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By S. M. Javad Koleini

Processing of phosphate ore sample was investigated for increasing phosphate content and reduction of its gangue minerals such as carbonates and silicates. Experimental designs were per-formed using Taguchi method. Different flotation methods were investigated for Moundon phosphate ore sample and three methods were used as follow: direct cellophane flotation, reverse calcite flotation and reverse quartz flotation. Because of the sensitivity of cellophane flotation to slime content, prior desliming was carried out before the experiments. Direct flotation experiments carried out and a concentrate contained 23.80% P2O5, 6.88% SiO2 and 72.33% recovery were produced. The achieved P2O5 content in the produced concentrate from reverse flotation of calcite was 26.44% and the recovery was 82.56%. The concentrate products obtained at optimum conditions by direct flotation of phosphate and indirect flotation of calcite were subjected to indirect flotation of calcite and direct flotation of appetite and final concentrates with P2O5 grade of the order of 24.19% and 26.96% were obtained, respectively. It was concluded that one stage direct flotation is unavoidable to achieve a product with low SiO2 content.

Jan 1, 2014

By V. V. Lvov, L. S. Chitalov

"The purpose of the research is intensification of physico-mechanical ore properties determination for ball grinding processes in comminution circuits. The research presents comparative studies aimed at intensification of Bond Ball Mill Work Index (BWi) determination, such as testing technique of Ahmadi and Shahsavari, Berry and Bruse, Gharehgheshlagh, Horst and Bassarear, Kapur, Magdalinovich. The subject of the research is a test procedure of apatite-nepheline, copper-nickel, gold-sulfide and iron ores for the Bond ball mill index. The Bond Ball Mill Work Index for the material firstly was determined by standard Bond test methodology. Two the most promising testing techniques - Ahmadi and Kapur testing techniques - were modified. For the Ahmadi technique it was proposed to pay attention to the circulating load, which should be stabilized on the value of 250% as fast as possible. Two methods were put forward to quicker stabilize the circulating load. For the Kapur technique it was proposed to use empirical coefficients, which is determined especially for the apatite-nepheline, copper-nickel, gold-sulfide and ores. The modified Ahmadi and Kapur techniques require no more than two cycles of ball grinding to determine BWi (while normally 6-8 cycles are required) and less than 5 kg of initial feed. The suggested modified Ahmadi and Kapur techniques allow to intensify the physico-mechanical ore properties determination for ball grinding processes and BWi test costs considerably, which makes them useful for mass sampling and monitoring strength properties of ores entering a concentrating mill. INTRODUCTION When designing concentrating mills, the choice of the technological scheme for ore pretreatment, particularly the type, quantity and size of the main process environment, the determination of optimal grinding conditions and the calculation of equipment load are carried out by preliminary studies of grinding in semi-industrial or laboratory-scale plants. Semi-industrial tests on full-scale plants provide the most reliable information for calculating specific loads for equipment. However, this requires a significant amount of ore samples, a high labor costs and the pilot plants. Thence the most researchers performed grinding tests with small laboratory equipment using small ore samples."

Jan 1, 2018

By L. Simpson

South African is a repository of significant deposits of a variety of minerals. The Citigroup confirms this assertion with an estimate of in-situ valuation of US$2.5 Trillion. The mining sector plays an important role in the South African economy. In addition to the mineral resource base South Africa has other comparative advantages. Firstly, South Africa retains major mining companies that participate globally, including Anglo American, Goldfields and De Beers. Their global involvement offers much to the local mining sector and the broader economy. Secondly, government established research councils. The Council for Geoscience (CGS) was established to manage the Geological Survey of South Africa, including the reduction of geo-scientific investment risk. The Council for Scientific and Industrial Research (CSIR) promotes industrial development, including mining technology development. Mintek undertakes mineral research from mineral examination of ores, to extraction and refining technologies and manufacture of end products. Thirdly, South African universities teach and conduct research along the mineral value chain. They have increased their minerals graduates? capacity, thus advancing knowledge and skills. Knowledge and technical progress are behind productivity growth and emergence of competitive advantage. The research and development (R&D) capabilities of industry, science councils and universities, working in unison, will enhance the competitiveness of the South African mining industry. The National System of Innovation (NSI) requires multi-disciplinary, collaborative research. Key R&D elements, including skills and expertise, funding and facilities, must be available to implement a long-term national strategy or programme. Improved international collaboration and partnerships between government, academia and industry driven human resource development (HRD), ultimately develop the critical mass for inter-generational skills requirements. This trend requires an expansion of research collaboration programmes. Decisions involving investments and collaborative actions pertaining to R&D in the sector necessitate an analysis of the South African mineral value chain R&D capability. This paper analyses the evolution of R&D capability from exploration to refining, tertiary education, science councils and industry. The political economy of the evolution of this capability is analyzed in relation to the central role that the South African government plays in creating an appropriate supporting environment and related initiatives to enhance R&D and innovation. Keywords: research and development (R&D), science councils, universities, industry, innovation policy, South Africa

