Search Documents

By A. Staley, W. J. Cashwell, M. S. Moats

In the 1990’s, Técnicas Reunidas developed the Modified ZINCEX® Process to recover zinc from ores and secondary materials. The heart of this process was the use of solvent extraction to produce purified zinc electrolyte instead of traditional zinc dust cementation. This development was commercialized by Reunion Mining and Anglo American for primary ore at the Skorpion mine in Namibia with the first SHG zinc produced in May 2003. Horsehead Corporation through Horsehead Metal Products, Inc., its wholly owned subsidiary, is presently commercializing the MZP for the treatment of Waelz oxide. This paper will review open source information about the lessons learned and process modifications that have occurred at Skorpion over the past decade. It will also provide an update on Horsehead’s facility being constructed in Rutherford County, North Carolina.

Jan 1, 2014

By E. Dernedde

A few studies have suggested that the rate of adsorption of hydrogen fluoride on smelter grade alumina is determined by kinetic factors. However, no performance equation for dry scrubbers has appeared in the literature so far. Experimental data from a pilot dry scrubber with co-current flow were compared with results of kinetic models of adsorption, film diffusion and pore diffusion. The pore diffusion model was deemed the most appropriate. It was transformed into a performance equation for steady-state operations of dry scrubbers by the inclusion of the alumina recirculation. Operating results of industrial dry scrubbers with co-current flow were successfully evaluated by means of the performance equation. The average fluoride content of the alumina was also estimated by using the pore diffusion model.

Jan 1, 2011

By A. J. Basu

Air quality in underground mining operations can fluctuate significantly during the working day, but until recently the only way to ensure a mine had sufficient air quality was to over-ventilate and, with significant delay in adjusting the volume or direction of the airflow, working conditions were tolerable but rarely ideal. Underground ventilation management systems have been considered to achieve improved energy efficiency since at least 1995 in Canada. However, Mine Ventilation Optimization, (MVO) and integrating it with Ventilation on Demand (VOD) is only becoming more of a reality in the last seven (7) years. A systems approach to MVO takes into account all the elements from the point the power is distributed into the ventilation fans through to the actual quality and quantity of fresh air to the working face. Opportunities exist throughout the system for energy savings but not all of them are cost-effective. Depending on the application, these opportunities can be easily realized by properly sizing, streamlining, maintaining and operating the ventilation system using premium mine proven energy efficient components throughout. Implementation of VOD is a key step in achieving the MVO objective. However, VOD is a concept, and it requires various tools, procedures, and strategies for cost-effective and operationally viable implementations. This paper provides a historical background in the development of VOD and provides a framework for proper and cost effective implementation. In addition, an optimized ventilation system will also allow increased airflow by reducing resistances and shock losses. This turn in would allow production target improvement, which could be an attractive objective compared to energy savings. Mine ventilation is the life support system of an underground mine, and contributes to sustainable development and corporate social responsibility goals assuring health and safety aspects of strategic planning. The proposed framework addresses implementing mine ventilation optimization integrating ventilation on demand as a vehicle for energy, health and safety improvement and overall productivity gains in the mining cycle efficiency while significantly reducing carbon footprint of a mine.

Aug 1, 2013

By G. A. McGuffin

"IntroductionWITH the increase in quantity of sour gas reserves in the Province of Alberta, and the wider market for sulphur brought about by mounting world demand and restrictions placed on the principal supply, it was inevitable that this important source of sulphur would be .developed. In the light of these facts, it seems timely that a general paper on sulphur recovery from petroleum gases be presented. This, then, is the purpose of the following text. A short discussion of each of the following subjects is presented:(1) Properties and uses of sulphur(2) Existing sources(3) Market research(4) The recovery process in Turner Valley(5) Hazards of sulphur productionNo pretext of originality of material is made since innumerable reports have been prepared on this and related topics and information contained in these has been used quite liberally.Properties and uses of SulphurSulphur is a non-metallic element having an atomic weight of 32.06. The stable crystalline form at atmospheric temperature is referred to as 'rhombic' sulphur. It is bright yellow and has a specific gravity of 2.05, equivalent to 129.2 lb./cu. Ft. Above 204°F. sulphur has another stable crystalline form, referred to as 'monoclinic'. This is reddish-brown and is slightly less dense than the rhombic variety (122.4 lb./cu. Ft.). Sulphur in bulk form weighs 84 to 90 lb. per cu. Ft. Sulphur melts at approximately 240°F. to a straw coloured liquid which is quite viscous."

