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By William E. Newman

Lead mining has been carried on in several localities of the Province of Ontario in a desultory fashion for the past 60 years, but up to 1916 the results have not been of much commercial importance. The most ambitious attempt was made by an English company which built a lead smelter at Kingston, Ont., in 1880 to treat the concentrates from the Frontenac mines. After 2 years' operation, the mines and smelter were abandoned. Up to the present there has not been a sufficient tonnage of concentrates to support an efficient blast-furnace plant and as most of the small properties could not stand the heavy freight and duty charges into the United States, development work has not been carried on in a systematic manner. As a result the industry has languished. At Galetta, in southeastern Ontario, considerable prospecting and development work has been carried on in the last few years and very promising deposits of galena have been found in the Chats Island group by the James Robertson Co., Ltd., of Montreal. The chief deposit is that of the Galetta or Kingdon lead mine, located on Chats Island in the Ottawa River about 5 miles east of the town of Arnprior. The rocks1 in the vicinity of the mines consist of an interbedded series of crystalline limestone and biotite gneisses of pre-Cambrian age. This part of the Ottawa River basin has been severely faulted and the overlying Paleozoic limestones may be seen in normal fault cantact with the pre-Cambrian. The vein filling is of a very well-marked fault fissure type and although the amount of displacement is not determined at this point, similar faults to the east show a displacement of from 1,500 to 1,800 ft. which would indicate mineralized fault fissures of considerable depth. The ore occurs in a highly crystalline calcite with some barite and fluorite, and the galena occurs more or less richly disseminated in clusters and crystal aggregates. In some cases these masses weigh several hundred pounds. Small amounts of sphalerite are occasionally encountered.

Jan 1, 1918

By Duncan MacVichie

THE iron fields described here are located in the Iron Springs and Pinto Mining districts, Iron County, Utah. This region is in southwestern Utah, about 260 miles south from Salt Lake City, and is reached by the Los Angeles & Salt Lake railroad of the Union Pacific system. The iron fields lie at an elevation of 5500 to 7500 ft. above sea level, and are essentially desert in character. They are covered with a light growth of sage brush, piñon pine, and scattered cedar. Weather conditions are unusually favorable for all-year mining operations, the winters being mild with little or no snow; and the summers not excessively hot, the temperature rarely rising to 100° during the day, while the nights are invariably cool. The iron-ore bearing area extends from the Iron Springs district to the Iron Mountain mining district, being approximately 25 miles long in a northeast-southwest direction, and from 1 to 3 miles wide in a northwest-southeast direction. In the Iron Springs and Pinto mining districts, the ore occurs at various points around three sides of Granite Mountain and Iron Mountain. This is readily understood by reference to Figs. 1-4. These mountains are composed of andesite, which has been forced up through the surrounding sedimentary formation, in the form of laccoliths. An extensive report on the geology of these districts was made by Leith and Harder,1 who state: The three dominating geological features of the district are three large andesite laccoliths which constitute the Three Peaks, Granite Mountain, and Iron Mountain; lying in a northeast-southwest line across the area in question. Three unconformable sedimentary series, aggregating 4000 ft. in thickness, outcrop in successive rings around these laccoliths, dipping outward asymmetrically, very steeply at the contact, less steeply further away. Still farther from the laccoliths, lava-flows 2000 ft. thick rest in nearly horizontal attitudes on the tilted sedimentary rocks. These general relations are modified by faulting. All of the rock formations of the district are more or less covered on the middle and lower slopes by unconsolidated and partly consolidated erosion debris, both aqueous and subaerial, which spreads out on the lower ground to make the deserts.

Jan 7, 1925

By J. R. Eckel

It has long been known that mud properties affect drilling rate and that drilling with water is as much as six to .seven times faster than with mud. However, it is not known why drilling rates with mud are lower. Recent studies show what fluid properties govern microbit drilling rate and also provide a quantitative correlation of these fluid properties and hydraulics with microbit drilling rate. All the microbit tests reported in this paper were made with a low permeability (about 10 md) limestone. They were conducted at constant bit weight and rotary speed with varying fluid properties, flow rate Q and nozzle dinnteter d. The tests showed that (1) drilling rate in a given system with constant circulating rate and nozzle velocity is a function of the kinematic viscosity [viscosity /density, (cp)/ p (density)] of the drilling fluid measured at near bit nozzle shear rates; (2) the combined effect of fluid properties and hydraulics on microbit drilling rate is defined by a Reynolds number function (kQp/dp); (3) for the same kinematic viscosity, drilling rate is independent of solids content; and (4) for the same kinematic viscosity, drilling rate is independent of fluid loss. INTRODUCTION The fact that mudding up reduces rate of penetration is well known, but the reduction varies from well to well. The rate with mud may be 80 percent of the water rate or it may be as low as 15 percent. Since this reduction of up to seven-fold takes place under conditions of constant bit weight, rotary speed and mud circulating rate in a uniform formation, it can only be a result of the change in fluid properties. Previous work1-" both in field tests and in laboratory microbit tests) showed that drilling rate with mud is lower than with water (Figs. 1 and 2). Microbit tests also confirm, at least qualitatively, the field observation that drilling rate slows with increased pressure differential from borehole to formation (Fig. 3). The qualitative effect of drilling rate of bit weight, rotary speed and rate of mud circulation are also the same for the field and microbit rig. For these reasons, the industry generally accepts microbit results as being qualitatively meaningful in terms of field application.

