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By Manuel Gomez

Carbon number distributions were obtained for tar acid fractions from five low-temperature tars by low-ionizing voltage mass spectrometry. Quantitative data for phenols representing seven structural compound types were examined by statistical analysis. It was shown that for the phenols discussed, the data could be represented by regression equations expressing phenolic concentration as a function of the reciprocal of the carbon number and the carbon-to-hydrogen ratio of the parent coal. The total concentration of each structural type present was found to depend on the molecular weight and boiling point of the initial member of the group. Carbon distribution data for the tar acid fractions studied support the view that low-temperature tars contain the same chemical compounds but in different proportions.

Jan 1, 1965

By G. W. Elger

The Bureau of Mines conducted laboratory and larger scale studies on samples of domestic perovskite and ilmenite ore concentrates to devise a procedure for recovering TiC from these ores. From the concentrates, mixtures of titanium and calcium carbides were produced. The carbides were then ground and reacted with water. This reaction decomposed the CaC2 to acetylene and hydrated lime and simultaneously liberated the TiC. Using a combination of elutriation and gravity-separation techniques to separate the hydrated lime, approximately 93 pct of the titanium was subsequently recovered as purified carbide containing 54 to 70 pct titanium with CaO content as low as 0,6 pct. This combination of techniques can be used to separate more than 90 pct of the CaO from the TiC. Therefore, this carbiding procedure is a viable method for treating titaniferous materials, including perovskite, that contain more than 20 pct CaO. Tests made in a static-bed reactor showed that for the reaction of TiC with elemental chlorine to produce titanium tetrachloride (TiCI4), a temperature of at least 940° F is desirable to achieve a suitable extraction of titanium in a laboratory chlorination reactor. In fluidized-bed tests at 840° F, 98 pct of the titanium contained in TiC was extracted.

Jan 1, 1980

By J. M. Stuve

Thermodynamic properties were determined by the Bureau of Mines for the intermetallic compound, TiA13. Heat capacities were obtained from 5 to 303 K by adiabatic calorimetry. The derived value of S2 1s is 22.08±0.07 cal/deg¬mole. Enthalpies relative to 298 K were obtained from 298 to 1,413 K by copper-block drop calorimetry. No anomalous thermal behavior was noted in the temperature ranges investigated. Low- and high-temperature data were combined with a known enthalpy of formation at 298 K to give values of enthalpy of formation and Gibbs energy formation, 0 to 1,400 K.

Jan 1, 1974

By Scott W. Hazen, George W. Gladfelter

This report presents the results of an initial investigation into some problems resulting from the use of assays representing unequal sample interval lengths and the use of the weighted average grade of ore in evaluating bedded mineral deposits . A mathematical proof and examples are given to show that the unweighted and weighted assay averages are equivalent when there is no correlation between assay value and sample interval length but that these averages are different when there is correlation between assay value and sample interval length . The amount of this difference between estimates is a function of the degree of correlation . One set of sample and assay data , based on 11 stratigraphic sections of the Phosphoria formation in Idaho , indicates that the relationship between the amount of difference between estimates and the correlation factor is approximately linear . If this correlation relationship can be established , within acceptable limits of precision , as a consistent attribute of deposits , the estimate of weighted average grade of ore could be predicted directly from the unweighted estimate of grade of ore by using the relationship as a prediction factor . Randomness tests on the sample and assay data from the Phosphoria formation , using the mean - square - successive - difference method , indicate that correlation between assay value and sample interval length ( each sample interval length represents an individual bed or stratum of the formation ) , apparently has little effect on the independence between successive assays , between successive sample interval lengths , and between the products of assays and sample interval lengths . Therefore , these data can be analyzed statistically as long as the original sample sections have been selected at random for sampling .

