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By Michael S. Moats, Prashant Bagri

"In recent years with increasing concerns about energy consumption in hydrometallurgical processing, there is an ongoing attempt to use Catalytic Titanium Anodes (CTAs) for copper electrowinning. For this work, anodes with IrO2 - Ta2O5 coatings were prepared in the laboratory with the same total coating loading but varying the number of layers by changing the speed of withdrawal in dip coating. A second set of CTAs were fabricated on niobium, Ti Grade 1, Ti Grade 7 and Ti Grade 36 metal substrates. All the anodes prepared in the laboratory were characterized using standard electrochemical techniques and subjected to accelerated life testing. It was found that the coating would not adhere to the niobium substrate, the grade of titanium had a minimal to no effect on the life of the anode, and it is observed that as the coating speed slows, there is an increase in the electrochemically active surface area of the coating which seems to directly contribute to an increase in the Tafel slope of the anodes. There was inconclusive evidence on the effect of coating speed on anode lifetime.INTRODUCTIONLarge scale hydrometallurgical extraction of copper has become widely practiced over the last 40+ years. The hydrometallurgical route entails leaching, solvent extraction and electrowinning. With the increasing desire to process refractory sulphides like enargite and chalcopyrite through the hydrometallurgical route, use of hydro-processing of copper is expected to remain high.In conventional electrowinning, copper is deposited on the cathode and an inert anode is used for oxygen evolution. Presently, the most common anode material is rolled lead-calcium-tin and the cathode is 316L stainless steel (Robinson et al., 2013). This lead alloy is fairly inexpensive and is robust, providing lifetimes typically of 4+ years. The main drawbacks of lead alloys are their relatively high oxygen evolution overpotential, the need for cobalt in the electrolyte to reduce their corrosion, the contamination of cathode product by lead, and the generation of harzardous by-products (Hiskey, 1999)."

Jan 1, 2016

By Yoshimasa Funakawa, Kazuhiro Seto, Akio Kobayashi

A new hot rolled high strength steel consisting of ferrite matrix and nanometer¬sized precipitates was developed. The ultra fine precipitates were identified as TiMoC2, and the strengthening by the precipitates was evaluated more than 300MPa in case of TS/800MPa grade steel. Due to the strengthening effect of the ultra fine precipitates, alloy elements for solid solution hardening can be reduced. It is notable that the steel shows very high yield strength (730MPa in case of TS/800MPa) and very high local elongation leading to excellent stretch flange formability at the same time. The mechanical properties of the steel are attractive for chassis parts and structural parts of auto body. The steel has been produced commercially, and applied to the parts successfully.

Jan 1, 2004

By J. W. Gregg, P. M. Dranchuk, D. L. Flock

"From preliminary investigations it has been observed that although evaporation losses may be estimated by comparing single values of certain physical properties of crude oils and their evaporation residues, such techniques possess little accuracy unless both the evaporation process and the variation of the property as a function of the process are completely known. The accuracy of estimation may be increased somewhat through the comparison of property mid-per-cent curves. Further increases in accuracy are possible if bottoms yield •curves rather than mid-percent curves are used. The use of both the mid-percent and bottoms yield curves however involves a prohibitive amount of effort in most cases. Examinations of distillation bottoms from Hempel type distillations carried to end points just short of the cracking point have indicated that these bottoms are not appreciably affected by the evaporation process. It was further observed that bottoms of identical API gravity, obtained from a crude oil and its evaporation residues behave as if they were pure components which were unaffected by evaporation. Based on these observations Hempel distillation bottoms of equal API gravity were obtained for a crude oil and its various evaporation residues from API gravity bottoms yield curves. The volume percent of these bottoms in the crude oil and its residues were used to calculate the evaporation losses suffered by the crude in order to yield the various residues. The results indicate that, although further refinements in technique are required, it is possible to calculate evaporation losses with an accept-able degree of accuracy through the use of this method."

Jan 1, 1960

By K. A. Natarajan, M. N. Chandraprabha

Selective separation of minerals from complex sulphide ores is a challenging task and it is often difficult to get commercially acceptable individual concentrates by conventional selective flotation using inorganic collector reagents. Microbially-induced mineral beneficiation has proved to be more effective, economically viable and an environmentally benign process for the effective separation of various minerals. Applications of microbially-induced mineral beneficiation are demonstrated in this paper with respect to beneficiation of complex multimetal sulfides. The role of adapted microorganisms and bioreagents in the beneficiation of complex sulphide minerals are also illustrated.