By O. J. Huber

HYDROGEN effects in titanium alloys have been the subject of extensive research in recent years. Lenning, Craighead, and Jaffee1 showed that hydrogen embrittles a titanium and, at the same time, elevates the temperature at which the transition from brittle to ductile failure occurs during impact testing. In later work: the same investigators concluded that several all-ß alloys tolerate large amounts of hydrogen without serious damage to mechanical properties, but two-phase alloys suffer varying degrees of embrittlement, depending upon the specific ß-stabilizing addition used and whether or not an a stabilizer is also present. The mechanism of hydrogen embrittlement has not been clearly established. Strain rate has been shown to be an important factor and, therefore, a strain-aging phenomenon is suspected to cause the effects that hydrogen has produced on mechanical properties.3-5 Ripling6 has pointed out that ductility damage varies inversely with strain rate in a-ß alloys and directly in a alloys. This effect in a alloys can be associated with transition-temperature behavior, but the embrittlemeat mechanism in two-phase alloys remains in question. During the course of research conducted for the U. S. Air Force, a dark-etching phase has been observed at the grain boundaries of certain two-phase titanium alloys after duplex (solution plus aging) heat treatments.5-7 An example of the dark-etching interface phase is shown in Fig. 1. Decrease in ductility accompanies the appearance of the minor phase but has not always been attributable solely to the presence of the phase. Although the dark-etching phase has been observed in alloys under a rather narrow range of heat-treatment conditions, it is of general interest since it is always associated with the presence of hydrogen. The known embrittling effect of hydrogen makes any facet of its behavior of particular importance. The intergranular phase has been observed in titanium-base alloys with relatively high amounts of the ß-stabilizing elements. Specific examples of such alloys include Ti-5 pct Mn-2.5 pct Cr, Ti-3.5 pct Cr-3.5 pct V, Ti-8 pct Mn, and Ti-3 pct Mn-1

Jan 1, 1958

By Charles R. Fettke

The permeability of an oil or gas sand is its capacity for transmitting fluids, either liquids or gases, under pressure. The permeability of a sand depends upon the size and shape of the openings in it and the extent to which these communicate with one another, as well as upon the ratio of their volume to the total volume of the sand. The apparatus employed and the method of procedure used by the authors in conducting the permeability tests have been described in a previous pub1ication.l For the tests described here 1/2-in. cubes were used. They were set in the lower end of a 1-in. union, inserted in a square hole cut in a hard rubber stopper which fitted into the lower end of the union. In the tests with air, volumes were measured with a wet American gas meter of 100 cu. ft. capacity. In those with water, distilled water at room temperature was employed, unless otherwise noted. DescRiption of Sands Tested The tests described in this paper were performed upon 18 samples representing typical oil and gas sands from 7 localities in northwestern Pennsylvania. For purposes of identification, the cores from which the samples came have been designated by capital letters, the sequence of the samples in the cores by numerals, and the individual cubes by small letters. All cubes from the same samples came from adjacent portions parallel to the bedding. Core A of the Bradford sand came from the north central part of the Bradford field, from an area where water-flooding operations have proved highly successful. Core B of the same sand was obtained from the southern part of the field. This core contained a so-called "loose streak," 7.5 ft. thick, in the middle portion of which B2 is a representative sample. The "loose streak" has given trouble in water-flooding but responded favorably to an air-drive, using a pressure of 300 lb. The natural production was increased approximately five times over a period of three years in which the air-drive was in operation. Core C, also of the Brad-

Jan 1, 1931

By C. G. Black

The purpose of this paper is to present data obtained from an investigation conducted on the grindability of coal by the American Society for Testing Materials Tentative Standard ball-mill method. This investigation has been conducted over a period of a year, during which time several hundred tests were run on a wide selection of different coals coming from Pennsylvania, Ohio, West Virginia and Kentucky. The data herewith presented tend to show that the tentative standard ball-mill method might give results that are misleading and that a volume measure might be more indicative of the true grindability of materials of varying specific gravity. A means whereby the time element might be reduced has been studied and other phases of this work such as preparation of samples, mechanical screening, reporting results and duplicating tests have been investigated. It is hoped that all criticism offered in this paper will be taken as constructive, with the purpose ill mind of perfecting the method now tentative to show the true conditions 2nd of making optional the manner in which certain parts of the test might be conducted to meet diversified laboratory conditions. Weight and Volume The results of grindability on extraneous material from the coal scam obtained with the present tentative standard ball mill method indicate easier grinding of these materials as compared to most coals. Varying amounts of these impurities in the coal therefore may cause a raising of the grindability index and may lead to the erroneous conclusion that coals containing large amounts of these foreign materials are easier to grind. For a true comparison of grindability, it would seem necessary to grind to the same particle weight. If material were sized in a commercial mill by means of an air current set at a velocity to remove 1.60 sp. gr. float coal ground to 80 per cent minus 200 mesh, any 1.60 sink particles would be left behind, and in order to remove this 1.60 sink material by the same current it would be necessary to grind finer and produce a

