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By J. L. Huisman

Bio(hydro)metallurgy is the latest development in the ongoing search for efficient and economic metal winning processes. In addition to bioleaching, other biotechnology-based applications are becoming more and more accepted. In this paper the THIOMET process for general effluent treatment is described. With this process, it is possible to produce sulfide on-site and on-demand and to use the sulfide to precipitate metals, even selectively when required. The process is ideally suited as a treatment to remove metals after, for example, an acid regeneration process. Another process is proposed that deals with stainless steel pickling bleeds. Such effluents typically contain nitrate, iron, nickel, chromium(VI) and other species. This one process handles these compounds, as well as other metals.

Jan 1, 2006

By Z. Zhang, M. -Y. Liu, X. -G. Chen, F. Breton

"The microstructures of AlSi10Mg foundry alloy in permanent mould (PM) and high pressure vacuum die (HPVD) castings were analyzed and compared. The as-cast microstructures of two castings mainly consisted of eutectic silicon particles, primary Mg2Si and Fe-rich intermetallic phases. The surface layer in HPVD castings, which has a unique feature and different structures, was carefully characterized. The dimension variation of microstructural phases along the cross section in PM samples is less than that in HPVD samples, although the size of microstructural phases in PM samples was much larger than that in HPVD samples. The mechanical properties of PM and HPVD samples were evaluated on as-cast and T6-treated conditions. The tensile properties of HPVD castings are remarkable better than those of PM castings on the as-cast condition. The T6 heat treatment greatly improves the tensile strength of PM castings while it has limited impact on the tensile strength of HPVD castings.INTRODUCTION The AlSi10Mg alloys are widely applied to the high pressure die casting (HPD) and high pressure vacuum die casting (HPVD). In the HPD process, the melt is injected into the die cavity under a high speed (30–50 m/s in the gate velocity for aluminum alloys), and solidified under a high pressure (up to 200 MPa in the cavity) and with a high cooling rate (up to ~103 Ks–1) (Gourlay, Laukli & Dahle, 2007; Ji, Wang, Watson & Fan, 2013). This results in a unique microstructure feature that is different to other casting processes under gravity. One major concern in HPD castings is porosity due to trapped air in the cavity (Ji et al., 2013), which seriously restricts the application of a heat treatment on the improvement of mechanical prosperities because of the formation of blisters on casting surfaces. For the process improvement, the high pressure vacuum die casting was developed in 1980s (Uchida, 2009). In this process, the melt is injected into the die cavity under reduced pressure (vacuum), which greatly reduces gas porosity in castings due to effectively avoiding the trapped air. Consequently, HPVD castings are heat-treatable without the formation of blisters on castings surface during heat treatment. The HPVD process has been widely applied to produce high quality structural castings in recent years attributed to reliable vacuum system development (Uchida, 2009). However, the microstructure features of HPVD castings are not systemically characterized yet."

Jan 1, 2018

By A. Boehm

"For recycling LD slag into the steel making process, the phosphorous containing calcium silcate phases have to be removed from iron oxide phases. One possible technical solution could be magnetic separation in a wide range of susceptibilities from ferromagnetic to paramagnetic. To check the feasibility of magnetic separation the distribution of the magnetic susceptibility in size classes as well as the liberation of the phosphorous containing phase were evaluated by a new method combining two dimensional physical property analysis with QEMSCAN analysis. The particle size classes of energy controlled comminution products were subdivided into fractions of defined magnetic susceptibility using a hand magnet of well known field properties (pick up method). On the one hand the susceptibility classes were wet assayed on the other hand analyzed by QEMSCAN followed by data evaluation using iDiscover 5.3.1(FEI), which was adapted to the data structure of two physical properties (size and magnetic mass susceptibility). The results allow the comparison of mass based (3D) cumulative distribution of grades from the wet assays with the area based (2D) distribution from QEMSCAN analysis, in order to control a systematic (size dependent) stereological error for this special type of material. As the physical separation property forms a crucial parameter the results from the liberation analysis by QEMSCAN can be interpreted more profound with respect to an expectable separation result. Once the various mineral compositions of the particles are assigned to the physical properties the Henry Reinhardt chart serves to predict the best possible separation result and thus the feasibility of a separation technique.INTRODUCTIONThe two Austrian steel plants operated by voestalpine AG produce about 650,000 t (voestalpine 2014) of LD slag in the course of steel production from pig iron according to the basic oxygen process blowing oxygen in the converter by an oxygen lance. The process is also known as the Linz Donawitz (LD) steelmaking process. By the addition of lime (CaO), carbon, phosphorus, silica, manganese and sulfur, which are present in the molten pig iron, shall be oxidized and bound in the slag either as oxide or silicate phases, or leave the slag in the gaseous phase (CO). The average chemical composition of the investigated LD slag is given in table 1."