Sep 1, 2012

By Jie-Liang Wang, Yongdan Cao, Zhao Cao

"The effect of ethylenediamine tetraacetic acid (EDTA) on flotation separation of fluorite from bastnaesite and its selectively depression mechanism on fluorite were studied by single mineral flotation, artificial mixed minerals flotation, solution chemistry analyses, Zeta potential and XPS measurements.The results show that fluorite can be deeply depressed by EDTA while the flotation of bastnaesite is almost unaffected when octanohydroxamic acid (OHA) is used as a collector. The separation index (SI) between bastnaesite and fluorite increases with the dosage of EDTA, SI can be raised from 1.18 to 12.66 when EDTA dosage increases from 0 to 2×10-3mol/L.Solution chemistry analyses show that EDTA is able to convert the Ca(OHA)2 hydrophobic precipitation on fluorite surface to a soluble Ca-EDTA complex but cannot complexly dissolve the Ce(OHA)3 precipitation on bastnaesite surface. Therefore, the Zeta potential of OHA conditioned fluorite can be reduced significantly by EDTA while the reduction degree to Zeta potential of bastnaesite is relatively low. XPS measurement shows that EDTA removes the chemically adsorbed OHA from fluorite surface but has little effect on the adsorbed OHA on bastnaesite surface. As a result, fluorite can be selectively depressed by EDTA in bastnaesite flotation, which behaves an important industrial application prospect in rare earth ore flotation.INTRODUCTIONNowadays, Rare earth elements (shortened as RE) and compounds are of significant importance for a range of rapidly expanding industrial applications including catalysis, metallurgy, renewable energy, and special materials due to their unique electrical, magnetic, optical and chemical properties [1]. The seventeen RE elements, including the lanthanide-group fifteen elements, yttrium and scandium, could be divided into three groups, i.e., light, medium and heavy RE elements based on the different solubility of RE sulfates [2]. Bastnaesite ((Ce,La)CO3), containing approximately 75% REO, is one of the most important light RE minerals [3]. Flotation is the common method to recover basetnaesite [4-6]. Nonetheless, basetnaesite is often associated with calcium-bearing gangue minerals such as fluorite, and the separation of basetnaesite and fluorite by flotation is usually difficult due to their similar surface properties and therefore floatability [7-9]. Therefore, research on high selective flotation reagents of bastnaesite over gangue minerals has attracted a lot of attention [10]."

Jan 1, 2018

By T. Kumaresan

The Bayer process used for refining bauxite to smelting grade Alumina serves as the linchpin of the Aluminum production industry worldwide. Even though the process is well established, the presence of impurities in the liquor affects the quality of product and imposes a major economic cost on the industry. This review article focuses on the issues pertaining to Gibbsitic (Al2O3.3H2O) precipitation circuit. The comprehensive review provides a basic understanding of the aluminum trihydrate precipitation and agglomeration phenomena. Crystal growth rate and agglomeration play a significant role in determining the output PSD of agglomerates. Hence, the effect of certain thermodynamic and hydrodynamic parameters along with the impact of impurities (oxalates, aldols, acids etc.) and additives on hydrate growth has been reviewed.