Jan 1, 1936

By C. G. Black

The purpose of this paper is to present data obtained from an investigation conducted on the grindability of coal by the American Society for Testing Materials Tentative Standard ball-mill method. This investigation has been conducted over a period of a year, during which time several hundred tests were run on a wide selection of different coals coming from Pennsylvania, Ohio, West Virginia and Kentucky. The data herewith presented tend to show that the tentative standard ball-mill method might give results that are misleading and that a volume measure might be more indicative of the true grindability of materials of varying specific gravity. A means whereby the time element might be reduced has been studied and other phases of this work such as preparation of samples, mechanical screening, reporting results and duplicating tests have been investigated. It is hoped that all criticism offered in this paper will be taken as constructive, with the purpose ill mind of perfecting the method now tentative to show the true conditions 2nd of making optional the manner in which certain parts of the test might be conducted to meet diversified laboratory conditions. Weight and Volume The results of grindability on extraneous material from the coal scam obtained with the present tentative standard ball mill method indicate easier grinding of these materials as compared to most coals. Varying amounts of these impurities in the coal therefore may cause a raising of the grindability index and may lead to the erroneous conclusion that coals containing large amounts of these foreign materials are easier to grind. For a true comparison of grindability, it would seem necessary to grind to the same particle weight. If material were sized in a commercial mill by means of an air current set at a velocity to remove 1.60 sp. gr. float coal ground to 80 per cent minus 200 mesh, any 1.60 sink particles would be left behind, and in order to remove this 1.60 sink material by the same current it would be necessary to grind finer and produce a

Jan 1, 1936

By Olin G. Bell

The year 1934 in Southwest Texas was marked by aggressive development and exploratory work and resulted in the finding of five new fields and a new producing horizon in one of the older fields. This activity is the result of a reasonable market outlet for production, on both oil and gas, and the fact that drilling and operating costs are reasonable and that possibilities of finding new productive areas are rather high. A large part of the area is prospective and very little, if any, satisfactory surface geological work can be done. This, together with the possibility of finding new productive areas, stimulates wildcatting throughout the counties under discussion. Development work continued actively in all of the newer fields. Exploratory work was most intense in Duval, McMullen, Starr and Zapata counties. The activity in Duval and McMullen counties was the result of persistent efforts to find new trends of production similar to and perhaps associated with the Government Wells group of fields. The activity in Starr and Zapata counties was stimulated by the discovery of the Sam Fordyce field in Hidalgo County as well as the continued effort to find new productive trends southeastward from some of the older fields in northeastern Zapata County and western Jim Hogg Comity. Statistics on production are shown in Tables 1 and 2. New Fields Lopeno.—The Lopeno gas field in the southwestern part of Zapata County was opened in August, 1934, by R. B. Morrison No. 1 Ramirez. This is an anticlinal structure mapable in Claiborne beds and the producing horizon is the Queen City sand at 2100 ft. in the Upper Mt. Selman. At the close of the year only two gas wells had been completed but drilling operations were in progress on several other wells and a gas line was being laid to the field so that withdrawals from the area will begin early in 1935. Comilas.—The Comitas field was opened by Merle Gunby No. 1 Haynes in a sand at 800 ft. in an area southwest of the Escobas field. The discovery well had an initial production of only about 16 bbl. of oil

Jan 1, 1935

By R. V. Whetsel, V. R. Garfias

Production of crude petroleum in Mexico during 1936 totaled approximately 40,309,000 bbl., showing a negligible increase over the previous year. While only four producing wells were completed in the Poza Rica area in 1936, its production increased from 9,468,000 bbl. in 1935 to 13,417,000, making it the ranking producing field in Mexico. This gain in output, however, was offset by abnormal losses due to artificial curtailment mainly the result of strikes and other disturbances in the heavy-oil district of the Northern fields, which declined 2,500,000 bbl., and in the South fields (Golden Lane), where output decreased 1,500,-000 bbl., while production in the Isthmus of Tehuantepec fields remained practically stationary. Production of natural gasoline for 1936 is estimated at 800,000 bbl., or 200,000 bbl. greater than in 1935. Crude run to stills in local refineries increased about 1,000,000 bbl., totaling 31,000,000 bbl. for 1936. Exports of crude and refined products were approximately 24,400,000 bbl., or over 2,000,000 bbl. greater than in 1935, the increase representing withdrawals from storage in Mexico. Exclusive of ships' bunkers, domestic consumption increased about 1,000,000 bbl. during the year, reaching an estimated total of 15,200,000 bbl. The Mexican domestic demand for gasoline is estimated at 2,540,000 bbl. for the year, an increase of 310,000 bbl. over 1935. In all, 70 wells were completed in Mexico during 1936, as compared to 74 in 1935 and 148 in 1934. In proven areas 59 completions resulted in 31 producers and 28 failures. Unusual results were obtained during the year over a scattered area in northeastern Mexico near the United States border, where out of eight completions six were fair-sized gas wells. A wildcat dry hole was completed in Chocoy in an attempt to extend the Northern fields to the northeast, and another in Quebrache, to the southeast of the heavy-oil district. A deep test (10,168 ft.) through the Cretaceous lime into the Jurassic was completed as a dry hole in Metlal-toyuca, 9 miles southwest of the Old Alamo field on the Golden Lane.

