsorbs, thereby forming a wettable surface."

Jan 1, 1935

By Frederick K. Allgaier

This report presents the final data from a 5-yr Bureau of Mines study designed to determine the surface subsidence characteristics resulting from longwall coal mining in a geologic environment common to the Western United States, It includes a description of the geologic setting of the study site, the mine plan, measurement techniques, and results of the monitoring program. Measured subsidence values were obtained over four adjacent longwall panels- Major subsidence characteristics such as longitudinal and transverse profiles, angles of draw, time-related subsidence development, and critical width are discussed. The maxima subsidence value of 5.8 ft was 68 pct of the mining thickness. The average angle of draw was 30°, Subsidence at the center of the first panel continued for 46 months following undermining. The lengths of the longwall panels precluded a definitive determination of the critical width and maximum possible subsidence.

Jan 1, 1988

By R. H. Sprute

The Federal Bureau of Mines conducted full-scale field tests in electro-kinetic dewatering and consolidation of slimes in cooperation with the Hecla Mining Co. at two of the firm's underground mines in north Idaho. To test the technique on new deposits, 4,000 ft3 of slimes from a collection sump, pumped into a watertight stope equipped with electrodes, were treated in two steps. Immediately after placement, direct current was applied using a floating electrode to hasten settlement of suspended fine particles. After removal of clarified water, the residue was further dewatered and hardened with electrokinetic treatment. In 25 hours, the material had become firm and dense with a surface capable of supporting workmen. In testing old deposits, 10,000 ft3 of slimes, placed in an unused tail drift 10 to 12 months previously, were treated. This material was sufficiently consolidated by electrokinetics to allow its removal from the mine with standard ore-handling equipment. In both tests, electrokinetic treatment densified slimes in a relatively short time with moderate power consumption.

Jan 1, 1976

By R. E. Peterson

Scrap iron is partially oxidized at elevated temperatures in the selective oxidation process to produce iron oxide and a dense residual metal of high purity. Investigation of the process was confined to converting automobile hulks into useful products. In one test series, compressed, sheared automobile scrap was processed at 1,000° C in a 36-foot-long rotary kiln at feed rates ranging from 300 to 1,200 lb/hr. Less fuel was required to maintain the temperature at the higher feed rates because of the heat generated from the burning of the combustibles and the oxidation of the iron. The bulk density of the residual metal exceeded 75 pounds per cubic foot. In an attempt to lower the quantity of contaminants in the residual metal, another test was designed using automobile hulks which had been prepared by ripping, a low-cost method of scrap fragmentation. Before oxidizing the ripped scrap approximately 62 percent of the total copper was removed in a tumbling, screening, magnetic separation and hand-sorting system. Cast iron made from the residual metal obtained by selective oxidation contained 0.15 percent copper; iron oxide scale obtained from the kiln averaged 0.13 percent copper. Pellets made from the scale demonstrated compressive strengths necessary for blast furnace reduction; lead and zinc were removed by volatilization when the induration was performed in a reducing atmosphere.

Jan 1, 1972

By A. Y. Lee

Prior work at the Bureau of Mines resulted in the successful development of a bench-scale, combination electrorefining-electrowinning method for recycling the lead from scrap batteries using waste fluosilicic acid (H2SiF6) as electrolyte. This paper describes larger scale experiments. Anodes cast from scrap battery lead were electrorefined in a 20-L multielectrode cell for 3 to 7 days. The anodes, containing 2 to 2.5 pct antimony, were ideal for obtaining firm and adherent slime blankets. Cathode deposits, assaying 99.99 pct Pb, were obtained, with current efficiencies near 99 pct. Sludge leaching was done in 100-L tanks followed by filtering in 61 cm square vacuum pan filtersu Lead of greater than 99.99-pct purity was recovered from the filtrate by electrowinning in a 20-L multielectrode cell using insoluble Pb02-Ti (lead dioxide-coated titanium) anodes and pure lead cathodes. The fluo-silicic acid electrolyte depleted in lead was repeatedly recycled to leach more sludge, and there was no problem with impurity buildup. The amount of Pb02 formed on the anodes during electrowinning was less than 1 pct of the total lead deposited on the cathodes, as long as the phosphorus concentration in the electrolyte was greater than 1.3 giL. Emissions of lead in air were less than 10 ~g/m3, well below the proposed OSHA limit of 50 ~g/m3.