Sep 1, 2012

By Imre Gombköto, Zoltán Pap, Ákos Debreczeni, Sándor Nagy

Eddy current separators have become generally used in waste recycling industry during the last decade. There are many papers dealing with separation processes on eddy current separators, and also many article describes particle trajectory and different particle features affecting particle trajectory. These data are used in modeling as well. Within the frame of R&D project called ‚Fundamental research into the exploitation of the economic development potentials of critical raw materials in international co-operation - CriticEl?, authors are aimed for using Eddy Current Separator (ECS) as a mechanical separation step of high value critical elements recovery of selected WEEE’s like display panels, PCB’s. ECS, equipped with 305 mm wide belt, and a concentric magnetic rotor is used for experiments targeted development of methodology for determining separability of different particles on ECS. The subject of our work was to investigate the behavior of model particles with different shape, conductivity (aluminum and copper), orientation and size in order to separate Al and Cu according to the results of many experiments were carried out in this field. However it looks like that throwing distance of one particle is only possible to describe by a certain distribution for even the same particle within the frame of the same conditions. Sample mean and standard deviation are depending on some of the particle feature and acting forces. The paper is going to draft the first results on the relationship between distribution of throwing distance and particle properties.

Jan 1, 2014

By Jannie van Deventer

"Innovation in the minerals industry has been lagging behind comparable industries like oil and gas. An incremental innovation culture that tolerates long lead times between invention and adoption has been exacerbated by a research grant structure that inhibits radical idea generation. Entrepreneurs who can make the link between ore source, technology and finance will cause a shift in innovation culture and open up substantial opportunities in the minerals industry of the future. By extrapolating existing trends in technology within and outside mineral processing, a crystal ball vision of future innovation is shaped with the aim to lower energy and water demand, reduce CO2 emissions, decrease operating and capital costs, reduce environmental impact, and secure a social licence to operate. Advances in nanotechnology, advanced materials and biotechnology will impact mineral processing, but the initiative for technology transfer must come from mineral processors. Laminates of graphene oxide can offer efficient filtration and separation media, while microfluidic devices will be used for desalination, solvent extraction and analysis. Substantial progress is expected on benign lixiviants and separation agents, such as nanoscale supramolecular hosts that can serve as high-capacity, selective and recyclable ligands and sorbents, and solid aminobiphosphonate-based adsorbents. Radical ideas for the recovery of precious metals from non-assayable ores and the generation of energy above unity will be adopted in selected minerals projects. In-situ mining in which microbes generate lixiviants at mineral surfaces will simplify processing circuits. Specific ores will be subjected to microwave processing and electropulse liberation to enhance recovery. Ultrafine grinding using devices of low energy consumption will be done mainly dry, followed by dry separation. New flotation cells will remove efficiently either coarse particles or ultra-fine particles, with mineral surfaces being modified not just by new reagents but also by selective microbes. Innovation in mineral processing indeed has a bright future."

Jan 1, 2014

By Pramila Misra, Jibardhan Meher, Debadutta Das

The concentrated coal-water slurry has been receiving considerable attention recently due its ability to replace fossil fuels. Attainment of stable and concentrated slurry has been succeeded so far through several physical and chemical techniques. The present article reports the formulation and stabilization of a highly concentrated coal-water slurry formed from five varieties of non-coking coals with variable ash contents obtained from Eastern part of India, employing three varieties of starch esters, such as starch benzoate, starch formate, and starch carbamate as dispersant. The apparent viscosity of the modified coal-water slurry has been measured by varying coal loading, dispersant percentage, pH, temperature, etc. The apparent viscosity of the slurry has been found to be decreased substantially on addition of 0.8% of adsorbate in the slurry. The particle-particle interaction has been considerably decreased and stable concentrated coal-water slurry containing high weight fraction of coal (61.5-63.5%) has been achieved in each case. The slurries stay in a non-settling form for about a month with viscosity in a permissible low range. The coal-water slurry has been found to behave as a non-Newtonian liquid. Comparison of the zeta potentials of the naked and modified coals evidences that adsorption of the dispersants at coal-water interface results in inhibition of the agglomeration of coal particles through mostly steric repulsions.

