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By E. G. King

This report contains experimentally determined heat-content values for cerium dioxide and Columbium (niobium) dioxide in the temperature range from 298° to 1,800° K. There are no previous similar data for Columbium dioxide, and those for cerium dioxide have an upper limit of 373° K. The heat-content and corresponding entropy-increment data are presented in tabular form. Equations were derived to represent the heat contents and heat capacities. The data for cerium dioxide are entirely regular, but those for columbium dioxide show two previously unreported anomalies at 1,090° and 1,200° K.

Jan 1, 1961

By James Noll

Total carbon (TC) is sometimes used to measure or characterize diesel particulate matter (DPM) in occupational settings such as underground mines. DPM samples are collected on quartz fiber filters. When using quartz fiber ?lters, adsorption of gas phase organic carbon (OC) has been reported, causing a positive bias in the particulate TC results (adsorption artifact). Most of the data on the sampling artifacts and corrections apply to environmental air sampling, where samples are collected at a much higher filter face velocity and the OC concentrations are generally much lower relative to occupational sampling. In this study, we investigated the effects of adsorption artifact on samples from occupational settings. Samples were collected with and without denuders to determine the amount of gas phase OC collected and the accuracy of certain corrections. In underground stone mines, the adsorption artifact was found to positively bias the particulate TC by greater than 20% for filter loadings below 25 µg/cm2 TC (8-h time weighted average) 262 µg/m3). The tandem ?lter correction reduced the effect of the artifact, as high as 60% of the TC value, to less than 11% for laboratory data. It also significantly reduced the effect of the artifact obtained for field samples.

Jan 1, 2008

By Albert H. Clough

The West Lynn Canal subarea of the Juneau Mining District (JMD) is defined by Lynn Canal on the east, Davidson Glacier to the north, Icy Strait to the south and the Glacier Bay National Park Boundary to the west (figs. C-l and C-2). This area extends along the main-land west of Juneau (across Lynn Canal) northerly, to approximately 20 miles south of the city of Haines. The only roads in the area are relatively new logging roads at the southern end constructed to support a U.S. Forest Service timber sale. There is also local road access near the community of Excursion Inlet. Access to the remainder of the region is either by boat, aircraft, or 'foot. Helicopters provide the only time effective access to all but the coastal parts of the West Lynn Canal subarea. Coastal areas may be reached by small boat or float aircraft. There is an unimproved dirt airstrip just north of the mouth of the Endicott River. This airstrip is suitable for use by light aircraft. The subarea lies within the Tongass National Forest and is managed by the Department of Agriculture, U.S. Forest Service. Approximately two-thirds of the forest lands are open to mineral entry under the current Tongass Land Management plan. The remaining forest lands comprise the Endicott River Wilderness area, which is closed to mineral entry. Private lands within the study area are sparse, with scattered homestead tracts along the coastal regions and in the Excursion Inlet area. Sealaska (Southeast Alaska Regional Native Corporation) also has land selections in the southern Chilkat Range. Tidal and submerged lands are owned by the State of Alaska.

Jan 1, 2012

By L. O. Bacon, H. R. Joesting, J. H. Getz

"INTRODUCTION For a number of years manganiferous iron ore has been mined on a small scale at Boston Hill, in Grant County, N. Mex. Total production up to 1943 is estimated to be over 793,000 long tons, containing 8 to 35 percent manganese and 26 to 46 percent iron. 4/ During 1941 to 1943 production was estimated to be 206,000 long tons, containing about 13 percent manganese and 37 percent iron. During 1944 daily production was several hundred tons, mostly from a single open pit. Several moderately large deposits have been mined: and many smaller ones have been found.From February to April 1945 geophysical surveys were carried out on Boston Hill by the Division of Geophysical Exploration, in cooperation with District 5, Central Region, Bureau of Mines, to determine if hitherto undiscovered manganiferous iron deposits exist. Field work was interrupted for a total of about 1 month during this period by work on other projects in nearby areas. Previous to the geophysical surveys, a preliminary examination was made by H. R. Joesting to determine if geophysical methods could be utilized in exploring the area. 5/Field measurements were made by L. O. Bacon and J. H. Getz, project geo¬physicists of the Bureau of Mines, under the general supervision of H. R. Joesting. A grid survey of the area, to locate geophysical stations, was made by Paul Russell, Bureau of Mines engineer, who also collected specimens for laboratory tests. Most of the computations and the preliminary magnetic and resistivity maps were made by L. 0. Bacon."