Jan 1, 1984

By F. P. Haver

A method to recover copper and elemental sulfur from chalcopyrite concen¬trate, using a ferric chloride leach, CuFeS2 + 3FeCl3 ? CuCl + 4FeCl2 + 2S, was reported by the Federal Bureau of Mines in 1971 (Report of Investigations 7474). Since that time, additional work has been done to improve certain steps in the procedure; that is, the recovery of sulfur from the leach residue, the recovery of copper and iron from the leach solution, and the regeneration of the leach solution. It was determined that over 99 pct of the elemental sulfur in the leach residue could be extracted at ambient temperature with an ammonium sulfide solution. Heating the pregnant solution precipitated crystals of rhombic sulfur (99.5 pct purity) and liberated ammonia and hydrogen sulfide for recycle. Copper with a purity in excess of 99 pct was obtained from the leach solution by electrolysis, using a diaphragm cell, with an energy requirement of less than 0.7 kW-hr/lb. Metal was deposited as a weakly adherent powder that could be easily dislodged from the cathode and withdrawn continuously from the cell in the form of a slurry. During electrolysis, part of the Fe(II) was oxidized to Fe (III) at the anode so there was no chlorine evolution. The leach solution was regenerated by direct oxidation of the spent electrolyte with air or oxygen in a turboaerator at 80° C. This precipitated the iron dissolved during leaching in an easily filterable form, Fe203.xH20, and converted the remaining Fe(II) to Fe(III).

Jan 1, 1975

By Frank E. Cash

"INTRODUCTION The iron—ore ranges in the Lake Superior district are the Marquette in Michigan, Menominee and Gogebic in Michigan and Wisconsin, and the Cuyuna, Mesabi, and Vermilion in Minnesota. These ranges produce about 85 percent of the iron ore mined in the United States. Accident experience in connection with this production is better than that of the regions producing the remaining 15 percent. Production and shipments vary slightly from year to year but closely approximate each other over a period of years.This information circular supplements, continues, and combines the data in Information Circular 7321,2/ including figures of 1944 and 1945.During the 6—year period 1940 to 1945, inclusive, 481,485,475 long tons of iron ore was shipped from the Lake Superior district. 4/ Michigan and Wisconsin shipped 93,787,648 tons, or 19,5 percent of the total, and employed annually an average of approximately 14,300 men; Minnesota shipped 387,697,827 tons, or 80,5 percent, and employed annually an average of approximately 9,300 men. The tons produced per man employed is much greater in Minnesota than in Michigan and Wisconsin, owing to the large open-cut production in Minnesota."

Jul 1, 1947

By F. E. Armstrong

This report describes development and application by the Bureau of Mines of techniques and instruments for using radioactive inert-gas tracers to determine flow paths through petroleum reservoirs that have natural fracture systems and for which water injection has been selected as the stimulative production method. A field test was made to prove the techniques and evaluate instrumentation. The feasibility of applying the techniques and instruments to the solution of reservoir problems in other stimulative methods of production also is discussed. Oil commonly is displaced from sandstone host rocks by the action of a driving force that causes the oil to move through interstices of the rock and into production wells. In addition to the requirements of oil being trapped within the sand pores and the presence of an effective displacement mechanism, the rock itself must have adequate permeability to permit flow of oil and other fluids.