Jan 1, 1952

By F. K. McKean

THE task of establishing a new corrosion testing laboratory is more difficult than it need be because there is very little information on the subject available in the literature. Many articles describing tests and results may be found, but a wide search will unearth only passing remarks on the different types of equipment that may be selected for accelerated corrosion tests. An article describing some of the apparatus needed in a corrosion laboratory should be of help to those interested in building a new unit or in making additions to an old one. In May of this year, the writer was given the assignment of equipping a laboratory for general corrosion testing, to form a part of the new Physical Metallurgy Research Laboratories of the Department of Mines and Resource~ at Ottawa. With the help of senior members of the staff, along with what could be gathered from other sources, a list of necessary equipment was compiled and a plan for arranging it in the rooms was decided upon. Where possible, the apparatus was constructed in the excellent machine shops at the disposal of this Department, while the rest was placed on order with the manufacturers.

Jan 1, 1945

By Malcolm Black

Introduction Before beginning to write this paper, I decided that I should first find suitable definitions of the words Sample and Sampling. The dictionary gives: "Sample.-A portion indicative of the whole"; and according to Baillie (1), sampling is "That process whereby a representative and comparatively small portion of material is selected from a large bulk, and preserved under such conditions as shall prevent contamination or avoidable alteration, with a view to the formation of valid conclusions regarding the suitability of the bulk for specified purposes". These comprehensive definitions are alike in substance, and indicate that unless a truly representative portion is taken, it is not a sample. Ore 'as mined' generally varies a good deal in composition, and, in crushing, segregation takes place. Some of the minerals present, due to differences in hardness and friability, break into smaller pieces than others, and, on reaching the bin, the coarse particles roll away, leaving the fines behind. The result of this segregation is generally quite noticeable on the conveyor feeding the mill, especially when the bin is nearly empty and the crushing plant shut down. Should the sampling period synchronize with either the coarse or the fines, the sample obviously would not be representative. I agree that this is rather far fetched, but I maintain that such a condition is possible. Assuming that a representative sample may be procured from the feed conveyor, the method of cutting it down for assay has considerable influence in maintaining the original condition of the sample. The finer the material is ground after each cut, the more uniform the sample will remain. To illustrate this point, let us take a quantity of fine sand and add, say, three grains of rice to represent metallic particles. We may mix this sample by any of the known methods, then cut it into four equal portions. It is obvious that at least one of the portions will be without a rice grain. But let us grind the three grains of rice into flour and proceed as before. Now there will be a much greater chance of including some of the rice in each portion.