Jan 1, 1937

By William A. Longacre

In a previous paper the author discussed the problem described by the title of this paper, outlining and reviewing the Gish-Rooney method, with comparison and brief analysis of the interpretation techniques of Roman2 and Tagg.3 Some aspects of the simple type of two-layer system were reviewed from various sources.4, 5, 6 The Two-layer Problem For the configuration shown in Fig. I, and for any electrode separation A, the SurfAce of earth p, DepthH i P2 Infinite depth Fig. i.—Two-Layer system. apparent resistivity is a function of the relative depth the overburden resistivity pl, and a factor K defined by the equation P2 + P1 where p, is the resistivity of the lower bed. Thus, by the known theory of electrical images, p = pi [1+ */(*-7)] where The Multilayer Problem As the number of isotropic, homogeneous, horizontal layers increases, the difficulties of interpretation multiply. The theory becomes much more involved, and in view of the state of our knowledge, the general problem is virtually impossible of exact solution. However, certain types of multilayer problems can be worked out in terms of two-layer theory. Humme1,7 Pirson,8 Tagg,3 Watson,9 and others have pointed out the possibility of building up approximations of multilayer resistivity curves with suitable combinations of two-layer curves. Many three-layer curves can be constructed in this way to a good degree of accuracy, and special types of four-layer curves can be approximated. It is very likely that as the number of layers increases, the method of combination will not give good approximations except in very special cases. In the analysis of actual field data, the author has found that many obviously multilayer curves can be solved partially with a good degree of accuracy, using the theory that thin adjacent beds may be considered as one layer or zone, and applying two-layer theory to the extremities of the field curve. Modified Tagg Method of Interpretation Tagg's second method, though superior to his first, necessitates a large number

Jan 1, 1946

By W. L. Phillips

Aluminum and copper single crystals were strained in shear, unloaded and rotated 60, 120, and 180 deg. The magnitude of the Bauschinger strain increased rapidly during the easy glide region and became constant as the easy glide limit was reached. An increment in stress was not required to continue slip in any close-packed plane or in the reverse direction during easy glide. A qualitative theory is proposed to explain the present results. FOLLOWING the initial work on tin by Bausch,' there have been several investigatorsB7 who have employed the shear test to study the deformation of aluminum. In all cases the shear technique was employed in an attempt to obtain a more homogeneous shear than in the conventional tension test The direct shear technique has the obvious advantage, relative to the tension test, that a crystal may be stressed in any predetermined plane and direction, including the reversal of strain sense. In the present investigation the shear technique was employed with aluminum and copper single crystals and their behavior was studied with respect to deformation in all close-packed directions in the octahedral plane. In contrast to previous investigations, the shear technique was used in an attempt to obtain a stress-strain curve in shear which is identical with the corresponding tension curve and then to use the additional degree of freedom of the shear test to study the mechanical behavior of crystals in all close-packed directions in the octahedral plane. PREPARATION OF CRYSTALS Single crystals 1/2 in. in diam and 6 to 7 in. long, were prepared from aluminum containing 0.001 pct Si, 0.001 pct Fe, and 0.001 pct Zn, by spectro-graphic ana1ysis and from OFHC copper. Crystals were grown from the melt in graphite at a rate of 1 5 in. per hr. The copper crystals were grown under an argon atmosphere. No lineage structure was observed in Laue patterns, though small angle boundaries were present in the crystals. The aluminum and copper crystals were annealed at 640" and 900°C, respectively, for 24 hr and furnace-

Jan 1, 1962

By William A. Longacre

In a previous paper the author discussed the problem described by the title of this paper, outlining and reviewing the Gish-Rooney method, with comparison and brief analysis of the interpretation techniques of Roman2 and Tagg.3 Some aspects of the simple type of two-layer system were reviewed from various sources.4, 5, 6 The Two-layer Problem For the configuration shown in Fig. I, and for any electrode separation A, the SurfAce of earth p, DepthH i P2 Infinite depth Fig. i.—Two-Layer system. apparent resistivity is a function of the relative depth the overburden resistivity pl, and a factor K defined by the equation P2 + P1 where p, is the resistivity of the lower bed. Thus, by the known theory of electrical images, p = pi [1+ */(*-7)] where The Multilayer Problem As the number of isotropic, homogeneous, horizontal layers increases, the difficulties of interpretation multiply. The theory becomes much more involved, and in view of the state of our knowledge, the general problem is virtually impossible of exact solution. However, certain types of multilayer problems can be worked out in terms of two-layer theory. Humme1,7 Pirson,8 Tagg,3 Watson,9 and others have pointed out the possibility of building up approximations of multilayer resistivity curves with suitable combinations of two-layer curves. Many three-layer curves can be constructed in this way to a good degree of accuracy, and special types of four-layer curves can be approximated. It is very likely that as the number of layers increases, the method of combination will not give good approximations except in very special cases. In the analysis of actual field data, the author has found that many obviously multilayer curves can be solved partially with a good degree of accuracy, using the theory that thin adjacent beds may be considered as one layer or zone, and applying two-layer theory to the extremities of the field curve. Modified Tagg Method of Interpretation Tagg's second method, though superior to his first, necessitates a large number