Jan 1, 2014

By T. Wajima

"A novel carbonaceous immobilizing agent for heavy metal contaminated soil was prepared from rice straw using sulfur immersion and pyrolysis, and the lead immobilization in artificial contaminated soils using sulfur-impregnated carbonaceous material was estimated. The rice straws were cut to 1 cm pieces, and then immersed in 0.1 - 1 M K2S solution for 0 - 24 h to prepare sulfur-immersed materials. The immersed-materials were heated at 400 oC for 1 h in nitrogen gas to produce the sulfur-impregnated carbonaceous material by pyrolysis. The abilities of the product to immobilize lead from aqueous solution were examined to obtain the product with high lead immobilization ability. With increasing K2S concentration, the immobilization ability of the product for lead gradually increases and then above 0.5 M K2S those are almost constant, while 15 min is sufficient for the immersed time to obtain the product with high lead immobilization ability. The product prepared from material immersed in more than 0.5 M K2S solution for less than 15 min has a maximum immobilization ability for lead ion. The lead immobilization using the sulfur-impregnated product is sustainable due to the formation of leadhillite [Pb4SO4(CO3)2(OH)2] and anglesite [PbSO4]. The product can immobilize lead ion in various artificial lead contaminated soils. By mixing artificial lead contaminated soil with the sulfur-impregnated product, the eluted solution became neutral, and the eluted concentrations of lead ion dropped below the Japanese elution standard for soil.INTRODUCTION Soil contamination with heavy metals is a worldwide problem. Accumulation of heavy metals in soils affect soil ecology, agricultural productivity, quality of agricultural products, water resources, and serious health problems for human and animal (Raicevic, et al., 2005). In the United States, for example, approximately 63 % of the sites on the National Priority List (NPL) for the treatment of contaminated soils are contaminated by metals, and lead is the most common metal, found at 15 % of the sites. In Japan, according to a report by the Ministry of Environment, 43 % of the contaminated sites that exceed the environmental quality standards are contaminated by lead compounds. Soil contamination by lead compounds is also prevalent in other developed and developing countries where lead compounds are used extensively in industrial activities without careful contamination management. Lead is a ubiquitous heavy metal pollutant in soils due to their use widely. The primary sources of Pb contamination include industrial activities such as mining, smelting of metals, and the use of Pb-containing products such as paints, lead-acid batteries, bullets, gasoline and pesticides (Cao, et al., 2009). It can damage human nervous (especially children) and reproductive systems (ATSDR, 2007). The high concentration of Pb in the soil poses risks to human and animal health by the leaching of metals from the soil into water and the consumption of edible plants growth in the contaminated soil. Therefore, proper remediation is necessary to reduce metal availability in soil for protecting human health."

Jan 1, 2018

By Alex Joseph

A tertiary amine containing polyamine in its back bone was grafted to exfoliated graphite oxide by means of a series of chemical reactions.The synthesized amine functionalized polyaniline grafted to exfoliated graphite oxide (EGAMPANI) was characterized using various techniques such as, FTIR, TGA, Raman, and X-Ray diffraction.The synthesized EGAMPANI was blended with carbon paste electrode, and used to study the response of Hg2+ in acetate buffer solution.Preliminary analysis showed that the anodic current intensity using the EGAMPANI modified electrode was higher during a potential sweep and 10-4 M concentration of mercury could be detected which could be improved to 10-6 M using anodic stripping voltammetric technique. Keywords: metal sensor, exfoliated graphite oxide, functionalization, polyaniline

Sep 1, 2012

By U. Dmitrakova, G. Sedelnikova, D. Kim, E. Savari

"The paper presents the results of research on the development of gold and silver extraction technology from refractory gold sulphide flotation concentrate of one deposits of Nord-East of Russia. The concentrate is due to the complex mineral composition. Gold and silver are finely disseminated in sulphide minerals (arsenopyrite and pyrite partially oxidized by 7-11%). These are characterized by high content of silver 219 g/t and sulphide sulfur 32%, the presence of poorly soluble silver minerals (silver sulfosalts, fahlore, finely dispersed hypergenic acanthite in iron hydroxides and jarosite, etc.), and impurity minerals capable of interacting with cyanide (pyrrhotite, marcasite, nonferrous sulphides) and causing higher than normal cyanide consumption. Pretreatment of refractory sulphide concentrate by biooxidation using a mixed association of mesophilic and moderately thermophilic bacteria at a temperature of 36-40 °C for 120 hours oxidized arsenopyrite by 97.5%, pyrite by 93.5%, unlocked refractory gold, and generally oxidized the minerals absorbing cyanide and oxygen before cyanidation. Further oxidation of these minerals-absorbents was facilitated by the aeration in calcareous medium of the solid biooxidation residues of the concentrate. Sorption cyanidation of the solid biooxidation residues with addition of lead (II) of recovered 91.2% of gold and 82.9% silver from biooxidation residue, compared with 80.1% and 46.6%, respectively, for sorption cyanidation without the preceding biooxidation step. Biooxidation of the concentrate prior to cyanidation improves the recovery of precious metals, especially silver, and significantly reduces cyanide consumption from 18.7 kg/t to 3-5 kg/t of concentrate. INTRODUCTION Biooxidation of gold sulphide concentrates using acidophilic microorganisms has been successfully applied worldwide (van Aswegen et al., 2007; Gericke et al., 2009; Sovmen et al., 2007; Sovmen et al., 2009). At least 15 full-scale plants for tank biooxidation of sulphide concentrates are presently in operation, and the construction of new ones is planned (Bulaev et al, 2015)."