Jan 1, 2016

By D. Rylander

The operation of Quarry and Aggregate sites are similar to factory production, since it contains sequential production processes, tasks and activities to produce the output product. Compared to the plant though, the quarry processes are generally not synchronized and controlled towards the overall throughput of the site in real time. Some quarries control parts of the production but do generally not utilize real-time technologies for the whole site and all its activities. This fact indicates a general improvement potential in increased productivity at quarry sites, but also unsolved challenges for the same reason. The main contribution of this paper is the presentation of a Lean based method for how to describe the processes to identify control improvement potential within a site. The aim of the identified improvements is to increase overall site productivity by optimizing site, fleet and machine utilization towards the overall throughput, and minimizing operational expenses and inventories. Further the paper exemplifies the method?s usability with field studies at operational quarry plants successfully identifying and quantifying potential wastes and improvements. In addition the identified productivity improvements based on increased control and automation indicate challenges and needs in wireless communication and sensing technologies.

Aug 1, 2013

By C. Acuña

The case is presented that the key role of frother is control of bubble size in the pulp zone. Compared to water alone, the addition of frother produces a narrower distribution and finer bubble size. An empirical model is presented for bubble size as a function of frother type using a normalized concentration. The model provides a benchmark for assessing operations. There is no agreed upon mechanism of how frothers act to reduce bubble size. Prevention of coalescence is a common explanation and this action is illustrated. The case against the 'coalescence' model alone is presented and a breakup mechanism is introduced based on pilot cell and single bubble studies. Phenomena associated with bubble shape, velocity and surface flows are used to illustrate the force associated with surface tension gradients. Breakup mechanisms resulting from this force are proposed. The concept can be extended to high salt concentrations which also promote small bubbles.

Jan 1, 2007

By F. N. Smith

The carbon steel casings of Heat Recovery Steam Generators (HRSGs) in a co¬generation plant were found to have developed cracks that originated on the inside surfaces. The HRSGs receive hot exhaust gases from the primary Gas Turbines (GTs), which are fuelled with pipeline natural gas. The GTs was initially operating without any suppression of nitrogen oxides (NOx). After being in service for about two years, some of the cracks were found to have penetrated right through the 1/4 in. thick casings. The casings are fitted with insulation on the inside (hot gas side). Examination of steel samples cut from the casing walls revealed (i) fine cracks propagating through the steel from the inside surfaces, and (ii) the presence of relatively large amounts of nitrate ion on the inside surfaces. It was concluded that the nitrate ions originated from nitric acid that was condensing on the relatively cool walls of the casings behind the insulation. Nitric acid was formed in the GT exhaust gases by the combination of water vapour (formed from combustion of the hydrocarbon fuel and from moisture in the combustion air) and nitrogen oxides (formed from nitrogen and oxygen in the combustion air).