Jan 1, 2009

By E. Ghali, W. Zhang, C. Su, N. Sorour, G. Houlachi

"Zinc electrowinning process is sensitive to the presence of metallic impurities such as lead ions that could substantially and negatively affect the power consumption and surface morphology. Effect of various concentrations of manganese ions and traces of lead ions up to 2.5 mg L-1 added to the electrolyte during electrowinning have been investigated by electrochemical polarization techniques such as galvanostatic, cyclic voltammetry and potentiodynamic. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were applied to examine the surface morphology and crystallographic orientation, respectively. Microwave plasma-atomic emission spectrometry has been used to determine the lead content in the deposit and in the electrolyte after electrodeposition. It was found that lead ions added to the zinc electrolyte led to the increase of cathodic overpotential and current efficiencies of zinc deposit. However, addition of Mn2+ into the zinc electrolyte resulted in the decrease of cathodic potential and current efficiency of zinc deposit. It can be stated as example that galvanostatic polarisation at 40?C and 52.5 mA cm-2 in presence of lead up to 0.1-0.2 mg L-1 in the electrolyte and 8-12 g L-1 Mn could be better considered as practical working parameters for electrowinning process.INTRODUCTIONApproximately 85% of the global production of zinc metal is produced by electrolytic process (Sinclair, 2005). The main goal of the zinc plant is to obtain pure zinc deposits with high current efficiencies. Smooth and pure deposits with high current efficiency (CE) are always obtained from pure electrolytes (Alfantazi & Dreisinger, 2001). The presence of metallic impurities in the zinc sulphate electrolyte is a major problem for the zinc electrowinning industry, since decreases in current efficiency, changes in deposit morphology and cathodic polarization are observed for electrolytes containing small concentrations of impurities (Ault & Frazer, 1988; Muresan, Maurin, Oniciu & Gaga, 1996). Low level concentrations as parts per million of these impurities are reported to influence negatively the zinc electrodeposition (Beshore, Flori, Schade & O'Keefe, 1987)."

Jan 1, 2016

By H. Chaouki

The aim of this work is to simulate the forming process of a green anode. For this purpose, a nonlinear compressible viscoelastic constitutive law is presented. The concept of natural reference configuration is considered. Within an isothermal thermodynamic framework, a Helmholtz free energy is proposed to take into account the nonlinear compressible deformation process occurring between natural reference configuration and current configuration. A dissipation potential is introduced in order to characterize the irreversible aspect of compaction process. Thus, the constitutive law is formulated through two equations: 1) an expression of Cauchy stress tensor and 2) a differential equation characterizing the evolution of the natural reference configuration. Material parameters are assumed to be a function of the bulk density. This allows capturing the micro-mechanical phenomena within the chosen macroscopic approach. An experimental study based on compaction tests is carried out in order to characterize the mechanical behaviour of the anode paste. A user's material VUMAT subroutine for finite element dynamic explicit analysis has been developed and implemented in the ABAQUS commercial software. To evaluate the model predictive capability, numerical simulations of the compaction forming process of anode paste were performed. Simulation results show that the constitutive law predicts the experimental trends and gives interesting physical responses. This constitutes a first step toward making a benchmark with experimental results on the forming process of anode paste.

Jan 1, 2011

By W. A. Dixon Edwards

Industrial mineral production in Alberta, worth $468 million in 1997, comes from a dozen types of industrial minerals, mined by about 400 producers. Cement and lime from Paleozoic limestone formations exposed along the Rocky Mountains account for the greatest production value. Sand andgravel is the primary source ofmineral aggregate. Almost two-thirds of this aggregate is consumed in the Edmonton and Calgary regions. Sulphur produced at 48 sour gas processing plants and two oil sands plants was valued at $84.8 million in 1997 and accounted for 80% ofCanadian sulphur production. Four companies solution mine the Elk Point salt beds to produce chlor-alkali chemicals, industrial salt and sodium chlorate. Natural brine is also produced as a dust control product. Al $22 million, peat moss is a major industrial mineral product in Alberta. Other minerals with noteworthy production include shale, stone, silica and ammolite. The commodities with the greatest development potential are diamond, silica and oil sands tailings by-product minerals.

