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By Richard D. Graves

Pitch from low-temperature carbonization of bituminous coal was hydrogenated at cracking conditions in a continuous bench-scale unit to produce low-molecular-weight oils and tar acids. The pitch contained 15.6 pct benzene-insoluble material, 4.0 pct hexane-soluble oil, and 80.4 pct asphaltene by weight. At 475° C, 7,500 psig, and 1.5 hours residence time, hydrogenation products, based on the weight of pitch, were about 36 pct oil boiling below 325° C, 24 pct hexane-soluble heavy oil, 17 pct asphaltene, 1 pct benzene insolubles, and 12 pct hydrocarbon gases. The yield of tar acids boiling below 250° C was 4.3 pct, and the yields of C6 to C8 paraffins, naphthenes, and aromatics were each less than 1.0 pct. The yield of tar acids was within the range of yields obtained by hydrogenation or high-temperature carbonization of bituminous coal (2 to 5 wt pct). Yields of oil boiling below 325° C increased with increased residence time or temperature. There was little or no effect of residence time on yields of alkali- soluble material which contained tar acids. Yields of hydro-carbon gases increased markedly with an increase in temperature from 475° to 500° C. Lowering the hydrogen pressure to 4,500 psig resulted in yields similar to those obtained at 7,500 psig.

Jan 1, 1962

By Keith L. Harris

Real gross national product3 (GNP) grew at a seasonally adjusted annual rate of 4.2% in the fourth quarter compared with a revised 4.3% rate in the third quarter, according to the most recent estimates released by the U.S. Department of Commerce (table 1). Expanding inventories, Government purchases of goods and services, residential fixed investment, and a narrowing of the trade deficit fueled the growth. Significantly reduced consumer demand led to the heavy inventory growth. Almost half of the buildup in inventories consisted of automobiles because consumers reduced purchases when Detroit ceased most incentive programs in late summer. Reduced consumer demand also affected imports, however, and the narrowing of the trade deficit resumed after widening in the third quarter. Nonresi- [ ] dential fixed investment also declined after a strong gain in the third quarter. On a year-to-year basis, the economy grew at an inflation-adjusted rate of 2.9%, the same as that of 1986. However, on a fourth-quarter-to-fourth-quarter basis, the real growth reached 3.8%, the highest growth since 19M, and exceeded the Reagan Administration's estimate of 3.4%. Rising merchandise exports accounted for about one-third of the growth in GNP for all of 1987 and are expected to continue to grow as domestic manufactures benefit from the lower value of the dollar vis-a-vis other major trading country currencies. Consumer demand became a less important factor of economic growth, but employment continued to grow (table 2), and civilian unemployment declined by 0.9 percentage points (December to December) as the industrial sector geared up to increase exports. Inflation, as measured by the fixed-weighted GNP price index, remained low at 3.4%.

Jan 1, 1988

By Thomas V. Falkie, R. Venkataramani

The method of analysis was to test a large model containing potentially significant variables and on the basis of the results obtained, to reduce the model to one containing only the essential significant variables. This stepwise procedure of "scanning" a large proposed model and subsequently condensing the model consisted of two cycles of the same series of computational procedures. Data Preparation A majority of the variables measured were continuous over a specific range of values; for example, the variable "Width Ratio" varied in practice from 0.25 to 1.00. However, "dummy" values were assigned to certain operational variables in order that these varia¬bles would have numerical expression. The following variables were described in this manner. Variable "Dummy" Value x3: Development/Pillaring 0, if pillar extraction was being done 1, if development mining was being done x4: Boxcut/Open Cut 0, if a box cut was being made 1, if an open cut was being made The variables under consideration are represented symbolically as follows: Y: Loading rate (tons per minuts): TONS/MIN x1: Ratio, width of cut/width of cutter: WDRATIO x2: Ratio, height of cut/diameter of cutter: HTRATIO x3: Development or pillaring: D/P

Jan 1, 1972

By L. C. IlsLey

Cooperation between the United States Bureau of Mines and the Safety in Mines Research Board of Great Britain, continuous since 1924, has made possible this and other papers on safety subjects. Grateful acknowledgment is made to representatives of the Board for their assistance in arranging visits to several mine safety stations, and to F. R. Wynne, Deputy Chief Inspector of Mines, for arranging visits to mines in Great Britain and other countries in Europe. During the summer of 1927 the writer had the privilege of visiting the mine safety testing stations in great Britain, Belgium, Germany, and France, in the order named. All of these countries have large coal mines, many of which are rated as gassy. Therefore, when the installation of electrical equipment is contemplated, each of these countries is confronted with the same safety problem as is the United States - the development of electrical equipment that will not ignite gassy atmospheres which through neglect or accident might surround the equipment. The means employed by these countries in safeguarding gassy mines should therefore be of general interest to safety engineers in American coal mines, and it is proposed to give a brief survey for each of the four countries mentioned. The third of these surveys covers conditions in Germany.

