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By B. I. Whittington

This paper examines the effect of cation type (i.e. NH4+, Na+ and K+) and anion type (i.e. SO42- and C1-) on the extraction of nickel during the pressure acid leaching of a Western Australian laterite ore. The results are compared with testwork conducted with other Western Australian nickel laterite ores and the possible process implications of adding an additive to a plant autoclave are considered. Addition of either (NH4)2SO4, Na2SO4 or K2SO4 increased both the nickel extraction and the acid consumption, provided that the level of additive was not too great. For example, the nickel extraction of 93% increased to above 96% in the presence of additives, but decreased to 94% when, for example, NH4 levels increased from 7 kg/t ore to 21 kg/t ore. The relative stability of the jarosite species formed when additives were present influenced the amount of jarosite in the residue and, hence, both the final free acidity and overall nickel extraction. The use of Cl- versus SO42- salts as additives had little effect on overall nickel extraction or overall free acid values, although the presence of SO42- additives appeared to enhance nickel extraction kinetics over the first 60 minutes of the reaction. In contrast, manganese extraction was enhanced by the presence of Cl- additives.

Jan 1, 2004

By R. W. Thompkins

"PREFACEThis paper will be published in three parts. Part 1, in this issue, will cover the occurrence of uranium, radiation from uranium ores, the uranium series, radioactive theory, radioactive equilibrium and application to the radon series, the working level, the theory of emanation and diffusion, transport by thermal diffusion of radon emanating from porous rocks, and definitions.Part 2, to appear in the October issue, will deal with radiation theory applied to uranium ores, other radon migration factors , fact ors affecting the radon gas release rate, measurement of radon gas emanation rates, the tunnel concept, variation of emanation rate with grade, and estimating radioactivity from grade analysis.The series will conclude with Part 3, in the November issue, which will discuss the techniques for controlling radiation and give some example calculations.1.0. Occurrence of Uranium1.0.1. Uranium is widely distributed in nature. Sedimentary rocks contain less than igneous or metamorphic rock s and as the outer 10 miles of the earth's crust is composed of 95 per cent igneous and 5 per cent sedimentary rock, it has been estimated that about 1.3 x 1014 tons of uranium exist in the earth's crust.1.0.2. It is not surprising, therefore, that radiation has existed naturally in the ear h ever since the beginning of time. It is found in such places as:(1) non-uranium mines;(2) houses not close to or connected to uranium mines;(3) ground-water tables supplying drinking water to large populations.1.0.3. All mines do not necessarily have abnormal radiation in them, but it is possible for many mines to have abnormal levels of radiation. Therefore, all underground mining operations should be tested for radiation."

Jan 1, 1982

By Ernest Becker

Golder Associates provided overall radiological direction and assistance to the client in their interactions with the Canadian Nuclear Safety Commission and operational radiation protection services for the remediation of a calciner that had been used to process uranium. The project was somewhat unusual in that the radioactivity from within the calciner room was removed from the site and the cleaned steel recycled. The presence of yellowcake within the process equipment required stringent radiation protection measures. This project was completed successfully with minimal radiation exposures to the workers and the effective protection of the environment.

Aug 1, 2010

By P. Lostritto, G. E. Agar, G. Labonte, M. Cherevaty

"A locked cycle flotation test was done on a sample from the ovoid portion of the Voisey 's Bay copper-nickel sulphide ore. The chemical conditions for this test were generated by prior independent testing. In this test work the time in each of the five separation stages was optimized prior to executing the locked cycle test. A numerical simulation of the continuous circuit material balance was done prior to the locked cycle test. The test results were not fully satisfactory because the flotation of pyrrhotite in the bulk rougher and cleaner stages was not consistent. The preliminary indication was that the samples had oxidized to varying degrees during storage.INTRODUCTIONINCO has performed batch laboratory flotation testing on ore from Voisey's Bay which is a mixture of chalcopyrite, pentlandite and pyrrhotite. Earlier, Lakefield Research was contracted by Diamond Field Resources to test the ""flotability"" of the ore, which included a pilot plant trial. INCO's J. Roy Gordon Research Laboratory has repeated many of the batch tests that Lakefield did to verify their results. Based on their own work, INCO has modified the circuit proposed by Lakefield Research. The modified circuit is based on batch test work, but no locked cycle test (LCT) was done. It is believed that this circuit will produce a copper concentrate at 29-30% copper and a primary nickel concentrate at 15-20% with recoveries of 80% or above.For several years the University of Toronto has been working with INCO to provide ""hands on"" experience for undergraduate students as an Industrial Research Project (IRP). This year, the objective for IRP was to optimize the time for each of the five separation stages for the Voisey's Bay ore then to numerically and experimentally simulate the material balance for a continuous circuit."