Feb 1, 1948

Any communication system requires at least three elements in order to function: a transmitting device, a receiving device, and a transmission line or propagation medium. Even the device children use, tin cans connected with string, consists or these three elements. One speaks into one can (transmitter), which vibrates at the same frequencies as the voice. The string (transmission path) picks up the vibrations of the can and carries them along its entire length. The other can (receiver) detects the vibration and reproduces the original sounds to a lesser extent depending on distance, tightness of string, type of string, etc. All communication systems depend on these three elements: transmitter, transmission path, and receiver. Communication systems can be divided into three fundamental categories: wired phone systems, radio systems, and carrier current systems. Sections 2.2, 2.3, and 2.4, respectively, describe these systems and explain the basic principles of how each works. Hybrid systems are those systems that use various combinations of the three basic communication methods. Hybrid systems are described in section 2.5. There are some other methods of signaling (stench warning, bell signaling, etc.) that can be used in underground mines to transmit or convey information. These systems, although they cannot be considered true communication systems since they do not provide voice or even two-way communication, are briefly described in section 2.6. 2.2 Wired Phone Systems Wired phone systems are all those that depend on a wire connection between phones with the wire carrying the voice signals. Figure 2-1 is a diagram of two typical wired phone systems.The top panel shows a simple single pair party line system. In this system each phone is connected to a common pair of wires, and a person speaking into one phone will be heard at all the other phones on the line. The bottom panel shows a multipair private line phone system. In this type of system, each phone is connected by its own individual pair of wires to a central switch or telephone exchange. To establish a call between two phones in this system, the lines between the two phones must be connected (switched together) within the telephone exchange. In early exchanges, the connections were made manually by an operator. These exchanges are called Private Branch Exchanges (PBX's). Today, equipment within the exchange can automatically connect each phone to any other phone in the system. These exchanges are called Private Automatic Branch Exchanges (PABX's). There are many different types of automatic exchanges. Some utilize switches to physically make each connection according to the number dialed. Other, more advanced exchanges are completely solid state and may even be computer controlled. [ ]

Jan 1, 1984

By C. A. Herbert

Information Circular 6746 reviewed the fatalities in Indiana coal mines. for the fiscal year October 1, 1951 to September 30, 1933. Since then Indiana has changed its fiscal year to the period July 1 to June 30, but as most statistical data on accidents are arranged according to calendar years, the data in this paper are for the last 3 months of 1932 and the calendar year 1933, rather than for the new Indiana fiscal year. Tables 1 and 2 list the fatalities in Indiana coal mines3/ by cause and occupation for the last 3 months of 1932 and for the calendar year 1933. The fatalities for the small wagon mines employing fewer than 10 men are separated from those employing 10 or more men to call attention to the ex- tremely high fatality rate in small mines, largely because the State mining law does not apply to them nor do they come under the jurisdiction of the Indiana mine inspectors; as a result health and safety conditions are ex- tremely bad. During the last 3 months of 1932, 5 (approximately 42 percent of the total) fatalities occurred in the small mines, while for the calendar year 1933, 12 (approximately 32 percent) of the fatalities occurred in them. The Indiana Division of Mines and Kining estimates that these small mines have an annual production of approximately 325,000 tons, or about 4.5 percent of the total coal-mine production of the State. In other words, for these small mines the fatality rate per tons mined during 1933 was about 10 times as great as for the mines employing 10 or more men. Another lamentable feature in connection with the fatalities in small mines is that very few carry any compensation insurance and the owners are not worth enough financially for dependents of victims to collect anything under the common law; as a result, the dependents of those killed usually are left penniless and subjects of public charity.

