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Effect of Iron on ash fusion temperature and waterwall deposits FeS, H2S on tube material corrosion and erosion [ ]

Jan 1, 2005

By Harold P. Rue

The problem of removing hydrogen sulphide from natural gas has become within the last few years one of major importance to the natural gas and petroleum industry. Several gas fields in the United States produce natural gas containing hydrogen sulphide, and a number of oil fields produce gas which contains hydrogen sulphide. 3 The percentage of hydrogen sulphide in natural gas produced in these fields varies from a fraction of 1 per cent t6 as high as 20.5 per cent by volume. 4 Hydrogen sulphide is probably the most toxic gas associated with natural gas,5 and from the standpoint of health and safety it is important that the hydrogen sulphide be removed if the gas is to be used for domestic purposes. Hydrogen sulphide, besides being toxic and therefore a hazard to animal life, is under certain conditions an active corrosive agent and very destructive to equipment. 6 The annual loss caused by the corrosive action of hydrogen sulphide on equipment amounts to hundreds of thousands, perhaps millions, of dollars. 7 The largest percentage of natural gas produced in the United States comes from wells which also produce oil. This associated gas invariably carries with it light fractions of petroleum, which when separated from the gas, condense to the liquid form at ordinary temperatures and pressure. Commercial application is made of this natural condition, and "wet gas" is processed to obtain so-called natural gasoline by employing the principles of absorption, adsorption, or compression and subsequent expansion accompanied by cooling. In the manufacture of natural gasoline from wet gas which contains hydrogen sulphide, if this contaminating gas is not first removed, some of the hydrogen sulphide may oxidize to form free

Jan 1, 1932

As in other countries, gold mining inNew Zealand has been cyclic in character. Looking at these cycles may provide insights as to what may occur in the future and that is the basis for this study.   New Zealand has experienced four gold mining cycles. The first began in 1857, peaked in 1866 and terminated in 1890. This cycle was characterised by alluvial gold mining by individuals and small groups. This is referred to as the Labour Led cycle. The second cycle began in 1890 and reached its peak in 1906 and terminated in 1929. This cycle was characterised by the use of dredges in alluvial gold mining and was also the peak of hard rock mining. This cycle is referred to as the Technology Led Cycle. The third cycle peaked in 1940. This cycle was far less significant than the previous cycles, arising out of the depression when the unemployed embarked on small scale alluvial mining. This overprinted the continuing decline that occurred after 1906. This cycle is here referred to as the Depression Overprint Cycle.   The fourth cycle began in 1984 when production began to climb rapidly from a very low base. The growth in production was spurred by rising gold prices in the early 1980s resulting in relatively low grade gold-bearing alluvial ground becoming economic. But in the 1990s, production from the new hardrock mines in Coromandel and Otago has overshadowed alluvial production. This cycle is here referred to as the Price Led cycle.   What are the future prospects for gold in New Zealand? Although there are many factors involved, this will be largely determined by two factors; firstly, continued access to prospective gold-bearing properties, and secondly, the price of gold. Based on these factors, three future industry scenarios have been developed. The first of these is industry collapse, in which access to prospective property is constrained and prices mayor may not weaken. The second is industry consolidation, in which the available ground is accumulated by a small number of large companies who can use economies of scale to weather price fluctuations. The third scenario is industry growth, in which access to prospective ground is constrained in environmentally sensitive areas but is otherwise relatively unconstrained. Efficient companies are allowed to work in a policy and economic framework that allows them to make a major contribution to the economy.   While the industry cannot control these critical factors, a good knowledge of the positive role gold mining could play in the future economy may provide a framework by which the access issue, in particular, may be addressed from a balanced perspective.