Jan 1, 1964

By J. Douglas Causey

The Bureau of Mines conducted mineral investigations of the Peace Rock and Deadwood River roadless areas in Idaho, in 1992. Literature research was done by the Idaho Geological Survey. The study areas contain black sand placers (thorium, columbium, tantalum, titanium, uranium, and rare earth elements), gold, and molybdenum prospects. Except for unrecorded placer gold, there has been no mineral production from the areas. No mineral resources were delineated, but a multi-million tonne molybdenum resource is in the Big Pine Creek area and a 142 million m' black sand deposit is in the Stolle Meadows, Peace Valley, and Deadwood River areas. The Deadwood mine produced zinc, lead, and silver. There are six mining districts in and adjoining the areas; Warm Lake, Deadwood, Garden Valley/Lowman, Banner, Summit Flat, and Grimes Pass. Few claims, mostly placer, were active in the study area in 1992. The study areas are underlain by granitic rocks of the Idaho batholith. Most of the deposits are alluvial accumulations of heavy minerals weathered out of the Idaho batholith. Stockwork and narrow veins along shears account for the base and precious metal concentrations. Eleven prospects were examined. Workings consist of drill holes, pits and adits. Geothermal resources (hot springs) occur mainly along the Middle Fork Payette River; Vulcan Hot Springs is a designated Known Geothermal Resource Area. Sand and gravel resources are of local interest.

Jan 1, 1993

By James H. Russell

Several solid sorbents were compared for their effectiveness in removing sulfur dioxide from flue gases. The materials were tested for the rate of sorption and capacity at about 300° C, and rate of regeneration around 700° C in thin beds and in 4-inch-diameter fluidized beds. Rates of material loss were also estimated. The sorbents tested included three samples of alkalized alumina, two samples of sodium carbonate-impregnated alumina, and one proprietary sample of porous silica impregnated with copper and iron compounds. The results showed that all the alkalized aluminas had good sorption capacities and rates, required high temperature regeneration, and suffered excessive material loss; the sodium carbonate-impregnated aluminas (1) had high sorption rates but barely adequate capacities, (2) required high temperature regeneration, and (3) suffered excessive material losses; and the copper-iron impregnated silica suffered only slight material loss and could be regenerated at a relatively low temperature, but the sorption rate and capacity were too small. None of the sorbents met all the arbitrary performance criteria that follow: sorption rate constant of 1 min-1, sorption capacity of 0.1 g sulfur per g sorbent, regeneration rate constant of about 0.075 min-1 at a reasonable temperature, less than 0.07 pct per hour material loss during operation, and a chemical life of 500 cycles.

Jan 1, 1971

By M. R. Geer

The use of the cyclone as a dense-medium cleaning device was first described by Driessen6/ in 1945, after development of the process in the Netherlands during the German occupation of World War II. A pilot plant was built in the Netherlands soon thereafter, and the first commercial plant was built in 1948. By 1958, 18 plants were operating or under construction.7/ Thus, economic factors in Europe, where the high cost of coal places a premium on efficient cleaning, dictated rapid adoption of the cyclone. American reception of the process differed. The Bureau of Mines presented the results of its own small-scale cyclone experiments in 1946;8/ showing a sharp separation between coal and impurity; adoption by industry now is taking place. There is now much greater emphasis on the efficient cleaning of fine coal, and the first American cyclone plant has begun operating; others are planned or under construction. With the present interest in improved treatment of fine coal, the Bureau of Mines felt that additional performance data on the cyclone would be helpful to industry. Therefore, a complete, open-circuit pilot plant was built to make cleaning trials on American coals covering a wide range of washability characteristics. Five raw coals and one middling product were included in the investigation, and each was cleaned at several densities; 17 cleaning trials are reported.

Jan 1, 1961

By J. Douglas Causey

In 1986 and 1987, at the request of the Bureau of Land Management, the U.S. Bureau of Mines studied 73,010 acres of the 76,480-acre Lower Owyhee Canyon Wilderness Study Area (OR-003-110) in order to evaluate its identified mineral resources. The study area is in Malheur County, OR, about 8 miles north of Rome. There are approximately 7.7 million tons of subeconomic zeolite (heulandite and/or clinoptilolite) resources with ammonia ion exchange capacities as high as 1.75 milliequivalents per gram in the Chalk Basin-Lambert Rocks area. The bed is 25 ft thick with less than 100 feet of overburden. This resource probably will not be mined in the foreseeable future.