Jan 1, 1998

By Y. M. Shneerson, V. M/ Shpaer, E. E. Zhmarin, A. Y. Lapin, E. M. Vigdorchik

This paper describes studies of zinc concentrate oxidizing pressure leaching using the method of mathematical modeling. The concept of a kinetic function was taken as a basis for mathematical modeling of the leaching process. The kinetic function describes dependence of the unreacted component share OJ on the relative time x (the relative time is the ratio of the test duration and the time of complete dissolution). This kinetic function is determined in accordance with the results of batch laboratory tests. The laboratory tests have been carried out on zinc concentrate produced from Kazakhstan zinc-copper ores. Zinc concentrate consisted mainly of three types of minerals: sphalerite (70%), pyrite (13%) and chalcopyrite (10%). Oxidation reactions of sphalerite, pyrite and chalcopyrite have been considered as principal ones. The kinetic characteristics of the process (kinetic function, reaction order, activation energy, duration of complete dissolution of the concentrate components) have been calculated in the course of laboratory tests. The mathematical model was used for estimation of the main technological leaching process parameters (such as process rate, degree of metals extraction, autoclave capacity, heat balance, etc.). Mathematical modeling based on the kinetic function concept allows safe designing of metallurgical equipment and scaling the technology to industrial capacity.

Jan 1, 2004

By D. Fredlund

The decommissioning of uranium tailings facilities often requires the design of a suitable cover system. In northern climatic environments there is a portion each year that can be considered to be ?inactive? while the remainder of the year can be considered to be ?active?. There are numerous engineering design assumptions required when analyzing both the ?active? and the ?inactive? portions of the year. Cover systems are subjected to complex boundary conditions and nonlinear unsaturated soil properties. The proposed paper describes the steps necessary for the preparation and the analysis of a multi-year climatic database for the design of a cover system in northern environments. The paper also explains how climate can be classified and how observed variations from one year to the next can be taken into consideration in cover design. The results of climatic records at two different sites are used to illustrate conditions that need to be taken into consideration when designing soil cover systems.

Aug 1, 2010

By Andreas Zielonka

To meet the increasing demands of the quality and long term stability of technical systems also the applied materials have to full fill higher standards. This is of special importance where the function of a whole system depends on the reliability of the used materials for example for connector systems in automotive, computer and other electronic equipment?s. In most cases for connector systems electro deposited top layers are applied. To improve the quality of the applied layers new electro deposited systems are developed. One important field of research are the development of composite materials as dispersion coatings and multilayer systems. Multilayers are systems with a high number of single inter-layers of different metals or alloys with the wide chance of the alloy composition. As gold is one of the most important contact material for high quality connector systems it is used as basis for the development of multilayer systems. For the electrodeposition of multilayers two different methods can be applied, the single and the dual plating process. As in the dual plating process two different electrolytes are used, the single plating process allows the formation of multilayers from one electrolyte. In the presented research results cobalt and nickel are used besides gold for the formation of the multilayers. The properties of the layers can be influenced in a wide range by the change of electrolyte composition and the process parameters as current density, current waveform, temperature, hydro-dynamic conditions at the electrode surface and by the number and thickness of the inter layers of the deposited materials. The paper describes the fundamentals of the electro deposition of multilayer systems. For the investigation of the properties of the multilayers different techniques are applied. One of the most important parameter are the thickness of the total layer and of the applied sublayers. The thickness of the sublayers can be varied between a few nanometers up to micrometers. The wear resistance, the contact resistance and the plug-in forces are measured as these parameters are important for the technical application of such layers. For the description of the structure composition and surface properties the sample where also investigated by scanning electron microscopy (SEM), energy dispersive x-ray-analyses (EDX) and glow discharge optical spectroscopy (GDOS). The paper shows that the deposition of gold based multilayers is possible and that the properties of such systems can be varied in a wide range what opens new fields of applications of such materials.