Jan 1, 2018

By Heramb M. Bal

This paper will underpin the future development of intellectuals having greater understanding of patent law and legislation, IP rights, and innovation. To understand this idea, I present a case study of China?s progress in the last 31 years in the rare earth research, innovation, and simultaneously patents area. Rare earth elements (REE) are at the centre of high technology and are the next wave of world innovation. Much of modern society depends on rare earth elements through their use in computers, lasers, telecommunications, iPods, medical technology, military applications, and so on (Long et al, 2010). The rare earth research, a large research body is being provided by Chinese sources. China devoted three or four university centers to the study of rare earths (Lifton, 2009). These measures are all designed to keep China at the forefront of REE production, materials, technology, and innovation. As a result in the last fifteen years there has been a shift from a US-dominated REE industry patents to Chinese patents. The world must identify strategic areas of rare earth innovation and provide funding to firms and universities that conduct such research. Not only research and innovation is vital but filing patents and preserving IP rights for research and innovation is even more important. We (rest of the world) need a comprehensive strategy to guide the development of patent and IP rights for research and innovation. To achieve this, the development of intellectuals with superior knowledge of patents and IP rights are the future need of minerals industry. Keywords: innovation, rare earth, patent, IP rights

Sep 1, 2012

By Rong Fan, Roger Smart, Ning Xu

As part of an Australian Research Council project with Newmont and Newcrest mining companies studying the influence of clay minerals on rheology, hydrodynamics and flotation response, the cryo-SEM technique has been used to capture and image the clay (low crystallinity kaolinite Q38) aggregate structures in the flotation pulp immediately after collector and before frother addition. Samples were also collected from the earliest froth phase and the froth overflow corresponding to early and later concentrates. In this technique, a copper tube is filled with the sample during operation of the cell. The tube is immediately plunged into liquid nitrogen vitrifying the water phase before it can crystallise as ice thereby retaining the structures without volume or other physical change. After sublimation of the vitrified water surface, the aggregate structures are revealed and can be compared between pulp and froth phases from clays in different feeds and flotation conditions. The images from both low-clay ore and ore with clay content reveal various levels of aggregation as predominantly edge-edge connected aggregates similar to those found in our previous studies of high-clay tailings. For the samples from the ore with clay content, more extensive edge-edge clay strings are found in the early froth phase as compared to exiting froth overflow and the pulp phase with short edge-edge connected strings. It is suggested that the strings of clay particles result from edge-edge aggregation in the Plateau borders of the bubbles before breakage during sampling and the more extensive edge-edge aggregation in early froth phase is induced by crowding in the bubble borders. The clay strings collected into the overflow concentrate are almost all broken up compared with the Froth before drop-back. The implications for entrainment and entrapment mechanisms of gangue capture in froth will be discussed.