Jan 1, 1961

By C. Özgen Karacan

Methane emissions from the active face areas and from the fractured formations overlying the mined coalbed can affect safety and productivity in longwall mines. Since ventilation alone may not be sufficient to control the methane levels on a longwall operation, gob vent boreholes (GVB), horizontal and vertical drainage boreholes, and their combinations are drilled and used as supplementary methane control measures in many mines. However, in most cases, the types of degasification wellbores chosen are decided based on previous experiences without analyzing the different factors that may affect this decision. This study describes the development of an expert classification system used as a decision tool. It was built using a multilayer perceptron (MLP) type artificial neural network (ANN) structure. The ANN was trained using different geographical locations, longwall operation parameters, and coalbed characteristics as input and was tested to classify the output into four different selections, which are actual degasification designs that US longwall mines utilize. The ANN network selected no degasification, GVB, horizontal and GVB, and horizontal, vertical and GVB options with high accuracy. The results suggest that the model can be used as a decision tool for degasification system selection using site- and mine-specific conditions. Such a model can also be used as a screening tool to decide which degasification design should be investigated in detail with more complex numerical techniques.

Jan 1, 2009

By M. D. Aldridge

This document reports the results of a two-year research effort aimed at improving communication systems used in coal mines. This work was conducted under a program whose original goal not only involved the development of practical and effective electronic systems for operational communications, but also for monitoring, at a central location, remote instruments at key positions in a mine. About half way through the originally proposed three year effort, the program was redirected to phase out the communication effort at the end of two years and to concentrate the program" resources on the investigation of new monitoring system concepts developed by this research. Thus, the work reported here is incomplete relative to the originally pro- posed program. However, the work was carried to the point of providing sufficient evidence to aid in the comparison of certain new communication concepts. For the concepts chosen for this study, the work was stopped short of hardware development and field testing, Several reports in the form of Master's theses and a Doctoral Dissertation have resulted from this research. They each report in considerable detail the results of several individual" contributions to this program. In preparing this report, an attempt has been made to provide a complete description of the significant results but with- out burdening the reader with the minute details. These more detailed reports are referenced heavily for the convenience of those interested. PRESENT COMMUNICATION METHODS Two types of communication systems are presently used In coal mines. They are: 1, Various forms of telephone systems, and 2. Carrier current radio systems using the trolley line as the interconnection circuit. Carrier current radio is used almost exclusively for control of rail trafflc by the dispatcher. Almost all other communication uses the telephone system, Telephone lines generally extend to areas where trolley lines are not present such as the outside offices and warehouse. Therefore the telephone system provides the primary means of voice communication. Telephones - Telephone systems employed in American coal mines fall into three categories. 1. Paging type telephone systems - these systems have individual stations which use battery powered transistor audio amplifiers to boost signal levels for normal communication. When in the page mode,

By M. Kanda, W. D. Bensema, J. W. Adams

Two different techniques were used to make measurements of the absolute value of electromagnetic noise in and above an operating coal mine, McElroy Mine, located near Moundsville, Nest Virginia. The electromagnetic environment created by 300 volt dc and 480 volt ac machinery was measured. In one technique noise was measured over the entire electromagnetic spectrum of interest for brief time periods. The noise was recorded using broadband analog magnetic tape. The noise data was later transformed to give spectral plots. In the other technique, noise amplitudes were recorded at several discrete frequencies for a sufficient length of time to provide amplitude probability distributions. The specific, measured results are given in a number of spectral plots and amplitude probability distribution plots.

Jan 6, 1974

By N. A. C. Smith

[The beau of Mines made its first survey of motor gasolines sold throughout the United States in 1915, a second in 1917, and a third in April. 1919. These surveys shored that motor gasoline had become notably less volatile during each two-year interval. In order to ascertain whether this change was continuing, it was planned to institute semi-annual surveys, the first of which teas made in January, 1920. Contrary to expectations based on the previous surveys, the average volatility of the gasoline tested at this time was practically identical with that of the average volatility of the gasoline from the same districts in 1919. The next survey, made in July, 1920, showed a very marked decrease in volatility but as it has long been recognized that the volatility of motor gasoline manufactured for sale during the summer months is loss tan that of gasoline made and sold during the winter, part at least of the change was attributed to this factor. The average boiling point of the samples collected in the present survey is 263 degrees Fahrenheit, as compared with 264 a year ago. This shows that the average gasoline marketed at the present time is fully as volatile as that marketed a year ago. There has been, however, a noticeable change in the character of the product: the initial boiling point and 20 per cant point are lower than a year ago, whereas the 90 per cent and end-points are higher, which indicates a greater proportion of gasolines made by blending casing-head, or natural gas-gasoline, and naphtha.]