Jan 1, 1929

By N. S. Dalal, B. Jafari, F. Y. H. Green, V. Vallyathan

"Using electron spin resonance (ESR) spectroscopy we have carried out a systematic study of the measurement of concentrations of organic free radicals in freeze-dried lung tissue. Sixty-six tissue samples were obtained from the National Coal Workers' Autopsy Study (NCWAS). The samples were characterized in terms of the concentration per gram of the free radicals, and examined in relationship to the histopathological parameters such as age, numbers of years in the mining atmosphere, the degree of disease, and smoking history. Preliminary results indicate a positive correlation between the free radicals in the lung tissue and the severity of pneumoconiosis.IntroductionThis paper summarizes our electron spin resonance (ESR) measurements of the concentration of organic free radicals in the freeze-dried lung tissue of autopsied coal miners. This work was undertaken because it is well known that most coals contain carbon-centered organic free radi¬cals,(1,2) and recent studies from our laboratories indicated that reactive free radicals might play a role in the biochemi¬cal mechanism of coal workers' pneumoconiosis (CWP) (3) Thus we obtained 144 lung-tissue samples from the Nation¬al Institute for Occupational Safety and Health (NIOSH) in Morgantown. The samples came from the data bank of the National Coal Workers' Autopsy Study (NCWAS). This selection was unique because fairly detailed histopathologi¬cal information was available for each sample.Other recent studies in this field are those of Ohta et al (4) who conducted ESR measurements on black dust deposited in autopsied human lungs, but no coal miner was included therein. Earlier Retcofsky (2) had examined one lung-tissue sample via ESR spectroscopy and had concluded that the free radicals in the lung tissue reflected simply the fusain (narrow component) ESR signals. The present study was thus undertaken to complement the earlier work (2-4) and the results indicate a positive correlation with the disease severity fairly strongly."

Mar 1, 1989

By W. I. Nissen

As part of its program to provide technology for reducing undesirable environmental impacts of mineral processing operations, the Bureau of Mines developed the citrate process for desulfurizing industrial stack gases that contain from 0.1 to 2 vol pet S02. In this regenerable flue gas desulfurization (FGD) process, S02 is absorbed from cleaned and cooled industrial flue gas with a citric acid-sodium citrate solution. The absorbed S02 is subsequently reacted with H2S to precipitate marketable elemental sulfur and regenerate the solution for recycle. Laboratory investigations of process parameters provided information for designing larger scale continuous operations. Information gathered from operation of two pilot plants, one at a copper smelter and one at a lead smelter, confirmed the laboratory results. Data were obtained for design and construction of a commercial-sized demonstration plant at the George F. Weaton Power Station, Monaca, PA. A preliminary operation of the plant was demonstrated, under a cost-sharing Bureau-industry contract. This bulletin describes the citrate process and gives results of the laboratory, pilot plant, and demonstration plant studies, as well as corrosion investigations.

Jan 1, 1985

By Lloyd Williams, H. K. Gibbs, William L. Crentz, J. W. Miller

"Reserves This investigation shows that the Poplar Creek is the most important bed in Scott County from a production standpoint. Although the Poplar Creek bed contains the largest reserve, the Big Mary has a larger recoverable reserve. Estimates of reserves also have been made for the Pewee, Red Ash, Windrock, Upper Pioneer, Jellico, and White Oak beds.Known measured and indicated reserves of coal, based on a minimum bed thickness of 14 inches and on 1,800 short tons per acre-foot of coal in place, are estimated to be 143 million tons as of January 1, 1954. Of this total, 74 million tons is in beds 28 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics are too meager for making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.Recoverable reserves of coal are estimated in beds 28 inches and more thick. This thickness is about the minimum now being mined by hand loading onto conveyors in the Appalachian region. The weighted average recovery for all beds in Scott County, as determined by this investigation, is 52.4 percent. This percentage is based on the total thickness of coal in the bed (less partings three-eighths inch or more thick) rather than on the thickness of the coal mined. Based on the weighted average percentage of recovery for all beds in Scott County, the recoverable reserves of coal are estimated to be 39 million tons as of January 1, 1954.Coal Analyses Chemical analyses of coal samples taken for this study show that the coal in Scott County is of high-volatile a bituminous rank except the Upper Pioneer bed, which is shown to be high-volatile B bituminous. The Pewee bed shows typical low-sulfur characteristics. The high ash and sulfur in the Big Mary are characteristic of that bed. The Poplar Creek is moderately low in ash and sulfur in areas where there is no parting in the bed."