Jan 1, 1935

By T. A. Chepushtanova, I. U. Motovilov, V. A. Luganov, G. D. Guseynova

"Kazakhstan has significant reserves of oxidized nickel ore with low nickel content. Processing of such ores is effective via pyrometallurgical technologies such as smelting to ferronickel or matte with consecutive extraction of metals from melting products. There are also many options for direct hydrometallurgical processing. However, they do not provide high nickel recovery.We studied extraction of nickel and cobalt by using combined technology of low-grade ore processing from the Shevchenko Kazakhstan deposit, which includes smelting to poor matte followed by hydrometallurgical processing of the matte. The nickel content in the initial ore was 0.75–0.9%. Pyrite concentrate of Sokolov-Sarybai Kazakhstan deposit containing 0.17% cobalt and 0.06% nickel had been used as a sulphidizer at smelting.As a result of the study, we were able to extract up to 98% of the nickel and up to 80% of the available cobalt. Obtained matte contained 3.1% nickel, 0.29% cobalt, 71.6% iron and 24.3% sulfur. Matte leaching was carried out by hydrochloric acid. The iron content in the pregnant solution was 170–185 g/dm3. Nickel and cobalt precipitation from the pregnant solution was carried out by hydrogen sulfide. Initial matte or cast iron was used as neutralizers during the process. Practically complete precipitation of nickel was achieved at 3–5% excess of neutralizer at 333–343°K in 4 hours; up to 95% of cobalt precipitation was achieved in 50% excess of neutralizer at 363°K in 8 hours. The purified solution contained 200–600 mg/dm3 of nickel, 80-100 mg/dm3of cobalt and 175–185 g/dm3 of iron. The purified solution allows to obtain iron oxides by high-temperature hydrolysis, and to regenerate hydrochloric acid.As a result of non-ferrous metals precipitation we obtained sulfide concentrate with concentration of Ni up to 25% and concentration of Co up to 5.5%. The technology is recommended for semi-industrial testing."

Jan 1, 2016

By Horace Freeman

The sulphur consumed in Canadian pulp mills and acid plants is worth approximately three million dollars annually and amounts to one hundred and fifty thousand long tons, all of which is imported from the United States. Concurrently with a decline in the value of newsprint there has been a gradual increase in the price of this raw material. Most pulp mills in Canada are situated within reasonable distance of domestic pyrite deposits; nevertheless it has not yet been found possible to mine these deposits and utilize the contained sulphur in competition with the imported material. It is the purpose of this paper to elucidate the reasons therefor, and to describe? a commercial-scale experiment undertaken with the object of introducing a native raw material into the Canadian pulp industry on the purely economic basis. Reasons for the Preferred use of Sulphur The known sulphur deposits in the United States are very large, so that at least a twenty-year supply of this material is assured. It is recovered cheaply and in pure condition. Although large deposits of pyrite are known in Canada, nothing has yet been developed to compare in size, cost of mining, or purity with the United States material. It has been necessary to handle and transport more than two tons of pyrite to equal a ton of sulphur.

Jan 1, 1930

By E. Dernedde

Cell rooms of aluminium smelters have large openings in the sidewalls and in the roof. These openings provide a high ventilation rate, which removes heat and contaminants emitted by the reduction cells and thereby ensures acceptable working conditions inside the cell room. However the large openings make the airflows through the smelter building sensitive to the wind. In this study equations for the airflow through the openings of a smelter building exposed to crosswinds were developed and verified against plant measurements. The equations were then used to estimate the airflows through a two-storeyed smelter building containing VS Soderberg cells. Wind protection by wind-covers over the sidewall openings and by upwind buildings made the airflows through the building less sensitive to the wind. Physical and mathematical modelling showed that working conditions inside the wind-protected cell room would be acceptable for crosswinds at speeds up to 16 km/h. These predictions were confirmed by measurements taken in a VS Soderberg smelter.

Jan 1, 2007

By G. V. Sirianni, G. E. Viens, R. A. Campbell, G. N. Banks

A combination shaft-electric furnace for the smelting of ores and the melting of metallized feed is being developed at the Mines Branch. When iron oxide pellets are smelted in this unit, they are preheated and partially reduced in the shaft before being transferred to the electric furnace where smelting is completed. Also, limestone flux added with the pellets is-preheated and calcined in the shaft. It has been demonstrated that, in smelting iron oxide in this unit, the throughput of the 250-kva electric furnace can be approximately doubled and the amount of electrical energy required can be very significantly reduced when the shaft furnace is operated in conjunction with the electric furnace. These benefits are achieved mainly by utilizing the sensible heat and latent energy contained in the arc furnace off-gases.