Jan 1, 2001

By H. Wotruba, L. von Ketelhodt, M. Kowalcyk, C. Kleine, M. Robben

Sensor-based sorting is a financially and technically viable technique that is operating with little or no water and relatively little power consumption. Sensor-based sorting has already proven its operational stability at two gold applications in South Africa. Sensor-based sorting cannot only turn waste dumps and diluted mining blocks into reserves. The implementation can also cause a decrease in specific operating costs of mill and mine when for example replacing selective mining by bulk mining methods with subsequent sorting. Successful installations, operational experience, test work data and flow sheet integration from mine-to-mill underline the impact and potential that sensor-based sorting can have on the gold mining and processing industry.

Jan 1, 2011

By H. Thalenhorst

For an advanced mineral exploration project that has a ?nugget? issue making the assessment of the deposit grade difficult, a bulk sampling program using a sample tower can provide information that is otherwise not obtainable prior to actual production. This information includes the verification of predicted resource grades for the bulk sample tonnage (and, indirectly, of the methods and parameters used for the grade estimate), confirmation of the physical and grade continuity of the mineralization, and geotechnical data for a future mining operation. The information gathered will improve the input of a feasibility study, particularly with respect to expected mining grades, which are the key economic parameter for most mining projects. The bulk sample rejects can be used for pilotscale metallurgical testwork. Bulk sampling is also useful in cases of potentially biased drill-hole assay results and in the reliable determination of ore grade before shipment of ore from production or development operations to an external beneficiation plant. This paper presents a practical bulk sampling and sample preparation protocol, lists design features for the sample tower, examines the sampling errors that will be encountered, provides information on quality control procedures, and looks at the costs and benefits of such a program, based on the experience of undertaking bulk sampling programs during the period of 1985 to 2008.

May 1, 2010

RÉSUMÉ L’estimation la plus précise possible des coûts de minage est d’extrême importance pour les études de préfaisabilité afin de diminuer les risques financiers des projets miniers. Les méthodologies existantes d’évaluation des coûts de minage ne permettent pas de les évaluer avec des marges d’erreur acceptables tout au long de l’évolution des projets miniers. Elles visent à évaluer les coûts unitaires de minage des études préliminaires de faisabilité, pour les principales méthodes d’exploitation, en prenant pour l’hypothèse que ces coûts dépendent principalement du taux d’extraction journalière. Si cette hypothèse peut être justifiée pour l’évaluation du coût d’opération, elle est fort discutable pour l’évaluation des coûts de minage. Pour démontrer que cette hypothèse est inadéquate nous avons analysé la méthode d’exploitation la plus populaire sur le continent nord-américain c’est à dire celle par chambres vides avec retrait horizontal (Hr – Horizontal retreat), ou « Longhole » et celle avec retrait vertical (VCr - Vertical Crater retreat). Il ressort de cette analyse que les coûts unitaires de minage dépendent principalement des conditions géotechniques du massif rocheux et de la largeur du gisement et non pas du taux d’extraction journalière du minerai.

Jan 1, 2010

By O. G. Olvera, L. S. Quiroz-Castillo, P. J. Valenzuela-Guerrero, D. G. Dixon

The effect of sulfuric acid concentration on the extractions of arsenic and copper in the catalyzed batch leaching of an enargite concentrate was studied. The acid concentrations studied were 60, 45, 30 and 15 g/L. The experimental series yields maximum copper extractions of 96 to 98% in an interval of 81 - 185 h leaching time for 60 - 15 g/L initial sulfuric acid concentration; all the copper extractions plateaued after these values; the rates and plateaus of copper extraction are increased with higher acid concentrations. Arsenic extractions reached maximum values of 89% in 57 hours, 57% in 49 hours, 33% in 25 hours, and 25% in 112 hours respectively; these maximum values were followed by a steep decrease in arsenic concentration, which indicates a precipitation event occurs in the process. According to the literature and process conditions, the arsenic precipitates obtained are iron arsenates similar to scorodite. The stability of the residues was tested using the Toxicity Characteristic Leaching Procedure (TCLP) from EPA; the residues for the four concentration levels passed the TCLP test, reporting arsenic leaching values below 1 mg/L.