Oct 1, 2003

By J. Graham Eby

"This paper describes the development and some typical applications of Wemco's large-capacity flotation machines, the No. 120 and the No. 144, with volumes of 300 and 500 cubic feet, respectively. During the 1960's, it became obvious that low-grade orebodies would be mined at high tonnage rates - plants and grinding mills would be larger, which would create a demand for larger flotation equipment. To meet this demand, Wemco developed a single-mechanism, 300-cubicfoot cell, having five times the volume of the standard No. 66 cell. The average production rate of the No. 66 cell on porphyry copper ore was 100 tpd per cell; and it was our intention that the No. 120 (300-cu. ft) cell would handle 500 tpd per cell, with at least equal metallurgical results and power consumption per ton. The success and industry acceptance of the No. 120 cell has since led to the development of a larger cell, the No. 144, having a volume of 500 cubic feet."

Jan 1, 1972

By Laszlo Imreh, Pierre Trudel, André C. Tessier

"The Siscoe gold mine is ranked as the fourth largest mine in the history of the Val d' Or mining district with a total production of 27.4 tAufrom1929 to 1949. Most of the gold mineralization occurred in quartz veins, hosted in a small (.69 km2) intrusion of altered quartz gabbro known as the Siscoe stock. The southern contact of the Siscoe stock is crosscut by a major shear zone (the ""K"" zone) trending 295/80 NE and from which gold mineralization was also exploited within the limits of the stock. Field and petrographic observations of the Siscoe stock combined with chemical analyses of major, trace and rare earth elements of the stock and its volcanic host rocks (Dubuisson Formation) suggest that:The Siscoe stock comprises four alteration facies formed from a homogeneous precursor: 1) the actinolite - Mg-chlorite facies, characterized by low FeOt,Na2O andTiO2 , and highAlp3 and MgO; 2) the albite- Fe-chlorite facies, containing high concentrations of FeOt and Nap; 3) the Mg + Fe-chloritefacies, which is transitional between the actinolite- Mg-chlorite and albite- Fe-chloritefacies; 4) the carbonate-chlorite facies, which consists of rocks that were subjected to extreme hydrothermal alteration, is spatially associated with mineralized veins and part of the K-zone. The first three facies are depleted in SiO 2, CaO and Au, and enriched in MgO, relative to fresh rocks of the Siscoe stock and the equivalent rocks of the Dubuisson Formation.Hydrothermal fluids introduced mainly along the K-zone ""channelway"" induced three types of element remobilization, resulting in the various alteration facies: 1) redistribution of elements within the stock from one facies to another (e .g., FeOt, Nap, Ti02 migrated from the actinolite- Mg-chlorite facies to the albite- F e-chlorite and Mg + Fe-chlorite facies); 2) remobilization of elements from the intrusive rocks into veins (e.g ., SiO 2 and CaO ); 3) introduction of elements by hydrothermal fluids in rocks of the Siscoe stock (e .g., Al2O3, MgO, H2O, CO2 and FeOt).The Siscoe stock and the Dubuisson Formation form part of the same tholeiitic suite. Similarly, the Bourlamaque batholith and the Val d'Or Formation belong to a single calc-alkaline suite. In view of this relationship, dissimilarities between the petrochemistry of the Siscoe stock and the Bourlamaque batholith suggest that the two intrusions are not co-magmatic.Finally, gold may have been leached from rocks of the Siscoe stock and remobilized into the quartz-carbonate mineralized veins. In order to account for the total production at the Siscoe mine, approximately 1.2 km3 of the Siscoe stock is thought to have been partially leached of its gold."