Feb 1, 1935

By O. M. Bishop

From October 1943 to March 1944, the Bureau of Mines conducted core drilling at the Victory fluorspar mine, Hardin County, Ill. to test the Fredonia limestone and the included sub-Rosiclare sandstone zone beneath the existing stopes. Twenty-one vertical holes were drilled to an average depth of 60 feet. Ore was penetrated in six holes. Since its discovery in 1927, the Victory mine has produced approximately 5 percent of the total fluorspar mined in the United states after that date. The ore discovered in the early mine development is now exhausted, except that contained in pillars drifting to the northeast has partly developed one substantial ore body, and company drilling has indicated another nearby. The increasing need for fluorite for war use in 1943 suggested the desirability of mining the pillars, provided it could be established that no ore beds existed below the stopes or in areas to which access would be obtained through the present workings. This work describes the work accomplished during the project and presents the data obtained.

Jan 1, 1948

By Robert W. Ageton

Optimal planning for mining the deep, lead-zinc-silver deposits of the Coeur d'Alene mining district, Shoshone County, Idaho, could be facilitated by a knowledge of the magnitude and direction of the pressure acting in the virgin rock. The distribution of primary stresses should be considered in order to prevent possibly destructive mining-induced stress concentrations. This particular investigation was concerned with determining stress in a zone 4,000 feet below the surface and known to be ender stress concentrations due to mining operations. Disking of the stress-relief cores obtained in a vertical down hole permitted qualitative evaluation from visual observations; the results indicate that a high lateral stress existed at the time the measurements were made. Stress-ellipsoid determinations gave a compressive principal stress of -13,000 psi oriented about N 45° W and nearly horizontal, a compressive principal stress of -11,000 psi oriented about S 45° W and abut 60° off the vertical pointing away from the vein, and a compressive principal stress -5 -7,000 psi oriented N 45° E and about 60° off the vertical, pointing toward the vein. Subsequent to the overcoring stress-relief drilling, a rock burst occurred about 100 feet northwest of the test site.

Jan 1, 1967

By John W. Moore

The discovery of porphyries in petroleum by Treibs (17-19) is one of the most significant achievements relating to the origin of petroleum. The presence of these remnants of chlorophyll and hematin in petroleum has immediate practical interest in several aspects of the petroleum industry. Because of their interfacial activities and film-forming tendencies, the metal-porphyrin complexes may be expected to affect the wettability of petroleum-reservoir rock surfaces and influence the flow of fluids in these reservoirs. Also, studies of the relationship of trace elements and porphyrins in petroleum may be expected to yield valuable information on source beds and petroleum migration. Finally, the extreme stability of several metal-porphyrin complexes complicates removal of these metals from some petroleum stocks where they exert deleterious effects on processing and utilization. Metal-porphyrin complexes are commonly associated with the asphaltic residues of crude oils in which they occur (8, 9, 15). However, investigations in this and another laboratory (15) show that small amounts of these complexes often remain in partly refined petroleum products, such as thermally cracked distillates and deasphalted stocks.

Jan 1, 1957

By William D. Riley

In order to evaluate the corrosion resistance of zirconium in mineral extraction processes, such as a clay-hydrochloric acid leaching process for extracting alumina, the Bureau of Mines conducted corrosion studies in HCl-AlC13-FeC13 environments. A series of weight loss and electrochemical tests were conducted at 25° and 65° C in aluminum chloride (AlC13) plus hydrochloric acid (HCl) solutions containing 0 to 1,000 ppm ferric ion. It was determined that zirconium, which normally exists in a passive state in chloride-containing solutions, undergoes pitting attack in solutions containing more than 100 ppm of ferric ion. It is also shown that an oxide film prepared in air at high temperature offers protection in acid solutions containing levels of ferric ion from 300 to 1,000 ppm.