Jan 1, 2014

By Vladimir Vigdergauz

"Electrochemical studies of metal sulfides in connection with their floatability are discussed. According Frumkin, sorption of electroneutral organic substances has a maximum near the potential of zero charge. This idea initiated attempts of application of electrochemical methods for the controlling of organic collector sorption and mineral flotation. The lecture reviews results of electrochemical studies of the processes taking place during sulfide flotation: redox-state of mineral surfaces and xanthate solutions, xanthate sorption and hydrophobic layer composition, surface wettability and flotation recovery of sulfide minerals. Redox-transitions of minerals, transport of ions and charging of mineral surfaces, electroreduction of dissolved oxygen and accompanying processes of oxidation of minerals and reagents-collectors, - all these matters became the subjects of detailed research. Cyclic voltammetry, rotating disk electrodes, spectro-electrochemical techniques and other modern experimental methods now routinely accompany studies of mineral processing. Relatively new electroanalytical techniques like the voltammetry of mineral particles immobilised on electrodes using polymeric binders have become extremely useful for studying weakly conductive minerals and dispersed flotation products. Full discussion of electrochemical studies of metal sulfides in relation to mineral processing must include bioelectrochemistry and electrocatalysis which open exceptional possibilities for selective leaching of gold and non-ferrous metals. At this time, the paper focuses on the sulfide flotation as a potential-dependent process; the problem of oxygen and its influence on the sulfide flotation; the electrochemical aspects of xanthate oxidation and sorption; theory of suspended electrodes as applied to the mineral slurries and experimental study of the effect of electrochemical pretreatment of flotation pulps."

Jan 1, 2014

By P. Braga, A. Chaves, S. França, A. Luz

"In Brazil, there are no official reserves of molybdenum, and the unofficial reserves are modest. Therefore, the molybdenum ore (molybdenite) produced as a co-product or by-product of emerald mining in the region of Campo Formoso, BA, has arisen as the only economic option. The flotation process is commonly used in Brazil for the recovery of molybdenite from emerald mining tailings, but it produces low-content molybdenite concentrates, thereby resulting in a product with low economic value. The molybdenite concentrate produced in Campo Formoso contains 83.5% MoS2 (50% Mo), which is less than the international standard product that contains > 90% MoS2 (54% Mo).This low value is due to the presence of talc, which is a naturally hydrophobic mineral that is also floated with the molybdenite during the flotation process. Separability studies were done in a Partridge-Smith cell using dextrin and quebracho as a molybdenite depressor in solution at different concentrations and pH values to produce a technical-grade concentrate (i.e., 90% MoS2). These basic studies were accompanied by measurements of the zeta potential and contact angle, which was determined by the capillary rise method. The results of these floatability studies were used in bench flotation tests, which were performed in a Denver laboratory flotation cell. A molybdenite concentrate of 93.4% MoS2 was obtained when dextrin was used at a concentration of 100 g/t."

Jan 1, 2014

By Mingxia Liu, Qi Liu, Tao Jiang

"In addition to physical parameters such as small mass and high specific surface area of fine and ultrafine minerals, chemical parameters such as the adsorption affinity of collectors on the minerals also plays an important role in fine particle flotation. In this study, we have examined collectors with two different ionized groups, carboxylate and hydroxamate, on the flotation of fine niobium oxide (pyrochlore). To facilitate comparison, two hydrocarbon radicals were tested: octyl and oleoyl, which led to four collectors that were studied: octyl hydroxamic acid (OHA), sodium octanoate (C8OONa), oleoyl hydroxamic acid (C18HA), and sodium oleate (NaOl). Small-scale flotation and isothermal microcalorimetric titration measurements were performed to determine the flotation recoveries of different sized pyrochlore and the enthalpic behavior after adsorption of the collectors on pyrochlore. It was found that the flotation performance of the carboxylate-based collectors was generally inferior to hydroxamate-based collectors. Sodium octanoate could not float pyrochlore irrespective of the particle size of the pyrochlore tested. With a longer hydrocarbon chain, sodium oleate was effective to float the relatively coarse pyrochlore (>20 µm) but its collection efficiency dropped sharply for particles smaller than 20 µm. On the other hand, the two hydroxamate-based collectors, octyl hydroxamic acid and oleoyl hydroxamic acid, showed good collecting ability to both the coarse and fine pyrochlore. The isothermal microcalorimetric titration studies indicated a consistent correlation of chain length with floatability of collectors for relatively coarse pyrochlore, as well as a positive relationship between the adsorption affinity and fine pyrochlore flotation recoveries. The key finding of this study was that efficient fine particle flotation could be achieved when strongly chemisorbing collectors were used.INTRODUCTION The first detailed study of the effect of particle size on flotation was made by Gaudin (1931) with sulphide ores. In 1942, Gaudin again demonstrated that (Gaudin et al., 1942) fine particles possess different flotation properties from larger particles. Since then the effect of particle size on froth flotation has been an important research topic by many researchers, e.g., Gaudin (1957), Miettinen et al. (2010), Warren (1976) Jameson (2010), summarizing the behavior of fine particles in terms of their low particle momentum, leading to low rate of collision with bubbles which reduces the chance of adhesion. The suggested remediation methods are mainly based on two approaches: increasing particle size or decreasing bubble size (Warren, 1976). Sand-fine splitting followed by separate flotation treatment of the sand and fines, using deep flotation cells, using starvation quantities of collectors, and using long flotation times, are also strategies to address the problems of fine particle flotation."