Jan 1, 1990

By Rick Coleman, Chelvan (Chevy) Veloo

"P.T. Freeport Indonesia's lrian Jaya Operation has been producing copper concentrate continuously since 1972. Numerous ore discoveries and five mill expansion programs have seen the initial milling rate of 7,200 MTPD escalate to the present rate of 125,000 MTPD, producing 2.5 million pounds of copper and 3,500 troy ounces of gold per day. The latest expansion, commissioned in February 1995, incorporates a 34 foot Semi- Autogenous Grinding (SAG) Mill, two 20'x30' Ball Mills, conventional roughing, cleaner column flotation, and attendant upgrades to the existing concentrate pumping and dewatering facilities. This paper will describe the SAG Plant flowsheet, and focus on the key training issues which contributed to a successful plant start-up.IntroductionP.T. Freeport Indonesia's operations in the Ertsberg mining district are located in the Jayawijaya Mountains of Irian Jaya, the easternmost province of the Republic of Indonesia. P.T. Freeport Indonesia (PTFI), the operator, is owned by Freeport MacMoRan Copper and Gold (81.3%), the Government of Indonesia (9.4%), and private Indonesian investors (9.4%). Geographical location, and sailing distances are provided on the attached location map.The operation stretches over 7 4 miles ( 114 km) from the dewatering and concentrate shipping facility at the Port of Amamapare on the Arafura Sea to the Grasberg open pit located at 3400m. The regional geology is covered in detail by Van Nort et al (1991 ), with current proven and probable reserves estimated at 1.13 billion metric tonnes grading 1.30% Copper, 1.42 ppm Gold, and 4.06 ppm Silver. The Grasberg open pit mining operation provides 92% of the mill feed, and is described in detail by Hickson (1991). The remainder of the mill feed is derived from several underground block caving operations. Current production rates provide a mine life in excess of 25 years. However, very favorable geology in the area leads to expectations that additional reserves will extend the life of the operation considerably."

Jan 1, 1996

By Y. N. Zhang

Friction Stir Welding (F SW) is a novel "green" manufacturing technique due to its energy efficiency and environmental friendliness. This solid-state joining process involves a rotating tool consisting of a shoulder and/or a probe. The shoulder applies a downward pressure to the work-piece surface, constrains the plasticized material around the probe, generates heat through the friction and causes plastic deformation in a relatively thin layer under the bottom surface of the shoulder. The rotating probe mainly drags along, plasticizes, and mixes the adjacent material in the stir zone, creating a joint without fusion. Friction Stir Processing (FSP), a variant of FSW, has been developed to manufacture composites, locally eliminate casting defects, refine microstructure and/or improve the associated mechanical and physical properties including strength, ductility, fatigue, creep, formability and corrosion resistance. However, major challenges such as tool design and wear currently limit the use of F SW/P for manufacturing applications, particularly for high melting temperature or high strength alloys. In this review, the FSW/P tools are briefly summarized in terms of the tool types, shapes, dimensions, materials and wear behaviors.

Jan 1, 2011

By A. E. McIlhinney, I. E. Puddington, C. E. Capes, A. F. Sirianni

"Two main problems are associated with the removal of pyritic sulphur from coals. The first is due to the fine state of dissemination of pyrite, which requires grindin1 to a very fine size to accomplish liberation. The second problem is caused by the similar surface chemical characteristics of coal and pyrite, which complicates separatio11 methods based on this property. In the work described here, the problem of fine particle size was overcome by using the selective oil agglomeratioa method developed at the National Research Council of Canada. Recovery of more than 90% of the combustible values was possible, even with particles only a few microns in diameter. Experiments using conventional chemical depressants for pyrite met with little success. It was found, however, that pyrite may be rejected during coal agglomeration through treatment with the iron.oxidizing bacteria, thiobacillus-ferrooxidans. The conditions for maximum pyrite separation are described and possible mechanisms by which the bacteria act are discussed."