Jan 1, 1921

By R. V. Lundquist

Aeration in water slurries and controlled drying of manganous hydroxide produced from dithionate leaching of Artillery Peak manganese ores from Arizona were investigated by the Bureau of Mines at its Electrometallurgical Experiment Station, Boulder City, Nev., to determine whether a simple process could be developed for converting this product into a battery-grade manganese dioxide. The properties of manganese dioxide prepared by the thermal decomposition of manganous nitrate were investigated also. Manganese dioxide suitable for use in batteries was not obtained from the dithionate leach product, but some of the factors controlling its oxidation were isolated. Aging of manganous hydroxide was of major importance in retarding its oxidation by aeration. Sodium hydroxide and sodium silicate promoted oxidation by drying. Optimum quantities were about 0.85 mol of sodium hydroxide and 0.2 mol of sodium silicate per mol of manganese, and drying temperatures of 200° C. produced yields of manganese dioxide up to 90 percent of the manganese present. Higher temperatures and concentrations of reagents carried oxidation of manganese beyond its tetravalent state.

Jan 1, 1957

By J. H. McClain

In the last 3 years' operation of the zirconium-production plant, zirconium metal has been employed to good advantage in many applications. The most frequent use has been in situations requiring resistance to attack by hydrochloric acid. In this service, it has been shown to be a serious competitor to Hastelloy. Zirconium also has excellent resistance to most other corrosives end could be considered for use as an all purpose metal. For example, this report cites 18 applications in hydrochloric acid, 4 applications in sulfuric acid, 5 applications in phthalic-hydrochloric acid, 3 applications in wet hydrogen chloride-chlorine atmospheres, and 2 applications in fused caustic.

Jan 1, 1954

By Mackenzie Burnett

The Brattice Window Method was used to measure the leakage rates of a total of 42 ventilation stoppings in 8 hardrock mines. Various types of stopping construction were evaluated. The following types are listed in order of decreasing effectiveness: 1) Cinder block, 2) Timber and mortar, 3) Timber and polyurethane foam, and 4) Timber and brattice material. There are slight differences in the effectiveness of the first three types, while the timber and brattice type is substantially inferior to the others. The repeatability of the Brattice Window Method was found to vary with physical conditions in the mine such as stopping location with respect to intersections, regularity of drift cross section, and the presence of hardware such as air and water pipes, timber sets and wire mesh. The Brattice Window Method is viewed primarily as a tool for estimating and comparing stopping leakages for the purpose of determining where repair efforts should be concentrated. A laboratory test program resulted in the derivation of several "rules of thumb" for employing the Brattice Window Method, which will aid in securing accurate and repeatable data.

Jan 1, 1979

In 1962 and 1963, two in situ combustion pilot tests were conducted in the shallow Second Venango sand near Reno, Pa. Because of poor oxygen utilization and lack of production response, both tests were considered failures and were terminated. The area was then relatively inactive until late 1966, when a development well drilled near the 1963 test site had surprisingly good production in what was considered to be a pressure-depleted reservoir. Other wells drilled in and around the old thermal pilot areas also came in as good oil producers. This report presents a study of the increased oil production from the Second Venango sand in the Reno area, and the apparent connection of the present production response and the old thermal pilot tests. Apparently combustion occurred in the Second Venango sand after the 1962 and 1963 experiments were terminated and, supported by large volumes of air left in the reservoir after the 1963 test, generated carbon dioxide which helped repressure the formation. This field evidence of combustion warrants another pilot experiment to further explore the use of properly designed in situ combustion techniques in increasing production from the Second Venango sand.

Jan 1, 1971

By L. G. Marshall

This report presents a cross section of the sand and gravel operations in the Minneapolis-St. Paul area. The study covers individual operations, economic problems peculiar to the industry, glacial geology of the area and its effect upon the grades and types of products, and past, present, and future trends of the expanding population and its effect upon the industry.

Jan 1, 1963