Jan 1, 1971

By E. Godfrey

The average man one meets on the street thinks of an explosive as a medium of death and destruction, something unstable which should be given a wide berth, because he knows little or nothing about its use or its stability. Briefly, explosives are compounds that develop very large quantities of heat and gas in an extremely short time and in a small space, thereby exerting enormous pressure upon surrounding bodies, and by the rapid expansion of this highly heated gas are able to perform a considerable amount of useful work. The amount of heat generated and the volume of gas produced by the decomposition of an explosive determines the amount of mechanical work it can do, and the time occupied by its change from solid or liquid condition to gaseous condition determines its shattering effect. Explosives manufactured by reputable people are not extremely dangerous, on the other hand they are quite safe if handled in a proper manner. Furthermore, before an explosive can be placed on the Canadian market a sample must be submitted to the Explosives Division of the Mines Department, who may condemn or permit its manufacture, according to their findings regarding its safety in handling and its stability during storage.

Jan 1, 1926

By S. Kelebek, E. Yalcin

This paper reports bulk flotation characteristics of a pyritic gold ore sample from the Barry District, Quebec using isopropyl and amyl xanthates. The ore sample was highly floatable with particles showing tendencies for self-aggregation that was most apparent in the first stage of flotation. A possible reason for this is discussed. The gold concentrate grade-recovery performance with respect to the particle size is presented for the rougher-scavengers as well as for the cleaners. The effects of copper sulphate as an activator, fuel oil and NaSH as a sulphidising agent are discussed along with the recovery by size behaviour.

Jan 1, 2011

By M. Mezbahul-Islam

Thermodynamic modeling of the Mg-Cu-Ni system is carried out as a part of multi component thermodynamic database for Mg alloys. This system is being modeled for the first time using the modified quasichemical model, which considers the presence of short range ordering in the liquid. The thermodynamic descriptions of the binaries Mg-Cu, Cu-Ni and Mg-Ni have been extrapolated to the ternary Mg-Cu-Ni system using Toop geometric model. The constructed database has been used to calculate and predict thermodynamic properties, isothermal sections and liquidus projections of the Mg¬Cu-Ni system, which showed very good consistency with the experimental data.

Jan 1, 2011

By N. Dobrin, R. Sheinman, Y. V. Kokotov, L. N. Braginsky

Increasing the production of a Mixer-Settler unit requires either increasing flow rates or increasing extractant concentration. The mixers still have to ensure complete emulsification and to maintain high values of specific interface surface area in order to provide a high rate of mass transfer. Theoretically, an increase in mixing intensity can support increased flow rates without reducing extraction efficiency. Unfortunately, conventional pump mixers and mixing systems create small droplets that do not separate easily. As pumping action and mixing intensities are increased, the quantity of small droplets increases. We describe the development and industrial application of a novel mixing system for efficient mass transfer without forming significant quantities of small droplets, targeting both high mass transfer rate and low entrainment values.

Jan 1, 2014

By A. G. Pathan

Rock and soil mechanics investigations were carried out in block VIII at Thar Coalfield, Pakistan. Most of the strata were mainly composed of sand, with an average content of 67.68 %. Laboratory studies of rock and soil samples from drill hole GT-01 revealed that the strata in block VIII are very weak with an average uniaxial compressive strength of 3.59 MPa, an average tensile strength of 0.68 MPa, an average Young?s Modulus value of 0.234 GPa, an average cohesion of 129.19 KPa, and an average friction angle of 55.47°. Slope stability analysis, based on a probabilistic approach, was carried out using Slide-V software. Monte Carlo simulations have been applied to investigate the probability of failure in the slopes of an open pit lignite mine in block-VIII. From the slope stability investigation, it was found that the probability of failure is 0 % at a slope angle of 16°.