Jan 1, 1973

By Jerry Ran

Many large underground mines using the open stoping method have changed their primary applications of consolidated rock fill (CRF) to paste or consolidated hydraulic fill due to considerations of demand in infrastructure and equipment, system reliability, backfill capacity and material sources. However, some smaller or even large mines still use or consider using CRF for backfill purpose due to factors such as capital expenditure, availability or suitability of other fill types or in some cases local regulatory requirements. As demands on CRF applications diminish among major mining companies, there is a lack of recent literature on application of CRF to open stoping in design and operation. There are several methods being used for fill strength design. Results from these methods have been successfully applied to paste or hydraulic fill. However, the design strength for CRF is much higher than that determined by use of these widely accepted methods. In operation, CRF preparation and placement have significant impacts on the quality of placed CRF and therefore the mining performance. This paper reviews the current fill design methods and their applications to open stoping with presentation of the bench marking data, presents fill failure cases and various CRF preparation and placement arrangements and discusses quality assurance and control programs.

Jun 1, 2012

By K. E. Waters, N. Brodusch, R. Gauvin, C. Teng, H. Demers

Rare earth elements play an increasingly important role in renewable energy devices and high-end electronics. In this project, the composition and morphology of REEs-bearing minerals are characterized with a field-emission scanning electron microscope at high spatial resolution and high counts rate using an X-ray silicon drift detector system. High spatial resolution imaging and energy dispersive X-ray microanalysis were applied at low and high magnification to obtain the composition of each phase in the minerals. From the standardless quantitative analysis results, the amount of REEs in each phase was measured and the relationships between those phases were identified.

Jan 1, 2014

By Man-Chao He

One of the critical problems involved in deep coalmines is unusual gas emissions. Many researchers agree that there is a relationship between coal gas emissions and geological features such as tectonics or geological disturbances, gas content, properties of the coal and rock and the mininginduced stress state in the coal seam and rock. Thus, the present paper intends to investigate complex mechanical phenomena during the process of gas emission in underground coal-mines. A program of laboratory testing was undertaken to study the effects of temperature and pressure on mechanisms of gas emission. It must be noted that this paper describes new techniques developed to simultaneously measure deformation and gas pressure, as well as flux during the test, taking the characteristics of gas transport into consideration under certain temperature and pressure conditions. The results indicate that under certain temperature and pressure conditions, gases adsorbed to coal start to desorb, and increase the pore pressure. High pressure gases entering coal fractures can generate high tensile stresses near the crack tips, leading to crack propagation and coalescence, which in turn can cause the specimen to dilate. From the experimental viewpoint, these test results may help us discern why mining seismic events can trigger gas emissions.

Aug 1, 2013

By T. Lamb

There are many honor stories about aluminum in the marine environment and many are not based on facts, so they are myths. Myths must be addressed before progress can be made. This paper attempts to dispel the myths and state the facts. A common perception is that aluminum ships cost significantly more than steel ships. This paper illustrates that even though the cost of the aluminum structure is over 50% more than the steel structure, an "equivalent" aluminum naval ship can be built within 7% of the acquisition price of a steel ship. This is possible because of the cascading benefits of the aluminum ship's significantly lighter weight. Aluminum ships also have a life-cycle cost advantage over steel ships because of reduced maintenance and fuel cost savings.

Jan 1, 2011

By Donka H. Andreeva

Gold catalysts based on different supports, titania, zirconia, ceria and mesoporous titania and zirconia, nonpromoted and promoted by vanadia in the reaction of complete benzene oxidation have been studied. XRD, HRTEM, TPR, Raman and ESR spectroscopy were applied for the characterization of the catalysts. The influence of gold on the reduction behavior, state and structure of vanadia on the surface was studied, as well as the role of supports nature on the properties and catalytic activity. A strong synergistic effect between gold and vanadia was observed for the all studied catalysts with an exception of the catalysts supported on mesoporous zirconia. In the last case the catalysts containing gold and gold-vanadia exhibit high and equal catalytic activity. The catalysts on ceria show highest and stable catalytic activity in the studied reaction among the all studied catalysts.