Jan 1, 1994

Plant based on the New Jersey refluxing process was installed at the Cockle Creek Works of Sulphide Corporation Pty. Ltd. to refine portion of the zinc output from the Imperial Smelting furnace.Refining of impure zinc is effected by distillation in two stages in vertical columns comprising a series of superimposed silicon carbide trays designed such that ascending zinc vapours and descending liquid metal are in intimate contact. In the first stage, portion of the zinc and its cadmium content are distilled from impure feed metal, condensed, and while still molten, fed to the second column in which zinc is boiled under controlled refluxing conditions to remove the cadmium content.The resultant zinc has a purity in excess of 99·995 per cent zinc.The availability of refined zinc has made possible the production of a number of zinc alloys for marketing in addition to the basic grades of zinc.

Jan 1, 1970

This paper reviews the development and operation of a small underground tin mine in NE Tasmania. Tin mineralisation was discovered in the Lottah area in the 1880s with early alluvial and eluvial workings leading to the development of large low grade open pit operations. Apart from short lived activities operations ceased in 1915. Intensive exploration in 1978 - 1981 outlined substantial tonnages of low grade tin mineralisation (0.2% Sn) of open pit material. An underground ore body was also located (800 000 tonnes 0.6 per cent Sn). Spectrum Resources Australia Pty Limited acquired a 98 per cent interest in the property in 1988. Mine and mill development began in early 1989 based on an underground mine utilising trackless mining using room and pillar with fill stoping. The milling circuit involves primary jaw crushing, Barmac secondary crushing to 1 mm, Mogensen and DSM screens with jigs and tables to make a wet concentrate. Final tin concentrates are produced by high tension and magnetic separation. Planned production rates are 500 t/day with a mine life of six to seven years.

Jan 1, 1990

This paper discusses the history and development of the system and the benefits that are being gained for Yabulu from Solar Drying. Following the end of mining of the local Greenvale and Brolga nickel deposits, QNI Yabulu Refinery is dependent upon imported ore from over 15 different mines in New Caledonia, Indonesia and the Philippines.

Jan 1, 2003

By F. G. Pickard

"The Strathcona Concentrator is one of three concentrators presently operated in the Sudbury District by the Nickel Division of Falconbridge Nickel Mines Limited. Production commenced in 1968 at a milling rate of 6,300 tons per operating day. Milling capacity was increased in 1970 to 7,200 tons per operating day. 7he ore contains iron, nickel and copper primarily in the form of pyrrhotite, pentlandite and chalcopyrite, while the common gangue minerals are feldspar, quartz, mica, talc and chlorite. The primary function of the concentrators is not only to liberate sulphides from silicate gangue minerals but also to separate pyrrhotite from the more valuable minerals pentlandite and chalcopyrite.SummaryExcessive wear on steel liners and blinding of grates in a regrind pebble mill of the Hardy Concentrator was corrected by the use of rubber liners and grates. The success of these resulted in their installation as original linings In all grinding units except the rod mills at the Strathcona Concentrator. The operation of rubber liners and grates when sized mine ore was used as the grinding medium was satisfactory confirming the Hardy Concentrator experience. Problems developed when the grinding medium was changed from sized mine ore to steel balls in that blinding of the grates occurred. This resulted in conversion of the units to overflow type mills through removal of the grates. The lifter bar life was significantly increased by using higher lifter bars.Grinding PracticeOperation of a regrind pebble mill commenced in 1961 in the Hardy Concentrator. This operation demonstrated the economic feasibility of using sized mine ore as grinding medium. Problems caused by excessive wear of metal liners and grates combined with blinding of the grates were corrected in 1964 through installation of rubber liners and grates."