Jan 1, 1946

By H. K. Shearer

Oil production in north Louisiana in 1937 was 28,668,070 bbl., an increase of 1,896,925 bbl., or 7.1 per cent over 1936, as against an increase of 178 per cent from 1935 to 1936. Gas production of 301,148 million cu. ft. from gas wells and 17,330 million cu. ft. of casinghead gas, a total of 318,483 million, was an increase of 33,483 million cu. ft., or 11.7 per cent over 1936. Well completions numbered 716, with 411 oil wells, 175 gas wells and 130 dry holes; compared with 346, 109 and 78, respectively, in 1936. There were 58 wildcat dry holes. In addition to the wildcat producers described and tabulated with the fields, there were two small, shallow gas wells in Sabine and Tensas Parishes, which did not open fields of any present importance. At the close of 1937 there were only five wildcat tests actually drilling, with nine others shut down or temporarily abandoned. Chief interest during 1937 was in development rather than discoveries. The only real discoveries were two deep gas and distillate fields, Bear Creek and Ruston. There were also three completions of gas-distillate producers from deeper formations in old fields, of which the most important was at Cotton Valley, one discovery of oil in a previously known gas sand and five or six extensions of some importance. Geological Section The columnar section in south Arkansas (Fig. 1, p. 317) also applies in north Louisiana, with a few changes noted below. The oldest known formation in north Louisiana is a bed of rock salt. Except on salt domes, only one well at Rodessa has been drilled into this salt, but it has been penetrated by a number of wells in south Arkansas. Salt domes have been discovered near Vicksburg and Hattiesburg, Miss., and a deep well in Limestone County, Texas, has drilled into rock salt. In Louisiana the distance between the "interior salt-dome basin" and a salt dome of the "Gulf Coast salt basin" is hardly 60 miles. In short, evidence is accumulating to indicate that all of Louisiana, with the possible

Jan 1, 1938

By N. W. Ratliff, P. J. Closmann

Production of oil by expansion from a cylindrical reservoir composed of two concentric regions of different properties has been determined as a function of time for a reservoir producing at constant terminal pressure. The parameters involved are permeability, porosity, compressibility and oil viscosity. Results agree with those of a generally accepted method for uniform reservoirs when all parameters are taken as uniform. Cumulative production at any given time is reduced below that of the uniform reservoir when a region of considerably lower permeability adjoins the well; cumulative production increases when a high-permeability region adjoins the well. Curves are presented illustrating quantitative effects of these variations. INTRODUCTION Most petroleum reservoirs can be exploited by release of pressure and consequent expansion of underground fluid. During part of the production history of certain reservoirs by this mechanism, fluid compressibility can be considered small and constant. Cumulative fluid produced by this means as a function of time was calculated for a uniform reservoir by van Everdingen and Hurst.l For certain cases where a production well has been damaged or where an acid treatment has been used, a zone of properties different from those of the reservoir may be created around the production well. In such a case, expansion of the reservoir fluid takes place in a system composed of two concentric cylindrica1 regions of different reservoir properties. Such composite systems were studied in connection with heat flow by Jaeger2 who presented a solution for temperature distribution in a radial system with an infinitely large outer radius. Similar heat flow problems have been studied by other authors Oil production from composite reservoirs was studied for constant production rate by Hurst,4 Loucks and Guerrero,5 and Carter.6 THEORY This work considers constant terminal pressure. Cumulative flow is calculated for a composite bounded system in which no flow takes place across the outer boundary (Fig. 1). Since the flow is considered to be purely radial, the problem involves only one space dimension and time. It is convenient to define the following dimen-sionless pressure drops (Fig. 1).