Jun 1, 1956

By Stephen A. Hare, O&apos

Powder metallurgy processing of commercial Raney nickel powders was examined. The typical angular particle shape, in conjuction with aluminum present in a eutectic phase, facilitated interlocking leading to excellent green strength after compaction. Density and porosity as influenced by the compacting pressure were studied over the range of 37.5 to 207 meganewton per square meter (MN/m2). Sintering in an inert atmosphere from 575° to 850° C caused a volume increase which is attributed to a solid state reaction between Al and Ni2Al3 phases. The reaction is 3Al + Ni2Al3 ? 2NiA13. A thermal pretreatment of 70 hours at 700° C was required to prevent this reaction from occurring during sintering. Density and porosity as a function of compacting pressure and sintering temperature were determined after a thermal pretreatment of the powder.

Jan 1, 1976

By Noel N. Moebs

This report summarizes a Bureau of Mines study on the use of geotechnology to identify and reduce ground control hazards at slate quarry operations in eastern Pennsylvania. The major ground control hazard is falling rock, attributed to weathered bedding plane faults, which weaken quarry highwalls. It was demonstrated that these faults can be detected outside of the quarry perimeter using surface resistivity measurements. Falls of ice from quarry highwalls constitute a second major hazard, which requires water diversion as a basic control method. In situ stresses seemingly cause only minor problems in slate extraction although they could interact with developed stresses and lead to failure of barriers between quarries. Pull tests showed that rockbolts anchor firmly in slate and should prove effective in securing loose rock.

Jan 1, 1986

By A. P. Grossman

'This report was prepared by Shell Oil Company, Mining Ventures Department in accordance with Cooperative Agreement No. 14-09-0070-b53 dated September 10, 1976, between the United States of America, Department of the Interior, Bureau of Mines and C(b) Shale Oil I Project, Ashland Oil Inc., Shell Oil Company, Operator. After completion of this report the Shell Oil Company withdrew from participation In the C(b) Shale Oil Project and advised the Bureau of Minus that plans for publication of this report had also been withdrawn. The Bureau of Mines acting under terms of the Cooperative Agreement hereby releases this report for general information.

Jan 1, 1976

By H. F. Yancey

One of the important duties of the Bureau of Mines is to sample and analyze coals and to publish the results of such analyses for the information of producers, consumers, and the general public. Numerous publications containing such analyses have been Issued from time to time. Although the chemical properties of a coal as revealed by its proximate and/or ultimate analysis and heating value aid one considerably in visualizing its probable behavior and in determining its usefulness and value for a specific purpose, they do not furnish complete information. The physical properties of a coal, such as its ability to retain its original form without undue breakage or degradation in size under the various conditions of storage and usage, are also of importance in determining its suitability, technically or economically, for a given purpose.

Jan 1, 1932

By Martin J. Gavin

During the recent study of lubricating oils carried on in the San Francisco laboratory of the United States Bureau of Mines, it became desirable to distill the oils used in the experimental work at pressures as low as 10 millimeters (mercury column) absolute. In the effort to Overcome difficulties and eliminate sources of error, certain changes were made in the apparatus for vacuum distillation used by the Bureau of Mines for crude petroleum.4 These changes were described in R.I. 2819, issued in July, 1927. Subsequent to the publication of R.I. 2819 several other changes have been made, and the present form of the apparatus for vacuum distillation of lubricating oils is described in this revision of R.I. 2819. These changes were found to give more accurate checks on duplicate distillations. The major part of the credit for the laboratory work which developed the changes in the apparatus and method revised herein is due to Boyd Guthrie, assistant petroleum chemist, and R. V. Higgins, junior chemist, o the San Francisco laboratory, United States Bureau of Mines. DESCRIPTION OF APPARATUS The distilling flask employed is essentially the Hempel flask as used by the United States Bureau of Mines for the analytical distillation of petroleum.5 he complete apparatus is shown in Figure 1. The fractionating column and exposed portion of the flask is wrapped with 4 inch asbestos rope and then surrounded by a cylindrical hood of 1/8 inch pliable asbestos sheet with a narrow air space between the wrapping and the cylindrical hood. This was found necessary to prevent any radiation or convection heat losses from the column, and resulted in obtaining a more even and constant fractionation by eliminating any dephlegmating action caused by temperature changes around the column.