Jan 1, 1974

This is the sixth in a series of reports on properties of commercial motor fuels, made in accordance with a cooperative agreement between the Cooperative Fuel Research (C.F.R.) Committee and the Bureau of Mines of the Department of the Interior. The first report gave data on motor gasolines sold during the winter of 1935-36.3/ The present report covers 54 brands of gasoline represented by 1,480 samples plus those from the Pacific Coast, which were averaged by the Pacific Coast Technical Group before being submitted and are published exactly as they were submitted. In some areas reports were received from 8 to 10 companies on the same brands of gasoline, whereas in other areas only one company reported on a brand. Thus, it can be seen that some of the data are more representative than others. The inclusion of data from several cities within some of the districts has improved the report by reducing the number of brands reported by only one company. Several changes have been made in the districts. A new district, Memphis, Tenn., has been formed to include Arkansas and western Tennessee. The Rocky Mountain areas have been divided into three sections. Salt Lake City and Denver form the Middle Rocky Mountain district; Laramie, Wyo., Idaho, Montana, and Spokane, Wash., are included in the North Rocky Mountain district, and Arizona, New Mexico, and El Paso, Tex., have been combined to represent the South Rocky Mountain district. The Cleveland district has been expanded to include Ohio an,"- Indiana. Eastern Pennsylvania, Maryland, and northern Virginia are included in the Washington (D. C.) district. The Atlanta district includes Georgia, South Carolina; Mississippi, and northern Florida.

Jan 1, 1938

By F. Habashi

The phosphate fertilizer industry is at present based mainly on the use of sulfuric acid. This technology results in the generation of large amounts of radioactive gypsum that represents disposal and environmental problems. Also it involves the use of expensive reactors for acidification that necessitates the frequent replacing the damaged agitators. Applying hydrometallurgical techniques such as in-situ, heap, or vat leaching to phosphate processing could solve these problems. In this case, however, nitric acid must be used and dicalcium phosphate (40% P2O5) may be obtained as a final product. It is insoluble in water but soluble in citric acid and is an excellent fertilizer. This technology does not interfere with uranium recovery if desired. In addition it permits the recovery of rare earths which are otherwise lost in the gypsum.

Jan 1, 2011

By A. Sheikh, S. Hardcastle

"Various methods of leaching are being used by Denison Mines Ltd. Uranium Operations. This study was designed to investigate the flood leaching operation of two parallel inter-connected stopes contained by pressure bulkheads. The teaching muck piles, created from large scale uppers production blasts, are aerated by compressed air lines laid beneath the pile prior to blasting.A SFr, tracer gas, injection technique has been employed to determine the post-blast integrity of the single-ended air distribution system. SF6 was injected into the compressed air line feed to the stopes and collected at borehole exhausts from the stopes in grab-sampling bags. Analyses of the air samples were performed with a gas chromatograph.The system was designed to give a sufficiency of oxygen to sustain bacterial activities used to enhance the leaching recovery in the muck piles. The results obtained indicated that there is a minor anomaly in the distribution system that may not be critical to the operation. Compared to an idealized case, the over-all efficiency of aeration throughout the muck is estimated at over 85%."

Jan 1, 1988

By Clyde N. Baker

Foundations for the Sohio Corporate Headquarters in downtown Cleveland have column loads of 11,400 kips, which increase to 15,000 kips with wind loading. An extensive exploratory program was conducted and comprehensive studies made to select the economically dependable support for the 46-story structure. A test on bond or socket friction for the caissons has usable values.

Jan 1, 1984

By John P. Powell

The increasing demands for petroleum and its products and the steadily increasing cost of discovering and developing new oil fields are factors that emphasize the importance of increasing the recovery of oil from known petroleum reserves. Water flooding is a valuable conservation measure, not only preventing premature abandonment of stripper leases but also reviving interest in many areas previously abandoned. The use of water flooding as a means for recovering additional oil from partly depleted oil-bearing formations was first tried in Oklahoma in 1931. Early water-flooding operations were confined to the area of shallow Bartlesville-sand formations in Nowata and Rogers Counties, where many of the projects were outstandingly successful. The results of these operations stimulated activities in other pools in Oklahoma, and by the end of 1949 water flooding had been tried in 25 of the 49 oil-producing counties in the State (fig. 1). Approximately 33 million barrels of oil, or 1,806 barrels per acre, had been recovered by December 31, 1949, from 18,221 productive acres included in the 162 active and abandoned projects in Oklahoma by injection of approximately 449 million barrels of water.

