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By D. Bai, F. Hamad, S. Abraham

For the integrity of welded structures such as pipelines, the toughness of the heat-affected zones (HAZ) is an important property. This property is often specified in terms of Charpy V-notch (CVN) impact toughness and determined by the standard test method. An experimental study has been conducted in an industrial laboratory to measure the impact toughness of the coarse grain heat-affected zones (CGHAZ) of an X80 line pipe material. The field girth welding conditions in terms of heat input were simulated, together with special edge preparation to improve the targeted testing of the CGHAZ. The effect of toughness of the neighboring regions, in particular the weld metal, on measured impact toughness of the CGHAZ was investigated. The fracture paths of the CVN tested samples were examined by both optical and scanning electron microscopy. The deviation of segments of the fracture path into the weld metal was found to have a significant effect on the measured impact toughness of the CGHAZ.

Jan 1, 2005

By P. E. Cavanagh

"The Davis tube test has been used for many years as a laboratory method for determining the magnetic iron re-coverable from a magnetite iron orebody. This paper de-scribes a method for determining the recoverable iron from ores of the Labrador Trough type, with the usua1 flow sheet utilizing spirals followed by magnetic separation.The mechanical structure of a metamorphosed iron ore, resulting from recrystallization over long periods of time, is the basis for the laboratory method developed. Similarities between the structures of such recrystallized ores and the structure of annealed and recrystallized steel are noted.A laboratory technique to determine the size of the different grains of gangue and iron ore minerals is de-scribed and the application of this information to arrive at recommended grinding techniques and flow sheets is demonstrated. The use of the method to determine recoverable iron in such ores is compared to actual iron recovery in the pilot-plant and commercial concentrations of the same ore.The use of a specified lower limit of recoverable iron as determined by this method, in order to design open-pit limits, achieves practical results when compared to designing a pit based on an arbitrary lower limit of total soluble iron. The Ungava Iron Ore deposits are used in giving an example of the resulting pit design changes."

Jan 1, 1968

SOFCs with thin electrolyte of two types: SDC (15um) single-layer and YSZ (5um) + SDC (15um) bi-layer were fabricated by screen printing and co-firing on Ni¬YSZ cermet substrates. Using in-situ sintered Sm0.5Sr0.5CoO3 cathode the SDC-cell shows high performance at low temperature, 1180mW/cm2 peak power density around 650°C, while the YSZ+SDC bi-layer cell generates about 340mW/cm2 at 650°C, and good performance at 700-800°C with almost theoretical OCV value. Many Zr-content micro-islands were found on the SDC electrolyte surface. The influence of co-firing temperature and thin film preparation methods on the Zr-islands' appearance was investigated.

Jan 1, 2005

By V. A. Leão, A. M. Silva, S. M. Bertolino, B. C. S. Ferreira, D. Guimarães

Although not considered a high risk pollutant as compared to toxic metals and acidity, environmental agencies worldwide are proposing regulations to control sulphate in effluents and drainages by setting a threshold value varying between 250 mg/L and 500 mg/L. The aim of this study was thus to compare four different techniques for removing sulphate ions from mining/metallurgy effluents. The first alternative studied was sulphate removal by precipitation as ettringite. Treating a synthetic solution containing 1650 mg/L sulphate at 22±1 ºC resulted in removals close to 85% during continuous precipitation. Sulphate sorption was also investigated using three different ion exchange resins as well as limestone. Fixed bed experiments produced sulphate loadings of up to 70 mg SO4 2-/L resin, at pH 2.0. In neutral wastewaters, limestone is also a potential adsorbent producing a maximum particle loading of 19 mg/g. Sulphate sorption on limestone seems to be an alternative to treating mine waters with sulphate concentrations below the 1200-2000 mg/L range, where lime precipitation is not effective. Subsequently, sulphate removal by sulphate reducing bacteria was also investigated and it was observed that reactor’s hydrodynamic conditions and the choice of substrate are important factors for the process. The different technical aspects of each technology are addressed.

Jan 1, 2014

By Q. H. Bui

The elastoplastic self-consistent model is one of the effective models to study the initial microstructure effect on the mechanical behavior of bulk materials. However, the use of this micromechanics-based model which takes into account only the Hall-Petch relationship at grain level for predicting the grain sized effects on the strength of the deformed materials is not accurate yet because of the fact that the dislocation density contributes also to the strengthening of this kind of materials. In this study, a modification made to the Hill-Hutchinson elastoplastic self-consistent model was proposed for investigating the microstructure dependence of the mechanical behavior of cold-drawn 6063 aluminium tubes. Because of the novel modification, an estimation procedure with two steps was required to identify the parameters of this micromechanical model. An acceptable agreement between experimental and theoretical stress-strain curves was achieved.