Jan 1, 2018

By Mario Gerards, Sergej Podkow, Marco Steinberg

"The JONES® WHIMS technology is based on the magnetic separation process and is widely used for the recovery of magnetically susceptible iron ore particles. The conventional machine design is well-known within the iron ore beneficiation industry for more than 50 years and recognized to be highly reliable, robust and extremely compact with the advantages of high capacity and selectivity. In 1981 Rana Gruber AS, Norway bought 14 JONES® WHIMS DP 317 separators when the magnetic separation plant was built and erected. Today, 11 of these old machines are still operating profitably and efficiently. The former supplier was the coal and minerals division of Klöckner-Humboldt-Deutz (KHD) which is today MBE Coal & Minerals Technology GmbH (MBE). This paper outlines a detailed description of the project of revamping the above mentioned old machines and describes the challenge of incorporating enhanced and newly developed technology into an existing processing plant. Further it gives an overview of the recent developments on the design of the JONES® WHIMS. In order to meet modern product requirements and to increase and secure plant productivity, in 2012 Rana Gruber AS settled a contract covering two new designed JONES® WHIMS DP 317 HFR separators to be implemented into the existing building and the upgrading of all 11 older JONES® WHIMS under the use of as many refurbished items as possible. The two new machines were fully developed by the product specialists of the supplier in cooperation with the operator Rana Gruber AS, thereby taking advantage of their great experience. The design of the new machine is based on the conventional design, i.e. the general operating mode as well as the overall dimensions are identical. Finally this paper gives an overview about the erection and commission phase of the two new machines and gives a detailed comparison between conventional and enhanced WHIMS technology."

Jan 1, 2014

By U. M. J. Boin, E. V. Verhoef

Pyrometallurgical reactors constitute a key processing component in the total primary and industrial/recycling resource cycle, being involved both in primary smelting, converting and extraction, as well as the reprocessing of scrap, from aluminium cans to end-of-life automobiles. Therefore the pyrometallurgical reactor?s role in achieving sustainability is the central theme discussed in this paper since optimising their operation minimises waste, residue and offgas (NOx, dioxin, CO2) and maximises product quality and therefore efficiency. To effectively control the overall resource cycle, one needs to take a systems modelling approach of the whole cycle, seeking to also understand the dynamic process behaviour of the individual components of the cycle, and then especially the part that contributes most to the chemical conversion, namely the pyrometallurgical reactor. This paper highlights the role of pyrometallurgical thermodynamics in the whole resource cycle and specifically places equilibrium thermochemistry in the context of process dynamics where large, variable inventories are recycled or maintained within the system. This paper will therefore review the semi-empirical dynamic modelling tools, which are used to model complex systems with the specific goal of developing dynamic predictive models, which also include slag-alloy chemistry, towards controlling the recycling in a feed forward manner. To illustrate the primary production of metals, high carbon ferrochrome and Ni-Cu-matte smelting will be presented as a brief case study. Also fundamental studies in blast furnace and waste incineration kilns will be given. It also will show how the distributed nature of the chemistry of melts in the case of primary extraction, and industrial (recycling) materials such as recycled end-of-life vehicles, have a significant impact on the process outcomes and model predictions. It is therefore argued that the fundamental thermodynamics and kinetics in metallurgical reactors play a final crucial role in modelling the closed material cycle, but only when it is used in conjunction with process systems theory based on reconciled data for parameter estimation and model calibration. System models for aluminium and car recycling will be given as well as a dynamical system model that describes the interconnected material flows for Ag, Au, Bi, Cu, Fe, Ni, Pb, PGM, Sn and Zn for a study on lead-free solder.