Jan 1, 2014

By S. Malopheyev, I. Vysotskiy, R. Kaibyshev, S. Mironov

"In this work, the effect of pre-strain rolling on the annealing behavior of friction-stir welded 6061-T6 aluminum alloy was studied. To this end, the as-welded material was rolled to 10 or 20 pct. of thickness reduction prior to the standard post-weld T6 heat treatment. Three rolling directions were the 3-mm thick sheet were considered: along the welding direction, perpendicular to the welding direction, and at the angle of 45° to the welding direction. At relatively low pre-strains (10 pct.), the annealing behavior was found to be very sensitive to the rolling path, and rolling along the welding direction was most effective in suppressing abnormal grain growth. On the other hand, increasing the pre-strains to 20 pct. of thickness reduction inhibited abnormal grain growth irrespective of the rolling path.INTRODUCTION Heat-treatable wrought Al-Mg-Si alloys are widely used due to attractive combination of strength, ductility, excellent corrosion resistance and low cost (Polmear, 2006). To provide the optimal balance of mechanical properties, these materials are typically commercially available in appropriately work- and precipitation-hardened conditions (Polmear, 2006). During conventional fusion welding, however, the prior strengthening effect is totally lost due to elimination of the work hardened structure and dissolution of the strengthening precipitations. An innovative friction-stir welding (FSW) technology may partially overcome this problem. Due to the solid-state character of this process, which involves very large strains, the welded material is characterized by fine-grained microstructure with moderate-to-high dislocation density, and thus the prior work hardening effect may be preserved or even enhanced (Threadgill et al., 2009; Mishra & Ma, 2005). However, heat input associated with FSW inevitably leads to dissolution and/or coarsening of strengthening precipitates, thus giving rise to the undesirable material softening. In an attempt to restore the strength of the friction-stir welded material, the standard T6 post-weld heat treatment has been applied, but this approach was found to lead to abnormal grain growth (Malopheyev et al., 2016; Mironov, 2013, Mironov et al., 2015)."

Jan 1, 2018

By R. M. de Carvalho

Empirical and phenomenological models of SAG and AG mills have dominated the scene for the last few decades, being used nearly every time a mill is scale-up or an attempt is made to improve its performance. However, in spite of their success, these models fail to describe the details of both the grinding environment and the breakage mechanisms. The result is a generally good track record, with a few ? but very important ? instances when these models fall short in their predictions, which can be very costly. Further, nearly all of these models require detailed calibration to industrial and pilot plant data, being costly in their application, although still with limited predictive capabilities. Recognizing these challenges, a new model framework has been proposed which overcomes the limitations of currently used models by coupling the microscale population balance model, the discrete element model and functions that describe internal classification at the mill grate. This model framework has already been applied to describe breakage in ball mills, with showing very promising results. However, in the case of SAG and AG mills a much greater level of complexity is involved in the model, given the interaction between the mechanical environment that is formed totally or, in part, by the ore itself, and the breakage response in the mill. The paper describes the model framework, demonstrating how it can address appropriately effects such as mill speed, mill filling and size distribution, on the response from the mill. Some of the advantages of the model are related to its intrinsic multi-component and dynamic nature, which allows simulating appropriately mixtures of ores of different competences in a transient manner.

Jan 1, 2012

By Liu Liu

In the recent 10 years the rapid development of Chinese steel industry has attracted the attention of the world. The technological progress of converter steelmaking has played an important role in this process. First of all, slag splashing has been extensively adopted by Chinese steel companies in various sizes of converters from largest to smallest ones, and even including those using special hot metal containing V and Ti. Remarkable metallurgical results have been achieved. Up to now the average converter campaign life has reached nearly 10,000 heats, and the longest exceeds 30,000 heats in three melt shops. Based on this process, the long-life combined-blowing converter steelmaking technology has been developed. Slag splashing has been used to form a gas permeable "slag mushroom" on the top of bottom nozzles to protect the nozzles. In order to keep the effective bottom blowing, furnace bottom thickness control technique has been developed to prevent the furnace bottom growth. It makes the service life of bottom nozzle the same as the converter campaign life (average 10,000 heats and longest > 30,000 heats). The complete combined blowing was ensured through out the furnace campaign. Concentration product [C][0] is in the range of 0.0023 ~ 0.0030%, the T.Fe in the slag is lowered by 4 ~ 6%, and the [0] in steel is decreased by 100 ~ 250 ppm.

Jan 1, 2004

By P. Duran

The metallurgical gas handling system at Chagres Smelter, like that of many smelters, can be the limiting constraint to processing more concentrate through the smelter. Mass and energy balances for the metallurgical gas handling system processing off-gases from the flash furnace and Peirce-Smith converters have been used by both operations and process engineering groups to help evaluate different operational scenarios in which the use of the installed capacity could be maximized and/or an operational strategy can be change with the purpose of removing a bottleneck or justifying an investment to relieve a constraint in the gas handling system. The present work describes the development of these process balances that were carried out in Exce®. The results were validated with operational data and, subsequently, some cases of industrial interest were simulated, detecting some conditions that were limiting the operation due to the present installed capacity in the Chagres Smelter.