By Henry B. Smith, S. Paul Lindau

ThREe years ago it was decided by the management to granulate the matte that is produced in the smelter of the St. Joseph Lead Co. at Hereulaneum, Mo., thereby doing away with a large amount of labor in handling the matte and in subsequent crushing. On Mar. 1, 1915, the granulator was put in operation and up to Jan. 1, 1916, 18,735 tons had been granulated. The four blast furnaces have a daily output of about 280 tons of pig lead and 100 tons of matte assaying about 11.0 per cent. Pb. It is expected that projected improvements in roasting methods will eliminate more sulphur from the charge, and cut down the matte-fall to about one-half of the present figure. The blast furnaces are tapped into movable forehearths or settlers, 6 ft. by 4 ft. by 22 in., the slag overflowing into 27-cu. ft. slag cars which are hauled to the dump by electric locomotives. Previous to the adoption of granulation, the matte was tapped from the forehearths into small slag pots which were dumped after cooling. The matte cakes were broken with sledges, and transported to the crushing plant for fine crushing and screening. Here the matte was reduced to 1/4-in. size before being fed to the roaster bins. A Wedge and a Holthoff mechanical furnace are used for preroasting before sintering on the Dwight and Lloyd machines. The matte is returned to the furnaces as an iron flux until the gradually accumulating copper content reaches about 7 per cent., after which it is put aside to be concentrated in a small copper blast furnace, the resultant high-grade matte being sold. When the matte does not settle readily from the slag, two settling devices are often used, the second one being a large catch-pot, which gathers any matte that may overflow from the forehearth, the slag then overflowing from the catch-pot into the slag cars. When full of matte, the catch-pot is removed, allowed to cool, and the contents broken and crushed. a With the present plan of granulating, the matte is tapped into 6-cu. ft. iron ladles. These are transported to the granulating plant by a 5-ton

Jan 1, 1917

By C. Laird, C. E. Feltner

IN previous workif2 we have shown that the steady state cyclic stress response of pure copper tested in the low cycle fatigue range was determined only by the plastic strain amplitude and the test temperature. hus, copper, at any given temperature, has a unique cyclic stress-strain curve independent of prior history. Cu-7.5 wt pct Al, however, showed a stress response for a given plastic strain amplitude and temperature which depended sensitively on prior history. From this work we predicted that all wavy slip mode materials, typified by copper, would have a unique cyclic stress-strain curve; whereas all planar slip mode materials, typified by Cu-7.5 pct Al, would not. This prediction has now been tested for a number of materials of widely varying crystal structure and slip character. Wavy slip mode materials studied include: Fe. Al, Cd, disordered FeCo-V, and Cu-3 pct Co (quenched and aged). Planar slip mode materials investigated include: Fe-3 pct Si, ordered FeCo-V, disordered Ni3Mn, ordered Ni3Mn, and Zn. The treatment and properties of these materials are listed in Table I. Cyclic stress-strain curves were determined by controlled plastic strain tests (see Ref. 1 for details) at room temperature for all materials in both the initially annealed and cold worked conditions. The results obtained for iron and Fe-3 pct Si are typical of wavy and planar slip mode materials, respectively. The cyclic stress-strain curves for these materials are shown in Fig. 1 and it can be seen that iron has a unique cyclic stress strain curve while Fe-3 pct Si does not. Aluminum, Cu-3 pct Co, and disordered FeCo-V showed a behavior like that for iron, while Ni3Mn in both the disordered and ordered condition behaved in the same manner as Fe-3 pct Si. These results therefore support the general conclusion drawn in Refs. 1 and 2 that. for wavy slip mode materials, a cyclic mechanical equation of slate it =t.(hcp, i. T) is approximated in which the satura-

Jan 1, 1970

By William Sharp

DISCOVERY of new ore in the Eureka district, Nevada, as a result of bold and persistent exploration based on a geologic interpretation of structure has recently aroused wide comment in mining circles. It may therefore be of interest to the profession to have a summary of the historical background and an account of the recent program of development. The mines of Eureka, discovered in the late 1860's, were the first important silverlead mines in the United States. They have a production record of more than fifty-one million dollars.1 After the ore bodies were apparently bottomed in the 1880's, repeated attempts to find new ore were unsuccessful until 1940, when a diamond-drill hole cut a 40-ft width of sulphide ore 1409 ft below the 841-ft level of the Locan shaft. The next hole cut 30 ft, of ore and three additional holes drilled in 1943 and 1944 showed the ore body to be continuous, Shaft sinking to reach and open up the ore body has been in progress since 1945. GEOLOGY Stratigraphy The ore in the Eureka district occurs in a series of Cambrian sediments which is exposed through a thickness of over 6000 ft. The stratigraphic column is as follows:2 [THICKNESS, FI ORDOVICIAN Pogonip limestone (upper part). Thin bedded limestone with some chert. UPPER CAMBRIAN: Pogonip limestone (lower part). Thin-bedded limestone (with shaly limestone and chert).... 425+ Dunderberg shale. Shale (clay and calcareous shale) and thin bedded limestone340+ Hamburg dolomite. Dolomite and limestonegoo+ MIDDLE CAMBRIAN: Secret Canyon shale. Shale and thin-bedded limestone1,035 Geddes limestone. Carbonaceous, flaggy limestone with some shale partings 335 MIDDLE (?) AND LOWER CAMBRIAN: Eldorado dolomite. Dolomite and limestone2,000 LOWER CAMBRIAN: Prospect Mountain quartzite. Quartzite with occasional inter calated conglomerate and shale 1,660+ The Prospect Mountain quartzite has been subdivided into two formations: Upper part, Pioche shale. Shale, quartzite with some intercalated limestone (Lower Cambrian fossils)-200 ft. Lower part, Prospect Mountain quart zite proper-I,460+ft. Total thickness6,695+] Much the most productive of these formations has been the Eldorado dolomite, which yielded more than $42,000,000 at Ruby Hill and an additional amount