Jan 1, 1989

By R. Hogg

"The basic population balance models for agglomeration processes are reviewed and procedures are described for extending their applicability to systems with size-dependent rate constants and to the formation and growth of porous agglomerates from rigid, solid particles. Simplified procedures for the further extension of the models to include simultaneous agglomerate growth and breakage arc also described. IntroductionThe association of small particles into clusters or agglomerates is a significant factor in many facets of particle processing. Agglomeration processes are widely used to facilitate handling, storage and utilization of fine powders. Processes such as coagulation or flocculation are used to aid solid-fluid separation in dispersed particulate systems. Agglomeration also occurs as an accompaniment, often unwanted, to other particulate processing operations such as fine grinding, mixing and blending, transport and flow.Reliable agglomeration models are needed for improved understanding of the processes in general and of the complex role of numerous, interacting variables as well as for direct application to the design and control of industrial processes such as flocculation, granulation and pelletization. Ideally, the models should account for the primary forces responsible for agglomerate ·formation and growth, the effects of external forces on process dynamics, the development of agglomerate structure and its role in the process itself, and the effects of concurrent processes such as structure modification (e.g. compaction) and agglomerate breakage or degradation.In its most general form, the process of agglomeration involves taking discrete, independent particles, bringing them into contact with one another, promoting (or allowing) interparticle adhesion to occur and then causing structure rearrangement, usually under the action of external forces. The relative importance of these steps varies with the nature of the particulate system being agglomerated and with the kinds of agglomerates being produced. Coagulation or flocculation of particles dispersed in fluids is generally dominated by the contact and adhesion steps. In the granulation of powders, on the other hand, particles are already in contact so that structure rearrangement is the principal step."

Mar 1, 1992

By Aarne Visnapuu

Dissociation and vaporization of gold chlorides and bromides were investigated by a static pressure method and by Knudsen cell mass spectrometer. Two distinct chlorine and three distinct bromine pressure-temperature relation-ships were observed for the respective salts. The chlorine pressures are attributed to the dissociation of Au2Cl6 and Au2C12, and the bromine pressures to the dissociation of Au2Br6, Au2Br4, and AU2Br2, These pressure-temperature relationships were used to calculate dissociation pressure equations, enthalpies, and entropies of dissociation for each salt. Mass analysis of the vapors over AU2Cls between 83° and 152° C confirmed the existence of gaseous AU2C16. Ionization potential of this molecule is 11.0±0.1 ev and enthalpy of vaporization is 28.l±2.0 kcal/mole. Mass analysis of the vapors over the gold bromides detected only Bra in the temperature range 15°-150° C.

Jan 1, 1971

By Louis C. Brichta

The rapid; depletion of' known high-grade ore deposits in the Tri -State lead-zinc district and the recognized need for the development of additional reserves led the Bureau of Mines to make preliminary examination of sites possibly adaptable to low-cost open-pit mining methods. Abandoned mines whose ore deposits were known to have occurred at shallow depths naturally presented favorable test points for the development of possible open-pit orebodies. The Lone Elm mine was in this category.