Jan 1, 1952

By F. F. Roberto

Many techniques that are used to characterize and monitor microbial populations associated with sulfide mineral bioleaching require the cultivation of the organisms on solid or liquid media. Chemolithotrophic species, such as Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans, or thermophilic chemolithotrophs, such as Acidianus brierleyi and Sulfolobus solfataricus can grow quite slowly, requiring weeks to complete efforts to identify and quantify these microbes associated with bioleach samples. Real-time PCR (polymerase chain reaction) assays in which DNA targets are amplified in the presence of fluorescent oligonucleotide primers, allowing the monitoring and quantification of the amplification reactions as they progress, provide a means of rapidly detecting the presence of microbial species of interest, and their relative abundance in a sample. This presentation will describe the design and use of such assays to monitor acidophilic microbes in the environment and in bioleaching operations. These assays provide results within 2-3 hours, and can detect less than 100 individual microbial cells.

Jan 1, 2009

By Javier Támara

Para aumentar la productividad de la empresa minera es necesario conocer el sistema de aire -en tanto se prioriza los intereses de los clientes, y así se puede suplir todos los componentes necesarios para garantizar una máxima eficiencia y confiabilidad del sistema completo de aire comprimido que va desde el filtro de admisión hasta el punto de uso. En ese sentido, el presente texto describe las estrategias para realizar Solucionazing en ahorro energético y así aumentar la produtividad de los sistemas de aire.

Aug 25, 2002

By N. Aouad

The deployment of large machinery for low cost, bulk surface mine production operations has resulted in high-impact shovel loading operations (HISLO). In extreme cases, shovels load large dump trucks with 100-ton (or more) passes generating high-impact forces under gravity. HISLO generates high-frequency shockwaves that cause severe truck vibrations exposing operators to whole body vibrations (WBV). Current research study in this area has established that the vibration levels affecting the operator?s seat, lower-back, lumbar and cervical regions fall within the extremely uncomfortable zone compared to the ISO 2631 comfort zone. These results pose health threats to truck operators over long-term exposure to these vibrations. In this paper, the authors will examine engineered solutions to mitigate these health threats.

Jan 1, 2011

By A. W. Khair

Laboratory studies indicate that the specimen size influences the compressive strength of coal significantly. In the past, the diameter/height ratio of coal and rock specimens with different geometry and its influence on failure characteristics was discussed (Khair, 1993; Khair, 1994; Khair and Xu, 1994). In the current attempt, tests are designed and carried out under uniaxial condition in the laboratory to investigate the influence of specimen size. Cubical specimens of coal with edge dimension ranging from 5 cm (2 in.) through 20 cm (8 in.) were prepared according to the standards and tested uniaxially. Results show that compressive strength of coal is dependent on specimen size until certain level and later the change in specimen size would not yield significant change in compressive strength. Cubical specimens were chosen for testing because they are not only in close resemblance to underground pillars, but they are also the most stable shape under loading. The failure characteristics of these specimens were analyzed and their applicability to pillar design aspects in coal mines is studied. A detailed analysis of the physical and mechanical properties of the tested coal seam is also presented.