Jan 1, 2007

By S. Abu-Samra

By virtue of its complex nature, the construction industry comprises a wide spectrum of interrelated variables and factors. This multifaceted character of the construction industry puts the use of engineering modeling tools and techniques on top of project management necessities. This research introduces a macro-level earthmoving management system using Genetic Algorithms (GAs) to reach the optimum allocation of earthmoving equipment. The Earthmoving Equipment Management System (EEMS) functions through four integrated modules: (1) A Central Database containing information about projects and available equipment; (2) An Equipment per Segment Selection module that calculates the cut and fill quantities, plots the Mass Haul Diagrams, and selects the equipment types to be used for each segment; (3) An Equipment Pool module which determines the production and cost for each available equipment, based upon the project site conditions; and (4) An Optimization Engine equipped with a GA optimization solver. This engine formulates the optimum earthmoving cost for all projects, by changing the number of allocated equipment. The Optimization Engine takes into account the number of available equipment and calculates the weekly equipment allocation. The EEMS model was implemented on an earthmoving company conducting five different projects on hand. The model proved to be an effective tool in providing decision makers with optimum equipment utilization on a multi-project scale to minimize the earthmoving cost. The results were then compared with the company?s existing micro-level management system, demonstrating better performance on the level of savings, amounting to 13% of total earthmoving cost.

Aug 1, 2013

By D. Bois, P. Keating, J. Lemieux, M. A. Vallée, M. Allard, R. S. Smith, L. Z. Cheng, M. Chouteau, D. K. Fountain

"Abstract -A test survey using the MEGATEMII airborne electromagnetic system was flown over the Iso and New Insco massive sulfide orebodies in the Rouyn-Noranda mining camp, Canada. The results were compared with data from historical systems (INPUT, DIGHEM) used to discover the deposits. The historical data show that the two deposits have comparable conductances. However, the modern MEGATEMII system reveals that the New Insco deposit has a much slower decay than the Iso deposit, and it is, therefore, interpreted to be more conductive. The MEGATEMII anomaly maps provide estimates of the location, depth, dip, and strike of the two deposits, information that was not available from the historical anomaly maps. The signal-to-noise ratio of the MEGATEMII data is greater than the historical data, yielding more sharply defined anomalies. The investigations also included a comparison between 90 Hz and 30 Hz MEGATEMII data. The 90 Hz data were found to be useful for mapping the less conductive parts of the Iso body, whereas the 30 Hz data demonstrated that the New Insco body is more conductive. Analysis of height attenuation data over the Iso body indicates that the body could be seen by the MEGATEMII system if it were buried an additional 230 m deeper (in highly resistive material). On the other hand, the INPUT system would detect the Iso body only if it were buried no deeper than an additional 60 m. Tests with the transmitter turned off showed that, for this flight, the MEGATEMII system noise levels on the processed data are about 300 pT/s. Sommaire - Dans le cadre d’un projet de recherche, un ensemble de levés d’essais électromagnétiques aéroportés employant le système de MEGATEMII a été effectué au dessus des dépôts d’Iso et de New Insco, Rouyn-Noranda, Canada. Les données ont été comparées avec les réponses des systèmes qui ont découvert ces deux dépôts (INPUT et DIGHEM). Les données antérieures montrent que le dépôt d’Iso a une conductance comparable à celle de New Insco. Cependant, les données de MEGATEMII démontrent que le dépôt de New Insco a une haute valeur de la constante de décroissance, ce qui reflète une plus forte conductivité. La carte d’anomalies de MEGATEMII indique la localisation, la profondeur, le pendage et l’orientation des deux dépôts, ce que la carte d’anomalies antérieure ne montrait pas. Le rapport de signal à bruit de MEGATEMII est plus grand que celui des données de INPUT et de DIGHEM; de plus, les pics sont mieux définis. Les tests ont également permis une comparaison entre les fréquences de base de 90 Hz et de 30 Hz. Les données de 90 Hz se sont montrées utiles pour cartographier la partie du dépôt Iso dont la conductivité est la plus faible, tandis que les données de 30 Hz montrent clairement que le dépôt de New Insco est plus conducteur. Les analyses de l’atténuation du signal avec la hauteur ont indiqué que le dépôt d’Iso pourrait être détecté par le système MEGATEMII s’il était enfoui à 230 m sous la surface (dans un milieu hautement résistant). D’autre part, le système INPUT pourrait seulement détecter le dépôt d’Iso s’l était situé à 60 m de profondeur. Les tests avec l’émetteur fermé démontrent que le niveau de bruit est des l’ordre de ±300 pT/s."