Jan 1, 2003

By Chenyang Zhang, Zhigang Yin, Wei Sun, Jingxiang Zou, Jianyong He, Yuehua Hu, Zhijie Xu

"In this work, a novel compound 4-Amino-5-mercapto-1,2,4-triazole was first synthesized and its selective adsorption mechanism on the surface of chalcopyrite was comprehensively investigated using UV-vis spectra, zeta potential, Fourier Transform Infrared Spectroscopy(FTIR), X-ray Photoelectron Spectrscpy Measurements(XPS), and Time of Flight Secondary Ion Mass Spectrometry (ToF-SIMS) and first principle calculations. The experimental and computational results consistently demonstrated that AMT would chemisorb onto the chalcopyrite surface by the formation of a five-membered chelate ring. The first principle periodic calculations further indicated that AMT would prefer to adsorb onto Cu rather than Fe due to the more negative adsorption energy of AMT on Cu on the chalcopyrite (001) surface, which was further confirmed by the coordination bonding energies of AMT-Cu and AMT-Fe based on the simplified cluster models at a higher accuracy level (UB3LYP/Def2TZVP). The bench scale results indicated that the selective index improved significantly when using AMT as a potential chalcopyrite depressant in Cu-Mo flotation separation.INTRODUCTIONFroth flotation is one of the most important processes to separate valuable minerals from gangue by taking advantage of differences in the physical chemistry of their surface properties(Laitinen et al., 2014), particularly in their surface hydrophobicity. Hydrophobicity differences between valuable and gangue minerals could be regulated by adding different chemical additives (surfactants)(Kor, Korczyk, Addai-Mensah, Krasowska, & Beattie, 2014), such as collector and depressant. It could be conducted economically to selectively separate and enrich the complicated and/or poor ores, by adopting appropriate surfactants. For example, the beneficiation of molybdenite usually relies on a two-stage process to realize flotation separation of molybdenite from other unwanted sulphide ores(Wie & Fuerstenau, 1974). In the first step, a bulk molybdenite concentrate is produced by utilizing kerosene/ diesel oil and pine oil/alcohols as collector and frother, respectively. Second, sodium hydrosulphide, sodium cyanide, ammonium sulphide, or Nokes reagent are adopted as depressants in the separation stage. However, these depressants are usually toxicant and cannot meet the requirements of environmental protection. A large number of efforts have been taken to develop alternative environmentally-friendly depressants (Ansari & Pawlik, 2007; J. H. Chen, Lan, & Liao, 2013; Li et al., 2015; Yin, Sun, Hu, Zhai, & Guan, 2017; Yin, Sun, Hu, Zhang, Guan, Liu, et al., 2017; Yin et al., 2016). Although some novel and environmental-friendly depressants have been reported to achieve good performance in Cu-Mo flotation separation at a laboratory scale, there are still some challenging problems, including toxicity, high price or poor performance in practice, which severely limit their practical applications in Cu-Mo flotation separation on a commercial scale."

Jan 1, 2018

By Jin Duan, Qi Zheng, Bo Yan, Li-cheng Ma, Xiao-kui Che

"The aim of this study was to develop an approach for the selectively removal of Zn(II) from heavy metal-bearing-wastewaters produced by gold chemical industry using magnetic chitosan based adsorbents. Chitosan beads were prepared by cross-linked modification of Fe3O4-chitosan bead using epichlorohydrin as the cross-linker. Both Zn(II) inprinted magnetic chitosan hydrogel bead (Zn-MCHB) and unprinted magnetic chitosan hydrogel bead (MCHB) were prepared and batch adsorption experiments were used to evaluate their adsorption capacities and selectivities. Single adsorption of Cu2+, Pb2+, Zn2+ and Ni2+ showed that both MCHB and Zn-MCHB adsorbs all the four metals and had an affinity in the order of Cu2+ > Pb2+ > Zn2+ > Ni2+. The binary adsorption revealed that the two adsorbents preferentially adsorb Cu2+/Pb2+ from Zn2+-Cu2+/ Zn2+-Pb2+ binary systems. However, MCHB does not show any selectivity in Zn2+-Ni2+ system. In contrast, Zn- MCHB preferentially adsorbs Zn2+ from Zn2+-Ni2+ binary system. Furthermore, the adsorption selectivity is predictable from stability constants of the metals with the amino group of chitosan. The information revealed in this work can be used for further applications in the treatment of wastewater containing a range of heavy metals from the gold chemical industry."

Jan 1, 2014