Oct 1, 2003

By B. MohammadSadeghi, S. Bakhshivash, M. Haghshenas, F. Rahimi

"Spring-Back/Forward in sheet metals is defined as recovery of elastic strain upon unloading in a deformed sheet specimen. Since this phenomenon can cause alternation in the dimensions of a part, leading to irrecoverable compensations, the operative parameters need to be investigated, thoroughly. To assess spring-forward and effective bending parameters, V-shaped bending dies are the most commonly used experimental approach. In the present research, the effect of bending angle and punch tip radius on the spring-forward behavior of an Al-Mg-Si alloy sheet specimen is studied. To this end, a V-shaped die with four bending angles (i.e. 30°, 45°, 60°, and 90°) was designed and fabricated. Specimens with thickness of 2 mm were cut with dimensions of 50 mm×10 mm. Results show that by increasing the bending angle, the spring-forward angle decreases. In addition, smaller punch tip radiuses lead to further spring-forward. The effect of these parameters on the amount of spring-forward angle, strain distribution and homogeneity along sheet thickness was assessed using finite element analysis (FEA). Simulation results show that as the bending angle increases, the strain is developed more homogenously. Finally, micro-hardness test was used to study the effect of strain hardening caused by bending operation on strength evolution. Results show higher hardness trends for the zones in which the maximum plastic strain occurs.INTRODUCTIONPrecise production plays a significant role in the durability of a part. When it comes to sheet metal forming, this issue should be taken into account as an important factor. In order to predict the alternations, bending dies with special geometric parameters (i.e. V-shaped, U-shaped and L-shaped dies) are commonly used (Wagoner, Lim, & Lee, 2013)."

Jan 1, 2016

By Floyd Smith

Based on underground observations made in .the coal mines of the Dominion Coal Company Ltd., this paper deals with the stress phenomena in the approach roads and headways and in the gob areas associated with the longwall method of total extraction. The deformation of roadways during development and the deformation of roadways during the total extraction period is delineated and presented in graphical form .. Conclusions are made as to the feasibility of the introduction of the retreat method of longwall extraction in one of the colhenes. The importance of future studies are enumerated, especially. those pertaining to the determination .of the opti.m.um sizes of protective pillars and to increasing the efficiency of the current methods of artificial roadway support.

Jan 1, 1967

By H. Sipilä, H. Vartiainen, H. Paarma

"The carbonatite massif of Sokli includes several low-grade Nb showings composed of ores and wastes as identified by routine analyses. More detailed lithologic proportions were determined in two orebodies in the Kaulusrova Nb-mineralized area by a careful geological study and by thorium radiation measurement on 10 cm-long drill core cuttings with a total length of 460 metres. The distribution of Nb in eight X-ray spectrometrically analyzed drill core sample intervals (totalling 35.8 m) was determined by analyzing the intervals semi-continuously by an X -MET analyzer. The geological studies suggest that Nb-mineralized bodies are feasible fo r the sorting of are and waste. This was confirmed by the semi-continuous determination of Nb on the X-MET analyzer.IntroductionThe Sokli carbonatite complex is located in eastern Finnish Lapland. The main ore of the carbonatite massif is a regolithic phosphorus ore in the weathered crust. Large-scale geophysical measurements and diamond drillings have also established several niobium showings within the magmatic carbonatites. Owing to the complicated geology of the massif, the niobium showings occur as irregular zones o r areas displaying complicated structure, texture, mineralogy and geochemistry (Vartiainen and Paarma , 1979; Vartiainen , 1980). The tonnages in areas such as this are large but the grades in-situ are low . The most intensely studied niobium showing is the Kaulusrova area.The exploitation of these showings depends on the feasibility of applying a sorting technique to upgrade the feed and to minimize the amount of material to be treated in the concentration plant. These possibilities o n the Kaulusrova area have been viewed by a detailed geological and X-MET an analyzing study."

Jan 1, 1985