Jan 1, 1947

By William Sharp

Discovery of new ore in the Eureka district, Nevada, as a result of bold and persistent exploration based on a geologic interpretation of structure has recently aroused wide comment in mining circles. It may therefore be of interest to the profession to have a summary of the historical background and an account of the recent program of development. The mines of Eureka, discovered in the late 1860's, were the first important silver-lead mines in the United States. They have a production record of more than fifty-one million dollars.' After the ore bodies were apparently bottomed in the 1880's, repeated attempts to find new ore were unsuccessful until 1940, when a diamond-drill hole cut a 40-ft width of sulphide ore 1409 ft below the 841-ft level of the Locan shaft. The next hole cut 30 ft, of ore and three additional holes drilled in 1943 and 1944 showed the ore body to be continuous, Shaft sinking to reach and open up the ore body has been in progress since 1945. Geology Stratigraphy The ore in the Eureka district occurs in a series of Cambrian sediments which is exposed through a thickness of over 6000 ft. The stratigraphic column is as follows:2 Thickness. Ft Ordovician : Pogonip limestone (upper part). Thin bedded limestone with some chert. Upper Cambrian: Pogonip limestone (lower part). Thin-bedded limestone (with shaly limestone and chert).... 425 + Dunderberg shale. Shale (clay and calcareous shale) and thin-bedded limestone............. 34°+ Hamburg dolomite. Dolomite and limestone.................... 900+ Middle Cambrian: Secret Canyon shale. Shale and thin-bedded limestone........ 1,035 Geddes limestone. Carbonaceous, flaggy limestone with some shale partings................ 335 Middle (?) and LoweR Cambrian: Eldorado dolomite. Dolomite and limestone.................... 2,000 Lower Cambrian: Prospect Mountain quartzite. Quartzite with occasional intercalated conglomerate and shale 1,660+ The Prospect Mountain quartzite has been subdivided into two formations: Upper part, Pioche shale. Shale, quartzite with some intercalated limestone (Lower Cambrian fossils)-200 ft. Lower part, Prospect Mountain quartzite proper- 1,460Sft. Total thickness................ 6,695 + Much the most productive of these formations has been the Eldorado dolomite, which yielded more than $42,000,000 at Ruby Hill and an additional amount

Jan 1, 1949

By William Sharp

Discovery of new ore in the Eureka district, Nevada, as a result of bold and persistent exploration based on a geologic interpretation of structure has recently aroused wide comment in mining circles. It may therefore be of interest to the profession to have a summary of the historical background and an account of the recent program of development. The mines of Eureka, discovered in the late 1860's, were the first important silver-lead mines in the United States. They have a production record of more than fifty-one million dollars.' After the ore bodies were apparently bottomed in the 1880's, repeated attempts to find new ore were unsuccessful until 1940, when a diamond-drill hole cut a 40-ft width of sulphide ore 1409 ft below the 841-ft level of the Locan shaft. The next hole cut 30 ft, of ore and three additional holes drilled in 1943 and 1944 showed the ore body to be continuous, Shaft sinking to reach and open up the ore body has been in progress since 1945. Geology Stratigraphy The ore in the Eureka district occurs in a series of Cambrian sediments which is exposed through a thickness of over 6000 ft. The stratigraphic column is as follows:2 Thickness. Ft Ordovician : Pogonip limestone (upper part). Thin bedded limestone with some chert. Upper Cambrian: Pogonip limestone (lower part). Thin-bedded limestone (with shaly limestone and chert).... 425 + Dunderberg shale. Shale (clay and calcareous shale) and thin-bedded limestone............. 34°+ Hamburg dolomite. Dolomite and limestone.................... 900+ Middle Cambrian: Secret Canyon shale. Shale and thin-bedded limestone........ 1,035 Geddes limestone. Carbonaceous, flaggy limestone with some shale partings................ 335 Middle (?) and LoweR Cambrian: Eldorado dolomite. Dolomite and limestone.................... 2,000 Lower Cambrian: Prospect Mountain quartzite. Quartzite with occasional intercalated conglomerate and shale 1,660+ The Prospect Mountain quartzite has been subdivided into two formations: Upper part, Pioche shale. Shale, quartzite with some intercalated limestone (Lower Cambrian fossils)-200 ft. Lower part, Prospect Mountain quartzite proper- 1,460Sft. Total thickness................ 6,695 + Much the most productive of these formations has been the Eldorado dolomite, which yielded more than $42,000,000 at Ruby Hill and an additional amount