Jan 1, 1981

By MINE SAFETY BOARD

Mining men and State officials in their efforts to make mining safer are confronted from time to time with various complicated questions . In recent years these questions have tended to increase with the use of mechanical appliances . Twenty- five years ago electricity had hardly been used in mines . To - day there is practically no other means of transmitting energy employed in American mines , except in metal mines where compressed air is used for drilling and small portable hoists . In coal mines there has been a great increase in mechanization and a tendency to concentrate the mining operation , which has resulted in attendant difficulties of ventilation and intensified the danger of coal - dust in bituminous and subbituminous mines . The answers to the questions which arise are not always obvious , as is shown by the fact that even able , experienced men differ in their opinions of the best way to overcome a particular mining hazard . The difficulty of solving the problems is also demonstrated by the varying provisions in mine safety rules , both in official regulations and in the rules of those mining companies who are endeavoring to do more than follow the letter of the law . Such differences of opinion on the best way of meeting a difficult situation are often found within the same mining organization , and so it has been in the Bureau of Mines .

Nov 1, 1929

A Helix Pressure Gauge to Indicate roof bolt loads was designed, fabricated and field tested. The gauge indicated loads between 3,000 and 15,000 pounds with a ± ten per cent error. The coat of fabrication of the gauge was estimated to be $3.39 including an assumed overhead and profit per indicator for a series production of 5,000 unite. The unit can be read on a bolt to within ± 1,000 pounds load from a distance of twenty feet.

Jan 1, 1974

By H. William Zeller

The Bureau of Mines is conducting research to determine whether the use of chemical surfactants improves respirable coal dust control and is evaluating laboratory test criteria for selecting effective surfactants. This publication presents the results from wetting effectiveness tests with emphasis on the capillary rise test. The test variables investigated included coal particle size, type of surfactant, surfactant concentration, test duration, and mineral con-tent of the water. In addition to the rise test, measurements of con-tact angle, zeta potential, and sink time for various coal and surfactant combinations were conducted. No significant correlations among the four wetting tests were observed, a surprising result which implies that each test type measures specific aspects of the wetting phenomenon and also that each test type should only be used to select surfactants for specific applications. For example, the rise test shows solution penetration into porous materials, and the sink test discriminates among surfactants for dispersing finely ground materials into suspension. Another important conclusion is that combinations of agents retain their individual wetting properties, allowing mixtures to be for-mulated to perform well in both rise and sink tests.

Jan 1, 1983

By B. B. Letson

The heats of formation of lithium chloride and lithium oxalate were determined with the aid of a Bureau-developed, glass Dewar-type solution calorimeter which uses thermistors as its temperature sensing element. Values obtained at 298.15° K were -98.38 ± 0.54 kcal/mole for lithium chloride and -329.02 ± 0.79 kcal/mole for lithium oxalate, using graphite as the standard state for carbon.

Jan 1, 1965

By Dennis A. Long

Slip and fall accidents are a major cause of lost-time injuries associated with large mobile equipment in surface mines. An evaluation of the safety hazards associated with getting on and off large surface mining vehicles showed that most of the accidents occur at the point where personnel attempt to mount or dismount the machine at ground level. The major hazardous design conditions were identified as excessively flexible supports for lower steps or rungs, inappropriate ground-level-to-first-step distances, poor step designs, access designs that use vehicle components as steps or walkways, and inadequate hand- rail and guardrail designs, Additional hazards are introduced by the lack of proper maintenance of ladder hardware and the work practices of operators in carrying articles while mounting and dismounting the vehicle. This Bureau of Mines report describes the design and in-mine testing of improved access system for large mobile mining equipment.

Jan 1, 1984

By D. Harrington

Most of those in the Health and Safety Branch, Bureau of Mines, necessarily participate in activities associated with essentially all phases of the mineral industries, including coal and noncoal mines, quarries, smelters, metallurgical plants, and various petroleum operations. One of the strictly war activities of the branch - the Explosives Control Division, which administers the Federal Explosives Act of December 26, 1941 - has functions that require contacts not only with nearly all phases of the mining and allied industries but also with those engaged in scores of other occupations that manufacture, store, use, or possess explosives, or many of the ingredients of explosives. The field men of the Health and Safety Branch (approximately 300 in number) Are occupied full time in health and safety activities and annually make thousands of contacts with people in the mineral industries as well as the plants in which they work. From these they formulate several thousand written reports containing sources of thousands of conclusions and recommendations aimed at reduction of health end safety hazards in these industries. Although such activities have been greatly increased during the war and immediate pro-war periods, they have been in effect to a considerable extent since the Bureau of Mines was created in 1910.