Jan 1, 2005

By C. Yoo

"Geosynthetics engineering has made phenomenal advances during the last decade in areas of manufacturing as well as practical applications. As a result, geosynthetics are now being recognized as essential construction materials that can be used to facilitate construction, ensure better performance of the structures and reduce the long-term maintenance in routine civil engineering works. The creative use of geosynthetics in geo-engineering practice is expected to continuously expand as innovative materials and products are becoming available. In this paper, a wide variety of geosynthetic products available to geoengineers to solve a wide range of problems are briefly presented along with their functions and possible applications. Fundamentals of geotextile filter design principles are then introduced for use in the tunnel drainage system. Practical applications of geosynthetics relevant for tunnel engineering are also highlighted with emphasis on the issues associated with the geotextile filter application for use in the tunnel drainage system.INTRODUCTIONGeosynthetics have emerged as essential engineering materials in a wide range of civil engineering applications, e.g., transportation, geotechnical, geoenvironmental, hydraulics, and private development since the first geosynthetic conference in Paris, 1977 (Koerner 2012). Due to their costeffectiveness, ease of installation, and well established mechanical and hydraulic properties, geosynthetics are now playing important roles in the field of geo-engineering.As indicated in the 9th Bucahanan Lecture paper by Holtz (2001), major developments in civil engineering have only been possible with the parallel developments in the technology of construction materials. For example, larger scale structures became possible with the help of developments in concrete, reinforced concrete, and prestressed reinforced concrete technology which replaced wood and building stone as construction materials. The best example of a parallel development in geo-engineering between the material and the geotechnical application may perhaps be the soil reinforcement technology which has a direct analogy with reinforced concrete as a polymeric reinforcement material provides added level of tensile resistance and stability to soils that have little to no tensile strength, thus giving additional margin of safety."

Jan 1, 2015

By Aalbert Zwijnenburg

One of problems connected with the use of gold/titania-based catalyst systems is the low yield in propene oxide (up to 2 wt %). It is shown that the low propene oxide yield is due to product inhibition. New options for propene epoxidation with hydrogen and oxygen are discussed. INTRODUCTION The direct gas-phase synthesis of propene oxide (PO), by the use of molecular oxygen, is still aimed for. Agbased catalysis is in principle possible, but selectivity at present is not promising. Highly dispersed gold on titanium containing catalysts show an extraordinary selectivity in the oxidation of propene to the corresponding epoxide (> 99 %), using a combination of H2 and O2 as oxidation mixture [1]. Additional studies of the epoxidation reaction have indicated several drawbacks of the Au/TiO2 catalyst. Firstly, the low conversion (1- 2 %) obtained under typical reaction conditions (atmospheric pressure, 323 - 423 K) cannot be increased by increasing the reaction temperature, because this leads to extensive by-product formation. Secondly, the low efficiency of hydrogen (relatively large amounts of water are formed) is hard to prevent. Finally, significant deactivation of Au/TiO2 catalysts within several hours on stream has been observed. Deactivation can be almost completely prevented by using dispersed TiO2 supports, such as TiO2/SiO2 and Titanium-Silicalite-1 (TS-1) [2]. In recent literature [2,3] a hydroperoxide-like intermediate has been proposed to be responsible for the selective epoxidation. This oxidising species is said to be formed over gold and subsequently used for epoxidation over the Ti-containing support. The support is responsible for the slow desorption of PO. One of the problems for future industrial application might be the low yield in propene oxide. Furthermore, the presence of minor amounts of by-products, not detected on lab-scale catalyst testing, might complicate the separation unit in an industrial process. The reason for the low PO yield over Au/TiO2-based catalysts will be discussed in this paper. Temperature Programmed Desorption (TPD) and micro-flow experiments have been carried out to study PO desorption and catalyst performance, respectively. A catalytic cycle is proposed together with its consequences for the maximum yield in PO. Finally, several process and catalyst options are discussed in view of potential future industrial application.