Jan 1, 1930

By Constantine C. Popoff

The Hermada antimony deposit is in the Sewtooth Range in southwestern Idaho, about 77 miles by road northeast of Boise. Stibnite mineralization occurs over an area one mile wide from west to east and two miles long. It is locally referred to as the Swanholm district. In 1947 high- grade stibnite ore was discovered on the East Fork of Swanholm Creek. Since then, ore in commercial quantity has been produced by the Hermada Mining Co. The total output for 1947-50 was about 5,000 tons of ore, containing 640 short tons of antimony metal.

Jan 1, 1953

By Je M. Oh

The U.S. Bureau of Mines is conducting research on the oxidation resistance and structural stability of Fe-(0-8)Cr-(0-16)Ni-(0-16)Mn-3.5Si-lAl alloys as potential substitutes for high-Cr stainless steels. Oxidation tests were conducted in air over the temperature range of 6000 to 9000 C for up to 1,000 h. Microstructures were analyzed at room temperature after hot rolling. The oxidation properties and the structural stability were found to be greatly affected by the Cr and Mn levels. Although substitution of Mn for Ni increased the oxidation rate, the Mn helped to stabilize the austenitic microstructure. Decreasing the Cr content or increasing the Mn content produced higher oxidation rates and earlier oxide spalling. In this study, reaction kinetics, oxide morphologies, and microstructure of the alloys were investigated using scanning electron microscopy, energy dispersive X-ray analysis, X-ray diffraction, and electron microprobe analysis.

Jan 1, 1989

By Robert L. Kranz

Mining-induced microseismicity data collected by the U.S. Bureau of Mines in a hard-rock mine were analyzed for spatial and temporal patterns that might prove useful for prediction of rock bursts or assessment of rock mass damage changes. Pattern attributes described and illustrated in the previous report (part 1) were applied to the study of aftershock sequences associated with two different stopes. The aftershock sequences were spatially and temporally fractal, and the fractality was maintained for up to 16 h following a sequence progenitor. This suggests mechanical interdependency among the after-shocks. No statistical difference was found in the distributions of fractal dimensions when comparing two different stopes or when comparing aftershock sequences initiated by blasts or bumps. This suggests a lack of sensitivity to both stress perturbation mechanism and local damage states. However, differences between the two stopes were found in other sequence attributes that support inferred differences in the magnitude of stress concentrations and damage near each stope, and over time as a stope is developed.

Jan 1, 2010

By R. Y. Williams

The investigative work described in this report was undertaken by the Bureau of Mines under a cooperative agreement with the department of mining engineering of the University of Illinois and the Illinois State Geological Survey." The purpose of this agreement was to provide for a comprehensive investigation of coal-mining conditions in the State, with especial reference to the possibility of lessening waste in the mining and preparation of coal and of reducing the dangers to which miners are exposed. The Bureau of Mines paid particular attention to those phases of the investigation that were of general interest from their bearing on safety and efficiency in the coal-mining industry as a whole. Thus, it studied the occurrence of gas (methane) in the mines of the southern part of the State," tested the inflammability of the coal dust from many mines, examined the efficiency of the control of ventilating currents, and investigated the factors affecting the humidity of mine air with respect to their bearing on the occurrence of mine explosions. Following the establishment of the fact that under certain conditions dry bituminous coal dust is inflammable, there arose the problem of finding efficient methods of preventing or limiting coal-dust explosions. Experiments in the gas-and-dust gallery at the Pittsburgh testing station of the Bureau of Mines verified the fact that certain dusts that explode violently when dry are rendered inert by proper humidi- .fication of the atmosphere within the gallery, and the importance of humidity as a factor in limiting the inflammability of coal dust in a mine is demonstrated by the fact that there has never been in Illinois a dust explosion during the summer months, whereas the records show a number of dust explosions during cold weather. It is easy to see that the warm moisture-laden air that enters a mine in the summer must deposit moisture on cooling, whereas the cold and relatively dry air that enters in winter must take up moisture as it becomes heated in traveling through the mine.

Jan 1, 1914

By J. E. Tiffany, Gaigler. Z. C.