Jan 1, 1996

By Peter Radziszewski

"Typical mining operating costs can be divided between extraction (30 % to 70 %), comminution (30 % to 50 %) and separation (5% to 20% ). Cornminition process costs, representing an important contribution to mining operating costs, can themselves be divided roughly between energy (50 %) and linerkharge wear (50 %). Developing the ability of predicting mill wear will allow a more accurate estimation of wear costs. However, total media wear in a given ball mill grinding process is a product of three recognized wear mechanisms those being abrasion, corrosion and impact. Further, the contribution to total media wear of each of these wear mechanisms has not been well established. In this paper, a overview of abrasive, corrosive and impact wear mechanisms is made from which an empirical wear prediction procedure is proposed. Further, future directions in wear prediction research is outlined. INTRODUCTIONTypical mining operating costs can be divided between extraction (30 % to 70 %), comminution (30 % to 50 %) and separation (5 % to 20 %). Comminition process costs, representing an important contribution to mining operating costs, can themselves be divided roughly between energy (50 %) and lined-charge wear (50 %). With respect to wear, world wide steel consumption as grinding media is estimated at over 600 000 tomes per annum (Malghan, 1982). As such, developing the ability of predicting mill wear will allow a more accurate estimation of wear costs.Charge media wear prediction is actually estimated using the Bond abrasion test. From Bond abrasion index tests, it is possible to determine a wear rate using the following function:"

Jan 1, 2000

By Filipe Beretta

This study investigates geophysical logging capacity to predict coal quality. It was analyzed for possible correlation, some parameters determined via laboratory analysis of coal against results for the same parameter derived from wireline logs recorded by a geophysical probe. These probes detect variations in some rock physical properties, such as their natural gamma ray emissions and electrical resistivity. Results showed a strong correlation between natural gamma and ash content, establishing a linear model to estimate ash content from geophysical logging data with a low estimation error (less than 5%). Besides, results showed that there is no correlation between sulphur content or volatile matter and resistivity, neither with natural gamma of the rocks. Ash content derived from gamma ray values can be used as secondary information to evaluate coal quality during resources estimation, using methods such as soft indicator kriging. The methodology is illustrated using a case study at a coal deposit in south of Brazil.

Oct 1, 2009

By A. K. C. Chan

Recent hotel investment projects in China often involve very tight programmes for design and construction. An example given in this paper involves a 24-storey reinforced concrete hotel tower with 460 bedrooms and a 3-level podium commercial complex. The building is supported by relatively widely spaced columns and shear walls below which 88 number large diameter piers were excavated through fill, silty and bouldery clay on to dolerite and slate at depths between 15 to 3 0m below ground level. Whereas much experience has been accumulated in Hong Kong, hand-excavated pier foundation was only adopted for the first time in Dalian. This paper describes and discusses the various factors influencing the choice of the type and design of the foundation system. The criteria for determining appropriate founding levels are then explained. During installation, revisions to the acceptance procedure were made to cater for local conditions. Emphasis is placed on the role of the geotechnical engineer in making on-site decisions during construction. The advantage of the foundation system in accommodating on-site changes resulting from local complex ground conditions is demonstrated. The pier foundations were successfully completed ahead of programme.

Jan 1, 2010

"The link between ore texture and mineral liberation has previously been established at a microscopic scale. To construct ore texture models that can be used in mining applications requires this relationship to be retained at a significantly larger scale. This is initially dealt with by finding a basic set of microtextures that form the elements of the ore textures at the next larger mesoscopic scale, simulating these mesotextures at a fine scale, then changing the support of the mesotexture simulations to generate the expected mining block/stope mesotexture distributions. Thus, a mutually exclusive and exhaustive set of spatially locatable mesotextures can be used to fully characterize the metallurgical properties of in situ material.A method that generates expected distributions of mesotextures for any mining block size or shape is proposed, and includes: (1) characterizing the spatial correlation of the set of mesotextures with a single covariance function; (2) generating multiple simulations of mesotextures at a fine scale; and (3) using the simulations at a fine scale to generate the expected mining block/stope mesotexture distributions. A case study, using the George Fisher sediment-hosted base metal deposit in Queensland Queensland, Australia, is developed to demonstrate the proposed methodology as well as show the inadequacy of off-the-shelf approaches.Mining-scale texture models can be used to improve the in situ discrimination of ore from waste by exploiting the joint spatial variability of grades and textures to quantify the expected metal recovery of in situ material, then calculate local marginal cut-off grades. An artificial case study is presented to demonstrate the changes in ore/waste selection when considering ore texture models compared to constant metal recoveries."

Jan 1, 2005