Oct 1, 2003

By C. Beaudry

Outline ? General Geology of Frieda River Project Area ? Exploration History ? Geology of Porphyry Deposits ? Porphyry Resource ? Update of Nena Deposit and High-Sulfidation Mineralization ? Nena Resource

May 1, 2006

By J R. O Walli

Large production shafts can be successfully sunk through the ubiquitous Blairmore formation of southern Saskatchewan by employing the freezing process and by the installation of a cast iron tubbing lining. Although the freezing technique for shaft sinking and the use of cast iron tubbing to preserve the shaft are new to the North American continent, these procedures have been employed in Europe for the past eighty years. More than 200 shafts, covering a wide variety of ground conditions, have been sunk by the freezing process, and most of these have been lined with cast iron tubbing. The No. 1 shaft of International Minerals and Chemical Corporation, near Esterhazy, Saskatchewan, comprises the first major example in Canada of the employment of European methods to overcome extremely difficult ground conditions. The Blairmore formation was solidified by the deep freezing process, employing a lithium chloride solution as the refrigerant, with input temperatures ranging to -55°F

Jan 1, 1964

By P. A. Peach, W. H. Gross

The modern economic geologist in Canada is well equipped to apply geological, geochemical or geophysical techniques in the exploration for ore. Recently, great advances have been made in geophysics and geochemistry, and a large number of new orebodies have been discovered by these methods. An attempt is made in this paper to show that there has also been a considerable advancement in geological knowledge and that the most effective application of geophysics and geochemistry often occurs in areas already considered geologically favourable for the occurrence of ore. Ali exploration methods sooner or later suffer from diminishing returns. Therefore, as time goes on, one can expect to see the application of some of the more subtle or refined geological techniques that are presently being developed.

Jan 1, 1967

By E. C. Sanford

A laboratory-scale batch extraction unit and operating procedure for studying the hot-water separation of bitumen from Athabasca tar sands are described. The extractor evolved from earlier units and has been in use by Syncrude Research for the past 10 years. By using a unit such as this, it is possible to study tar sand feed quality and the effects of chemicals on the hot-water extraction process, while process variables are held constant. Data are presented to demonstrate the importance of surfactants to the process and the interrelated role of inorganic bases and surfactants.

Jan 1, 1979

By R. Kumar, A. K. Verma

"In this paper, an anisotropic shear behavior of rock joints is investigated under constant normal load condition (CNL). The natural rock joint roughness is transferred to artificial rock samples using room temperature vulcanizing (RTV) silicon rubber. Artificial cylindrical rock joint samples (90 mm diameter and 50 mm height) are made by mixture of cement, sand, and water in the ratio of 1:1.5:0.45 (by weight). Direct shear tests are conducted on these samples in twelve directions at 30º apart at four different normal stresses (250kPa, 500kPa, 1000kPa, and 1500kPa). Thus, 48 samples are tested in laboratory. Test results shows that the peak shear strength (?) of rock joints is anisotropic in nature due to change in morphological features in particular shearing direction. Joint roughness coefficient (JRC) is determined in each shearing direction by trial and error method using Barton’s model (1973). Further, cohesion ( c) and angle of friction ( ? )of joint surface in each direction is determined. Finally, a relationship between angle of friction ( ? ) and joint roughness coefficient (JRC) is developed. Experimental shear strength and Barton’s shear strength is compared and it is found that effect of anisotropic decreases with increasing normal stress. INTRODUCTIONRock mass is generally composed of discontinuity which refers collectively to joints, faults, bedding plane and folds etc. ISRM (1978) defined joint as a line of break of geological origin along which there is no visible displacement. Joint is three dimensional discontinuity which composed of two matched/mismatched surfaces. The presence of joints in rock mass plays an important role to define its overall shear strength, deformability behavior, in-situ stresses and hydro-geological properties. The shear strength of rock joints is important in the design of near surface/ deep geotechnical works (mining excavation, dam foundation, power plants, underground caverns, and slopes).In last 40 years, many constitutive models are developed to predict shear strength of rock joints under CNL conditions (Patton 1966; Landanyi and Archambault 1969; Barton 1973; Goodman 1976; Barton and Choubey 1977; Plesha 1987; Desai ad Fishman 1991; Amadei and Saeb 1992; Maksimovic 1992; Wibowo et al. 1993; Huang et al. 1993; Amadei et al. 1998; Indraratna 2000; Homand et al. 2001; Wang et. al. 2003; Samadhiya et. al. 2008; Asadollahi and Tonon 2010; Ghazvinian et al. 2012). These constitutive models have limitations to predict shear strength of rock joints in one direction. Till date, among all constitutive models, Barton (1973) model is widely used in practice due its simplicity. It includes parameters such as joint roughness and joint compressive strength (JCS) to quantify joint surfaces."