Jan 1, 1944

By Albert E. Schreck

[THE COMPOUNDS of strontium were confused with those of barium until 1790, when A. Crawford discovered that the mineral strontianite, long believed to be a barium mineral, was a compound of a new element. This discovery was confirmed 2 years later by I. C. Hope. The mineral was named strontianite because it was found near the town of Strontian in Argyllshire, Scotland. In 1808 Sir Humphrey Davy isolated strontium metal by the electrolysis of fused chlorides. Celestite (strontium sulfate) and strontianite (strontium carbonate) are the principal strontium minerals. Because of its more widespread occurrence, celestite is more important commercially.]

Jan 1, 1959

By Robert J. Evans

The Hopper-Feeder-Bolter (HFB) is a prototype multifunctional machine designed to improve productivity by minimizing continuous miner place changes. It is designed primarily to work beside a two-pass continuous miner, bolting on one side and then place changing to bolt the other side while simultaneously providing a surge car and lump breaker located directly behind the continuous miner. Surface testing was conducted at the Bureau of Mines Mine Equipment Test Facility (METF) to evaluate overall system performance and reliability. Tests were conducted to evaluate place changing, tramming, lump breaking, roof bolting, drawbar pull, conveying, temporary roof-support (TRS) capacity, lighting, and noise. Surface test results indicate the HFB is ready to be tested and evaluated underground in a production mode.

Jan 1, 1988

By A. B. Hooker, Iilsley. L. C.

"Flame safety lamps have been used for about one hundred years in coal mines where a dangerous accumulation of explosive mine gas (methane) might occur and thus render the use of ordinary unprotected flame lamps dangerous. Flame safety lamps are not only used for illumination, but also for detecting the presence of dangerous percentages of methane mixed in the air of the mine.The safety of the lamp depends chiefly upon the cooling qualities ofThe safety of the lamp depends chiefly upon the cooling qualities of the wire gauze used to permit free circulation of the air through the lamp. If one enters a part of the mine where methane is present in the air, the methane enters the lamp and coming in contact with the wick flame is ignited and continues to burn within the gauze without igniting the methane surrounding the lamp. If the air within the mine is traveling at a velocity of several hundred feet per minute the burning gases may be driven through the gauze by the air current. If the gauzes are properly designed and of the proper material, these burning gases will be so cooled as they pass through the gauze that they will not cause an ignition of the gas surrounding the lamp. In order to test the effectiveness of a given safety lamp, tests are made in moving explosive mixtures of gas and air arranged to simulate mine conditions.The Bureau of Mines investigated many features relative to the safety of flame lamps and in 1915 established an official schedule known as Schedule 7 whereby flame lamps having certain prescribed qualifications would be approved as permissible for use in gaseous mines."

May 1, 1920

By Gerald W. Elger

The Federal Bureau of Mines developed a modification in the conventional Kroll process for preparing high - purity hafnium metal . This modification involved the partial replacement of magnesium by sodium in the batch reduction of purified hafnium tetrachloride to sponge metal . The raw tetrachloride was purified either by thermal degassing of the volatile contaminants to the atmosphere or by fused- salt treatment . In the fused- salt treatment , the tetrachloride was contacted with molten alkali chlorides to remove the impurities . The reaction byproducts were removed from the metal by heat treatment in an evacuated furnace . The metal sponge was consolidated by melting into buttons or ingots , which were analyzed for impurities . The purity of the metal prepared by the modified process is superior to that of the metal produced by the conventional method . The hafnium metal was comparable to crystal - bar hafnium except for the oxygen content , despite the abnormally high impurity concentrations in the raw tetrachloride . Several ingots were successfully cold - rolled to sheet .

Jul 1, 1960