Jan 1, 1949

By R. V. Ramani, R. L. Frantz

"The U.S. Bureau of Mines (USBM) established on August 15, 1983, a Generic Mineral Technology Center (GTC) for Respirable Dust within the Mining and Mineral Resources Research Institutes (MRls) at The Pennsylvania State University (PSU) and West Virginia University (WVU) in association with participating MRis at Massachusetts Institute of Technology (MIT) and the University of Minnesota (UMN). The primary goal of the Center is to reduce the incidence and severity of respirable dust disease through researching and advancing the fundamental understanding of all aspects of respirable ~~9t associated with mining and milling and the interaction of dust and lungs. Other Center activities include the training of engineers and scientists, graduate students and undergraduate students through their respective institutions, and the technology transfer to the industry. The Center also serves as the reference center for publications in the respirable dust area. IntroductionExposure to respirable contaminants in mine atmospheres has long posed a serious hazard to miners. The control of these hazards, some of which can have sudden and catastrophic effects and some others, slow and long enduring consequences, has been a major concern for labor, management and government alike. This concern has manifested itself in four primary mechanisms of control -- (1) regulatory control through minimum standard setting by the passage of mine health and safety laws, (2) engineering control through design and operation of mines according to the best recommended practices, (3) interaction of dust and lung control through periodic physical examinations, wearing personal protection devices, etc., and (4) legal and social control through workmen's compensation laws for occupation related health deterioration.The stated objective of the Federal Mine Safety and Health laws is to"" permit each miner the opportunity to work underground during the period of his entire adult working life without incurring any disability from pneumoconiosis or any other occupation-related disease ."" Significant progress has been made in lowering the dust levels in mines since the inception of the Bureau's respirable dust research program. It is generally agreed that mines are less dusty today than they were a decade ago. However, the most serious hazard for workers in the mining and minerals processing industries is still the exposure to respirable dust, and solutions to the problem of respirable dust disease remain to be found."

Mar 1, 1989

By Michael J. Magyar

The Federal Bureau of Mines has developed a hydrametallurgical method to recover aluminum, aluminum oxide, and fluxing salts from aluminum salt slags. The slag is leached with water at room temperature to produce a saturated brine slurry. Screening of the slurry yields an aluminum-rich fraction that can be returned to the dross furnace. The remaining slurry is vacuum filtered, yielding a clear brine solution and an aluminum oxide filter cake. Evaporation of the clear filtrate produces a high-purity fluxing salt for reuse in the dross furnace. Over 80 pct of the metallic aluminum is recovered in the aluminum-rich oversize fraction, while essentially all the fluxing salts are recovered by evaporation. This report contains the final results of an investigation on a process research unit scale, an economic evaluation of the method, and recommendations to further improve the process.

Jan 1, 1979

By P. T. Brooks

This Bureau of Mines study describes a process for recovering nickel, cobalt, molybdenum, and chromium contained in complex waste superalloy grindings that, for lack of an economical domestic recovery process, are being largely marketed abroad. The process, devised by laboratory scale operations, includes scrap preparation, dissolution of metallics in hot chlorinated acidic liquor, carbon adsorption, three successive solvent extraction separations, and selective chemical precipitations. Nearly 90 percent of the nickel, cobalt, molybdenum, and chromium were separated and recovered as oxides, carbonates, and basic sulfate products.

Jan 1, 1969

By E. J. Gleim

The Bureau of Mines customarily publishes lists of equipment meeting its safety standards to keep the mining industry informed as to the development and availability of mining equipment that can be used safely. The present list supplements Bulletin 543, Permissible Mine Equipment Approved to January 1, 1953, as well as Information Circular 7722, Permissible Mine Equipment Approved During the Calendar Years 1953-54. Because standards have been revised and new ones added by the Bureau, this list contains classes of equipment not previously covered.

Jan 1, 1958

By Raymond P. Maloney

The Bureau of Mines investigated the White Mountain mercury deposit, in the Kuskokwim River Basin, to better determine the extent of mercury mineralization and to encourage its development by private industry. A program of diamond drilling, augering, bulldozer trenching, and sampling was carried on during four field seasons, from 1960 to 1963, inclusive. Significant amounts of cinnabar, with only trace amounts of arsenic and antimony, occur in dolomite over an area about 4,000 feet long and 1,500 feet wide. The deposit differs from other mercury deposits in the Kuskokwim River Basin by the absence of silica-carbonate and rhyolite intrusives. Small-scale mining was started in 1963 as the result of Bureau investigation and continued during the summers of 1964 and 1965. The investigations indicate that open pit mining might be the most feasible method of working this deposit.