Jan 1, 2015

By William Petruk

Mineralogical investigations in connection with gold metallurgy are usually performed to find the reason for poor recoveries by cyanidation or by other leaching techniques. Poor recoveries most commonly are obtained when (I) native gold is encapsulated in an insoluble mineral as "invisible gold"; (2) native gold is coated with a precipitate; (3) gold-bearing products are insoluble in cyanide solutions; (4) carbonaceous material in the ore adsorbs gold; and (5) associated minerals decompose and consume cyanide. Samples of refractory material quite often have low gold tenors. It is difficult to find the gold-bearing minerals in such samples with an optical microscope because the probability of finding trace minerals in samples is small. The probability decreases with decreasing grain size of the gold-bearing mineral and with decreas¬ing gold tenor of the sample. Techniques have been developed to increase the success rate of finding gold grains; some are (1) concentrating heavy minerals; (2) preparing special polished sections; (3) searching with an image analyzer; and (4) dissolving associate silicate and sulphide minerals.

Jan 1, 1989

By R. P. Zahn

The need for quantitative mineralogical data to characterize ore types before they are processed is becoming increasingly necessary. Mineralogical data (modal abundances, grain size, liberation/locking characteristics, mineral textures and associations) can provide invaluable information to facilitate the identification of metallurgical issues that may arise during processing of a particular ore. This paper will discuss the use of QEMSCAN analysis in conjunction with bench scale flotation test work to determine metallurgical characteristics for several ore types that will be fed to the Morenci concentrator upon commencement.

Jan 1, 2007

By Grant S. Diamond

THE BIBLIOGRAPHY on the use of static electricity in mineral beneficiation consists largely of patents. Some references are found in mineral textbooks, but very little data on flow-sheets of commercial installations are known to the writer. As a matter of fact there have been relatively few successful commercial applications of importance. Johnson prepared and published a Table showing the polarity and static field intensity requirements of many minerals. There have been reports of successful beneficiation of rutile, zir-con, coal, potassium chloride, and phosphate rock. Otherwise, the field of success has been very limited. This may be due to three reasons: first, the mining industry has been averse to dry processes, be-cause of dust nuisances in dry crushing; second, the electrostatic processes used in the past apparently developed no substantial economic advantages; and third, because flotation or other . methods have proven successful on many minerals, the industry has not felt the need for a radically different process. In the feldspar industry there was ?an attempt at electrostatic beneficiation about twenty years ago which was based on the use of fluoride fuming of the pegmatite head feed, in order to make the mineral reactive in a static field. This process was originally said to be successful, but was discontinued because of corrosion damage to machinery. Another effort by use of a chemical additive such as an or-ganic hydroxyl compound has also been attempted. Neither of these processes is known to be in use today.