"PREFACEIn presenting this list of permissible explosives and blasting devices, the Bureau of Mines desires to call attention to pages 16 and 21 outlining the conditions in use under which, and only under which, the explosive or blasting device is permissible.In view of a recent publication recounting trade practice favoring the use of a blasting device without stemming, particular emphasis is placed upon condition 4 on page 16 and condition 2 on page 21. An explosive or a blasting device enumerated in the permissible lists of this Bureau is not permissible in use unless it is properly confined with clay or other incombustible stemming.PERMISSIBLE EXPLOSIVES TESTED UNDER SCHEDULE 17CAn active list of permissible explosives was published in December 1937 as part of Bureau of Mines Report of Investigations 3361, under the title ""Active List of Permissible Explosives and Blasting Devices Approved Prior to June 30, 1937.n This list included 196 brand names.Changes in the list that have been authorized to June 30, 1938, placed 7 additional brands of permissible explosives on the active permissible list as a result of tests, changes in brand names, or transfer from the inactive list. Twelve permissible explosives were transferred from the active to the inactive list. The present list contains 191 brand names. The brand names of the permissible explosives placed on the active list are as follows:"

Oct 1, 1938

By Roger L. Williams

The Bureau of Mines investigated northern New Jersey as a potential future source of yttrium and the rare-earth elements. The studies, consisting of geophysical surveying, sampling, and exploratory drilling, began in the spring of 1959. A total of three and one-half months were spent in the field collecting data. Thirty-three deposits were investigated, of which five demonstrated some potential resources of yttrium and rare-earth minerals. Results indicate that the deposits examined do not contain quantities of yttrium and the rare-earth elements recoverable under present economic conditions. Detailed studies conducted at the Scrub Oaks mine, near Dover, N. J., delineated a yttrium and rare-earth-bearing zone within the magnetite-hematite ore body that represents a potential low-grade deposit. Beneficiation studies on this deposit indicate that a final product, averaging 31.3 percent rare-earth oxides including yttrium, could be produced through amine and fatty acid flotation procedures with 77 percent recovery. Two hundred and eighty-five feet of diamond drill core was obtained from exploration studies conducted at the Bemco prospect in Sussex County. The deposit averages 2.30 percent rare-earth oxides (including yttrium), 0.45 percent uranium and 0.24 percent thorium. Low-grade deposits were identified at the Canfield phosphat2 mine and the Tanners Brook Monazite placers in Morris County, and the Marble Mountain prospect in Warren County.

Jan 1, 1967

By J. M. Goris

Cable bolt supports are becoming an important ground control technique in underground mines in the United States and Canada. They show great versatility and are adaptable for use with many mining techniques, they have high load-carrying capacities, they can be installed in small areas with low roots, and they are cost effective. Investigators in a number of research institutes in North America have conducted studies to assess the material and support properties of cable bolts, evaluate their support capabilities under various mining conditions, and provide design criteria for using cable bolt supports as roof control systems under varying mining conditions. While conducting these studies, personnel have collected important information on the history, application, performance, and economics of these supports. This U.S. Bureau of Mines report documents this information so that ground control personnel unfamiliar with cable bolt supports can gain an understanding and appreciation of their use. A comprehensive bibliography of technical information on cable bolt supports was selected by the authors and is also presented.

Jan 1, 1994

By Raymond B. Ladoo

[Inquiries are frequently received by the Bureau of Minas relative to occurrence, mining, treatment and utilization of the natural hydrocarbons' such as gilsonite, elaterate, wurtzilite, grahamite, and ozokerite although have been known and used for many years, they are not yet well understood and the amount of recent literature dealing with them as comparatively small. This paper is intended merely to summarize the present knowledge The natural hydrocarbons included in this series are gilsonite, elaterite, wurtzilite, glance pitch, manjak, grahamite, albertite, arid ozokerite and many other minor varieties. With the exception of ozokerite and the other mineral waxes, then all more or less resemble asphalt in that they are dark brown or black bituminous substances of organic origin, generally with a resinous luster. Ozokerite usually light an color with a waxey luster, is closely allied to the others of the series, but is usually considered separately, Unfortunately authorities differ as to nomenclature so that determinations of physical and chemical properties from different sources may riot be readily compared. Abraham Herbert, Asphalts and Allied Substances, 1918, 606 pp. has made one of the most detailed studies of these subjects in recent years, and his classification is used in the main. The following definitions are given by him]

Jan 1, 1920