Aug 1, 2013

By S. D. Tolgyesi

Kidd Creek Background ? Located in Northern Ontario, Canada ? Underground base metal mine ? Operating since 1966 ? Total of 125Mt mined to date (2.43% Cu, 6.60% Zn) ? Current plan at 2.4Mt/Y (6575t/D) Current Practices ? Evaluating stope margins to ensure that value is added ? Scheduling sulphide and Cu stringer ore to limit oxidation in passes ? Scheduling to maintain uniform grades to concentrator ? (SOPs highlight problem stopes on mine plans, and limit blast sizes in those stopes which may contain sulphides prone to oxidation) ? Scheduling high-Pb stopes to avoid spikes to concentrator ? Providing weekly, monthly and long-term forecasts ? Reconciling mine and mill production ? Underground grade and dilution estimates by mine supervision ? Terminate mucking when grade becomes sub-economic ? Laser cavity surveys to provide feedback and improve Designs Cut-off Grades ? Ore value is obtained from copper, zinc and silver ? Ore outlines at 2% copper equivalent used to guide stope planning; sulphide outlines obtained from contacts while copper stringer outlines drawn from block model (kriged) ? Datamine block model and CADD software used to evaluate alternative stope shapes ? Stopes classified as waste, incremental, or full-cost based on margin calculations for each stope ? Incremental ore may be mined if it does not displace fullcost Ore Conclusions ? Grade control remains an important function for optimizing the ore extraction at Kidd ? The scope of the function has changed to a scheduling focus ? A change in grade control practices over time has not led to significant changes in concentrator feed ? The lead and iron sulphide content of the ore display upwards trends and may require more attention in the future ? The key function of field observations has shifted to flagging exceptions and terminate mucking at grade cut-off

May 1, 2003

By Dave M. Jakelski, Gerhard W. Heinrich, Peter F. Wells, Daniel F. Suarez, Jamie B. Beauchamp

"A need for increased copper concentrate production and for less nickel contamination in that concentrate at Falconbridge's Strathcona Concentrator during 1993 required the installation of a third flotation column and improvements in the operation of the existing circuit. Innovations in wash water distributor and launder design were fundamental in achieving objectives on a new 3 meter diameter column. Minnovex plug-type spargers were tested on a 2.1 meter diameter column in order to reduce maintenance requirements. The paper details the measures taken to enhance column flotation circuit performance and the results obtained.IntroductionFalconbridge's Strathcona Mill receives 10% of the ore feed from a rich copper zone in the Strathcona mine. This ore typically grades 7% copper and 1 % nickel and, because of its high copper content, it is processed in a separate circuit ('C' circuit) which consists of conventional grinding, rougher flotation with the concentrate being treated with lime to pH 12.3 and cyanide followed by column flotation. The columns are operated with mechanical flotation scavengers and the scavenger concentrate is returned to the column feed. Testwork conducted in 1991 showed that the original flotation column (Column 2) could only produce 5.5 mtph of concentrate with less than 0.5% nickel (Figure 1).Between 1991 and spring of 1993, production was increased at times by open circuiting the scavengers. Metallurgical improvements were obtained by improving the wash water distributor of Column 2 and by wash water sprays in conventional cells (1 ). However, the scavenger concentrate assayed 0. 7 -0.8% nickel and was not acceptable for long term operation. When Copper ore production targets were significantly increased for 1993, it became clear that an additional flotation column was required. The new flowsheet employs mechanical scavenger cells on the column tails as in Column 2 circuit (Figure 2). A -parallel configuration was chosen as pulp solids fraction has been shown to be a critical variable and the second column in series would receive a lower density feed."