Jan 1, 2006

By Jaime Meléndez Martínez

Recent interest in unconventional reservoirs motivates our work in laboratory measurements of seismic anisotropy. Seismic anisotropy is the variation in speed of a wave as a function of its direction of propagation. Analyzing anisotropy in unconventional reservoirs is important since anisotropy leads, for example, to differential stresses upon loading and could affect hydraulic stimulation (Reinicke et al., 2010, Zimmermann and Reinicke, 2009); in this sense, laboratory measurements are an important tool to study seismic anisotropy at small scales which can aid in the characterization of larger formations. The purpose of this work is to describe the laboratory methodology used to simultaneously measure ultrasonic P and S-waves in three different directions from a single core sample. Elastic anisotropy of a Proterozoic sedimentary rock from south-west Alberta is investigated. In metamorphic rocks seismic anisotropy is caused by preferred mineralogical alignment or foliation. Assuming a transversally isotropic medium, arrays of compressional and shear piezoelectric ceramic transducers were mounted on a sample trimmed from a core to measure travel times of ultrasonic P-waves and S-waves as a function of confining pressure at directions perpendicular, parallel, and oblique to the plane of foliation (bedding). Results show strong anisotropy agreeing with the assumption of a transversely isotropic medium. Dependence of travel times and hysteresis effects can be observed when pressurizing and depressurizing.

Jun 1, 2012

By Georges Croisé, Les-Lee Thompson, Adrien Debergé

Membrane filtration systems have regained focus in recent years as an effective means of liquid-liquid separation to increase the concentration of valuable elements, recover reagents or remove impurities. ORANO Mining (formerly AREVA) investigated this cost optimization process opportunity as early as 2011 for implementation at the Trekkopje project (Namibia). The key focus was to separate and recycle bicarbonate from the uranium bearing eluate solution. The performance targets were successfully achieved at lab- and pilot scale with an ultrafiltration and nano-filtration configuration system. Early 2015, ORANO Mining further launched an investigation into the use of membranes for acid recycling at the KATCO In Situ recovery mine in Kazakhstan based on the favorable results from the original bicarbonate application. KATCO is the world leader in ISR uranium mining with an eluate processing capacity of 80 000 m3/yr. This site consists of two processing plants namely, Muyumkum and Tortkuduk, located 40 kilometers apart, both operating under acidic conditions whereas precipitation and packaging are based in Tortkuduk only. This paper serves to present the results from the integration of a nano-filtration system at the Muyumkum satellite processing plant. The project consisted of screening laboratory bench studies conducted at ORANO-CIME followed by process validation at KATCO through further bench and pilot test work. The feasibility study assessments were successfully concluded which led to the implementation at an industrial scale in Muyumkum of a nano-filtration process to reduce eluate volumes being sent to the uranium precipitation section whilst achieving effective separation of uranium from sulfuric acid. Nano-filtration technology has drawn significant attention due to the efficiency and reproducibility of the process and its moderate capital cost relative to operational savings. The reliability of the previous results is a great opportunity to reduce operative expenditures within ORANO’s next ISR mining project in Mongolia.

Jan 1, 2020

By E. J. Schwarz, A. A. Winir

"Absolute magnetite contents were determined for asbestos specimens in various stages of milling by using a Faraday-type thermomagnetic balance. Comparison of these results with magnetic ratings (MR) supplied by the mining companies cooperating in this study reveals strong scatter. The main cause of this scatter is thought to be that the MR values were obtained in magnetic fields well below the saturating field of magnetite (5,000 oe). However, only the saturation moment is an intrinsic property and consequently must be used for the purpose of obtaining reliable estimates of the magnetite content. Curie points indicate that virtually pure magnetite and possibly Ni3Fe is present in all samples, and another phase, probably (Cr, Al) magnetite, is present in a few samples. The susceptibility in fields stronger than 5,000 oe is positive and falls in the normal paramagnetic range, whereas sy nthetic chrysotile exhibits weak diamagnetism. This suggests that, as a general rule, the least adulterated natural chrysotile concurs with the samples showing the smallest positive susceptibility above 5,000 oe. The magnetite appears to increase in quantity with a decrease in fibre length and to be somewhat more uniform in distribution for samples showing substantial fiberization (opening of the fibres)."

Jan 1, 1971