Jan 1, 2011

By G. Bonnivard

"A complete laboratory process for the treatment of lateritic ores containing a high proportion of iron, as well as chrome and alumina, has been established. The ores treated originate from the tropical zones and result from superficial climatic alteration. According to recent estimates, the known reserves of such ores reach many billions of tons, thus representing huge potential reserves for the elements they contain.The process used is based on the alkaline roasting of pelletized ore in the presence of sodium carbonate. This treatment results in the separate recovery of pellets of upgraded iron ore, pure chrome oxide and hydrated alumina. The research described in the paper aims at determining the best experimental conditions for obtaining the highest extraction of the required oxide from this type of ore."

Jan 1, 1967

By S Sokhanvaran

Electrodeposition of silicon from a cryolite based electrolyte at a relatively low temperature (1000°C) is a promising approach to generate high purity silicon. In order to obtain fundamental data pertaining to electrowinning of silicon from Cryolite?SiO2 melts, density and electrical conductivity measurements were made. A range of temperatures and SiO2 contents was studied for each property. It was found that while density has an inverse relationship with temperature, the dependence for electrical conductivity is direct. Increasing silica content up to the saturation limit (~ 5 wt%) increases the density whereas further increase in SiO2, lowers the melt density. On the other hand, the conductivity is lower for the melts with greater SiO2 content, at any temperature.

Jan 1, 2011

By D. B. Apel

As depths to the ore bodies keep increasing around the globe, the problem how to deal with the increasing temperature of undisturbed rock mass becomes very important. In extreme cases the rock temperature at the bottom of the mine could raise up to 80 °C. In deep mines, geothermal heat is considered as the primary heat load contributor, which accounts for 50?90% of the total heat load depending on different geological conditions. Thus the geothermal heat control in underground mines is the most important and demanding issue to ensure a suitable working environment. In this study, expanded perlite aggregate (EPA) was incorporated as a lightweight substitute for sand. Five mixtures were prepared using 0, 25, 50, 75 and 100% replacement ratios of sand by EPA. These, mixtures were tested in the laboratory for both the insulating and strength properties of the developed shotcrete. The goal of this research was not only to develop shotcrete which would exhibit good insulating properties but also which would exhibit strength properties similar to the regular shotcrete. This paper not only reports the results of the laboratory tests but also discusses the output of numerical model which was performed to evaluate the benefits of using the insulating shotcrete in reducing the cooling costs at hot underground mines.

Aug 1, 2013

By Y. Feng

Perovskite structured oxide 15% Y-doped BaCeO3 (BCY15) has been evaluated for use as proton conducting electrolyte in SOFC with propane as the fuel and Pt as both electrodes. Under the fuel cell conditions, BCY15 exhibited high proton conductivity and good cell performances. Propylene was detected as product at the anode outlet, and the product distribution suggests that propane dehydrogenation underwent competition with cracking to lighter hydrocarbons. Stability during cell performance tests showed that there was no obvious degradation for BCY15 electrolyte during operation of C3H8-O2 fuel cell.

Jan 1, 2005

By G. Zárate, G. Tapia

Anglo American Chile has been doing copper concentrate leaching studies at the laboratory and small pilot plant scale since 1992. Among the processes evaluated are bacterial leaching and pressure leaching using Mantos Blancos, Salobo Project and Quellaveco Project concentrates. Late in the nineties, it was decided to focus the research on pressure leaching, either medium or total pressure oxidation. Preliminary scouting tests were run with Mantos Blancos concentrate samples during 2000, which were repeated during 2003 together with samples of Los Bronces and El Soldado concentrates, in order to define the most suitable concentrate for running a pilot plant campaign at AARL, which was carried out in two campaigns, a first one from November 2003 through January 2004 and a second one during April 2004. Mantos Blancos was the selected concentrate and the laboratory and pilot plant results are discussed in this paper together with some preliminary economic estimates.

Jan 1, 2004

By Liu Liu

In the recent 10 years the rapid development of Chinese steel industry has attracted the attention of the world. The technological progress of converter steelmaking has played an important role in this process. First of all, slag splashing has been extensively adopted by Chinese steel companies in various sizes of converters from largest to smallest ones, and even including those using special hot metal containing V and Ti. Remarkable metallurgical results have been achieved. Up to now the average converter campaign life has reached nearly 10,000 heats, and the longest exceeds 30,000 heats in three melt shops. Based on this process, the long-life combined-blowing converter steelmaking technology has been developed. Slag splashing has been used to form a gas permeable "slag mushroom" on the top of bottom nozzles to protect the nozzles. In order to keep the effective bottom blowing, furnace bottom thickness control technique has been developed to prevent the furnace bottom growth. It makes the service life of bottom nozzle the same as the converter campaign life (average 10,000 heats and longest > 30,000 heats). The complete combined blowing was ensured through out the furnace campaign. Concentration product [C][0] is in the range of 0.0023 ~ 0.0030%, the T.Fe in the slag is lowered by 4 ~ 6%, and the [0] in steel is decreased by 100 ~ 250 ppm.