Jan 1, 1967

By R. Hogg

"The basic population balance models for agglomeration processes are reviewed and procedures are described for extending their applicability to systems with size-dependent rate constants and to the formation and growth of porous agglomerates from rigid, solid-particles. Simplified procedures for the further extension of the models to include simultaneous agglomerate growth and breakage are also described.INTRODUCTION The association of small particles into clusters or agglomerates is a significant factor in many facets of particle processing. Agglomeration processes are widely used to facilitate handling, storage and utilization of fine powders. Processes such as coagulation or flocculation are used to aid solid-fluid separation in dispersed particulate systems. Agglomeration also occurs as an accompaniment, often unwanted, to other particulate processing operations such as fine grinding, mixing and blending, transport and flow.Reliable agglomeration models are needed for improved understanding of the processes in general and of the complex role of numerous, interacting variables as well as for direct application to the design and control of industrial processes such as flocculation, granulation and pelletization. Ideally, the models should account for the primary forces responsible for agglomerate formation and growth, the effects of external forces on process dynamics, the development of agglomerate structure and its role in the process itself, and the effects of concurrent processes such as structure modification (e.g. compaction) and agglomerate breakage or degradation."

Jan 1, 1989

By G. E. Rennick

A siphon-type laboratory airlift well was designed and operated by the Bureau of Mines to study the concurrent flow of air and oil in small-diameter pipes. Glass flowstrings ranging from to 1 inch in diameter and from L4 to 64 feet in length were equipped with various-sized air-entry jets. Liquid holdup volumes were used to correlate vertical-flow data, and empirical equations for computing gas requirements were derived. The effect of flowstring length on flow efficiency, oil- and gas-production rates, and gas-oil ratios was relatively minor at all flowing pressures. Air-jet sizes and flowstring diameters, however, had a marked effect on flow efficiency and oil- and gas-production rates. The small air-jet sizes increased maximum flow efficiency and its associated flowing pressures but decreased oil- and gas-production rates. An increase in flowstring diameter increased maximum flow efficiency with its associated flowing pressure and also increased the production rates of oil and gas.

Jan 1, 1965

By H. M. Thorne

The oil-shale deposits of the Puertollano basin in the Spanish province of Ciudad Real appear to have been give little consideration in discussions of oil-shale resources throughout the world. A small, integrated oil-shale operation has been conducted at Puertollano since about 1922 by a French company, Sociedad Mimora y Metalurgica de Penarroya, hereinafter referred to as "Penarroya", but only within recent years have the potentialities of the Spanish oil-shale deposits been recognized. Empresa Nacional "Calvo Sotelo" do Combustibles y Lubricantes, hereinafter designated as "Calvo Sotelo," which was created in 1942 by the National Industrial Institute of Spain to produce liquid fuels from oil shales, has made marked progress in the design and construction of a complete oil-shale plant at Puertollano. Penarroya is mainly a coal-mining company, and the oil-shale operations were on a small scale of approximately 220 tons a day in October 1947. It is an integrated operation comprising oil-shale mining and retorting and shale-oil refining. Motor gasoline, Diesel fuel oil, light burner fuel oil, lubricants, paraffin wax, cresols, and ammonium sulfate are manufactured.

Jan 1, 1950

By Ruth F. Brinkley

This circular summarizes the research and technologic activities and publications of the Federal Bureau of Mines Division of Explosives Technology4/ during fiscal year 1959 (July I) 1958-June 30, 1959). Part I briefly describes the programs that were active during the report period and presents a summary of some of the information not published elsewhere. In many instances the results are only preliminary and are subject to revision on the basis of continuing investigations. Detailed reports of all programs not security classified will be made later. Part II lists and describes briefly the publications of the Division during fiscal year 1959. If the published material has some bearing on activities still current during the report period, this is indicated by references in Part I.

Jan 1, 1961