Jan 1, 1957

By T. Fekete, D. L. Flocks, R. T. Hart

The plugging effect of bacteria was investigated by injecting various concentrations of dead bacteria cells though sandstone cores. Pressure profiles along the cores were recorded periodically during the injection cycles. The plugging effect was analyzed using a plot of the ratio of reduced permeabilities to the initial permeability versus input volume. Results indicated that Tock permeability has little effect on plugging, but that the concentration of bacteria in the injection water has a significant effect on plugging characteristics. The pressure profile curves showed that bacteria penetrated several inches through the core but that the greater portion of the bacteria accumulated at the in-put end of the core.

Jan 1, 1960

By J. H. Nantel, J. F. Archibald

"The presence of radon from uranium-bearing ores, waste and from backfill material introduced underground to provide ground support, work platform and waste disposal functions, requires that ventilation controls be established to maintain safe working level concentrations. One approach has been developed at Queen's University to quantify radon and radon daughter source level s and to estimate ventilation requirements necessary to maintain these safe levels.Knowledge concerning the sources of radioactive contaminants and their production quantities is of value for planning and design stages of ventilation control systems. For any given mine layout, radiation level estimates may be forecast and modified by ventilation network design where excessive production quantities may exist.Behaviour of Radon Gas in MinesRadon gas, produced from the decay of Ra-226 in a host medium, will diffuse through porous media. In areas adjacent to mine workings, radon will be liberated into the mine atmosphere. The rate of radon emanation is proportional to the rate at which radon is produced within the host material (a function of the ore grade of U308) , to the radon concentration gradient in the host pores and to the diffusion properties of the material.The radon source concentration is determined by the rate at which Rn-222 is produced by the decay of Ra-226, and by the emanating coefficient (E), or fraction of the radon which escapes from the source matrix and is free to diffuse through the pore spaces."

Jan 1, 1984

By J. A. Brusset

Introduction The West Canadian Collieries, Limited, operate three bituminous coal mines in the Crowsnest Pass district of Alberta. Two seams are worked; their thickness varies from 10 to 20 feet and their pitch from 10 to 45 degrees. The Bellevue mine was opened in 1903, the Greenhill in 1914; both are gassy and dusty, and at both the haulage is a problem, as the workings are spread over distances of several miles. Compressed-air locomotives are used at Bellevue, rope-haulage at Greenhill, both of which solutions of the haulage problem are costly in installation an operation, and lack flexibility. In 1943, the Adanac mine was opened; and the question soon arose as to which system of haulage should be selected. Compressed-air locomotives and ropes were rejected on the ground of high cost. Since, under the Alberta Mines Act, the use of trolley locomotives underground in coal-seams is not permitted, the choice lay between storage battery locomotives and Diesel locomotives. The preference of the author, who had had experience with both in French gassy coal mines prior to 1930, was for Diesel locomotives, due to lower cost of installation and greater flexibility and reliability. However, Regulation No. 13 of the Mines Act of Alberta reads: 'No gasoline-driven engines shall be used underground in any mine, and no internal combustion engine shall be used underground in any coal mine, except only when authorized by the Chief Inspector in writing, and on such terms as he may prescribe"

Jan 1, 1948

By Zhiqing Zhang, Changyun Chen, Qing Liu, Lin Lin, Zhihong Jia, Guangjie Huang, Lipeng Ding

The effect of interrupted quenching (IQ) treatments on natural aging and bake hardening response of Al-Mg-Si alloy was investigated by hardness measurements, tensile test, differential scanning calorimetry (DSC) and transmission electron microscopy (TEM). The results show that interrupted quenching at 100oC could effectively suppress natural aging and improve bake hardening response. The optimized interrupted quenching treatment is 100oC for 45min, which gives the alloy a relatively low T4 temper strength and higher bake hardening response. The formation of highly dense cluster(2) during the interrupted quenching could be the reason for suppressing the natural aging and accelerating the precipitation of ß? phase during the paint bake treatment. In addition, interrupted quenching at higher temperature (170oC) results in unfavorable properties in both T4 temper and paint bake treatment. The formation of large precipitates is responsible for these undesired effects.

Jan 1, 2015