Jan 1, 1994

By S. F. Guo, B. W. Zheng, X. L. Huang, S. W. Qi

"The study of mechanical characteristics of rock discontinuities under different shear deformation velocities is an important premise of rock slope dynamic response analysis. According to disposing and calculating the experimental results of previous research about peak shear strength of rock discontinuities under different shear deformation velocity of constant normal loading, the law of influence of shear velocity on the total friction angle is studied. Based on the research results, it can be found that the total friction angle of rock joint specimens varies in the form of negative logarithm with the variation of shear deformation velocity. It’s also indicated that the total friction angle of rock joints decreases with the increase of shear deformation velocity for rock joints of relative strong homogeneity and isotropy. However, the total friction angle of rock joints increases with the increase of shear deformation velocity for rock joints of relative strong heterogeneity and anisotropy and the latter amplitude of increase is less than the former amplitude of decrease. The physical property and microscopic geometry of rock joints play an important effect on the increase or decrease tendency and amplitude variation of total friction angle with the increase of shear deformation velocity.INTRODUCTIONThe rock slope dynamic response is largely restricted by rock discontinuities. Hence the study of dynamic characteristics of rock discontinuities, especially the dynamic shear characteristics is an important premise of rock slope dynamic response analysis (Qi et al., 2007). Seismic load is both dynamic load and cyclic load (Liu et al., 2011). Under the dynamic and cyclic shearing actions of seismic load, the rock slope which is stable under the condition of static load may slide along the rock discontinuities whose shear strength reduce and then the earthquake landslides occur. The strength degradation and deformation mechanism of rock discontinuities under the dynamic and cyclic shearing actions is one of the key problems to be solved in the work of earthquake prevention and control of engineering slope. Based on the above understanding, predecessors conduct some researches which focus on the shear behavior mechanical characteristics of rock joints under cyclic shearing actions (Plesha, 1987; Hutson & Dowding, 1990; Jing et al., 1992, 1993; Huang et al., 1993; Qiu et al., 1993; Homand et al., 2001; Lee et al., 2001; Jafari et al., 2003; Liu et al., 2011, 2013). However, there are a few researches about the mechanical characteristics of rock joints under different shear deformation velocities because of the restriction of shear apparatus. Crawford and Curran (1981) conducted a series of one-way cyclic direct shear tests on four kinds of natural rock joints under different shear deformation velocities varying from 0 to 200 mm/s. The tests showed that at low normal stresses the peak shear strength of soft rock joints exhibited an increase up to a certain velocity, after which it remained essentially constant. For rock joints of intermediate hardness, the peak shear strength was essentially independent of shear deformation velocity; whereas for hard rock joints, the peak shear strength of which showed a significant variation with the shear deformation velocity. Jafari et al. (2003) carried out a series of conventional triaxial tests on artificial rock joints of regular saw-tooth shape with axial loading rate from 0.05 mm/s to 0.4 mm/s."

Jan 1, 2015

By H. A. Wentworth

The Central Manitoba mining district, as spoken of in Manitoba, refers to that portion of the country lying between lake Winnipeg on the west and the Ontario boundary on the east, and from a few miles north of the Wanipigow (or Hole) river on the north, to a few miles south of the Bird river. It embraces two known mineralized belts; the gold area in the north, extending from the shores of lake Winnipeg almost to the Ontario boundary (in a slightly southeasterly direction) a zone some eight or ten miles wide and perhaps forty miles long, lying (for the most part) north, and parallel to, the Manigotagan river; and the Bird river copper and coppernickel deposits, an area not yet clearly defined, but in general lying immediately north of, and roughly parallel to, the Bird river. To the south of the Bird river is a somewhat differently mineralized area, numerous pegmatite dykes being found, with minerals typically associated with such rocks. More specifically, the known gold deposits are largely segregated in the above belt; (1) around English brook; (2) along the north shore of Wanipigow lake; the Rice lake area (about midway of the belt); and the Long Lake-Bulldog lake area, at the eastern end of the belt. Not all the known gold occurences are found in these segregations, but the density of claim staking in these areas is perhaps an indication of the greater number of prospects found in them to date.

Jan 1, 1925

By A. E. McIlhinney, I. E. Puddington, C. E. Capes, A. F. Sirianni

"Two main problems are associated with the removal of pyritic sulphur from coals. The first is due to the fine state of dissemination of pyrite, which requires grindin1 to a very fine size to accomplish liberation. The second problem is caused by the similar surface chemical characteristics of coal and pyrite, which complicates separatio11 methods based on this property. In the work described here, the problem of fine particle size was overcome by using the selective oil agglomeratioa method developed at the National Research Council of Canada. Recovery of more than 90% of the combustible values was possible, even with particles only a few microns in diameter. Experiments using conventional chemical depressants for pyrite met with little success. It was found, however, that pyrite may be rejected during coal agglomeration through treatment with the iron.oxidizing bacteria, thiobacillus-ferrooxidans. The conditions for maximum pyrite separation are described and possible mechanisms by which the bacteria act are discussed."

Jan 1, 1973