Jan 1, 1949

By W. O. Philbrook, K. M. Goldman, G. Derge

T. Rosenqvist—The most interesting point in this paper is the observed transfer of iron into the slag in the initial stage of the desulphurization process, after which the iron again is reduced to the metallic state. The authors interpret this observation as showing that the sulphur enters the slag as an iron-sulphur compound which subsequently is decomposed by the slag. The present writer has previously suggested the following equation for the desulphurization process: S + O2- ? S2- + O For equilibrium in the blast furnace the oxygen potential is defined by equilibrium with graphite and CO of 1 atm pressure: C + O ? CO [2] During the desulphurization process the reactions proceed in the direction of the arrows. If one assumes eq 2 to be significantly slower than eq 1, the transfer of sulphur into the slag, in accordance with eq 1, will build up a local oxygen potential at the metal-slag interface very much higher than that corresponding to the value defined by eq 2. This is possible because the equilibrium oxygen potential in eq 1 is high as long as the sulphur content in the slag is low. This oxygen potential will again be able to oxidize some iron: Fe + O ? Fe2+ + O2- and an increase in the iron content of the slag will be observed. Adding up eqs 1 and 3 one obtains: S + Fe ? S2- + Fe2+ The net effect is thus in harmony with the experimental observation but is obtained without assuming any close ties between the sulphur and iron atoms during the process. Furthermore, it follows from eqs 1 and 2 that when the sulphur content in the slag increases, and equilibrium with C and CO is finally approached, the local oxygen potential at the metal-slag interface will decrease, and the iron in the slag will be reduced back into its metallic state. C. E. Sims-—The data and conclusions presented in this paper are thoroughly convincing in establishing the mechanism of sulphur transfer from iron to slag as in a blast furnace. The evolution of gaseous CO in step 3 of the reactions given on p. 1112 makes the process virtually irreversible. Assuming that the process is similar in slag-metal systems other than in the blast furnace, it is readily seen why free CaO and re-ducing conditions so greatly favor desulphurization. On the other hand, the very effective desulphurization obtained in oxidizing slags when strongly basic, must be attributed to the relatively high stability of CaS as compared to FeS. The ease and simplicity with which the reactions of classic chemistry agree with the experimental data and explain the mechanism is noteworthy. The concept of molecules of FeS, soluble in both phases (metallic iron is not soluble in the slag), migrating from the iron to the slag and there reacting with CaO, which is soluble only in the slag phase, is clear and uncomplicated. This is likewise true for step 3. Those who would deny the existence of molecules or molecular-type combinations in liquid iron, must strain to provide a mechanism so lucid. In the absence of molecules, the Fe and S exhibit a remarkable collusion. L. S. Darken—The investigation and interpretation of rate phenomena in the range of steelmaking temperatures is a difficult task. Most of the laboratory investigations of steelmaking reactions have been concerned with equilibrium. Having determined the equilibrium, our attention naturally focuses next on the mechanism and rate of approach to equilibrium. The authors seem to have contributed substantially to our understanding of these factors for the case of sulphur transfer. I should like to ask the authors whether they consider that the sulphur transfer reaction is diffusion controlled as many high-temperature reactions seem to be. If so, it would seem reasonable to suppose that the slow diffusion step of the process is the transfer across a pseudo-static layer or film similar to that considered in heat flow problems. As the diffusivity and fluidity are smaller for the slag than for the metal, it may tentatively be assumed that the sulphur gradient exists in a thin layer in the slag adjacent to the slag-metal interface and that the metal and the main mass of slag are each maintained uniform by convection. On this basis the amount of sulphur transferred across unit area per unit time is D p (?S%)/100 ?1, where D is the diffusivity, p the density, (?S%) the difference in percent sulphur on the two sides of the layer, and ?l is the layer thickness. At the beginning of the experiment the main body of the slag and hence one side of the layer contains no sulphur; therefore (?S%) may be replaced by (S%), the sulphur content of the slag at the slag-metal interface, which in turn is equal to L[S%] where [S%] is the sulphur content of the metal and L is the distribution coefficient. The rate of transfer thus becomes DpL[S%]/100 ?l, which the authors designate K[S%]. Equating these two quantities and setting D = 10-6 cm2 per sec, p = 3 g per cm3, L = 40, and K = lo-+ g cm-2 sec-1, it is found that ?l, the film thickness, is about 0.01 cm—a value of the order of magnitude of that found in heat transfer problems in liquids. The uncertainty of the numerical values used leaves much to be desired, but at least it can be said that this calculation tends to support the proposed model involving diffusion through a film. Although this does not seem to affect the general argument, I should like to call attention to the fact that the diffusivity3 of sulphur in hot metal is found (on conversion of units) to be about 10-4 cm2 per sec rather than 104 cm2 per sec as stated by the authors. The three equations written by the authors to express the steps in the overall process of sulphur transfer may alternatively be written ionically as only two Fe + S = Fe++ + S-- Fe++ + O-- + C (graphite or metal) = CO (gas) + Fe where the underscore is used to designate the metallic phase; ionic species are slag constituents. After the authors have so neatly demonstrated that iron and sulphur transfer together (at least initially), this fact seems almost self evident; from eq 4 it is seen that if sulphur acquires a negative charge during transfer

Jan 1, 1951