Jan 1, 2004

By J. Erik Scheel

Overview ? About Hard Creek Nickel ? Turnagain property ? Proposed power line ? Recent Preliminary Assessment ? Favourable economics ? Property Geology ? Mineralization and metallurgical characteristics of major lithologies ? Development of the acNi (ammonimum-citrate H2O2) technique ? Overview of necessary steps ? Results of the technique ? Conclusions

May 1, 2008

By C. G. Anderson

As the global demand for copper and gold steadily increases and the need for environmentally sound processing also grows, successful hydrometallurgical treatment of enargite (Cu3AsS4) concentrates has come to the forefront. This type of concentrate contains considerable arsenic so that successful arsenic fixation, for example as scorodite, is of the essence. This paper outlines the successful application of low temperature and low pressure nitrogen species catalyzed (NSC) hydrometallurgical pressure oxidation of enargite concentrates. The successful stabilization of the arsenic as an iron arsenate compound is discussed. Also, the use of experimental design software is highlighted as a process application and optimization tool.

Jan 1, 2006

CSIRO Minerals, in association with the AJ Parker CRC for Hydrometallurgy, has an active program of hydrometallurgical research in which physical and computational modelling are used to better understand and improve a range of different unit operations. The modelling is based on flow simulation (Computational Fluid Dynamics or CFD), but incorporates other physical and chemical phenomena of importance, such as droplet break-up and coalescence, species transport and reaction. This paper reviews some of the major projects that have been undertaken at CSIRO Minerals and will illustrate the critical importance of hydrodynamics to the performance of unit operations and the improvements that can be made to performance using such modelling techniques. Unit operations that are discussed include solvent-extraction, gravity thickeners, flotation cells, bio-heap leaching and stirred tanks.

Jan 1, 2005

By H. Craig Boyle, Craig H. B. Leitch

"The Trout Lake stockwork molybdenum deposit is located in the Selkirk Mountains of British Columbia, 50 km southeast of Revelstoke. The property is being explored by a joint venture between Newmont Exploration of Canada and Esso Minerals Canada.The deposit is associated with a small granodiorite stock of Upper Cretaceous age (76 Ma) which has variably altered the surrounding schists, argillites and marbles of the lower Paleozoic Lardeau Group to hornjelsic biotite schists and skarn. The intrusive is composed of a small stock and an intersecting network of northeast- and northwest-trending dykes at surface that coalesce downward into a larger stock. There are two main phases of intrusion, with an earlier quartz porphyritic granodiorite cut by an intra-mineral ""quartz diorite"" porphyry. A strong sub-vertical north-trending fault controls the distribution of the mineralized stock work and displays post-mineral movement.Molybdenite, accompanied by pyrite and pyrrhotite, is mainly present along the margins of veins in a well-developed quartz stock work, but occasionally is strongly disseminated in microfractured intrusives. The stock work is strongest in and around the contacts of the intrusive and its apophyses, and occurs over a vertical range of more than 1,000 m. As defined by the 0.10% MoS] contour, the main mineralized zone is up to 300 m long by 200m wide. Preliminary drill-indicated reserves, currently being revised, are approximately 50 million tonnes of 0.23% MoS2, within which are several zones of higher-grade material. Hydrothermal alteration, as defined by quantitative X-ray diffraction studies on composite core sections, is composed of a central quartz/K-feldspar/albite/minor biotite zone coincident with molybdenum mineralization, which is overlapped by a slightly later, antipathetic quartz/ sericite/pyrite zone. Ankeritic carbonate is also a common alteration mineral, but only traces of fluorite, and no topaz or sulfosalts, have been observed. Analysis for trace elements such as Sn, W, Bi, Sb, As, Hg, U, Ag, Au, Mn, Cu, Pb, Zn and F has been limited except for Sn and W, which appear to be zoned inside and outside the Mo zone respectively; the other elements do not show detectable patterns thus far."

Jan 1, 1983

By G. R. Parslow

U, Fe, Mn, Ni, Cu, Zn and Co data for the sediment in both Key and Seahorse lakes, which overlie portions of known economic uranium deposits in the region, are presented. With the exception of U, Fe and Mn, the elemental distributions can be considered anomalous, in a statistical sense, in both lakes. The U values are of particular interest in that Key Lake is not anomalous, whereas Seahorse Lake is markedly anomalous. Tentative correlations made with background data from other surveys in an attempt to differentiate between anomalous and background values indicate that deviations from linearity in a distribution, and not absolute mean or maximum values, are indicative of anomalous samples within the distribution.

Jan 1, 1979

By Scott Hommema

? Bitumen in the oil sand averages Bitumen 12 wt%; water makes up 4 wt% ? Imperial Oil (operator) and ExxonMobil developing Kearl Leases #6, 36, 87 (~200 sq. km) ? Target resource > 4 Billion Barrels ? 3 Phase development, ~100 kbd per phase High-quality resource ? Surface mineable bitumen ? Average properties (full lease) ? TV:BIP < 8 ? Grade > 12 wt% bitumen ? Ore thickness of 40 m ? Overburden thickness of 20 m Status ? Phase 1 ? Front end engineering and design underway ? Detailed engineering to start 2008

May 1, 2008

By G. Vibert Douglas

THE prospecter and geologist in the field, in the search for gold, are very often faced with a real difficulty. The: mineralized rock _frequently contains gold which is so finely divided or associated with sulphides that it is not recognizable in the gold pan. In recent years, the practice has been to take samples, send them to an assay office, and sit down and wait for results. This paper describes a method of solving the difficulty of proving the presence of this fine gold. The investigation is still in an experimental stage; but certain results have been obtained which would seem to justify publication. We do not consider that the method outlined is quantitative, but we believe that qualitative results are assured. The procedure has the great merit of simplicity. A sample of approximately two pounds of the mineralized rock should be taken and powdered as fine as is practicable. This powder is theo panned and the heavy minerals concentrated. Approximately two grams of these concentrates are taken for the test (one gram can be roughly gauged in the field by heaping up the powder on a Canadian twenty-five cent piece). The material is placed in a test-tube and 6 c.c. of a 10 per cent solution of iodine in alcohol are added (one-third of a test-tube full is approximately equal to 6 c.c.). Heat gently for about ten minutes over a spirit lamp, but without actual boiling. Allow to stand undisturbed until the sediment has settled to the bottom. Remove the clear iodine solution with an eye dropper. Allow it to fall, drop after drop, on a warmed pyrex watch-glass (the drops should be of equal size), taking care that the successive drops fall in the same place and that each drop evaporates before the next drop falls. Heat is applied to the lower side of the watch-glass by means of a spirit lamp. If gold is present in amounts of $2.00 or more per ton, a gold mirror will be formed on the watch-glass. This process of dropping and evaporating should be continued until no clear solution remains. If no mirror has appeared when all the solution has been used, another 6 c.c. of the iodine solution should be added to the powder and the process repeated. The absence of a mirror after the double treatment denotes an amount of gold less than two dollars per ton at the present price, or that the ore contains no gold. The mirror obtained must be washed with nitric acid ( 1: 1) to remove any copper, silver, lead, zinc, and iron. The yellow mirror remaining is pure gold.

Jan 1, 1937

By H. Arima, Y. Kudo

In general, the iron content of zinc leach residue produced by sulphuric acid leaching from calcine is disposed as jarosite or goethite into a tailing dam. More recently, these iron residues have been treated pyrometallurgically to avoid waste disposal. The Iijima refinery selected a different zinc leach residue treatment process for iron control when it was established in 1971. The Iijima refinery is the only plant in the world that has processed a zinc leach residue by the combination of SO2 pressure leaching and O2 pressure hematite precipitation. The process enhances zinc recovery and recovers gold, silver, copper, lead and rare metals in saleable by-products. This paper focuses on the two stages of autoclave application in the zinc leach residue treatment process. The detailed flowsheet and recent advancements to improve the quality of by-products are discussed.

Jan 1, 2004

By Adrian E. Scheidegger

"AbstractThe possibilities of deriving pertinent information about fractures in an oil pay from data obtained by core analysis are investigated. It is shown that it is possible to obtain an estimate of the fractured area per unit volume of the pay, and that the size of the fractures can be estimated if their shape is known. A suggestion of a routine procedure for the analysis of fractures is given.1.-IntroductionMany oil fields are producing essentially from cracks or fractures. Where this is the case, it is important to be able to obtain a knowledge of the size and distribution of those fractures in the oil pay. This knowledge has to be derived from the analysis of cores taken from the fields, as it is generally impossible to follow a fracture through the pay by direct means. The necessity of using statistical methods to extrapolate the meagre information obtained from the cores of the wells is therefore indicated.It is known that the fractures are much bigger than the diameter of the cores; thus, if they strike a core, the latter will generally fall into two pieces. The angle of the fracture with the vertical can be measured and, if oriented cores are taken, the exact position of the surface element representing the intersection of the fracture with the drill stem can be determined. Sometimes the edge of a fracture can be seen in a core. The number of •Cores that show such an edge can be noted. Of course, one has to be careful to distinguish between original fractures in the pay and fractures in the core caused by drilling operations. Only the former are relevant."

Jan 1, 1955